• The Journal of the Petrological Society of Korea
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• v.13 no.2
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• pp.47-63
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• 2004

This study focuses on the petrography and petrochemical characteristics of the volcanic and plutonic rocks in Gadeog island, Busan, Korea. Based on textural and mineralogical characteristics, intermediate volcanic rocks can be divided into andesitic lava flows (porphyritic and massive andesites) and andesitic pyroclastics. Felsic volcanic rocks are composed of rhyolite, rhyolitic welded tuff, and tuff breccia. Plutonic rocks are intruded rhyolite and andesitic rocks, and composed of hornblende granodiorite which contains lots of mafic magma enclaves. Volcanic rocks are composed of andesite, dacite and rhyolite having a range in SiO$_2$ from 59 to 78wt.%. The volcanic rocks belong to the calc-alkaline rock series. Plutonic rocks have a range in SiO$_2$ from 63 to 69wt.%. This compositional variations correspond to those of Cretaceous volcanic and plutonic rocks in the southeastern Gyeongsang basin. The trace element composition and rare earth element patterns of the volcanics, which are characterized by high LREE/HFSE ratios and enrichment in LREE, suggest that they are typical of calc-alkaline volcanic rocks produced in the subduction environment around continental arc. We concluded that volcanic and plutonic rocks in Gadeog Island were evolved from orogenic andesitic magma which was produced by partial melting of the mantle wedge in the subduction environment.

• Journal of the Korean Institute of Gas
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• v.25 no.5
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• pp.30-36
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• 2021

Residual life assessment of reformer tubes of mod HP steel used in the refinery and petrochemical industry were investigated by quantitative metallographic evaluation method. Area fractions of precipitated carbides were measured by using surface replication and its relationship with the remaining life of the tube was investigated. The microstructures of the virgin and other tubes were examined using optical microscopy (OM) for service periods of 1.8, 6.0, 7.2, 8.5, 9.7, and 16.2 years at 950 ℃ and the area fractions of the precipitates were measured by image analysis using ImageJ software. As the area fraction of the precipitates increased, the residual life was decreased accordingly. The results showed that the LMP was the highest in the virgin and the LMP decreased as the service time increased and the residual life decreased. A regressional equation showing the relation between the area fraction of carbides and LMP was experimentally derived. The obtained relationship can be used with the surface replication method for on-site residual life assessment.

• Journal of the Korean Society of Marine Environment & Safety
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• v.23 no.7
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• pp.810-819
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• 2017

The purpose of this study is to evaluate port use and the distribution of risk factors in 15 major ports in Korea, delineating the risk of each port after classifying the ports into four risk groups based on estimated risks. The placement of response vessels is then analyzed accordingly. Based on the results, danger was estimated to be especially high in ports where large-scale petrochemical facilities are located, such as Yeosu Gwangyang ports (1.85), Ulsan port (1.33) and Daesan port (1.25). The ports showing the next highest degree of danger were Pusan (0.95) and Incheon (0.83), which have significant vessel traffic, followed by Mokpo (0.71) and Jeju (0.49), which expanded their port facilities recently and saw an increase in large vessel traffic. Next is Masan (0.44), for which many fishing permits in the vicinity. When the relative ratios of each port were graded based on the Yeosu Gwangyang Ports, which showed the highest risk values, and risk groups were classified into four levels, the highest risk groups were Yeosu Gwangyang, Ulsan, Daesan and Pusan, with Incheon, Mokpo, Jeju, and Masan following. Pyeongtaek Dangjin, Pohang, Gunsan, and Donghae Mukho were in the mid-range danger group, and the low risk groups were Samcheonpo, Okgye, and Changsungpo. Among these, all response vessel placement ports specified by current law were above the mid-range risk groups. However, we can see that ports newly included in mid-range risk group, such as Mokpo, Jeju, and Donghae Mukho, were excluded from the pollution response vessel placement system. Therefore, to prepare for marine pollution accidents these three ports should be designated as additional response vessel placement ports.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.7
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• pp.599-606
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• 2019

Most facilities that manufacture products made from the hazardous materials operate at high temperatures and pressures. Therefore, there is a risk of fire explosion. In particular, an explosion accident is a major risk factor for facilities with hazardous materials, such as oil, chemical, and gas. Propylene is often used in sites producing basic raw materials and synthetic materials by addition polymerization at petrochemical plants. To prevent an explosion in the business using propylene, the explosion range with the oxygen concentration was calculated according to the changes in temperature and pressure using an inert gas, carbon dioxide. In these measurements, the temperature was $25^{\circ}C$, $100^{\circ}C$, and $200^{\circ}C$ and the amount of carbon dioxide in the container was $1.0kgf/cm^2.G$, $1.5kgf/cm^2.G$, $2.0kgf/cm^2.G$, and $2.5kgf/cm^2.G$. The explosion limit was related to temperature, pressure, and oxygen concentration. The minimum oxygen concentration for an explosion decreased with increasing temperature and pressure. The range of explosion narrowed with decreasing oxygen concentration. In addition, no explosion occurred at concentrations below the minimum oxygen concentration, even with steam and an ignition source of propylene.

• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.1
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• pp.97-112
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• 2021

This study introduces lessons learned from investigation and analysis of major domestic and overseas cases of marine chemical incidents involving hazardous and noxious substances (HNS) during maritime transportation by chemical tankers carrying petrochemical products in bulk. The study then suggests plans to improve domestic marine HNS training curricula based on these lessons. Lessons learned from six incident cases are classified into the following six categories: 1) incident-related information, 2) safety, 3) pollution, 4) response, 5) salvage and 6) others. Based on these six categories, it is suggested that the curriculum provided by the Marine Environment Research & Training Institute for marine pollution prevention managers aboard noxious liquid substance carriers should be changed from the existing two-day training of eight subjects (16 h) to a three-day training of sixteen subjects (24 h). In addition, it is proposed that the marine chemical incident response course of the Korea Coast Guard Academy should be changed from the existing five-day training of fifteen subjects (35 h) to a six-day training of thirty-two subjects (48 h). These results are expected to contribute to sharing experiences and lessons learned about response to marine chemical incidents and to be used as basic data for improving the education and training courses for response personnel in preparedness for marine HNS incidents.

• Membrane Journal
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• v.32 no.4
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• pp.218-226
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• 2022

Hydrogen, a carrier of large-capacity chemical and clean energy, is an important industrial gas widely used in the petrochemical industry and fuel cells. In particular, hydrogen is mainly produced from fossil fuels through steam reforming and gasification, and carbon dioxide is generated as a by-product. Therefore, in order to obtain high-purity hydrogen, carbon dioxide should be removed. This review focused on free-standing polymeric membranes and mixed-matrix membranes (MMMs) that separate hydrogen from carbon dioxide reported in units of Barrer [1 Barrer = 10^-10 cm³ (STP) × cm / (cm² × s × cmHg)]. By analyzing various recently reported papers, the structure, morphology, interaction, and preparation method of the membranes are discussed, and the structure-property relationship is understood to help find better membrane materials in the future. Robeson's upper bound limits for hydrogen/carbon dioxide separation were presented through reviewing the performance and characteristics of various separation membranes, and various MMMs that improve separation properties using technologies such as crosslinking, blending and heat treatment were discussed.

• Journal of Environmental Health Sciences
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• v.49 no.4
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• pp.190-200
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• 2023

Background: Gunsan has been constantly affected by pollutants generated by the Saemangeum development and the construction industry since the completion of the Saemangeum seawall on April 27, 2010. However, there are limitations to its study, such as taking into consideration weather conditions, geographical factors, and foreign inflows. Objectives: In this study, we compared the Existing-CAPSS emissions of Gunsan with Recalculated-CAPSS emissions data to analyze the differences in emissions characteristics by year (2016~2019). Methods: Using Existing data on CAPSS emissions (2016~2019) and Recalculated-CAPSS emissions (2016~2019) for Gunsan, which were Recalculated following the improvement of emissions calculations for 2020, we organized CO, NO_X, SO_X, PM₁₀, VOC_S, and NH₃ emissions by substance and investigated the differences and characteristics of the Recalculated emissions by year. Results: For Re-CO and Re-PM₁₀, the emission characteristics of CO were examined as energy industry combustion and PM₁₀ emission characteristics were examined as ship cargo from non-road transportation sources, as ship leisure sources were excluded from non-road transportation source emissions. Conclusions: Comparing the emissions of Existing-CAPSS and Recalculated-CAPSS in Gunsan, the emissions of Recalculated-CAPSS by substance decreased by 39.76% for CO, 9.98% for PM₁₀, 5.53% for VOC_S, and 9.24% for NH₃, while Re-NO_X increased by 2.86% and Re-SO_X increased by 1.97%. On the other hand, when comparing the emissions characteristics of Existing-CAPSS and Recalculated-CAPSS in Gunsan, Jeonju, and Iksan, the emission characteristics of Re-NO_X, Re-SO_X, Re-VOC_S and Re-NH₃ were similar to those of Ex-NO_X, Ex-SO_X, Ex-VOC_S, and Ex-NH₃. As such, Gunsan, Iksan, and Jeonju, showed differences in the comparison of different emission characteristics due to the geographical characteristics of the region (population, area, topography, weather factors) and the characteristics of the industrial complex (metal, petrochemical).

• Clean Technology
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• v.15 no.1
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• pp.54-59
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• 2009

In this study, the separation of water/bitumen emulsion was investigated by chemical demulsification method. Motor oils (GS Caltex Deluxe Gold V 7.5W/30, Hyundai gear oil 85W/140) and asphalt (AP-5, KS M 2201, Dongnam Petrochemical MFG. Co.) were used as model oils in the preliminary experiments to effectively remove water from water/bitumen emulsion. The bitumen extracted from Canadian oilsands was used in this study. The water/oil emulsion was not separated without demulsifiers, and Hyundai motor oil showed higher efficiency of water separation at a low concentration of demulsifier compared with that for GS Caltex motor oil. However, as the concentration increased, the efficiency did not rapidly increase compared with that of GS Caltex motor oil. It was highly speculated that the water phase of Hyundai motor oil was not dispersed well compared with that of GS Caltex motor oil because the viscosity of Hyundai motor oil was much higher than that of GS Caltex motor oil. The demulsifier of higher HLB (hydrophilic - lipophilic balance) value had high separation efficiencies in water/oil emulsion. The TWEEN 20 (polyoxyethylene sorbitan monolaurate solution) showed better separation efficiency than other demulsifiers.

• Journal of Industrial Convergence
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• v.21 no.5
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• pp.1-13
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• 2023

Carbon neutrality is the concept of reducing greenhouse gases emitted by human activities and making actual emissions zero through removal of remaining gases. It is also called "Net-Zero" and "carbon zero". Korea has declared a "2050 Carbon Neutrality policy" to cope with the climate change crisis. Various carbon reduction legislative processes are underway. Since carbon neutrality requires changes in industrial technology, it is important to prepare a system for carbon zero. This paper aims to understand the status and trends of global carbon neutrality technology. Therefore, ROK's web platform "www.naver.com." was selected as the data collection scope. Korean online articles related to carbon neutrality were collected. Carbon neutrality technology trends were analyzed by future signal methodology and Word2Vec algorithm which is a neural network deep learning technology. As a result, technology advancement in the steel and petrochemical sectors, which are carbon over-release industries, was required. Investment feasibility in the electric vehicle sector and technology advancement were on the rise. It seems that the government's support for carbon neutrality and the creation of global technology infrastructure should be supported. In addition, it is urgent to cultivate human resources, and possible to confirm the need to prepare support policies for carbon neutrality.

• Journal of Navigation and Port Research
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• v.47 no.3
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• pp.167-173
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• 2023

The manufacturing industry is the backbone of the Korean economy. Among them, the petrochemical industry is a strategic growth industry, which makes a profit through reexports based on eminent technology in South Korea which imports all of its crude oil. South Korea imports whole amount of crude oil, which is the raw material for many manufacturing industries, by sea transportation. Therefore, it must respond swiftly to a highly volatile tanker freight market. This study aimed to make an early warning model of crude oil shipping market using a signal approach. The crisis of crude oil shipping market is defined by BDTI. The overall leading index is made of 38 factors from macro economy, financial data, and shipping market data. Only leading correlation factors were chosen to be used for the overall leading index. The overall leading index had the highest correlation coefficient factor of 0.499 two months ago. It showed a significant correlation coefficient five months ago. The QPS value was 0.13, which was found to have high accuracy for crisis prediction. Furthermore, unlike other previous time series forecasting model studies, this study quantitatively approached the time lag between economic crisis and the crisis of the tanker ship market, providing workers and policy makers in the shipping industry with an framework for strategies that could effectively deal with the crisis.