• Title/Summary/Keyword: Petrochemical

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CHARACTERIZATION AND CLASSIFICATION BY NEAR INFRARED SPECTROSCOPY OF WAXES USED IN DAIRY TECHNOLOGY

  • Barzaghi, Stefania;Giardina, Claudia;Cattaneo, Tiziana M.P.;Giangiacomo, Roberto
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1252-1252
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    • 2001
  • The aim of this study was to evaluate the possibility to characterize and classify waxes applied on some type of cheeses to obtain good stability during handling and transportation. Generally, waxes are obtained from the petrochemical industry, nowadays there is the possibility to also use biodegradable waxes produced from microorganisms. Preliminary studies were carried out to optimize sample presentation in NIR analysis, such as melting conditions (influence of temperature) and coat thickness of wax. 12 waxes (biodegradable or not) were analysed by using an InfraAlyzer 500 (Bran+Luebbe). The sample size was performed cutting pieces of 1.5 cm (height) x 1.5 cm (width) x 1.5 mm (thickness), previously melted at 9$0^{\circ}C$. NIR spectra were collected at room temperature, and data were processed by Sesame Software (Bran+Luebbe) to evaluate qualitative differences among samples by cluster analysis. Waxes were gathered on the basis of their origin (petrochemical or microbial). To better understand the significance of the NIRS bands discriminating among waxes, a two-dimensional correlation with FT-IR spectra, collected by a FT-IR/ATR 420 (JASCO) instrument, was made using 2DCORR program (Galactic Industries). On the basis of its classification power, NIRS appears to be a promising tool when used in routine analysis for a qualitative control of raw materials.

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The Loss Control Management System for Continuous Improvement of the Petrochemical Industries (석유화학산업에서의 지속적 발전을 위한 손실관리시스템 개발)

  • Ko Jae Wook;Lim Dong Ho;Yoo Jin Hwan
    • Journal of the Korean Institute of Gas
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    • v.9 no.3 s.28
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    • pp.15-20
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    • 2005
  • Recently, Environmental and Safety Management is approaching in order to reduce the loss cost of accidents in effect, efficiency, excellency. In the side that is a large production enemy of the industrialization times, Most companies are focused on decreasing the loss that can let their companies grow healthily than a productivity improvement. The this study analyzed a matter asked f3r basic requirements and continuous development of ISO14001, OHSAS18001, PSM, Responsible Care operating in petro-chemical industries basically, and developed a LCMCI(the Loss Control Management system for Continuous Improvement of the Petro-chemical Industries) fer continuous development of petro-chemical companies in order to be able to continuously manage a loss.

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Petrochemical Study on Igneous Rocks in the Hamyang area, Kyongnam, Korea (경남(慶南) 함양지역(咸陽地域)에 분포(分布)하는 화성암류(化成岩類)에 대(對)한 암석화학적(巖石化學的) 연구(硏究))

  • Park, Jay-Bong;Kim, Yong-Jun;Kim, Cheong-Bin
    • Economic and Environmental Geology
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    • v.23 no.1
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    • pp.105-123
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    • 1990
  • Igneolls rocks of the Hamyang area consist of Hamyang foliated granites and hornblende diorite. Hamyang foliated granites are classified into four rock types in terms of mineral composition and texture. The four rock types are foliated hornblende biotite granodiorite, foliated porphrytic granodiorite, foliated fine biotite granodiorite and foliated leuco granite. Petrochemical data of these rocks suggest that Hamyang foliated granites is calc-alkali rock series of differentiated products of cogenetic magma by fractional crystallization. Igneous rocks of studied area correspond to I-type, peraluminous and calc alkali rock series. Rb-Sr age and $Sr^{87}/Sr^{86}$ initial ratio for foliated prophrytic granodiorite is $200{\pm}Ma$and $0.711{\pm}0.0037$, respectively. K-Ar(hornblende) age of hornblende diorite is $179{\pm}9Ma$. These data come to an coincidence with Igneous activity of South Korea which were proposed by O.J. Kim(1975), that is, they correspond to Hamyang foliated granites of products of Songrim Disturbance, and to hornblende diorite of Daebo Orogeny.

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Concentrations of Water-soluble Particulate, Gaseous tons and Volatile Organic Compounds in the Ambient Air of Ulsan (울산 대기 중의 입자상, 기체상 물질의 수용성 이온 성분과 휘발성 유기화합물의 농도)

  • 나광삼;김용표
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.4
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    • pp.281-292
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    • 1998
  • Ambient concentrations of gaseous, particulate phase ionic species, and VOCs (volatile organic compounds) were measured at two monitoring sites in the City of Ulsan during August 1997: one in industrial area and the other in downtown area. At each site, a three- stage filter pack sampler was used to collect fine particles and gaseous species, and air for VOC analysis was collected in stainless steel canisters. Concentrations of the ionic species at both sites were similar to each other. The VOC concentrations at the industrial site were approximately twice higher than those at the downtown site. This might be mainly due to the release of VOCs from the petrochemical industries. Daily variations of VOC concentrations at the industrial site were higher than that at the downtown site. This might be explained by the fact that emissions from industries were more irregular than those in downtown. The VOC concentrations in downtown were affected by both the local emissions and the emission from the petrochemical industries. The concentrations of selected hazardous organic components (HAPs) at the industrial site were similar to those of Yocheon industrial area but slightly higher than other cites and industrial areas, while those at the downtown site were comparable to those in other urban areas.

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Optimization of biodiesel production via methyl acetate reaction from cerbera odollam

  • Dhillon, Sandip Singh;Tan, Kok Tat
    • Advances in Energy Research
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    • v.4 no.4
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    • pp.325-337
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    • 2016
  • Cerbera Odollam (sea mango) is a proven promising feedstock for the production of biodiesel due to its high oil content. Fatty acid methyl esters (FAME) were produced as the final reaction product in the transesterification reflux condensation reaction of sea mango oil and methyl acetate (MA). Potassium methoxide was used as catalyst to study its reacting potential as a homogeneous base catalyst. The initial part of this project studied the optimum conditions to extract crude sea mango oil. It was found that the content of sea mango sea mango oil was 55%. This optimum amount was obtained by using 18 g of grinded sea mango seeds in 250 ml hexane. The extraction was carried out for 24 hours using solvent extraction method. Response surface methodology (RSM) was employed to determine the optimum conditions of the reaction. The three manipulated variables in this reaction were the reaction time, oil to solvent molar ratio, and catalyst wt%. The optimum condition for this reaction determined was 5 hours reaction time, 0.28 wt% of catalyst and 1:35 mol/mol of oil: solvent molar ratio. A series of test were conducted on the final FAME product of this study, namely the FTIR test, GC-FID, calorimeter bomb and viscometer test.

Exposure Assessment of volatile Organic Matters (VOCs) Using Exposure Biomarker in the Residents Living Near Petrochemical Industry Areas (공단지역 주민에서 휘발성 유기오염물질의 호흡기 노출에 대한 생체지표 평가)

  • 신동천;박성은;임영욱;양지연;김명수
    • Environmental Analysis Health and Toxicology
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    • v.15 no.3
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    • pp.81-91
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    • 2000
  • Residents who live near petrochemical industrial areas are exposed to a variety of petrochemicals, including benzene or benzene-containing liquids. It is a serious concern because some VOCs are carcinogens naturally present in petroleum and gasoline. The aim of this study was to assess the exposure to VOCs, measured by personal/indoor/outdoor air sampling, and to estimate the relationship between the air samples and biological monitoring data. Through biological monitoring, we investigated VOCs in blood and s-phenylmercapturic acid (s-PMA) , minor urinary metabolites of benzene. The external benzene exposure of subjects was measured using passive dosimeters and urinary s-PMA and blood-benzene were determined by GC/MS. More than 80% of subjects were detected for m-xylene, ethylbenzene, and toluene in blood samples and not detected at all for chloroform, 1 , 1 , 1 -trichloroethylene, and tetrachloroethylene. The mean concentration of benzene in the breathing zone of residents was 6.3 $\mu\textrm{g}$/m$^3$, personal, indoor and outdoor concentrations were strongly correlated to each other. s-PMA detected in all subject samples was affected by personal exposure (p< 0.05) and the level was different by age (p< 0.01). Blood benzene was not affected by external benzene during these periods .

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Magnetic Susceptibility and Petrochemical Compositions of Mesozoic Granites in Korea (국내 중생대 화강암의 대자율 특성과 화학조성)

  • 홍세선
    • The Journal of the Petrological Society of Korea
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    • v.13 no.1
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    • pp.16-33
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    • 2004
  • By relating mineralogy, petrology and geochemistry to observed magnetic properties, an understanding of the geological factors that control magnetic signatures is obtained. Magnetic susceptibility measurements and geochemical analyses were carried out for 160 samples in the Jurassic to Cretaceous granitoids, which is distributed to Pocheon, Jipori, Geumsan, Namwon, Songnisan, Yongdam, Masan, Jindong, and Taebaeksan areas. The magnetic properties of igneous infusion in these granites reflect bulk rock composition, reduction-oxidation state, hydrothermal alteration which are controlled by tectonic setting, composition and history of the source region, depth of emplacement and nature of wall rocks.

A Study on the Pollution of Nonylphenol in Surface Sediment in Gwangyang Bay and Yeosu Sound (광양만과 여수해만의 표층퇴적물에서 Nonylphenol의 오염에 관한 연구)

  • Jo, Hyeon Seo;Kim, Yong Ok;Seol, Sun U
    • Journal of Environmental Science International
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    • v.13 no.6
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    • pp.561-570
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    • 2004
  • This study was carried out to survey the pollution of nonylphenol (NP) in surface sediments around Gwangyang bay and Yeosu sound. NP was suspected chemicals as endocrine disruption. Gwangyang bay is located on the mid south coast of Korea. It is a semi-closed bay which Yeosu petrochemical industrial complex, POSCO (Pohang Steel Company) and Gwangyang container harbor are there. The surface sediments were collected at 15 stations with gravity corer at October, 1999, February, May and August, 2000. Also, the stream and intertidal sediment were collected at 5 sites at August, 2000. Concentrations of NP in surface sediments were in the range of 6.89 to 202.70 ng/g dry wt.. Seasonal range (mean value) of NP is 13.98 to 30.48 (23.46) ng/g dry wt. at October, 10.35 to 54.91 (28.10) ng/g dry wt. at February, 29.05 to 202.70 (82.32) ng/g dry wt. at May and 6.98 to 83.40 (25.37) ng/g dry wt. at August. NP was seasonally fluctuated, and the highest mean value and range was detected at May, 2000. NP was highly distributed in the inner part of Gwangyang bay than Yeosu sound. Concentrations of NP in stream and intertidal sediments showed the highest value in downstream near Yeosu petrochemical industrial complex and Yondung stream. It suggests that the source of NP is industrial wastewater and municipal sewage.

Development of Health Monitoring System Using Self Magnetization Magnetostrictive Sensor (자기자화자왜센서를 이용한 설비 off-line Health Monitoring 시스템 개발)

  • Kim, Yi-Gon;Moon, Hong-Sik;Kim, Jun;Kim, Ji-Hyeon
    • Journal of the Korean Institute of Intelligent Systems
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    • v.22 no.4
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    • pp.481-486
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    • 2012
  • This thesis examines the development and application of 'Health Monitoring System' which monitors periodically the state of a pipe of petrochemical plant by using magnetostrictive sensor technology. The existing guided-wave inspection methods cannot be applied to welding part inspection in pipe, and has a limit of precision when applied to general parts because of noise, reflected waves, and so on. This technology uses the information on displacement of a defect through periodic monitoring, which makes more precise inspection, and can be utilized very usefully in a petrochemical plant.

Recent Advances in the Mechanistic Studies of Alkylaromatic Conversions over Zeolite Catalysts (제올라이트 촉매상에서의 알킬 방향족 화합물 전환 반응기구에 대한 최근 연구 동향)

  • Min, Hyung-Ki;Hong, Suk Bong
    • Korean Chemical Engineering Research
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    • v.51 no.1
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    • pp.1-9
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    • 2013
  • The transformation of alkylaromatic hydrocarbons using zeolite catalysts play big part in the current petrochemical industry. Here we review recent advances in the understanding of the reaction mechanisms of various alkylaromatic conversions with respect to the structural and physicochemical properties of zeolite catalysts employed. Indeed, the shape-selective nature of zeolite catalysts determines the type of reaction intermediates and hence the prevailing reaction mechanism together with the product distribution. The prospect of zeolite catalysis in the developement of more efficient petrochemical processes is also described.