• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.12
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• pp.446-452
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• 2016

Recently, heat resistant super alloys (which are wear-resistant, corrosion-resistant, and heat-resistant), have been used as the basic structural material in offshore and petrochemical plants. On the other hand, making valves from very expensive, high heat-resistant alloys increases the production cost and decreases its market competitiveness. To solve these problems, the technique of overlaying only those that flow on the fluid has been used as an effective method. Nevertheless, because the former technique of overlaying the ball is performed manually, it takes too much time and perfect welding is difficult to perform. To solve this problem, this study developed a robot automation system that can make uniformly overlay welding of the ball for ball-valves. The system consists of a 6-axis welding robot with a welding torch and additional 2 axes for the rotation of positioner, the controller, and a robot path OLP (Off-Line Programming). The CAD drawing data was entered in the Off-line program to obtain the robot teaching point and drive source. Overlay welding paths were implemented using Matlab. Through an automated overlaying system that implemented the OLP, the productivity rose 2.58 times, as the amount of time required for work decreased from 88 hours to 41 hours.

• Membrane Journal
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• v.25 no.4
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• pp.343-351
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• 2015

In this study, we synthesis polyimide with high gas selectivity using 2,2-bis(3,4-carboxylphenyl) hexafluoropropane, 2,4,6-Trimethyl-1,3-phenylenediamine (DAM) and 4,4-Methylenedianiline (p-MDA), and then the asymmetric membrane was fabricated by non-solvent phase separation method. To confirm the property change of the membrane using different solvent, we measured and compared the viscosity of the polymer solution, cloud point and non-solvent phase separation coefficient. The morphology and gas separation property of membrane prepared by phase separation method was confirmed using Field Emission Scanning Electron Microsope and the single gas permeation measurement apparatus. The single gas ($CH_4$, $N_2$, $O_2$, $CO_2$) permeation property and selectivity value of the membrane prepared with NMP was higher than the membrane prepared with DMAc. We confirmed that the gas selectivity of the membrane increased and the permeation property decreased with increasing of the solvent evaporation time.

• Journal of the Korean Geotechnical Society
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• v.32 no.2
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• pp.53-62
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• 2016

Among several factors controlling soil compaction, temperature is the factor that varies with region and season. Although earthwork is performed in many projects in the cold regions of the earth, studies on quantifying soil compaction associated with temperature are limited. This experimental study investigates the temperature effect on the soil compaction of cohesionless soil. Jumunjin sand was selected for the tests to represent cohesionless clean sand, which is widely used as an engineering fill at petrochemical projects such as northern Alberta of Canada and Russia. The laboratory test program consists of performing a series of standard proctor tests varying temperature of soil samples ranging from $-10^{\circ}C$ to $17^{\circ}C$. Test results indicate that soil specimen volume expansion occurred from bulking and its range was 0% to 6% with zero above temperature. For increasing temperature from $0^{\circ}C$ to $17^{\circ}C$, water content corresponding to maximum volume (minimum dry unit weight) was decreased and water content corresponding to minimum volume (maximum dry unit weight observed after reaching minimum dry unit weight) was slightly increased with increasing temperature. In zero below temperature, dry unit weight gradually decreased with increasing water content. In this case, no bulking effect was found and soil specimen volume increased due to the higher unit volume of ice.

• Korean Chemical Engineering Research
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• v.46 no.2
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• pp.402-407
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• 2008

Recent popularity in mobile electronics requires higher standard on the mechanical strength of electronic packaging. Thus, the method of soldering between chip and substrate in electronic packaging process is changing from conventional method using intermetallic compound to a new method using organic solderability preservative (OSP) in order to improve the stability and the reliability of final product. Since current organic solder preservatives have several serious problems like thermo-stability during packaging process, however, it is necessary to develop new OSPs having thermo-stability. The main purpose of this study is to investigate the effect of MeOH/IPA (Isopropyl alcohol) ratio on the fluxing of a new OSP, developed in previous research, andto find out an optimum formulation of flux components for the application of the OSP in current packaging process. As a result of this study, it was revealed that higher MeOH/IPA ratio in flux showed better performance of fluxing a new OSP.

• Journal of the Korean earth science society
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• v.26 no.1
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• pp.78-92
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• 2005

Petrographical and petrochemical analyses for late Miocene basalts in Goseong-gun area. Gangwon province, were carried out to interpret the characteristics and the origin of magma. The basaltic rocks occurred as plug-dome in the summit of several small mountain and developed columnar jointing with pyroxene-megacryst bearing porphyritic texture. And the basalt contains xenoliths of biotite granite (basement rocks), gabbro (lower crustal origin) and Iherzolite(upper mantle origin). The basalts belong to the alkaline basalt field in TAS diagram and partly belong to picrobasalt and trachybasalt field. On the tectonomagmatic discrimination diagram f3r basalt in the Goseong-gun area. they fall into the fields for the within plate and oceanic island basalt. The characteristics of trace elements and REEs shows that primary magma for the basalt magma would have been derived from partial melting of garnet-peridotite mantle. This late Miocene basalt volcanism is related to the hot spot within the palte.

• Journal of the Korean earth science society
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• v.18 no.6
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• pp.480-492
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• 1997

In order to understand the processes involved in the petrogenesis and the differentiation of the primary magma spectrum, a petrological and geochemical properties were investigated for the Chonju and the Sunchang foliated granites, which are located in the southwestern part of the Okchon zone and extends up to the northwestern boundary of the Ryongnam massif as two subparallel batholiths. Major element analyses show that the Chonju and Sunchang foliated granites are classified petrologically into a weakly to strongly peraluminous or calc-alkaline, but do not fit neatly into either of the I/S-type or magnetite/ilmenite-series classification schemes for granites, although the I-type and magnetite-series characteristics seem to be predominant based on the major element chemistry. In normative compositions, the Chonju granite is petrographically evolved from granodiorite to granite, whereas the Sunchang granite is from granodiorite to quartz monzodiorite. It seems to suggest a difference of the magmatic evolution processes such as crustal assimilation and/or fractional crystallization in magma. The REE patterns of both batholiths show high similarity and strongly fractionated REE distributions which show high $(Ce/Yb)_N$ ratios and little or no Eu anomalies. These REE patterns correspond broadly to those seen in the pre-Cretaceous granitoids of Korea. Apparently, the evidences obtained from the bulk compositions strongly suggest that the two foliated granitoids were formed by partial meltings of a relatively restricted and similar, may be common, source material which contains a continental crust component having an igneous composition, and have undergone a similar magmatic differentiation processes.

• Journal of the Korean earth science society
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• v.34 no.2
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• pp.109-119
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• 2013

Duibaejae basalts from Goseong, Gangwon-do, are divided into the lower basalt and the upper basalt depending on the properties, such as occurrence, mineral compositions, and major and trace compositions of the basalts. The lower basalts have characteristics of agglomerate rocks as well as contain, crustal and mantle xenoliths, and olivine, pyroxene, and plagioclase xenocrysts. The upper basalts with columnar joints contain relatively more mantle xenolith and olivine xenocryst than the lower basalts. The major and trace element compositions suggest that the composition of the upper basalts is close to primary magma composition. Enrichment and depletion patterns of the trace and the rare-earth elements of the lower basalts are similar to those of the upper basalts, whereas the lower basalts are more LREE enriched than the upper basalts. The source magmas of the lower and upper basalts from Duibaejae volcanic edifice were generated from about 0.8-1.2% and 3.7-4.0% batch melting of garnet peridotite, respectively. The abundance of granite xenolith, and plagioclase and quartz xenocrysts with reaction rim indicates that the lower basalts, compared with upper basalts, might have been assimilated with the crustal materials during ascending to surface.

• Spatial Information Research
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• v.10 no.2
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• pp.247-261
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• 2002

There are much damage of people and property because of heavy rain every year. Especially, there are problem to major facility such as dam, bridge, road, tunnel, and industrial complex in the ground stability. So the counter plan for landslide or ground failure must be necessary In the study, the technique of regional landslide susceptibility assessment near the Ulsan petrochemical complex and Kumgang railway bridge was developed and applied using GIS. For the assessment, the geological structures such as bedding and fault were surveyed and the geological structure, topographic, soil, forest, and land use spatial database were constructed using CIS. Using the spatial database, the factors that influence landslide occurrence, such as slope, aspect, curvature and type of topography, texture, material, drainage and effective thickness of soil, type, age, diameter and density of forest, and land use were calculated or extracted from the spatial database. For application of geological structure, the geological structure line and fault density were calculated. Landslide susceptibility was analyzed using the landslide-occurrence factors by probability method that is summation of landslide occurrence probability values per each factors range or type. The landslide susceptibility map can be used to assess ground stability to protect major facility.

• Elastomers and Composites
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• v.47 no.1
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• pp.54-64
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• 2012

Acrylonitrile was introduced in the emulsion SBR to increase compatibility between silica and rubber. AN-SBR/silica compounds showed faster vulcanization time and higher delta torque values than SBR 1721/silica compounds because interaction between nitrile group of AN-SBR and silanol group on the silica surface could make hydrogen bond that prevented adsorption of the accelerator on the silica surface, which improved the vulcanization reaction efficiency and enhanced the degree of crosslinking. AN-SBR/silica compound showed higher values in minimum torque than SBR 1721/silica compound during the vulcanization because AN-SBR has higher molecular weight than SBR 1721 in the raw material. When PEG was added to the SBR 1721 and AN-SBR compounds, vulcanization time was faster than SBR 1721 and AN-SBR compounds without PEG because PEG has a large number of ether linkages which show high compatibility with silanol group on the silica surface that prevented the adsorption of the accelerator and the ingredients on the silica surface, which improved the vulcanization reaction efficiency. In the mechanical properties, AN-SBR compounds showed higher modulus values at 100%, 300% than SBR 1721 compounds because interaction between nitrile group of AN-SBR and silanol group on the silica surface enhanced the degree of crosslinking. In the dynamic properties, AN-SBR compounds showed lower tan ${\delta}$ values at $0^{\circ}C$ than SBR 1721 compounds in accordance with the $T_g$ values. AN-SBR compounds showed lower tan ${\delta}$ values at $60^{\circ}C$ than SBR 1721 compounds because interaction between acrylonitrile and silica caused strong filler-rubber interaction that induced low energy dissipation by the filler-filler interaction.

• The Journal of the Petrological Society of Korea
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• v.5 no.1
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• pp.108-120
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• 1996

This study reports petrography and geochemical characteristics of the Cretaceous volcanic rocks that are distributed in the vicinity of the Cheonsungsan area, Yangsan-Gun, Gyeongsangnam-Do. The Cretaceous volcanic rocks composed of andesitic rocks, Wonhyosan tuff, Cheonsungsan tuff in ascending order. Sedimentary rock is the basement in the study area cofered with volcanic rocks. These volcanic rocks are Wonhyosan tuff and Cheonsungsan tuff that represented the early phase of the Bulgugsa igneous activity. Wonhyosan tuff are classified into dacite tuff and dacite welded tuff based on the rock texture and their mineral composition. They are covered with Cheonsungsan tuff. Dacite tuff composed of lithic lapilli ash-flow tuff and vitric ash-flow tuff. Most dacite welded tuff are lapilli ash-flow tuff. Cheonsungsan tuff overlying the Wonhyosan tuff consists of rhyolite tuff and rhyolite welded tuff. Rhyolite tuff are lithic crystal ash-flow tuff and crystal vitric ash-flow tuff with somewhat accidental fragments of andesitic and sedimentary rocks. Rhyolite welded tuff is distinguishe from rhyolite tuff by is typical eelded fabrics and its rock color. According to petrochemical data, the volcanic rocks in study area belong to high-K orogenic suties. On the discriminant diagrams such as La/Yb versus Th/Yb, these rocks falls into the discriminant fields for the normal continental margin arc.