• 제목/요약/키워드: Pesticide analysis

검색결과 593건 처리시간 0.028초

드론을 활용한 재난관리활용의 문제점 개선에 관한 연구 (A Study on Problems and Improvement of Disaster Management Activities Using Drones)

  • 조한광;강휘진;양옥희
    • 한국방재안전학회논문집
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    • 제10권1호
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    • pp.67-74
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    • 2017
  • 드론은 취미생활 및 농약 살포, 배송 등 다양한 분야에 활용되고 있다. 하지만 재난관리 분야의 활용도는 상대적으로 미미하여 구호품의 운송, 동영상의 활용 등 제한된 분야에서 일부 기능만을 사용하고 있는 것이 현실이다. 특히 재난을 전문으로 하는 기관이나 재난 전문가의 드론에 대한 이해 부족으로 활성화에 어려움이 가중된다고 판단한다. 이에 본 연구에서는 드론의 조종법에 대한 개략적인 특성과 재난관리 분야에서 드론이 활성화가 되지 않는 원인을 분석하여 제도적 측면에서는 법적 규제와 활용 측면에서는 카메라, 열 감지카메라, 적외선센서, RFID 등 센서 기반 등의 융합 적용상의 문제점을 도출하고 이에 대한 개선방안 방향에 대해 제시하고자 한다.

피레스로이드계 살충제의 MCF7-BUS세포에 대한 에스트로겐 및 항에스트로겐 효과 (Estrogenic and Antiestrogenic Insecticides in MCF7-BUS Cell Line)

  • 오승민;정규혁
    • 약학회지
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    • 제45권6호
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    • pp.694-700
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    • 2001
  • Synthetic pyrethroids are analysis of a natural chemical moiety, pyrethrin derived from the pyrethrum plant Chrysanthemum. The natural pyrethrin structure has been modified to be highly lipophilic and photostable, creating an effective pesticide and resulting in an increased presence in the environment. Worldwide, they are commonly used insecticides against ticks, mites, mosquitoes, and as treatment for human head lice and scabies. Therefore, human exposure to their compounds in extensive. Several studies on the effects of pyrethroids on thyroid hormone regulation, estrogen and androgen function have been reported and yet little has been done try assess their potential hormonal activities. Among humans, a pyrethroid compound was suggested to be the causal agent for gynecomastia in a group of Haitian men. The reports suggest that some pyrethroid compounds are capable of disrupting endocrine function. Therefore, we examined estrogenic/antiestrogenic potential of three pyrethroid insecticides, that is permethrin, allethrin and fenvalerate in human breast cancer cell and action mechanism mediated by the estrogen receptor. Fenvalerate showed weak estrogenic activity but aallethrin and permethrin showed no effect. In combination with high levels (10$^{-10}$ M, 10$^{-11}$ M) of 17$\beta$-estradiol and three synthetic pyrethroids inhibited cert proliferations in MCF7-BUS cell by 17$\beta$-estradiol. Whereas, fenvalerate increased cell proliferative activity at lower level of estradiol (10$^{-12}$ M, 10$^{-13}$ M). The relative affinities to the estrogen receptor were observed by allethrin and permethrin treatment, but not by fenvalerate. These results indicated that some of pyrethroid insecticides may modulate estrogen functions in human breast cancer cell. The action mechanisms of estrogen receptor mediated antiestrogenicity by allethrin and permethrin were postulated.

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학교급식 식재료 구매관리 및 품질관리 실태조사 (Food Purchasing and Quality Management Practices in School Food Service)

  • 김경아;곽동경;이경은
    • 대한영양사협회학술지
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    • 제12권4호
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    • pp.329-341
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    • 2006
  • The purposes of the study were to examine food purchasing management practices and to assess dietitians' awareness on food quality standards, use of food purchasing guidelines(food quality guidelines, supplier selection criteria), and organizational collaboration related to purchasing at school food service. A total of 400 dietitians working at elementary schools in Kyunggi Province were surveyed and 247 responses were returned. Excluding responses with significant missing data, 240 responses(60%) were used for data analysis. Compared to the previous reports, competitive bidding and shorter contract periods were preferred for purchasing food supplies. A dietitian, school staff, and food service staff participated in receiving and inspection together at 58.4% of the schools. An average score of the dietitians' awareness on the food quality standards was 3.28 based on a 5-point scale(1:strongly disagree, 5:strongly agree). Their awareness scores for the quality standards related to the genetically modified organism foods, organic foods, and pesticide residues were the lowest. The awareness scores increased significantly with their age(p<.001). In general, the food purchasing guidelines were used well at the schools ; the usage levels of the food quality guidelines and supplier selection criteria were significantly different by length of operation(p<.05) and dietitians' age(p<.05), respectively. The dietitians' perception score of the organizational collaboration related to purchasing was rated 3.46 and differed significantly by dietitians' educational background(p<.05). For improving food procurement management, standardized food quality and purchasing criteria need to be developed. As the demands on high quality food supplies increase for school food service, the dietitians should improve their knowledges on the food quality standards and implement effective and creative purchasing methods.

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잔류농약의 액체 크로마토그래피 분석법 개발에 관한 연구 (II) Thiocarbamates 제초제의 잔류농약 분석법 개발 (Studies on the Development of Liquid Chromatographic Methods for Pesticide Residues (II) : The Development of the Analytical Method for Thiocarbamates Herbicides)

  • 이대운;최용욱
    • 대한화학회지
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    • 제36권1호
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    • pp.66-74
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    • 1992
  • HPLC로 11종의 티오카바메이트들의 다성분 동시분석법을 연구하였다. 배추시료에 넣은 티오카바메이트는 추출, 분배, 세척, 및 분리-검출이 단계로 분석되는데, 추출용매로서는 아세톤을 선택하였고, 분배용매로서는 50% 염화메틸렌/석유에테르 혼합용매가 좋은 회수율을 보였다. 분배효율은 물층의 pH 영향을 받는데 산성 혹은 중성에서는 영향이 없으나 염기성에서는 감소하였다. 세척단계에서 공추출물의 제거효율은 응고액 처리법 보다는 컬럼 크로마토그래피법이 우수하였다. 흡착제로는 활성탄/마그네시마/셀라이트 1/2/4)의 흡착제가 좋은 효율을 보였으며, 클로로필드 효과적으로 제거되었다. 이 방법으로 배추에 있는 2ppm정도의 티오카바메이트의 동시 분석의 결과는 평균회수율이 91%, 상대표준편차가 약 8%, 검출한계가 2.2${\sim}$9.3ng이었다.

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Ovicidal Activity of Lactic Acid Produced by Lysobacter capsici YS1215 on Eggs of Root-Knot Nematode, Meloidogyne incognita

  • Lee, Yong Seong;Naning, Kyaw Wai;Nguyen, Xuan Hoa;Kim, Sun Bae;Moon, Jae Hak;Kim, Kil Yong
    • Journal of Microbiology and Biotechnology
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    • 제24권11호
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    • pp.1510-1515
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    • 2014
  • Lysobacter capsici YS1215 isolated from soil previously showed nematicidal potential for biological control of the root-knot nematode. In this study, lactic acid, a nematicidal compound, was isolated from culture filtrate of YS1215, and its ovicidal activity was investigated. Purification and identification of lactic acid were performed by a series of column chromatographies and identified by $^1H$ and $^{13}C$ NMR spectra and GC-MS analysis. Our results showed that bacterial culture filtrate containing lactic acid significantly inhibited egg hatching. The lowest egg hatch rate (5.9%) was found at a high concentration ($25 {\mu}l/ml$) of lactic acid at 5 days after incubation, followed by 20 (15.2%), 15 (23.7%), 10 (29.8%), and $5(36.4%){\mu}l/ml$, while egg hatching in the control (sterile distilled water) was 44.5%. This is the first report of lactic acid as an ovicidal compound, and it may be considered as an alternative of chemical pesticide against root-knot nematodes.

The Synthesis of Eu3+ Doped with TiO2 Nano-Powder and Application as a Pesticide Sensor

  • Yao, Fei;Sun, Yang;Tan, Chunlei;Wei, Song;Zhang, Xiaojuan;Hu, Xiaoyun;Fan, Jun
    • 대한화학회지
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    • 제55권6호
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    • pp.932-935
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    • 2011
  • Using tetrabutyl titanate as precursor, $Eu^{3+}$ doped $TiO_2$ nano-powder was prepared by sol-gel method, the nature of luminescence of nano-powder was studied. The interaction of chlorpyrifos with $Eu^{3+}$ doped $TiO_2$ was studied by absorption and fluorescence spectroscopy. The results indicated the fluorescence intensity of $Eu^{3+}$ doped $TiO_2$ was quenched by chlorpyrifos and the quenching rate constant ($k_q$) was $1.24{\times}10^{11}\;L/mol{\cdot}s$ according to the Stern-Volmer equation. The dynamics of photoinduced electron transfer from chlorpyrifos to conduction band of $TiO_2$ nanoparticle was observed and the mechanism of electron transfer had been confirmed by the calculation of free energy change (${\Delta}G_{et}$) by applying Rehm-Weller equation as well as energy level diagram. A new rapid method for detection of chlorpyrifos was established according to the fluorescence intensity of $Eu^{3+}$ doped $TiO_2$ was proportional to chlorpyrifos concentration. The range of detection was $5.0{\times}10^{-10}-2.5{\times}10^{-7}mol/L$ and the election limit ($3{\sigma}$) was $3.2{\times}10^{-11}$ mol/L.

우리 나라 주요 하천유역에 서식하는 양서류 및 어류의 유기질소계 농약류 축적 (Accumulation of Organonitrogen Pesticides in Fishes and Amphibians from the Basin of Major Rivers of S. Korea)

  • 오동진;김영복;이지영;문지용;정기호
    • 분석과학
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    • 제15권6호
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    • pp.489-495
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    • 2002
  • 본 연구는 우리나라 수계에 서식하는 어류와 양서류에 대해 trifluralin, atrazine, metribuzink, alachlor, malathion, nitrofen, permethrin, cypermethrin, fenvalerate, parathion 등의 유기 농약의 잔류실태를 조사한 것이다. 전국의 주요 하천 유역 31개 지점에서 양서류와 어류를 채집하였으며, 이들의 근육 부분을 최종 분석시료로 하였다. 전처리 과정에서 아세토니트릴로 추출한 후 n-헥산으로 씻어 지질성분을 제거하고 정제수를 넣고 디클로로메탄으로 재추출하였다. 추출액을 탈수 농축하여 플로리실 컬럼으로 정제한 후 동위원소 표준물질을 첨가하여 GC-MS를 이용하여 분석하였다. 검출된 농도 범위는 양서류에서는 $0.17{\sim}6.8{\mu}g/kg$, 그리고 어류에서는 cypermethrin이 최대 $16{\mu}g/kg$을 비롯해서 $0.26{\sim}16{\mu}g/kg$의 농도로 검출되었다.

재배농법에 따른 국내산 배추의 위해미생물 및 중금속 오염평가 (Analysis of Pathogenic Microorganism's Contamination and Heavy Metals on Kimchi Cabbage by Cultivation Methods in Korea)

  • 오소영;남기웅;윤덕훈
    • 한국식품위생안전성학회지
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    • 제32권6호
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    • pp.500-506
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    • 2017
  • 본 연구는 자가제조퇴비를 사용하는 유기농가와 관행농가로 구분하여 생산되는 배추와 토양의 위생지표세균(Aerobic plate count, coliform count, yeast & mold)과 식중독발병 가능성이 있는 유해미생물(Staphylococcus aureus, Environmental listeria, Bacillus cereus)의 밀도를 분석하였다. 그 결과, 토양과 식물체 모두 식품에서 위해균 허용한계치인 5.0 Log CFU/g 이하로 검출되었다. 또한 토양에서 위해균 검출량과 식물체 표면의 위해균 검출량간의 상관 관계를 분석한 결과 정의 상관관계에 있었다. 또한 토양과 식물의 중금속 오염도를 조사한 결과 검출되지 않거나 허용한계치 이하로 검출되었다.

일개 응급의료센터에 내원한 노인 중독 환자의 중증도 예측인자 (Severity Predictors of Elderly Poisoning Patients Admitted to an Emergency Medical Center)

  • 박창용;차경만;소병학;정원중
    • 대한임상독성학회지
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    • 제17권2호
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    • pp.94-101
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    • 2019
  • Purpose: This study examined the clinical characteristics of severe elderly poisoning patients to determine the factors that can prevent them. Methods: Data were collected from patients over 65 years of age presenting to the emergency center with poisoning from 2013 to 2018. Their medical records were analyzed retrospectively, and patients with a poisoning severity score of three or more were defined as the severe poisoning group. The risk factors were evaluated by univariate and multivariate analysis. Results: This study analyzed 292 patients, of whom 37 (12.7%) belonged to the severe poisoning group. The severe poisoning group showed a significantly higher association with pesticide poisoning and intentional suicide attempts. Loneliness and somatization were the cause of the suicidal ideas. No significant differences in age, sex, drinking, ingestion time, poisonous materials other than pesticides, and neuropsychological consultation were observed between the two groups. Conclusion: The severe elderly poisoning patients were the result of intentional poisoning for suicide. Loneliness and somatization were the most influential causes of suicidal poisoning. Therefore, psychiatric screening and frequent medical treatment for elderly people are required to prevent severe poisoning in elderly patients.

Effect of Pesticide Residue in Muscle and Fat Tissue of Pigs Treated with Propiconazole

  • Jeong, Jin Young;Kim, Byeonghyeon;Ji, Sang Yun;Baek, Youl Chang;Kim, Minji;Park, Seol Hwa;Kim, Ki Hyun;Oh, Sang-Ik;Kim, Eunju;Jung, Hyunjung
    • 한국축산식품학회지
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    • 제41권6호
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    • pp.1022-1035
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    • 2021
  • This study estimated the effect of exposure to propiconazole through implementation and residues in finishing pigs. We analyzed the expression of fibrosis-related genes and performed histological analysis of the blood, liver, kidney, muscle, ileum, and fat tissues. The animals were exposed for 28 d to different concentrations of propiconazole (0.09, 0.44, 0.88, 4.41, and 8.82 mg/kg bw/d). Quantitative, gene expression, and histological analyses in tissues were performed using liquid chromatography mass spectrometry, real-time PCR, and Masson's trichrome staining, respectively. Final body weight did not differ among groups. However, genes involved in fibrosis were significantly differentially regulated in response to propiconazole concentrations. Glucose, alanine aminotransferase, and total bilirubin levels were significantly increased compared with those in the control group, while alkaline phosphatase level was decreased (p<0.05) after exposure to propiconazole. The residue limits of propiconazole were increased in the finishing phase at 4.41 and 8.82 mg/kg bw/d. The liver, kidney, and ileum showed blue staining after propiconazole treatment, confirmed by Masson's trichrome staining. In conclusion, these findings suggest that propiconazole exposure disturbs the expression of fibrosis-related genes. This study on dietary propiconazole in pigs can provide a basis for determining maximum residue limits and a better understanding of metabolism in pigs and meat products.