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Partitioning of Heavy Metals between Rice Plant and Limestone-stabilized Paddy Soil Contaminated with Heavy Metals (석회석을 이용하여 안정화한 중금속오염 논토양에서 토양과 식물체(벼) 간의 중금속 전이특성)

  • Koh, Il-Ha;Kim, Eui-Young;Kwon, Yo Seb;Ji, Won Hyun;Joo, Wanho;Kim, Jinhong;Shin, Bok Su;Chang, Yoon-Young
    • Journal of Soil and Groundwater Environment
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    • v.20 no.4
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    • pp.90-103
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    • 2015
  • The agricultural soil, meets soil environmental standards whereas agricultural product from the same soil does not meet permissible level of contaminants, is identified in the vicinity of the abandoned mine in Korea. This study estimated the stabilization efficiency of Cd and Pb using limestone through the flood pot test for this kind of agricultural paddy soil. We had the concentration of the monitored contaminants in soil solution for 4 months and analyzed fractionations in soil and concentrations in rice plant. In soil solution of plow layer, the reductive Mn had been detected constantly unlike Fe. The concentrations of Mn in limestone amended soil was relatively lower than that in control soil. This reveals that the reductive heavy metals which become soluble under flooded condition can be stabilized by alkali amendment. This also means that Cd and Pb associated with Mn oxides can be precipitated through soil stabilization. Pb concentrations in soil solution of amended conditions were lower than that of control whereas Cd was not detected among all conditions including control. In contaminants fractionation of soil analysis, the decreasing exchangeable fraction and the increasing carbonates fraction were identified in amended soil when compared to control soil at the end of test. These results represent the reduction of contaminants mobility induced by alkali amendment. The Cd and Pb contents of rice grain from amended soil also lower than that of control. These result seems to be influenced by reduction of contaminants mobility represented in the results of soil solution and soil fractionation. Therefore contaminants mobility (phytoavailability) rather than total concentration in soil can be important factor for contaminants transition from soil to agricultural products. Because reduction of heavy metal transition to plant depends on reduction of bioavailability such as soluble fraction in soil.

Development of GPS Multipath Error Reduction Method Based on Image Processing in Urban Area (디지털 영상을 활용한 도심지 내 GPS 다중경로오차 경감 방법 개발)

  • Yoon, Sung Joo;Kim, Tae Jung
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.36 no.2
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    • pp.105-112
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    • 2018
  • To determine the position of receiver, the GPS (Global Positioning System) uses position information of satellites and pseudo ranges based on signals. These are reflected by surrounding structures and multipath errors occur. This paper proposes a method for multipath error reduction using digital images to enhance the accuracy. The goal of the study is to calculate the shielding environment of receiver using image processing and apply it to GPS positioning. The proposed method, firstly, performs a preprocessing to reduce the effect of noise on images. Next, it uses hough transform to detect the outline of building roofs and determines mask angles and permissible azimuth range. Then, it classifies the satellites according to the condition using the image processing results. Finally, base on point positioning, it computes the receiver position by applying a weight model that assigns different weights to the classified satellites. We confirmed that the RMSE (Root Mean Square Error) was reduced by 2.29m in the horizontal direction and by 15.62m in the vertical direction. This paper showed the potential for the hybrid of GPS positioning and image processing technology.

Improvement of Hygienic Quality of Panax Ginseng Leaf Tea (고려인삼 엽록차의 위생적 품질개선 연구)

  • 이영주;김종군;권중호;변명우;김석원;조한옥
    • Journal of Food Hygiene and Safety
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    • v.5 no.1
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    • pp.13-19
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    • 1990
  • The microbial populations of exportable ginseng leaf tea were $3.6{\times}10^{5}/g$ in mesophilic aerobic bacteria, $2.1{\times}10^{3}/g$ in mesophilic aerobic spores, $1.6{\times}10^{4}/g$ in yeast, $1.9{\times}10^{4}/g$ in molds and $1.2{\times}10^{4}/g$ in coliforms, respectively, which are higher levels than the legaJIy permissible loads of microorganisms for ginseng powders in Korea. In a comparative study of the decontaminating effects on microorganisms, ethylene oxide fumigation and 5 kGy irradiation could decrease microorganisms below the detectable level. And there is no growth of microorgllnisms after three months of storage at $30{\pm}1^{circ}C$. The decimal reduction doses (Dw value) for microorganisms contaminated were 0.70 kGy in coliforms, 0.75 kGy in total bacteria, 0.85 kGy in molds. and 0.95 kGy in yeast, respectively. In the organoleptic test for ginseng leaf tea, the irradiated samples showed no significant difference from the control group in overall flavor, taste, color and acceptability. However the extracts of ethylene oxide fumigated sample were significantly different in color and taste from other groups even after three months storage.

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Environmental Approach to Blasting Effect on the Surrounding Area when the Mine Blasting (광산 발파 시 인근지역에 미치는 발파영향에 대한 환경적 접근)

  • Jeong, Beonghun;Lee, Seungho
    • Journal of the Korean GEO-environmental Society
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    • v.16 no.12
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    • pp.5-12
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    • 2015
  • Since blasting noise is impact noise, it will give a sudden shock to the human. In the case, such as the blast vibration, it has given aging buildings and livestock great damage to move the vibration along ground in nearby regions. In this study, the influence of the blasting generated during excavation was analyzed for effects on regional. A couple of field and laboratory surveys about geological were carried out to figure out the geological ratio in the study-performed area. Blast vibration noise was compared to the domestic and abroad case studies and each of the institutions permissible standards established the most appropriate criteria in site condition. The vibration velocity of blasting vibration exploits the values which were measured from test blasting on the ground in order to examine blasting effect. Considering the blasting point as the shortest distance from safety facilities (farms, private houses, etc.), the examination of the influence range, which was derived from the vibration velocity of blasting vibration, was performed to figure out how the point affected the safety facilities. Three-dimensional numerical analysis was performed a time history analysis in order to analyze the behavior of the structure for a dynamic blast load, which was determined in three directions of the blast vibration value. The results of three-dimensional numerical analysis and the blasting effect of blasting vibration estimation equation blasting vibration of impact circle with accompanying test blasting were compared. And the analysis confirmed similar results figures.

A Study on the Proper Crown Height of GT 100,000Ton Cruise ship and DWT 100,000Ton Container ship (10만톤급 크루즈선과 컨테이너선의 적정 마루높이에 관한 연구)

  • Kim, Seungyeon;Lee, Yunsok
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.24 no.2
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    • pp.157-162
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    • 2018
  • The increase of risk in port due to the increase in ship size and sea level rises, the standard crown height will increase. In this study, cruise and container ships will need to raise their crown height due to the projected wind pressure areas becoming larger due to the ships' size increase. The mooring assessment was evaluated with the rise of the crown height. The cruise ship of GT 100,000 tons exceeded the permissible breaking force of the mooring line under the crown height conditions of wind speed of 30 kts when the wind direction was $45^{\circ}$ to the direction of the bow. Also, the elevation angle of the pier and mooring line was analyzed and exceeded the crown height, and it was determined that it is necessary to adjust the crown height. Container ships of DWT 100,000 tons were analyzed to exceed the limit of sway motion at the crown height and it was determined that they need to be adjusted to the minimum crown height standard.

Trial Burns of Low-Level Radioactive Wastes the Demonstration-Scale Incineration Plant at KAERI (한국원자력 연구소 실증소각시설에서의 저준위방사성폐기물 시험소각)

  • Yang, Hee-Chul;Kim, In-Tae;Kim, Jeong-Guk;Kim, Joon-Hyung;Seo, Yong-Chil
    • Nuclear Engineering and Technology
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    • v.27 no.5
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    • pp.767-774
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    • 1995
  • Behavior of radionuclides such $^{60}$ Co, $^{54}$ Mn and $^{137}$ Cs in the incineration Process was Studied by trial burns of simulated wastes with radio-isotope tracers. Behavior of nonvolatiles, $^{60}$ Co and $^{54}$ Mn, was similar to that of particulate matters in the process. Decontamination factors(DFs) for $^{60}$ Co and $^{54}$ Mn were 4.7$\times$10$^{5}$ and 6.2$\times$10$^{5}$ , respectively. Behavior of semivolatile radio-isotope, $^{137}$ Cs, was temperature dependent. DFs for $^{l37}$Cs at In different incineration temperature of 85$0^{\circ}C$ and $700^{\circ}C$ were 2.8$\times$10$^3$ and 2.6$\times$10$^4$, respectively. Trial bums of dry active waste(DAW) transported from nuclear power station(NPS) Kori 3,4 were also performed. DF for gross $\beta$/${\gamma}$ radioactivity in DAW was 1.1$\times$10$^{5}$ . This was a little higher than the estimated value, which was calculated from the tracer test results and nuclides distribution in the DAW. Average emission concentration was 0.019 Bq/N $m^3$, which could meet the maximal permissible concentration(MPC) in stack emission.n.

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Antimony Content of Natural Mineral Water in Korean Market and Migration into Water from Bottle Material (국내유통 먹는샘물 중의 안티몬 함량 및 용기 이행 특성)

  • Huh, Yujeong;Yang, Mihee;Cho, Yangseok;Ahn, Kyunghee;Lee, Younhee;Chung, Hyunmee;Kwon, Ohsang;Park, Juhyun
    • Journal of Korean Society on Water Environment
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    • v.30 no.2
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    • pp.199-205
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    • 2014
  • The knowledge on the migration of antimony (Sb) from PET bottles into the water is of greate concern. Antimony in all bottled water marketed in korea and in raw water was analyzed. The detection rate of antimony in total bottled water was 88 % and 100% in PET (Polyethylene terephthalate, PET), 55% in PC (Polycarbonate, PC) bottled water. 55% of raw water contained antimony. The average concentration of Sb in PET bottled water was $0.39{\mu}g/L$, higher than PC bottles ($0.20{\mu}g/L$) and the raw water ($0.22{\mu}g/L$). The migration of Sb into water that is stored in different conditions (room temperature, $45^{\circ}C$, and direct sunlight exposure) was investigated for 180 days. The migration tendency increased with the storage time and temperature. PET bottles showed a sharp increase of Sb concentration at $45^{\circ}C$, but there was no differences between the room temperature and sunlight exposure. The Sb migration in all simulated solution(deionized water, 4% acetic acid, and 20% ethanol) also increased with storage time and temperature. The Sb migration values ranged from 0.35 to $0.49{\mu}g/L$ in all simulated solution, which was far below the permissible korean migration level of $40{\mu}g/L$. There was a tendency that the number of re-use of a bottle and the amount of leaching were in inverse proportion.

Characterization and Two-Phase Neutralization of Acid Mine Drainage (두 단계 중화적정에 의한 산성 광산 유출수 중의 중금속 제거)

  • Jeong, Byeong-Ryong;Chung, Jong-Bae
    • Applied Biological Chemistry
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    • v.42 no.1
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    • pp.73-78
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    • 1999
  • Acid mine drainage (AMD) results from sulfuric acid produced by the oxidation of pyrite, and contains large amounts of toxic elements. In the neutralization of AMD, iron and aluminum hydroxides are the major precipitates and those two can be separated with two-phase neutralization. In this study, removal of toxic elements by the two phases of neutralization was investigated using an AMD collected from the abandoned antimony mine in Gachang, Taegu. Contents of As, Cd, Cu, Mn, Pb and Zn in the AMD were higher than the criteria of river water quality or permissible waste water discharge. In the first phase, the AMD was neutralized to several % (25, 50, 75, 100, and 125) of $Fe(OH)_3$ equivalence point with solid $Ca(OH)_2$. In the second phase, the supernatant of the first phase neutralization was titrated to pH 7.5. After neutralization of the AMD to 100% of the $Fe(OH)_3$, equivalence point, most of Fe and Pb were removed but levels of As, Cd, Cu, Ni, Mn, and Zn were not reduced in the supernatant solution. In the second phase neutralization, levels of those toxic elements in the supernatants dropped below the wastewater discharge or river water quality criteria. This result suggests that the precipitate formed in the first phase of the neutralization process may be disposed without any special cares. Thus the two-phase neutralization scheme can reduce the cost of disposing precipitates containing toxic metals in comparison with the monophase neutralization scheme.

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Characteristics of Pesticide Residues in Leafy Vegetables Collected from Wholesale and Traditional Markets in Cheongju (청주지역 도매시장과 재래시장 유통 엽채류 중 농약의 잔류 특성)

  • Noh, Hyun-Ho;Lee, Kwang-Hun;Lee, Jae-Yun;Park, Hyo-Kyoung;Park, So-Hyun;Kim, Sun-Ho;Kyung, Kee-Sung
    • The Korean Journal of Pesticide Science
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    • v.15 no.4
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    • pp.453-462
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    • 2011
  • This study was carried out to survey the residual characteristics of pesticides and assess their safety. Nineteen agricultural commodities, collected from wholesale and traditional markets in Cheongju. Nineteen agricultural commodities including perilla leaves were collected from the markets on October 29th, 2010. Total 240 pesticides which can be analyzed by multiresidue analysis method by GLC and HPLC were monitored and the pesticides detected were confirmed by GC-MSD and LC-MS. Five pesticides, alachlor, bifenthrin, endosulfan, procymidone and triflumizole, were detected from five samples, such as welsh onion, leek and celery in case of wholesale market and perilla leaves and welsh onion in case of traditional market. Detection rate of 13.2% was obtained as a result of pesticide analysis but 2.6% of the pesticides detected exceeded their maximum residue limits. The estimated daily intakes (EDIs) and maximum permissible intakes (MPIs) of the pesticides detected were less than 26% and 0.05% of their acceptable daily intakes (ADIs) respectively, representing that residue levels of the pesticides detected would be safe.

The Development of a Multi-Purpose Irradiator and the Characteristic of Dose Distribution (다목적 방사선 조사장치 개발 및 선량분포특성)

  • Lee, Dong-Hoon;Ji, Young-Hoon;Lee, Dong-Han;Kim, Yoon-Jong;Hong, Seung-Hong
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.39 no.6
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    • pp.42-48
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    • 2002
  • The design, construction and performance test of a convenient multi-purpose irradiator is described. A multi-purpose irradiator using Cesium-137 has been developed for studies of low dose radiation effects in biology and for calibration of Thermo Luminescent dosimeter(TLD). During the operation, three rods of radioactive material which are 10cm in length revolve 180 degrees and irradiate biological samples, or TLD, and return to their shielded position, after the programmed time. A programmable Logic Controller(PLC) controls the sequence of operation, interlock, motor rotation and safety system. The rotation speed of biological samples can vary up to 20 RPM. A real time monitoring system was also incorporated to check and control the operation status of the irradiator. The capacity of the irradiation chamber was 4.5 liters. The isodose distribution at arbitrary vertical planes was measured by using film dosimetry. The dose-rate was 0.13 cGy/min in air and 0.11 cGy/min in water equivalent material in the case of Cesium-137. Range of activity was 2 Ci. The homogeneity of dose distribution in the chamber was ${\pm}$7%. The actual radiation level on the surface was within permissible levels. The irradiator had a maximum 0.35 mR/min radiation leakage on its surface.