• Journal of the Korea Organic Resources Recycling Association
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• 제20권3호
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• pp.21-24
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• 2012

In this study, Anaerobic Membrane Bioreactor(AnMBR) treating food waste leachate was operated to investigate treatment efficiency of anaerobic process, operational parameters and production of biogas. AnMBR was operated under the condition of filtration type of inside-out mode. AnMBR was operated under the condition that range of permeate flux was from 15 to 20 LMH and range of transmembrane pressure was from 1 to $3 kgf/cm^2$. It was not good that AnMBR was performed under direct connection between anaerobic reactor and external UF module. so, this connection method changed to indirect connection using buffer tank was placed between anaerobic reactor and UF external module. TCOD and SCOD values were that influent were about 113 g/L, 62 g/L and effluent were 25 g/L, 12 g/L, respectively. also TCOD and SCOD removal efficiency were 77% and 81%, respectively. but after added UF process, COD and SCOD removal efficiency was increased to 93% and 86%, respectively.

• Journal of the Korea Organic Resources Recycling Association
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• 제11권3호
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• pp.51-59
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• 2003

In this study, the efficiency of M/F(micro filtration) system was investigated about the wastewater generated from the production process of ${\beta}-glucan$. M/F membrane used the pellicon 2 cassette filter module of millipore(USA) for the operation of M/F plant system. Flux was rised as operation pressure increased, and decreased with the operation time. As concentration ratio increased, the recovery of ${\beta}-glucan$, which was remaind in retentate was effective. As the fermentation solution of ${\beta}-glucan$ reused, the conversion ratio was 42.5%, and the status of fermentation was stable. Based on these results, we suggested that permeate was applicable as water reuse in cleaner production technology.

• Membrane and Water Treatment
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• 제1권2호
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• pp.121-137
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• 2010

This work presents inexpensive inorganic precursor formulations to yield submicron range symmetric ceramic microfiltration (MF) membranes whose average pore sizes were between 0.1 and $0.4{\mu}m$. Incidentally, the sintering temperature used in this work was about 800 to $950^{\circ}C$ instead of higher sintering temperatures ($1100^{\circ}C$) that are usually deployed for membrane fabrication. Thermogravimetric (TGA) and X-Ray diffraction (XRD) analysis were carried out to evaluate the effect of temperature on various phase transformations during sintering process. The effect of sintering temperature on structural integrity of the membrane as well as pore size distribution and average pore size were evaluated using scanning electron microscopy (SEM) analysis. The average pore sizes of the membranes were increased from 0.185 to $0.332{\mu}m$ with an increase in sintering temperature from 800 to $950^{\circ}C$. However, a subsequent reduction in membrane porosity (from 34.4 to 19.6%) was observed for these membranes. Permeation experiments with both water and air were carried out to evaluate various membrane morphological parameters such as hydraulic pore diameter, hydraulic permeability, air permeance and effective porosity. Later, the membrane prepared with a sintering temperature of $950^{\circ}C$ was tested for the treatment of synthetic oily waste water to verify its real time applicability. The membrane exhibited 98.8% oil rejection efficiency and $5.36{\times}10^{-6}\;m^3/m^2.s$ permeate flux after 60 minutes of experimental run at 68.95 kPa trans-membrane pressure and 250 mg/L oil concentration. Based on retail and bulk prices of the inorganic precursors, the membrane cost was estimated to be $220 /$m^2$ and $1.53 /$m^2$, respectively.

• Applied Chemistry for Engineering
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• 제5권1호
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• pp.127-138
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• 1994

In the process of pervaporation separation for aqueous ethanol solution through cellulose tai-acetate(CTA) membrane, the modelling on the solution-diffusion permeation mechanism was built up on the basis of sorption and permeation experimental results. Also its function type and parameter were examined. The composition of sorption equilibrium in three component system(Ethanol/Water/CTA) were compared with the calculated value by Flory-Huggins' equation using the pure component sorption data. In order to apply the thermodynamic equilibrium relationship between the membrane free composition in the membrane and the equilibrium composition in the liquid phase, the apparent activity this system, however, the results were not satisfied. Diffusion equations were expressed with the concentration gradient considering permeate alone, and a concentration-dependent diffusion coefficient which includes a parameter was used. And this model was fitted with the measured permeation rates. If the permeation rate and the amount of sorption of one component were much larger than those of the other, the bulk flow term could not be negligible. The flux and selectivity were increased with increasing temperature, and with decreasing downstream pressure.

• Membrane Journal
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• 제29권6호
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• pp.314-322
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• 2019

A worsened drought in Chungnam province of Korea due to climate change and increasing water demand at Daesan industrial complex have motivated the 100,000 ㎥/d seawater desalination project. In this study, therefore, the comprehensive analysis of parameters affecting the reverse osmosis (RO) performance was conducted. Under the various conditions of feedwater salinity and temperature in Daesan, energy consumption was calculated as 2.39 ± 0.13 kWh/㎥. The decrease in membrane flux and recovery rate positively impacted annual operation cost. The average total dissolved solids (TDS) of the permeate and energy consumption with highly permeable membrane according to the membrane manufacturer were 3.84 mg/L and 2.22 ± 0.13 kWh/㎥, respectively. In addition, energy saving up to 0.29 kWh/㎥ or cost reduction of membrane module up to 15.6% is expected by changing the RO configuration from full two pass to partial or split partial two pass.

• Journal of Korea Water Resources Association
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• 제32권3호
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• pp.311-319
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• 1999

Membrane separation process is considered as an alternative of conventional water purification system using coagulationㆍsedimentation＋sand filtration. In this study, it was examined that the application possibility of Hollowfiber Microfiltration membrane for water purification process. A $20m^3/day$ scale pilot plant was used for studying the possibility of long-term operation and the stability of water quality under the optimum conditions, 0.03m/h permeate flux, filtration for 10 minutes, pause for 2 minutes(including air-scrubbing for 30 seconds), obtained by lab-scale experiment. As a result, it was proved stability of pilot plant over one year and filtrate quality(Turbidity. SS etc). Therefore, it was proved that membrane separation process using Hollowfiber Microfiltration membrane can be applied for water purification system

• Membrane Journal
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• 제28권3호
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• pp.196-204
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• 2018

The anaerobic fluidized bed bioreactor (AFBR) treating synthetic wastewater to simulate domestic sewage was operated under GAC fluidization to provide high surface area for biofilm formation. Although the AFBR achieves excellent COD removal efficiency due to biological activities, concerns are still made with nutrient such as nitrogen remaining in the effluent produced by AFBR. In this study, forward osmosis membrane was applied to treat the effluent produced by AFBR to investigate removal efficiency of total nitrogen (TN) with respect to the draw solution (DS) such as NaCl and glucose. Permeability of FO membrane increased with increasing DS concentration. About 55% of TN removal efficiency was observed with the FO membrane using 1 M of NaCl of draw solution, but almost complete TN removal efficiency was achieved with 1 M of glucose of draw solution. During 24 h of filtration, there was no permeate flux decline with the FO membrane regardless of draw solution applied.

• Membrane and Water Treatment
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• 제2권4호
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• pp.251-266
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• 2011

This work deals with the use of High Resolution Scanning Electron Microscopy (HRSEM) to verify ultrafiltration membrane selectivity at the end of the production line as well as membrane ageing. The first part of this work is focused on new membranes. It is shown that it is better to use sputtering metallization than vacuum deposition, as this latter technique entails thermal damage to the skin layer. Moreover, the impact of the metallization layer on the determination of the membrane pore size is studied and it is observed that no impact of the metallization step can be clearly defined for a metallization layer ranging from 3 to 12 nm. For example, an average pore size of 16.9 nm and a recovery rate of 6.5 % are observed for a 150 kDa cellulose acetate membrane. These results are in agreement with those given by the manufacturer: pore size ranging from 10 to 15 nm and recovery rate ranging from 5 to 10 %. The second part of this work focuses on the study of membrane ageing. A PVDF hollow fibre membrane is studied. It is shown that a 65 % decrease in the permeate flux can be linked to a decrease in the number of pores at the surface of the membrane and a decrease in the recovery rate. In conclusion, a mapping of the pores is performed for several new hollow fibre membranes used to produce drinking water, made of different materials, with different geometries and molecular weight cut-off. These results provide reference data that will help better understand the phenomena of membrane fouling and membrane ageing.

• Membrane Journal
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• 제5권2호
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• pp.74-80
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• 1995

Asymmetric poly(vinyl alcohol) (PVA) membranes were prepared by varying the precipitation conditions of the phase inversion technique, and the influences of precipitation conditions on the water uptake of the membrane were investigate. The degree of water uptake of the membrane increased and reached a certain maximum value, as the precipitation time increased. However, it decreded after that. As the precipition temperauure became lower, the degree of water uptake increased more or less. The addition of a nonionic surfactant to the precipitaon solution was effective reducing the precipitation time by lowering the surface tension of the precipitation solution, but ig didn't change the maximum value of its own degree of water uptake. In addition, the relationship between the degree of water uptake and the separation characteristics and mechanical properies of the membrane were investigated. The selectivity factor of the membrane for pervaperation separation decreased, but the permeate flux increased, respectively, with increasing the degree of water uptake. The tensile strength and elongation of the membrane, respectively, increased to a maximum value with increasing the degree of water uptake, and then decreased abtuptly.

• Membrane Journal
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• 제6권1호
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• pp.44-52
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• 1996

For the purpose of the optimal design of a frame and plate type of pervaporation module, model equations which can predict the effects of feed flow condition on the temperature distribution of the feed developed in the module were established and the temperature distribution with feed flow condition was investigated through the model si$$\mu$ation. With increasing the Reynolds number of feed flow in the module, the flow velocity gradient in the channel height-direction as well as the volume rate of feed which acts as energy source for the evaporation of perrneants on the permeate-side surface of a membrane increased to such an extent that both mass and heat flux in the channel height direction could increase and the temperature drop of feed due to the evaporation of the permeant could be reduced correspondingly. A decrease in channel height caused the temperature drop of feed because of decreasing feed flow in the module. It was observed that the si$$\mu$ation result on the effect of Re on the temperature distribution of feed in the module has an agreement with experiment.