• 한국건설순환자원학회논문집
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• 제10권4호
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• pp.569-576
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• 2022

본 연구에서는 유·무기계 자기치유재료를 기반으로 박테리아 펠렛과 고상캡슐을 각각 혼입하여 사용한 하이브리드 자기치유 콘크리트의 치유성능을 조사하였다. 치유성능 평가방법으로 정수위 투수시험을 적용하였으며, 평가지표로 치유율과 등가균열폭에 의해 산출된 치유된 균열폭을 활용하였다. 정수위 투수시험 결과 초기 균열폭이 0.3 mm일 때 MC-BP와 MC-SC의 치유율은 MC와 비교하여 2.1~3.0 %pt 높았으며, 하이브리드 콘크리트의 치유된 균열폭은 0.017~0.018 mm 증가하였다. 결론적으로, 두 가지 치유소재를 함께 사용하더라도 자기치유 성능은 크게 향상되지 않은 것으로 나타났다.

• 한국구조물진단유지관리공학회 논문집
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• 제10권1호
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• pp.123-130
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• 2006

콘크리트의 열화 및 철근부식에 대응하기 위하여 다양한 보수재료가 존재하나 이러한 보수재료를 평가하는 방법은 단순히 염해, 중성화 등의 단독열화만을 대상으로 하고 있어 여러 가지 열화인자가 복합적으로 작용하는 실제 환경과는 차이를 나타내게 된다. 따라서 본 연구에서는 폴리머시멘트계 보수용 단면복구재가 KS 기준을 만족하는지 확인한 후 복합열화 환경 하에서 염해, 중성화. 철근부식을 평가하였다. 실험결과 각각의 보수재료들은 KS 기준을 만족하였지만 내구성능은 상이하게 나타나 향후 이에 대한 고려가 필요할 것으로 사료된다.

• Geomechanics and Engineering
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• 제27권6호
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• pp.583-594
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• 2021

The gas permeability behavior of unsaturated bentonite-based materials is of major importance for ensuring effective sealing of high-level radwaste repositories. This study investigated this by taking a sample of Granular Bentonite Material (GBM) at the end of the Engineered Barrier Emplacement (EB) experiment in the Opalinus Clay, placing it under different humidity conditions until it achieved equilibration, and testing the change in the gas permeability under loading and unloading. Environmental humidity is shown to have a significant effect on the water content, saturation, porosity and dry density of GBM and to affect its gas permeability. Higher sensitivity to confining pressure is exhibited by samples equilibrated at higher relative humidity (RH). It should be noted that for the sample at RH=98%, when the confining pressure is raised from 1 MPa to 6 MPa, gas permeability can be reduced from 10^-16 m² to 10^-19 m², which is close to the requirements of gas tightness. Due to higher water content and easier compressibility, samples equilibrated under higher RH show greater irreversibility during the loading and unloading process. The effective gas permeability of highly saturated samples can be increased by 2-3 orders of magnitude after 105℃ drying. In addition, cracks possibly occurred during the dehydration and drying process will become the main channel for gas migration, which will greatly affect the sealing performance of GBM.

• Tribology and Lubricants
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• 제39권5호
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• pp.197-202
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• 2023

Recently, research on experimental and analytical techniques utilizing microfluidic devices has been pursued. For example, lab-on-a-chip devices that integrate micro-devices onto a single chip for processing small sample quantities have gained significant attention. However, during sample preparation, unnecessary gases can be introduced into the internal channels, thus, impeding device flow and compromising specific function efficiency, including that of analysis and separation. Several methods have been proposed to mitigate this issue, however, many involve cumbersome procedures or suffer from complexities owing to intricate structures. Recently, some approaches have been introduced that utilize hydrophobic device structures to remove gases within channels. In such cases, the permeability of gases passing through the structure becomes a crucial performance factor. In this study, a method involving the deposition and sintering of diluted Ag-ink onto a silicon wafer surface is presented. This is followed by unstructured nano-pattern creation using a Metal Assisted Chemical Etching (MACE) process, which yields a nanostructured surface with unstructured pillar shapes. Subsequently, gas permeability in the spaces formed by these surface structures is investigated. This is achieved by experiments conducted to incorporate a pressure chamber and measure gas permeability. Trends are subsequently analyzed by comparing the results with existing theories. Finally, it can be confirmed that the significance of this study primarily lies in its capability to effectively evaluate gas permeability through unstructured pillar-like nanostructures, thus, providing quantitative values for the appropriate driving pressure and expected gas removal time in practical device operation.

• Food Science and Biotechnology
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• 제17권3호
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• pp.675-678
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• 2008

Permeability of resveratrol, piceid, rhapontigenin, and rhaponticin in Caco-2 cell assays using high-performance liquid chromatography were compared. Caco-2 cell monolayers were used to evaluate the transport rates of stilbene analogues from the apical to the basolateral sides. All stilbenes experimented in this study were transported to the basolateral side by times. For comparing the permeability of 4 stilbenes, we calculated the slope of the cumulative concentration of each stilbene in basolateral sides over time, resulting in those values of resveratrol, piceid, rhapontigenin, and rhaponticin with $3.766{\times}10^{-5}$, $4.330{\times}10^{-6}$, $5.430{\times}10^{-5}$, and $2.458{\times}10^{-5}\;{\mu}M/sec$, respectively. Apparent permeability coefficient of resveratrol and rhapontigenin were calculated to $9.994{\times}10^{-6}$ and $1.441{\times}10^{-6}\;cm/sec$, respectively, while those of piceid and rhaponticin were to $1.149{\times}10^{-7}$ and $6.523{\times}10^{-7}\;cm/sec$, respectively. These results suggest that aglycones would be absorbed more effectively than glycosides in stilbenoids.

• Advances in concrete construction
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• 제2권3호
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• pp.193-207
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• 2014

The study presented herein aims to investigate the durability related properties of rubberized concrete. Two types of waste scrap tire rubber were used as fine and coarse aggregate, respectively. The rubber was replaced with aggregate by three crumb rubber and tire chips levels of 5, 15, and 25% for the rubberized concrete productions. In order to improve the transport properties and corrosion resistance of rubberized concretes, SF was replaced with cement at 10% replacement level by weight of total binder content. The transport properties of the rubberized concretes were investigated through water absorption, gas permeability, and water permeability tests. The corrosion behavior of reinforcing bars embedded in plain and silica fume based rubberized concretes was investigated by linear polarization resistance (LPR) test. The results indicated that the utilization of SF in the rubberized concrete production enhanced the corrosion behavior and decreased corrosion current density values. Moreover, the reduction in the water and gas permeability coefficients was observed by the incorporation of SF in plain and especially rubberized concretes.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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• pp.355-360
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• 2002

The purpose of this study was to remove the excessive air foaming which was produced in mixing the RSLMC(latex-modified concrete with rapid- setting cement) by choosing the best antifoam agent type and the optimized quantity for performance improved RSLMC. A series of RSLMM(latex-modified mortar with rapid-setting cement) experiments were carried out as the basic for RSLMC with the main experimental variables such as antifiamer types(A, B, C, D), antifoamer contents(0, 1, 2, 3%). Air content test and compressive, flexural tests were carried out to measure the improved properties of RSLMM and RSLMC. Chloride ion permeability test was carried out to estimate water permeability resistance. The results of RSLMM showed that the decrease of 50% air content was obtained by admixturing a antifoam agent by 1%. The compressive strength and flexural strength at 3 hours after RSLMC placement were 235kgf/cm$^2$ and 49kgf/cm$^2$, respectively, which exceeded the flexural strength criterion of 45kgf/cm$^2$ in order to open the RSLMC placed to traffic. The chloride permeability using A and C antifoamer at 28 days were below 100 coulombs, which was the permeability rating of negligible according to ASTM.

• Computers and Concrete
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• 제14권2호
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• pp.175-191
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• 2014

In recent years, the emergence of nanotechnology and nanomaterial has created hopes to improve various properties of concrete. Nano silica as one of these materials has been introduced as a cement replacement material for concrete mixture in construction applications. It can modify the properties of concrete, due to high pozzolanic reactions and also making a denser microstructure. On the other hand, it is well recognized that the use of mineral admixtures such as silica fume affects the mechanical properties and durability of cementitious materials. In addition, the superior performance of self-consolidating concrete (SCC) and self-consolidating mortars (SCM) over conventional concrete is generally related to their ingredients. This study investigates the effect of nano silica and silica fume on the compressive strength and chloride permeability of self-consolidating mortars. Tests include compressive strength, rapid chloride permeability test, water permeability, capillary water absorption, and surface electrical resistance, which carried out on twenty mortar mixtures containing zero to 6 percent of nano silica and silica fume. Results show that SCMs incorporating nano silica had higher compressive strength at various ages. In addition, results show that nano silica has enhanced the durability SCMs and reduced the chloride permeability.

• Elastomers and Composites
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• 제33권1호
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• pp.37-43
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• 1998

The permeation of gas through polymer membrane at temperatures above its glass transition, generally occurs by a solution-diffusion mechanism. This mechanism is performed by the affinity difference between polymeric materials and gas molecules, and various technologies, such as copolymerization, impregnation and so on, have been researched to improve the affinity of polymeric material for the gases. In this study, permeability and selectivity for some gases were obtained from steady-state rates of gas permeation through silicone rubber membrane which is prepared by supercritical fluid extraction method. The permeability was measured by the volumetric method proposed by Barrer. Permeability was increased generally with temperature and permeation pressure. Silicone rubber membrane shows a higher permeability to $CO_2$ than to $O_2$, $N_2$. This results probably reflect the relatively high solubility of CO_2 in silicone rubber membrane, which is due to the affinity of $CO_2$ molecules. Since separation powers of $CO_2/N_2$, $CO_2/O_2$ were more than 200, and 100, respectively, it is able to separate $CO_2$ from the air, and the optimum temperature and pres-sure was 328.15 K, 60 cmHg respectively. In future, it is possible that the silicone rubber membrane can be used for separation or concentration of $CO_2$ through experiment for mixed gas separation.

• 멤브레인
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• 제29권4호
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• pp.191-201
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• 2019

산업 응용에 적용할 수 있는 중합체 막의 상용화 전에, 고성능 중합체가 실질적인 도전, 즉 연장된 서비스 시간에 대한 장기 안정성을 극복해야하는 과제가 남아있다. 매우 높은 분수 자유 부피(fractional free volume) 및 높은 투과성을 나타내는 고유한 미세 다공성 중합체(polymers of intrinsic microporosity)는 비효율적 무작위 패킹에 의해 생성된 여분의 부피가 물질의 부피적 평형에서 멀어짐과 동시에, 다시 부피적 평형 상태로 복귀하려는 특성, 즉 자유 부피를 줄여가는 특정으로 인해 투과성을 감소시키는 물리적 노화에 영향을 받기 쉽다. 본 논문에서 우리는 미세 다공성 고분자의 물리적 노화를 재검토하고 PIM에서 물리적 노화를 완화하려는 가장 두드러진 시도 중 일부를 논의할 것이다.