• Title/Summary/Keyword: Permeability, ${\mu}$

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Temperature Dependence of Self-Diffusion of THO in Copolymer Hydrogel Membrane as a Function of Gel Compositions

  • Soon Hong Yuk;Sang Il Jeon;Mu Shik Jhon
    • Bulletin of the Korean Chemical Society
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    • v.5 no.3
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    • pp.104-108
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    • 1984
  • The self-diffusion experiment of THO was performed across a series of copolymer hydrogel membranes at different temperatures. Copolymer hydrogel membranes were prepared by copolymerizing 2-hydroxyethyl methacrylate (HEMA) and 2-aminoethyl methacrylate (AEMA) in the presence of the solvent and the crosslinker, ethylene glycol dimethacrylate (EGDMA). By changing the crosslinker content and the ratio of HEMA and AEMA monomer, two series of copolymer hydrogel membranes were synthesized. The tagging material was THO and efflux of THO was counted on a Liquid Sc-intillation Counter. The experimental data show that the permeability decreases as the amount of EGDMA and the mole fraction of HEMA increase, and the permeability is proportional to the temperature. The partition coefficient shows a parallel trend with permeability. Using the relationship between viscosity and diffusivity, the viscosity of water within the membrane was obtained. According to the result, the viscosity of watler within the membrane has the same value with those of supercooling water. And we obtained the activation energy of THO for transport in the membrane by using Arrhenius plotting.

The Magnetic Properties of Nanocrystalline Fe73.5Cu1Nb3Si15.5B7 Alloy Powder Cores (Fe73.5Cu1Nb3Si15.5B7나노 결정립 합금 분말 코아의 자기적 특성)

  • Noh, T.H.;Choi, H.Y.;Ahn, S.J.
    • Journal of the Korean Magnetics Society
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    • v.14 no.1
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    • pp.7-12
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    • 2004
  • The annealing-temperature dependence of magnetic properties in compressed powder cores being composed of ball-milled F $e_{73.5}$C $u_1$N $b_3$S $i_{15.5}$ $B_{7}$ alloy powders (size 250∼850${\mu}{\textrm}{m}$) and 5 wt% of ceramic insulators has been investigated. When annealed at 5$50^{\circ}C$ for 1 h and so transformed to $\alpha$-Fe phase nanocrystalline structure with the grain size of 11 nm (electrical resistivity : 110 $\mu$$.$cm), the highest effective permeability of 125 and quality factor of 53 were obtained, and the permeability persisted up to about 500 KHz. Further the core loss measured at the frequency of 50 KHz and the induction amplitude of 0.1 T was very low (230 mW/㎤). However the dc bias characteristics was not satisfactory as compared to that of conventional powder core materials(MPP, Sendust etc.). The inferior dc bias property of F $e_{73.5}$C $u_1$N $b_3$S $i_{15.5}$ $B_{7}$ alloy powder cores was attributed to the fact that the size of powder was too large for obtaining the same permeability with that of conventional materials.

Effects by Variation of Raw Materials on Physical Properties of Ni-Zn Ferrite (원료 변화에 따른 Ni-Zn Ferrite의 물리적 특성에 미치는 영향)

  • Koh, Jae-Gui
    • Korean Journal of Materials Research
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    • v.16 no.9
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    • pp.578-583
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    • 2006
  • We studied the physical properties of Ni-Zn ferrites by adding different chemicals such as $SO_4$, Cl, and $NO_3$. Specimens were prepared by the coprecipitation method and sintered at temperatures $950^{\circ}C,\;1,150^{\circ}C,\;and\;1,350^{\circ}C$, respectively. X-ray diffractions showed a spinel structure and the optical microscopy revealed grain size of 0.3 to 0.6 ${\mu}m$. The optimum sintering temperature to obtain fine, sintered microstructure depended on the additive : Cl and $NO_3\;at\;950^{\circ}C\;and\;SO_4\;at\;1,150^{\circ}C$. According to particle size analysis, higher magnetic permeability and magnetization value were observed with Cl and $NO_3\;than\;SO_4$. As sintering temperature was raised from $950^{\circ}C$ to $1,350^{\circ}C$, the average grain diameter, initial permeability and the magnetic moment also increased.

Magnetic properties of high silicon steel processed by powder metallurgy (분말야금 공정에 의한 고규소강의 자성특성)

  • Yim, Tai-Hong;Chung, Hyung-Sik;Kang, Won-Koo;Chung, Young-Ho
    • Proceedings of the KIEE Conference
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    • 1990.07a
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    • pp.231-235
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    • 1990
  • Soft magnetic silicon steels containing up to 6.5wt% of silicon were prepared by powder metallurgical processing and their magnetic properties were evaluated. The magnetic properties of P/M silicon steels are similarly affected by the silicon addition as those of conventional ingot processed ones but are also significantly affected by density and interstitial impurities particularly oxygen content. Magnetic flux density, $B_{10}$ and coercivity, Hc, tends to decrease with silicon content whereas maximum permeability, ${\mu}m$, decreases first and then increases rapidly above 5 wt% silicon. Increasing density also increases magnetic flux density and maximum permeability but reduces coereivity. The latter two properties are, however, affected more strongly with oxygen content.

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Transdermal Delivery of Piroxicam Using Microemulsions

  • Park Eun-Seak;Cui Yu;Yun Bum-Jin;Ko In-Ja;Chi Sang-Cheol
    • Archives of Pharmacal Research
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    • v.28 no.2
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    • pp.243-248
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    • 2005
  • To improve the skin permeability of piroxicam, a new oil-in-water microemulsion containing $0.5\%$ piroxicam was developed. Among various oils investigated for their suitability as an oil phase for the microemulsion system, oleic acid showed both excellent solubility and skin permeation enhancing effect for piroxicam. Microemulsion existence ranges were identified through the construction of the pseudo-ternary phase diagram. The effect of the content of oleic acid and the ratio of the surfactant/cosurfactant on skin permeation of piroxicam were evaluated with excised rat skins. The optimum formulation with the highest skin permeation rate ($47.14\;{\mu}g/cm^2/h$) consisted of $0.5\%$ piroxicam, $10\%$ oleic acid, $60\%$ Labrasol/ethanol (1:5) and water.

The Effects of Non-Stoichiometry and Sintering Temperature on the Magnetic Properties of Ni-Zn Ferrites (비양론 화학적 조성 및 소결온도가 Ni-Zn Ferrite 의 자기적 성질에 미치는 영향)

  • 박준철;임호빈
    • Journal of the Korean Ceramic Society
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    • v.17 no.2
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    • pp.89-95
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    • 1980
  • The effect of non-stoichimetry and sintering temperature on the magnetic properties of materials in the system $Ni_{0.39}Zn_{0.61}Fe_{2.0+x}O_4$ have been investigated. The value of x used in initial weighing of oxides were varied from -0.04 to -0.12. The value of x, however, appears to be from +0.04 to -0.04 after ferrite powder preparation due to iron pick up during ball mill mixing and grinding. The densities of specimens which were deficientinrion were higher than those with excess ion. Specimens with near stoichiometric composition showed maximum initial permeability an dminimum coercivity whereas high values of quality factor (Q) were observed in iron deficient specimens. The quality factor decreased monotonically with increasing sintering temperature, but the permeability showed maxima with increasing sintering temperature. Thus highest value of figure of merit $\mu$Q was obtained in composition $Ni_{0.39}Zn_{0.61}Fe_{1.98O4}$ sintered at 100$0^{\circ}C$ for 3 hrs. in an air atmosphere.

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The estimation on the insulation performance of thermal insulation materials according to water vapor permeance (투습성에 따른 단열재의 단열성능평가 및 고찰)

  • Kim, Seok-Hyun;Park, Jong-Il;Lee, Min-Woo;Hong, Jin-Kwan
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.1012-1018
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    • 2006
  • In this study, the insulation performance of thermal insulation materials such as glass wool, polyetylene and flexible lastomeric foam according to water vapor permeance was estimated by using experimental correlation equation. The results showed the conductivity increment of flexible lastomeric foam which has very low-permeability (${\le}0.15[ng/{\cdot}s{\cdot}Pa]\;or\;{\mu}{\ge}1,000$) is about 50% lower than that of glass wool with the lapse of ten years. The conclusion is that moisture inevitably accumulated in permeable Insulations reduces insulation performance and also accelerates surface condensation in the case of cold water system.

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The Shielding of Magnetic field of 765kV transmission line by use of ${\mu}$-metal (${\mu}$-metal을 이용한 765kV 송전선의 자계 차폐에 관한 연구)

  • Lee, Seung-Chul;Chang, Yong-Moo;Lee, Bang-Wook;Kim, Jung-Han;Koo, Ja-Yoon
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1328-1329
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    • 2008
  • 2000년 대 이후 송전선의 상태 및 송전선 주변 환경을 감시하기 위한 각종 센서들을 하나의 시스템으로 통합하여 실 선로에 적용하는 연구가 활발히 진행되고 있으며, 국내에서도 최근 765kV급 송전선을 감시하기 위한 통합 센서 시스템 개발을 진행 중에 있다. 이를 위해서는 송전선로에서 발생되는 자계로부터 센서 통합 시스템을 보호하기 위한 자계 차폐에 대한 연구가 선행되어야 한다. 따라서 본 논문에서는 상용 주파수에서 약 80,000[H/m]이상의 투자율(${\mu}_r$ : relative permeability)를 갖는 강자성체인 ${\mu}$-metal을 사용하여 765kV급 송전선 (2,000A/single phase)에 대한 차폐율을 연구하였고, 이를 위해 ${\mu}$-metal의 차폐율을 검증할 수 있는 magnetic probe를 자체 설계 제작하였다. 그 결과 magnetic probe에 의해 측정된 자계의 크기 및 분포를 통해 ${\mu}$-metal의 layer의 개수에 따라 변화하는 자계 차폐율을 분석할 수 있었다.

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Development of Nano Ceramic Filter for the Removal of Ultra Fine Particles (초미세입자 제거를 위한 고온용 나노 세라믹 필터 개발)

  • Kim, Jong-Won;Ahn, Young-Chull;Yi, Byeong-Kwon;Jeong, Hyeon-Jae
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.22 no.1
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    • pp.13-20
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    • 2010
  • Airborne particulate matters have two modes of size distributions of coarse mode and fine mode. The coarse mode which is formed by break down mechanism of large particles has a peak around the $100\;{\mu}m$, and the fine mode formed by condensation and build up mechanism of evaporated vapors has a peak at several ${\mu}m$. The coarse mode particles can be removed easily by conventional collecting equipments such as a cyclone, an electrostatic precipitator, and a filter, however the fine mode particles can not be collected easily. Usually the fine mode particles are generated in the high temperature conditions especially through boilers and incinerators, so the high efficient and temperature filter is essential for the filtration. In this study, a nano ceramic filter for the removal of fine particles in the high temperature is developed and tested for several characteristics. The nano ceramic filter has double layer of micro and nano structure and the pressure drop and the filtration efficiency for $0.31\;{\mu}m$ at 3 cm/s are 15.45 mmAq, and 96.75%, respectively. The thermal conductivity is $0.038\;W/m{\cdot}K$, and the coefficient of water vapor permeability is $3.63\;g/m^2{\cdot}h{\cdot}mmHg$. It is considered that the sensible heat exchange rate is very poor because the low thermal conductivity but it has high potential to exchange latent heat.

Percutaneous absorption for Rat about Thioglycolic Acid Salt In vitro (In vitro에서 티오글리콜산염에 대한 흰쥐의 경피 흡수)

  • Kim, Jong-Man;Oh, Eun-Ha;Yoo, Hyun-Oh
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.2
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    • pp.103-109
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    • 2009
  • Chemicals for cosmetics, including skin, the skin absorbs some of the research in the field of science or pharmacy recently, about the environment and the health of the heightened interest in skin absorption. Many other human attributes and absorption evaluation studies are underway in various areas. This study were used rats and carried out to find out the effects of commercial permanent wave products to skin which are composed with thioglycolic acid and bases. Results were as follows. Permanent wave penetrated to 3 hours later with steady state in skins and was not significant changeable after 20hr later. In case of neutralizer with thioglycolic acid lag time and permeability coefficient in healthy skin were 3.32hr and $0.101{\mu}g/cm^2/hr$, in old skin were 3.08hr and $0.117{\mu}g/cm^2/hr$, and in wounded skin were 3.02hr and $0.166{\mu}g/cm^2/hr$. In conclusion, lag time and permeability coefficient in old skin and wounded skin were faster than healthy skin. In vivo, We were studied to general time and method of permanent wave. We found out that fine wrinkle and rash of skin were changeable in the case of treating with permanent wave drugs than normal skin.