• Title/Summary/Keyword: Performance recovery

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Analysis of Crushing/Classification Process for Recovery of Black Mass from Li-ion Battery and Mathematical Modeling of Mixed Materials (폐배터리 블랙 매스(black mass) 회수를 위한 파쇄/분급 공정 분석 및 2종 혼합물의 수학적 분쇄 모델링)

  • Kwanho Kim;Hoon Lee
    • Resources Recycling
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    • v.31 no.6
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    • pp.81-91
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    • 2022
  • The use of lithium-ion batteries increases significantly with the rapid spread of electronic devices and electric vehicle and thereby an increase in the amount of waste batteries is expected in the near future. Therefore, studies are continuously being conducted to recover various resources of cathode active material (Ni, Co, Mn, Li) from waste battery. In order to recover the cathode active material, black mass is generally recovered from waste battery. The general process of recovering black mass is a waste battery collection - discharge - dismantling - crushing - classification process. This study focus on the crushing/classification process among the processes. Specifically, the particle size distribution of various samples at each crushing/classification step were evaluated, and the particle shape of each particle fraction was analyzed with a microscope and SEM (Scanning Electron Microscopy)-EDS(Energy Dispersive Spectrometer). As a result, among the black mass particle, fine particle less than 74 ㎛ was the mixture of cathode and anode active material which are properly liberated from the current metals. However, coarse particle larger than 100 ㎛ was present in a form in which the current metal and active material were combined. In addition, this study developed a PBM(Population Balance Model) system that can simulate two-species mixture sample with two different crushing properties. Using developed model, the breakage parameters of two species was derived and predictive performance of breakage distribution was verified.

The Development of Tidal Power System Can be Installed in Existing Dykes - The Open Channel Experimental Verification (기존 방조제에 설치 가능한 조력발전 장치 개발 - 개수로 현장실험 검증)

  • HyukJin Choi;Dong-Hui Ko;Nam-Sun Oh;Shin Taek Jeong
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.35 no.1
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    • pp.13-21
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    • 2023
  • As problems such as difficulties in securing stable energy resources and global warming due to the emission of greenhouse gases due to the use of fossil fuels have emerged, interest in the development of renewable energy is increasing. Since the tidal phenomenon has a regularity that occurs regularly with a certain period, it is possible to predict accurately in advance, which has a advantage in terms of energy recovery. Therefore, various methods have been devised to utilize the tide as an energy source. Tidal power using barrages is a representative method that is widely operated, but the promotion of tidal power generation projects is being delayed or stopped due to the decrease in the level of water in the tidal basin, changes in water quality and in the ecosystem. In this study, a field experiment was conducted to develop and verify the performance of a tidal power device applicable to sea areas where dykes are already installed. As a result of carrying out four cases of experiments using two water tanks, pipe lines, open channels, weirs, and water turbine and generator, the possibility of developing a power generation system capable of 10 kW output or more and 60% efficiency or more was confirmed. These research results can be used for small-scale tidal power by utilizing the existing dykes.

Determination of residual novobiocin in livestock products and fisheries products by HPLC (HPLC를 이용한 축·수산 식품 중 잔류 노보비오신의 분석)

  • Lee, Byung Kyu;Lee, Cheol-Woo;Lee, Sang-Ju;Jung, Eun Ha;Lim, Hyun Kyun;Han, Sang Beom
    • Analytical Science and Technology
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    • v.20 no.4
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    • pp.347-354
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    • 2007
  • A simple and rapid high-performance liquid chromatography assay for the determination of residual novobiocin levels in bovine, porcine, chicken, flatfish and japanese eel muscle has been developed and validated. The separation condition for HPLC/UV was optimized with phenyl hexyl ($4.6{\times}150mm$, $5{\mu}m$) column with 10 mM monobasic sodium phosphate buffer (pH 2.5)/acetonitrile (50/50, v/v) as the mobile phase at a flow rate of 1.0 mL/min and detection wavelength was set at 254 nm. Residues were extracted from tissue by blending with methanol and lipid materials were removed with n-hexane. Then, the methanol extract was evaporated to dryness under a nitrogen stream, reconstituted in the mobile phase. Aliquot of the organic extract was decanted and filtered through $0.45{\mu}m$ syringe filter. The $20{\mu}L$ of the resulting solution was injected into the HPLC system. The calibration ranges were $0.5{\sim}5{\mu}g/g$ and calibration curves were linear with coefficients of correlation better than 0.95. The limits of quantification were $0.5{\mu}g/g$ for all muscles. The recoveries of bovine, porcine, chicken, flatfish and japaneseel muscles were 99.8%, 102.4%, 91.0%, 104.0% and 93.0%, respectively. The procedures were validated according to the CODEX guideline, determining specificity, linearity, accuracy, precision, quantitation limit and recovery.

Analysis of mercury and methylmercury in river sediment samples (하천퇴적물 중의 수은 및 메틸수은 분석 연구)

  • Lee, Jung-Sub;Park, Jae-Sung;Kang, Hak-Gu;Cho, Jae-Seok;Hong, Eun-Jin;Jeong, Gi-Taeg;Cha, Jun-Seok;Jung, Kwang-Yong;Kim, Young-Hee
    • Analytical Science and Technology
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    • v.22 no.1
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    • pp.44-50
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    • 2009
  • In this study, the use of purge & trap GC-MS technique for determination of methylmercury in sediment samples was described. The method detection limit of the method was determined as 0.06 ng/g and the recovery of the method was $102{\pm}11.4%$, with precisions better than 11.2%. The method was validated by analysis of CRMs such as ERM CC580 (estuarine sediment) and IAEA 405 (sediment). Additionally, the performance of the method was tested on river sediment samples and the analytical results were compared with those of the GC-CVAFS, which has been widely used for methylmercury analysis.

Effect of L-carnitine on Field Potential and ATP-dependent K+ Channel of Rat Cardiac Muscles (L-carnitine 투여가 흰쥐의 심근 Field Potential과 ATP-dependent K+ channel에 미치는 영향)

  • Kim, Jee-Youn;Sim, Young-Je;Chang, Hyun-Kyung;Kim, Chang-Ju
    • Korean Journal of Exercise Nutrition
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    • v.13 no.1
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    • pp.15-21
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    • 2009
  • Ergogenic aids are substances, devices, and practices that enhance an individual's energy use and production, and recovery from fatigue. L-carnitine increases enhance performance and aerobic capacity by stimulating lipid oxidation in muscle cells during long term exercise. L-carnitine is a well known and widely used ergogenic aid. In the present study, the effect of L-carnitine at concentrations of 100 nM, 1 μM, 10 μM, and 100 μM on the amplitude of field potential in rat cardiac muscle slices was measured using multi-channel extracellular recording (MED 64) system. In the present result, L-carnitine was shown to enhance field potential as a does-dependent manner. The increasing effect of the L-carnitine on field potential was not affected by application of the glibenclamide, an ATP-dependant K+ channel antagonist. The increasing effect of L-carnitine on field potential was suppressed by application of the diazoxide, an ATP-dependent K+ channel agonist. Present data show that L-carnitine potentiates field potentials by inhibition on ATP-dependant K+ channel in cardiac muscles. The enhancing effect of the L-carnitine on the field potential in cardiac muscles can be suggested as one of the underlying mechanism of ergogenic aid of the L-carnitine.

Mapping Burned Forests Using a k-Nearest Neighbors Classifier in Complex Land Cover (k-Nearest Neighbors 분류기를 이용한 복합 지표 산불피해 영역 탐지)

  • Lee, Hanna ;Yun, Konghyun;Kim, Gihong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.43 no.6
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    • pp.883-896
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    • 2023
  • As human activities in Korea are spread throughout the mountains, forest fires often affect residential areas, infrastructure, and other facilities. Hence, it is necessary to detect fire-damaged areas quickly to enable support and recovery. Remote sensing is the most efficient tool for this purpose. Fire damage detection experiments were conducted on the east coast of Korea. Because this area comprises a mixture of forest and artificial land cover, data with low resolution are not suitable. We used Sentinel-2 multispectral instrument (MSI) data, which provide adequate temporal and spatial resolution, and the k-nearest neighbor (kNN) algorithm in this study. Six bands of Sentinel-2 MSI and two indices of normalized difference vegetation index (NDVI) and normalized burn ratio (NBR) were used as features for kNN classification. The kNN classifier was trained using 2,000 randomly selected samples in the fire-damaged and undamaged areas. Outliers were removed and a forest type map was used to improve classification performance. Numerous experiments for various neighbors for kNN and feature combinations have been conducted using bi-temporal and uni-temporal approaches. The bi-temporal classification performed better than the uni-temporal classification. However, the uni-temporal classification was able to detect severely damaged areas.

Key Elements for Standardizing the Estimation of Greenhouse Gas Emissions Reduction Induced by Remanufactured Products (재제조품의 온실가스배출 저감효과 산정 표준화를 위한 핵심 요소 도출)

  • Nam Seok Kim;Kook Pyo Pae;Jae Hak No;Hong-Yoon Kang;Yong Woo Hwang
    • Resources Recycling
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    • v.33 no.2
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    • pp.62-72
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    • 2024
  • Although the Paris Agreement in 2015 aimed to limit global temperature increases to below 2℃ and eventually to 1.5℃ to address the climate crisis, global temperature continues to rise. Developed countries have proposed a circular economy as a major strategy to tackle this issue. Detailed implementation methods include reusing, remanufacturing, recycling, and energy recovery. Remanufacturing has a greater potential to achieve high added value and carbon neutrality than other resource circulation methods. However, currently, no standardized method for quantitatively evaluating the greenhouse gas (GHG) reduction effects of remanufacturing exists. This study compares and analyzes recent research trends since 2020 on the calculation of GHG emission reduction effects from remanufacturing. It also examines international standards for environmental impact assessment, including GHGs and environmental performance labeling systems. This study derives the key factors for standardizing the calculation of the GHG emission reduction effects of remanufactured products.

Anaerobic digestion for food wastewater using HADS Pilot Plant and analysis of microbial community in the digester (HADS Pilot Plant를 이용한 음폐수의 혐기성 소화 및 미생물 군집 변화 분석)

  • Ju, Dong-Hun;Lee, Jung-Min;Park, Seong-Bum;Sung, Hyun-Je;Bae, Jae-Sang;Sang, Byoung-In
    • Journal of the Korea Organic Resources Recycling Association
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    • v.18 no.2
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    • pp.76-83
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    • 2010
  • We(Hansol EME Co. Ltd.) proceeded anaerobic digestion test for domestic food wastewater applying to two operating method for increasing of OLR. The methods are as follows. One was the rapidity operating method which was increasing the OLR continuously and rapidly and the other was the terraced operating method which was increasing the OLR having adaptation period for each step. As a result of this tests, the ratio of VFA/Alkalinity of the process was very unstable under the rapidity operating method then the volume of produced biogas was dramatically decreased. However the process was shown stable performance under the terraced operating method maintaining the ratio of VFA/Alkalinity less than 0.4. Also, the process was performing the biogas recovery of $0.8Nm^3/kgVS_{rem}/d$ and the VS removal ratio of 85%. T-RFLP analysis about the community of bacteria and methanogen is also conducted to check the change of the microbial community according to the methods of OLR increasing operation. The microbial community was changed by the methods of OLR increasing operation according to the result of T-RFLP analysis. Although the anaerobic digestion test was executed by same pilot plant, the reactivity and the tolerance of microbial community for surrounding environment could be considerably changed by the operating method for the process.

Impact of the Opening Policy of China's A-Share Market on the Stock Market (중국 A주 시장의 대외개방이 주가에 미친 영향)

  • Furong Jin;Shanji Xin
    • The Journal of the Convergence on Culture Technology
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    • v.10 no.4
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    • pp.711-719
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    • 2024
  • This study examined the policy of opening up the Chinese A-share market and its performance in four aspects: institutional investors system, cross-trading system with overseas stock markets, inclusion of A-shares into global indices, and establishment of a new board. Then, the impact of these policies on the Stock Index was empirically analyzed, and it was confirmed that institutional investors system such as QFII and RQFII, cross-trading system with overseas stock markets such as Shanghai-Hong Kong Stock Connect and Shenzhen-Hong Kong Stock Connect, inclusion of A-shares into global indices such as the MSCI EM index and FTSE Russell index, and the establishment of a new board of the Science Innovation Board all had statistically significant positive impacts on the stock index. Based on the results of these analysis, we conclude that China should further expand its stock market opening to the outside world, that mutual efforts are needed to alleviate political conflicts and improve understanding, and that easing industry regulations, including real estate, will help China's economic recovery and foreigners' investment in the A-share market.

Development of Simultaneous Analysis Method for Dimenhydrinate Containing Complex Pharmaceuticals Using RP-HPLC (고성능 역상 액체 크로마토그래피(RP-HPLC)를 이용한 Dimenhydrinate 함유 복합제제의 동시분석법 개발)

  • Keun-Sik Shin;Jin-Young Park;Jae-Ho Sim
    • The Journal of the Convergence on Culture Technology
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    • v.10 no.5
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    • pp.775-780
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    • 2024
  • In this study, a simultaneous analysis method was developed using reversed-phase high-performance liquid chromatography(RP-HPLC) for the main components of motion sickness medication: Dimenhydrinate, Caffeine, Methyl Paraben, and Propyl Paraben. The analysis was conducted after pretreating the four components, utilizing a C18 column with Acetonitrile and H2O as the mobile phase. UV detection was carried out at a wavelength of 254nm. As a result of the experiment, the values of Resolution(Rs) was well over Rs > 1.5, which indicates that the separation of the four components was efficient. Additionally, the symmetry factor of the components was 0.989, 1.120, 1.256, and 1.280, respectively, showing their symmetrical stability. In the stability assessment, the calibration curves for the four components showed excellent linearity with R2 > 0.9991 to 0.9998. Furthermore, the limit of detection(LOD) ranged between 0.017 to 3.060㎍/ml, while the limit of quantification(LOQ) ranged between 0.050 to 9.180 ㎍/ml. The recovery rates range from 98.28% to 101.71%, and repeatability showed precision within the range of 0.447 to 0.550, and robustness confirmed values with %RSD < 2. The quantitative analysis results of this study demonstrated the effectiveness of a simultaneous analysis method for motion sickness medication components.