• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2011년도 제37회 추계학술대회논문집
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• pp.400-403
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• 2011

직경 22 mm 정도의 케이블 절단을 위한 케이블커터의 화약량 예측을 위하여 인스트론을 사용한 정적 절단 시험과 Impact test machine을 이용한 낙하충격 시험을 실시하였다. 인스트론 시험 결과 케이블 절단에 필요한 에너지는 21.3 J로 측정되었다. Impact test는 5종류의 에너지 레벨에서 각각 8번씩 시험하였다. Impact test 시험 결과를 Probit 방법으로 분석한 결과, 99% 신뢰도에서 99.99% 절단하는 에너지는 37.7 J 로 예측되었다. 이 에너지는 ZPP 230 mg 이면 발생 가능할 것으로 판단 된다.

• 대한화학회지
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• 제27권1호
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• pp.24-30
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• 1983

반양성자성 용매인 아세토니트릴 중에서 1-(2-pyridylazo)-2-naphthol (PAN)의 폴라로그래프법적 거동을 조사하였다. $10^{-2}$몰농도의 과염소산 테트라에틸암모늄 아세토니트릴 용액에서 PAN은 1전자 2단계의 환원과정을 거쳐 hydrazo화합물이 되었다. 각 환원파는 확산지배적이었고 가역성도 비교적 좋았다. 아세토니트릴에서 PAN의 환원반응 메카니즘은 아래와 같이 결론지을 수 있다.

• Bulletin of the Korean Chemical Society
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• 제26권9호
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• pp.1335-1338
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• 2005

Thianthrene cation radical perchlorate ($Th^{+{{\cdot}}}{ClO_4}^-$) reacted readily with two isomeric thiols, benzylthiol (1) and 4-methylbenzenethiol (7) in an acetonitrile solution at room temperature. From the reaction of 1, the major products, N-benzylacetamide (4) and benzyl sulfide (5), are characteristic of benzyl carbocations while the minor one, benzyl disulfide (6) implies free radical component of the reaction. It is unprecedented that the formation of a benzyl carbocation was caused by the extrusion of sulfur atoms from benzyl sulfur cations (3). In contrast, from the reaction of 7, only p-tolyl disulfide (10) was obtained from both sulfur radicals and cations. In the reaction of 7 the thio-extrusion was not observed from the p-tolyl sulfur cation (9). A thianthrene cation radical ($Th^{+{{\cdot}}}$) was reduced quantitatively to thianthrene (Th) in both reactions.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2009년도 제33회 추계학술대회논문집
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• pp.207-210
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• 2009

고체 로켓 추진제로 널리 사용되는 물질은 AP/HTPB 복합추진제이다. 고체 로켓 주위에 열 하중이 가해진다면(화재 등) 추진제가 발화할 수 있고, 사고의 원인이 된다. 본 연구에서는 AP/HTPB 복합추진제의 주위에 열 하중을 가함으로써 AP/HTPB의 발화특성을 확인해 보았다.

• Bulletin of the Korean Chemical Society
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• 제28권3호
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• pp.417-420
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• 2007

Mononuclear mixed-anions Mn complex of TPAMn(η2-NO3)(η-ClO4), where TPA is tris(2-pyridylmethyl)-amine, has been synthesized and characterized. The neutral TPAMn(η2-NO3)(η-ClO4) was obtained from the reaction between Mn(NO3)2·4H2O and [H3TPA](ClO4)3 in MeOH. X-ray crystallographic structure of mononuclear TPAMn(η2-NO3)(η-ClO4) complex showed a seven-coordinated geometry with a tripodal tetradentate TPA, a terminal perchlorate and an η2-bound nitrate.

• Journal of Photoscience
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• 제7권1호
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• pp.21-26
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• 2000

The photoemission and excitation spectra of cis-[Cr(cyclam)F$_2$]ClO$_4$ (cyclam = 1,4,8,11-tetraazacy-clotetradecane) taken at 77 K are reported. The 298 K mid- and far-infrared spectra are also measured. The vibrational intervals of the electronic ground state are extracted from the far-infrared and emission spectra. The ten electronic bands due to spin-allowed and spin-forbidden transitions are assigned. The zero-phonon line In the excitation spectrum splits into two components by 169 cm$^{1}$, and the large $^2$E$_{g}$ splitting can be reproduced by the ligand field theory. According to the ligand field analysis, we can confirm that nitrogen atoms of the cyclam ligand have a strong c-donor character, and fluoride ligand also has strong $\sigma$- and $\pi$-donor properties toward chromium(III) ion.n.

• Macromolecular Research
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• 제9권5호
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• pp.292-295
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• 2001

A cross-linked solid polymer electrolyte was prepared by copolymerizing photochemically acrylonitrile (AN), oligo(ethylene glycol ethyl ether) methacrylate, oligo(ethylene glycol) dimethacrylate in the presence of lithium perchlorate as a lithium salt, ethylene carbonate-propylene carbonate as a mixed plasticizer, and poly(ethylene oxide) as a polymer matrix. The maximum ionic conductivity of the polymer electrolyte was 2.35$\times$10$\^$-3/ S/cm. The interface resistance of the polymer electrolyte was very low compared to that of the polymer electrolyte without AN. The former electrolyte was stable up to 4.3 V and the Ah efficiency was nearly 100% during the charge-discharge cycle.

• Bulletin of the Korean Chemical Society
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• 제35권1호
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• pp.111-116
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• 2014

The kinetics and mechanism of oxidation of sulfanilic acid by N-chloro-p-toluene sulfonamide (chloramine-T) have been studied in acid medium. The species of chloramine-T were analysed on the basis of experimental observations and predominantly reactive species was taken into account for proposition of most plausible reaction mechanism. The derived rate law (1) conforms to such a mechanism. $$-\frac{d[CAT]}{dt}=\frac{kK_1[RNHCl][SA]}{K_1+[H^+]}$$ (1) All kinetic parameters were evaluated. Activation parameters such as energy and entropy of activation were calculated to be $(61.67{\pm}0.47)kJmol^{-1}$ and $(-62.71{\pm}2.48)kJmol^{-1}$ respectively employing Eyring equation.

• Bulletin of the Korean Chemical Society
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• 제24권9호
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• pp.1329-1332
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• 2003

Stepwise dechlorination of 1,2,4-trichlorobenzene was observed at a glassy carbon electrode in dimethylformamide containing 0.1 M tetraethylammonium perchlorate. Especially, dechlorination to dichlorobenzene and further to monochlorobenzene or benzene was successfully demonstrated with a porous reticulated vitreous carbon electrode. Electrochemical dechlorination of polychlorobenzenes employing a flow cell with a reticulated vitreous carbon working electrode is also described. Preliminary experiments with a flow cell showed that dechlorination of trichlorobenzene to dichlorobenzene was partially completed while dechlorination to benzene or monochlorobenzene was not successful, suggesting that a flow rate and electrolysis time should be further optimized for the complete electrolysis.

• Bulletin of the Korean Chemical Society
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• 제27권12호
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• pp.1985-1988
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• 2006

The polymeric membrane electrodes based on urea derivative as an ionophore were prepared and studied for the iodide-ion selective electrode. This membrane exhibits a linear stable response over a wide concentration range ($1.0\;{\times}\;10^{-5}\sim1.0\;{\times}\;10^{-2}$) with a slope of -57.7 mV/decade, a detection limit of log[$I^-$] = -5.63, and a selectivity coefficient for iodide against perchlorate anion (log$K^{pot}_{I^-,j}$ = -1.42). The selectivity series of the membrane gives the follow as $I^-$ > $SCN^-$, $Sal^-$ > $ClO_4^-$ > $NO_3^-$ > $Br^-$ > $NO_2^-$ > $Cl^-$ > $F^-$. The proposed electrode showed good selectivity and response for iodide anion over a wide variety of other anions in pH 5.0 buffer solutions.