• Title/Summary/Keyword: Peg3

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Synthesis of Aniline from Nitrobenzene and Fe(CO)5 with PEG/γ-Al2O3 as Phase Transfer Catalyst (PEG/γ-Al2O3 상이동 촉매상에서 니트로벤젠과 Fe(CO)5로부터의 아닐린 합성)

  • Oh, So-Young;Lee, Hwa-Su;Park, Dae-Won;Park, Sang-Wook;Shin, Jung-Ho
    • Applied Chemistry for Engineering
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    • v.4 no.1
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    • pp.144-152
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    • 1993
  • Immobilized polyethylene glycols onto metal oxides such as ${\gamma}-Al_2O_3$, ${\alpha}-Al_2O_3$, $SiO_2$ and $TiO_2$ were used as phase transfer catalysts for the room temperature synthesis of aniline from nitrobenzene and ironpentacarbonyl. The amount of attached PEG molecules increased with specific surface area of metal oxides. Among the immobilized catalysts tested PEG/${\gamma}-Al_2O_3$ showed the highest activity. The reaction rate increased with the chain length of PEG mole-cules and the aqueous NaOH concentration. Mechanistic study carried out using infrared spectrometer revealed that the role of PEG was to increase the formation of $HFe(CO)_4{^-}$ ion, which is known as active species, and its movement from aqueous to organic phase.

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Germination Characteristics of PEG Priming Seed in Barley (Hordeum vulgare L.) (PEG로 프라이밍 된 보리(Hordeum vulgare L.)종자의 발아특성)

  • 이성춘;박문수;배창휴
    • Korean Journal of Plant Resources
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    • v.15 no.1
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    • pp.18-25
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    • 2002
  • These experiments were conducted to evaluate the variability of seed germination, and seedling growth of PEG priming barley. The average germination percentage(AGP) of PEG priming seed was higher than control, but those were low with extend the treatment period. The AGP of washing seed after PEG priming was higher than unwashed seed, and that of redried seed after priming was lower than control. The germination time of priming seed was short compare to control seed, and that was prolonged with extend the priming period, and that of washing seed after priming was shortening, and that of redried seed after priming was prolonging. The emergence percentage(EP) of priming seed was higher than control, and the emergence time was shortest in 50% field moisture capacity soil. The seedling and root length of priming seed was shorter than control.

Polyethylen Glycol을 이용한 수침침엽수재의 안정화

  • Hoffmann Per
    • 보존과학연구
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    • s.11
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    • pp.221-233
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    • 1990
  • 4종의 상태가 좋은 그리고 2종의 열화된 수침 침엽수재(Pinus massoniana,Pinus.densiflora, Cunninghamia lanceolata, Crypto meria japonica)를 PEG400과PEG4,000용액으로 처리하였다. 모든 종이 안정화처리에 똑같게 반응을 보였다. 전체적으로 건전재나 약간 열화된 수침재는 PEG400 20%용액으로 처리한 결과 치수안정화가 달성되었다. PEG4,000의 50%용액으로 처리한 목재의 건조에 대한 수축은 심하게 열화된 목재에 대해 열화되지 않은 목재에서는 1/2에서 1/3정도 감소하였다. 엄격한 상관관계가 최적안정화를 위해 PEG와 목재의 밀도간에 존재한다. 최적으로 처리된 목재는 86%상대습도 이하에서는 축축하게 되지 않는다. PEG400과 PEG4,000으로 처리한 2단부함침이 황해에서 구조된 중국 정크선의 목재를 안정화시키는데 대해 추천된다.

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Laparoscopic-Assisted Percutaneous Endoscopic Gastrostomy Reduces Major Complications in High-Risk Pediatric Patients

  • Balogh, Brigitta;Szucs, Daniel;Gavaller, Gabriella;Rieth, Anna;Kovacs, Tamas
    • Pediatric Gastroenterology, Hepatology & Nutrition
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    • v.24 no.3
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    • pp.273-278
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    • 2021
  • Purpose: Percutaneous endoscopic gastrostomy (PEG) is a safe method to feed patients with feeding difficulty. This study aimed to compare the outcomes of conventional PEG and laparoscopic-assisted PEG (L-PEG) placement in high-risk pediatric patients. Methods: In our tertiary pediatric department, 90 PEG insertions were performed between 2014 and 2019. Children with severe thoracoabdominal deformity (TAD), previous abdominal surgery, ventriculoperitoneal (VP) shunt, and abdominal tumors were considered as high-risk patients. Age, sex, diagnosis, operative time, complications, and mortality were compared among patients who underwent conventional PEG placement (first group) and those who underwent L-PEG placement (second group). Results: We analyzed the outcomes of conventional PEG placement (first group, n=15; patients with severe TAD [n=7], abdominal tumor [n=6], and VP shunts [n=2]) and L-PEG placement (second group, n=10; patients with VP shunts [n=5], previous abdominal surgery [n=4], and severe TAD [n=1]). Regarding minor complications, 1 (6.6%) patient in the first group underwent unplanned PEG removal and 1 (10%) patient in the second group had peristomal granuloma. We observed three major complications: colon perforation (6.6%) in a patient with VP shunt, gastrocolic fistula (6.6%) in a patient with Fallot-tetralogy and severe TAD, and pneumoperitoneum (6.6%) caused by early tube dislodgement in an autistic patient with severe TAD. All the three complications occurred in the first group (20%). No major complications occurred in the second group. Conclusion: In high-risk patients, L-PEG may be safer than conventional PEG. Thus, L-PEG is recommended for high-risk patients.

Effects of Polyethylene Glycol on Glucoamylase Production in Recombinant Yeast Culture (Polyethylene Glycol이 재조합 효모 배양에 의한 Glucoamylase 생산에 미치는 영향)

  • 차형준;유영제
    • KSBB Journal
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    • v.11 no.3
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    • pp.311-316
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    • 1996
  • The effects of polyethylene glycol (PEG) on glucoamylase production in recombinant Saccharomyces cerevisiae were studied. By PEG addition, the cell growth was not affected. However, the glucoamylase production was increased in all range of PEG molecular weights and concentrations. The optimal molecular weight of PEG was 6000 and the optimal concentration was 1g/L. Using these optimals, the extracellular glucoamylase activity was 23% higher in PEG-containing medium than that in medium without PEG.

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Effect of Plasticizer on Electrolyte Membranes for Dye Sensitized Solar Cells (염료감응형 태양전지를 위한 고분자 전해질막에서의 가소제의 효과)

  • Cho, Doo-Hyun;Jung, Yoo-Young;Yun, Mi-Hye;Kwon, So-Young;Koo, Ja-Kyung
    • Membrane Journal
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    • v.20 no.1
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    • pp.13-20
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    • 2010
  • Using poly(ethylene oxide) (PEO) as a polymer host, poly(ethylene glycol) (PEG) as a plasticizer, potassium iodide and iodine as sources of $I^-/{I_3}^-$ PEO-PEG-KI/$I_2$ polymer gel electrolytes were prepared. Based on the polymer gel electrolytes, solid-state dye-sensitized solar cell(DSSC)s were fabricated. The content of PEG in the electrolyte was changed from 0 to 85%. The electrolyte showed self-supporting form through whole range of the PEG content. As the PEG content increased, the ionic conductivity and ${I_3}^-$ diffusivity increased and the light-to electrical energy conversion efficiency increased under irradiation of 100 $mWcm^{-2}$ simulated sunlight.

Effect of Polycaprolactone on the Mechanical Properties of PEG/HMX Propellant (Polycaprolactone이 PEG/HMX 추진제의 기계적 성질에 미치는 영향)

  • 정병훈;홍명표;임유진
    • Journal of the Korean Society of Propulsion Engineers
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    • v.2 no.3
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    • pp.62-69
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    • 1998
  • Mechanical properties of polyethyleneglycol(PEG)/cyclo-tetramethylene tetranitramine(HMX) propellant were studied by adding polycaprolactone(PCP) and silane derivatives as coupling agent. Mechanical properties of the propellant were enhanced by increasing the content of PCP which was partially replaced with PEG. PCP/HMX propellant showed 17% increase in maximum tensile strength and 59% increase in elongation compared to those of PEG/HMX propellant. However, as the content of PCP was increased, the hydrolytic stability of this propellant was found to be deteriorated due to the ester group of PCP by measuring hardness drop of cured propellant and swell ratio difference of PEG/PCP binder stored at $40^{\cire}C$ and 90% relative humidity. Hardness of the PEG/PCP/HMX propellant was decreased with increasing triethoxysilyl propionitrile(TESPN) and dinitrosalicylic acid (DNSA) content from accelerated aging at $60^{\cire}C$.

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Effects of the Methods of Polyethylene Glycol Impregnation and Drying on the Volumetric Shrinkage of Wood (Polyethylene Glycol 주입방법과 건조방법이 목재 부피수축률에 미치는 효과)

  • Lee, Won-Hee;Kang, Chun-Won;Hong, Seung-Hyun;Kang, Ho-Yang
    • Journal of the Korea Furniture Society
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    • v.27 no.1
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    • pp.43-48
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    • 2016
  • PEG (Polyethylene glycol) impregnation in wood reduces the occurrence of checking during kiln drying. The volumetric shrinkages of wood PEG impregnated by pressure (PEG-P) or soaking (PEG-S) methods, and oven-dried by vent (VD) or air-tight (AD) methods were measured and compared with the controls. The average oven-dry weight of PEG impregnated specimens was larger than that of the controls by 3.6 g, but was not influenced by the drying methods. The average of the total volumetric shrinkage of PEG-P-VD specimens was the least (2.3%), while that of CON-S-AD specimens was the largest (28.9%). Within a drying method the total volumetric shrinkage of the control was the largest followed by PEG-S and PEG-P specimens, which implied that residual PEG in wood restrained its shrinkage during drying.

Ionic Conductivities of the LiCF$_3$SO$_3$Complexes with Liquid Crystalline Aromatic Polyesters Having Oligo(oxyethylene) Pendants

  • Lee, Jun-Woo;Joo, Sung-Hoon;Jin, Jung-Il
    • Macromolecular Research
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    • v.12 no.2
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    • pp.195-205
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    • 2004
  • We have synthesized new aromatic polyesters (DiPEG-HQ and DiPEG-BP) by condensation polymerization of a terephthalic acid derivative bearing a pendant oligo(oxyethylene) (DP = 7, MW = 350), which has a methoxy terminal group, and two different aromatic diols, hydroquinone and 4,4'-biphenoI. The synthesized polymers were characterized by differential scanning calorimetry (DSC), polarizing microscopy, and X-ray diffractometry for their liquid crystallinity (LC), thermal transitions, and structural morphologies in mesophases. The morphology of the LC phases depends strongly on the length of the rigid backbone repeating unit. The DiPEG-BP polymer having a longer repeating unit exhibits both layered and nematic structures before isotropization, whereas the DiPEG-HQ polymer having a shorter repeating unit shows only the layered structure in the mesophase. We found that the layer spacing for DiPEG-HQ is larger than that for DiPEG-BP. Both polymers easily form complexes with LiCF$_3$SO$_3$; we studied this complex formation by FT-IR spectroscopy. The layer spacing of the polymer-electrolyte composites increases upon increasing the amount of the lithium salt. The polymer/salt electrolyte mixtures we investigated at molar ratios of EO:salt in the range of 5-20 exhibit electrical conductivity values at 40$^{\circ}C$ of 2.4${\times}$10$\^$5/ and 1.1${\times}$10$\^$-5/ S/cm for DiPEG-HQ/LiCF$_3$SO$_3$ and DiPEG-BP/LiCF$_3$SO$_3$, respectively. At 80 $^{\circ}C$, these values are higher: 4.6${\times}$10$\^$-3/ and 1.1${\times}$10$\^$-4/ S/cm, respectively. The activation energy of conductivity depends strongly on the salt concentration.

Studies on the Dimensional Stabilization of Wood -Especially by the Solution of Different Composition by PEG Molecular Weight- (목재(木材)의 치수 안정화(安定化)에 관(關)한 연구(硏究) -Polyethylene Glycol의 혼합액(混合液)을 중심(中心)으로-)

  • Oh, Joung Soo;Cheon, Cheol
    • Journal of Korean Society of Forest Science
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    • v.76 no.2
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    • pp.119-126
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    • 1987
  • This study was carried out to elucidate the desirable PEG molecular weight and it's blending methods which can promote the dimensional stabilization of Corpus controversa, Quercus variabilis and Prunus sargentii. The results may be summarized as follows: 1. PEG polymer loading in woods was affected by specific gravity of wood. And the PEG polymer loading was satisfactory except in Quercus variabilis, which shows the blending method of PEG V was proper. 2. Bulking coefficiency of PEG V was high in Corpus controversa and Prunus sargentii, and it is necessary to paint or coat water-proofing wood preservative: for high bulking coefficiency of Quercus variabilis. 3. In the treatment of PEG V, the antishrink efficiency of Prunus sargentii was 82.59% and that of Quercus variabilis 62.79%. 4. Dimensional stabilization of hardwoods did not have apparant relation with PEG blending method. 5. Judging from results, PEG-400 and PEG-1000 would be enough for dimensional stabilization of hardwood having high specific gravity if other factors are considered well.

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