• 제목/요약/키워드: Peak current density

검색결과 239건 처리시간 0.024초

낮은 최고전류밀도 조건에서 파형전류전해에 의한 Pb-Sn합금 전착층의 조성 및 조작특성 (Composition and microstructure of Pb-Sn alloy electrodeposits in pulse plating with low peak current density)

  • 예길촌;백민석
    • 한국표면공학회지
    • /
    • 제24권2호
    • /
    • pp.88-95
    • /
    • 1991
  • The tin-lead alloy was electrodeposited in the low range of peak current density in order to investigate the change of composition and microstructure of them. The Pb content of alloy deposits, which was decreased with increasing average current density, was relatively lower than that of D.C. plated alloy deposit. The preferred orientation of alloy deposit was changed with increasing peak current density and the surface morphology of alloy deposits was closely related to the preferred orientation of them.

  • PDF

팔라디움-니켈 합금전착층의 조성 및 조직에 미치는 파형전류인자의 영향 (The effect of pulse parameters on the composition and the structure of Palladium-Nickel alloy electrodeposits)

  • 예길촌;오유청
    • 한국표면공학회지
    • /
    • 제27권5호
    • /
    • pp.285-291
    • /
    • 1994
  • The effects of pulse current parameters on the composition and the microstructure of Pd-Ni alloy electrodeposits were studied. The cathode current efficiency of p.c. electrolysis conditions decreased with increasing both mean and peak current density and was lower than those under D.C. electrolysis condition. Palladium content of Pd-Ni alloy increased with increasing both peak current density and on-time, while it decreased with increasing mean current density and duty cycle. The preferred orientation of Pd-Ni alloys changed with increasing mean current density in the sequence of (111)+(110).(100) or (110)longrightarrow(111)longrightarrow(100) or random distribution of crystal structure. The surface morphology of Pd-Ni alloy changed mainly according to the mean current density and was related to the preferred orientation.

  • PDF

AlIanAs/GaInAS계 공명터널링 다이오드의 부성저항 특성에 관한 수치 해석 (Numerical Analysis of NDR characteristics in resonant tunneling diodes with AllnAs/GaInAs Structure)

  • Kim, SeongJeen
    • 전자공학회논문지A
    • /
    • 제32A권7호
    • /
    • pp.51-57
    • /
    • 1995
  • The theoretical analysis for AlInAs/GaInAs resonant tunneling diodes (RTDs), which have shown the improved negative differential resistance (NDR) characteristics, has scarcely been made in comparison with AlGaAS/GaAs RTDs. In this paper, the static current-voltage relation of Al$_{0.48}In_{0.52}As/Ga_{0.47}In_{0.53}$As RTDs were numerically estimated by using a self-consistent method. Assuming a simplified RTD with single quantum well structure and spacer layers, the peak current density (J$_{P}$) and the peak-to-valley current ratio (PVCR) were analysed as the function of the thickness of the well, the barrier and the spacer layer, and temperature. As the results, the peak current density and the peak-to-valley current ratio indicated a reciprocal relation roughly in respect to the thicknesses of the well and the barrier, and it was theoretically predicted that it be not attainable to provide a high peak current desity (J$_{P}$) over 1${\times}10^{5}A/cm^{2}$ as well as the large peak-to-valley current ratio (PVCR) over 10 that were the the critical conditions for the practical use.

  • PDF

Ni Sulfamate-chloride 전기도금 용액에서 전류밀도와 첨가제의 농도 변화가 Ni 박막에 미치는 영향 (Effects of the Changes of Current Density and Additive Concentration on Ni Thin Films in Ni Sulfamate-chloride Electrodeposition Baths)

  • 윤필근;박덕용
    • 한국표면공학회지
    • /
    • 제51권1호
    • /
    • pp.62-70
    • /
    • 2018
  • Sulfamate plating solution containing a small amount of chloride bath was fabricated to study the properties of the electrodeposited Ni thin films. Effects of the changes of current density and additive concentration on current efficiency, residual stress, surface morphology and microstructure of Ni thin films electrodeposited from Ni sulfamate-chloride baths were investigated. The current efficiency was measured to be more than about 95%, independent of the changes of current density and saccharin concentration in the baths. Residual stress of Ni thin film was appeared to be the compressive stress modes in the range of $5{\sim}30mA/cm^2$ current density. Maximum compressive stress was observed at the current density of $10mA/cm^2$. Compressive stress values of Ni thin/thick films were increased to be about -85~-100 MPa with increasing saccharin concentration from 0 to 0.0195 M(4 g/L). Surface morphology was changed from smooth to nodule surface appearance with increasing the current density. Smooth surface morphology of Ni thin films electrodeposited from the baths containing saccharin was observed, independent of the saccharin concentration. Ni thin/thick films consist of FCC(111), FCC(200), FCC(220), FCC(311) and FCC(222) peaks. It was revealed that the FCC(200) peak of Ni thin films is the preferred orientation in the range of $5{\sim}30mA/cm^2$ current density. The intensity of FCC(200) peak was gradually decreased and the intensity of FCC(111) peak was increased with increasing saccharin concentration in the baths.

전해연마 용액에서 안정화 시간과 표면 거칠기에 따른 오스테나이트 스테인리스강의 전기화학적 특성 (Electrochemical Properties of Austenitic Stainless Steel with Initial Delay Time and Surface Roughness in Electropolishing Solution)

  • 황현규;김성종
    • Corrosion Science and Technology
    • /
    • 제21권2호
    • /
    • pp.158-169
    • /
    • 2022
  • The objective of this study was to investigate the electrochemical behavior and damage degree of metal surface under different conditions by performing a potentiodynamic polarization experiment using an electropolishing solution for UNS S31603 based on initial delay time and surface roughness (parameters). A second anodic peak occurred at initial delay time of 0s and 100s. However, it was not discovered at 1000s and 3600s. This research referred to an increase in current density due to hydrogen oxidation reaction among various hypotheses for the second anodic peak. After the experiment, both critical current density and corrosion current density decreased when the initial delay time (immersion time) was longer. As a result of surface analysis, characteristics of the potentiodynamic polarization behavior were similar with roughness, although the degree of damage was clearly different. With an increase in surface roughness value, the degree of surface damage was precisely observed. As such, electrochemical properties were different according to the immersion time in the electropolishing solution. To select electropolishing conditions such as applied current density, voltage, and immersion time, 1000s for initial delay time on the potentiodynamic polarization behavior was the most appropriate in this experiment.

고속도금된 3가 크롬도금의 전류효율 및 조직특성에 미치는 첨가제의 영향 (The Effect of Additives on the Current Efficiency and the Microstructure of Trivalent Cr Electrodeposits Plated in Flow Cell System)

  • 예길촌;서경훈
    • 한국표면공학회지
    • /
    • 제37권2호
    • /
    • pp.92-98
    • /
    • 2004
  • The current efficiency and the microstructure of the trivalent Cr deposits plated in flow cell system were investigated according to additives in sulfate bath and current density. The current efficiency of the deposits plated in the formic acid complexed bath was noticeably higher than that of the deposits from glycine complexed bath. The current efficiency of the deposits from the complexed baths with boric acid buffer increased linearly with current density in the range of 60-100 A/dm$^2$, while that of the deposits from the baths with both Al sulfate and mixed buffers increased parabolically with current density. The nodular crystallite size of the deposits increased with current density, and the deposits plated in low current density region had relatively smooth surface appearance with fine grains. The structure of the deposits from the complexed baths with boric acid buffer changed from amorphous structure to crystalline one with strong (110)peak with increasing current density. The deposits from the baths with both Al sulfate and mixed buffers had generally amorphous structure.

마크 밀도 변화에 강한 버스트 모드 자동 전력 제어 회로 (A Burst-mode Automatic Power Control Circuit Robust io Mark Density Variations)

  • 기현철
    • 대한전자공학회논문지SD
    • /
    • 제41권4호
    • /
    • pp.67-74
    • /
    • 2004
  • 기존의 버스트 모드 자동전력제어 회로는 데이터 율이 증가함에 따라 마크밀도 변화 영향을 심하게 받아 에러를 야기하였다. 이 문제를 해결하기 위해 높은 데이터 율에서도 마크밀도의 영향을 배제시킬 수 있는 새로운 구조의 첨두 비교기를 고안하고 이를 자동전력제어 회로에 적용하여 마크밀도 변화에 강한 버스트 모드 자동전력제어 회로를 제안하였다. 제안한 자동전력제어 회로 내의 첨두 비교기는 높은 데이터 율에서 뿐만 아니라 광범위한 기준전류 및 차 전류 변화에서도 미소한 마크밀도 변화 영향만을 보여 마크밀도 변화에 매우 강한 특성을 확인 할 수 있었다.

양극산화 시간 및 전류밀도 변화에 따른 다공질 실리콘의 특성 변화 (Effects of Current Density and Anodization Time on the Properties of Porous Si)

  • 최현영;김민수;김군식;조민영;전수민;임광국;이동율;김진수;김종수;임재영
    • 한국표면공학회지
    • /
    • 제43권3호
    • /
    • pp.121-126
    • /
    • 2010
  • The PS(porous Si) were fabricated with different anodization time and current density. The structural and optical properties of PS were investigated by SEM(scanning electron microscopy), AFM(atomic force microscopy), and PL(photoluminescence). It is found that the pore size and surface roughness of PS are proportional to the current density. The PL spectra show that the PL peak position is red-shifted with increasing anodization time. This behavior corresponds to the change of pore size which is consistent with the quantum confinement model. The FWHM(full width at half maximum) of PL peak is decreased from 97 to 51 nm and the PL peak position is blue-shifted with increasing current density up to 10 mA/$cm^2$. The PL peak intensity of the PS fabricated under 1 mA/$cm^2$ is the highest among samples.

실온 펄스도금법을 이용한 STS 316L 표면의 Ni 도금 저가형욕 연구 (Study of Ni-coating on 316L Stainless Steel by Pulse Electroplating in Various Bath Conditions at Room Temperature)

  • 정세진;조계현
    • 한국표면공학회지
    • /
    • 제35권1호
    • /
    • pp.53-63
    • /
    • 2002
  • Ni coating was carried out by pulse plating at room temperature. So, experimental conditions for Ni-coating were based on Watt's bath, and new additives(propionic acid) were introduced in the Watt's bath electrolyte as $H_3$$BO_3$ alternatives. By adding propionic acid, coating layer demonstrated a good adhesion and uniformity without special pre-treatment of the 316L stainless steel at room temperature. With a decrease of amount of propionic acid and applied average current density, cathode current efficiency increased. Also, edge effect was decreased with decreasing a peak current and increasing a pulse frequency in the same bath condition. It was found that the optimum condition for Ni coating was a current density of 10~20mA/$\textrm{cm}^2$ at below 500 mA peak current in the $5m\ell/\ell$ propionic acid solution.