• Title/Summary/Keyword: Pd/Si

Search Result 243, Processing Time 0.038 seconds

Exhaust gas purification characteristics of M-90 fueled SI engine for passenger car (자동차용 M-90 스파크 점화기관의 배기가스 정화특성)

  • 김재휘;홍영표
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.20 no.4
    • /
    • pp.43-49
    • /
    • 1996
  • With the recent interest in methanol as a SI engine fuel, aldehyde emissions have become a greater concern. A M-90 fueled passenger car was operated in a chassis dynamometer using FTP 75 driving cycle to examine formaldehyde emissions. Formation process of aldehyde and methods to reduce them are discussed in this paper for a SI-engine passenger car operating by M-90. Aldehyde emissions have been found to be 3 to 7 times higher from M-90 than from gasoline, while CO, NOx, THC are as low or lower than gasoline. Noble metal compositions appeared to play a role in formaldehyde and unburned methanol emission performance. For example, catalyst Pd showed better reduction of both formaldehyde and methanol than catalyst Pt. however, emission rates of formaldehyde and methanol for catalyst Pt were relatively similar to catalyst Pt/Rh.

  • PDF

Partial Discharge Resistance of Epoxy-Nanocomposites (에폭시-나노콤포지트의 부분방전 저항성 특성연구)

  • Park, Jae-Jun;Lee, Chang-Hoon;Choi, Tae-Jin;Choi, Tae-Il;Park, Yong-Byum;Lee, Sung-Il
    • Proceedings of the KIEE Conference
    • /
    • 2009.07a
    • /
    • pp.1375_1377
    • /
    • 2009
  • PD의 저항성은 에폭시원형을 포함한 3종류 즉, 에폭시 마이크로 콤포지트를 실란처리 및 미처리한 경우 그리고 나노-마이크로입자가 혼합된 콤포지트의 부분방전저항성을 연구하였다. 이들 재료들은 rod - gap - plane 전극 하에서 PD가 적용되었다. 원형에폭시수지보다 마이크로 콤포지트가 부분방전저항성이 우월하였다. 더욱이 SiO2 나노입자-마이크로 혼합된 콤포지트가 더욱더 큰 저항성을 얻었다. 이는 마이크로 입자사이로 나노입자가 치밀한 조직을 갖고 있기에 이러 우월한 특성을 나타낸 것으로 판단된다.

  • PDF

The Partial Discharge Resistances of Epoxy-Nano-and-Micro Composites

  • Lee, Chang-Hoon;Park, Jae-Jun
    • Transactions on Electrical and Electronic Materials
    • /
    • v.11 no.2
    • /
    • pp.89-91
    • /
    • 2010
  • Partial discharge (PD) resistances were investigated for three types of samples: original epoxy resins, epoxy micro composites with and without the silane processing, and mixture composites with micro and nano particles. The PD was applied to these materials using rod, gap, and plane electrodes. The partial discharge resistance found in the micro composites was better than that found in the original epoxy resin. Moreover, the mixture composites of $SiO_2$ nano and micro particles had much larger resistances than the original epoxy resin or microcomposites. It can be regarded that this excellent property was due to the fact that the nano particles have a dense structure between the micro particles.

On Enhancing of Inner Loop Regulators for Remote Control in Robotic Systems

  • Masaki, Sano;Jung, Si
    • 제어로봇시스템학회:학술대회논문집
    • /
    • 2001.10a
    • /
    • pp.24.1-24
    • /
    • 2001
  • This paper present the idea that the inner loop regulator inside the servo can be enhanced its performance by replace the conventional control with a fuzzy proportional derivative control. In this paper, we replace an inner loop regulator of a Futaba servomotor with a fuzzy PD control paradigm. We then test the proposed system and compare the result with the original scheme. The fuzzy control used here is based on the supervisory scheme of the conventional PD yet embedded a fuzzy decision for the final control action. The proposed control scheme for the servomotor has shown robustness and effective performance in handle input disturbance along with its tracking ability. Moreover, when we embedded the new implemented on a real six-legged insect robot designed by the authors, we found that the control system for this application under the ...

  • PDF

Synthesis and Applications of Noble Metal and Metal Silicide and Germanide 1-Dimensional Nanostructures

  • Yoon, Ha-Na;Yoo, Young-Dong;Seo, Kwan-Yong;In, June-Ho;Kim, Bong-Soo
    • Bulletin of the Korean Chemical Society
    • /
    • v.33 no.9
    • /
    • pp.2830-2844
    • /
    • 2012
  • This review covers recent developments in our group regarding the synthesis, characterization and applications of single-crystalline one-dimensional nanostructures based on a wide range of material systems including noble metals, metal silicides and metal germanides. For the single-crystalline one-dimensional nanostructures growth, we have employed chemical vapor transport approach without using any catalysts, capping reagents, and templates because of its simplicity and wide applicability. Au, Pd, and Pt nanowires are epitaxially grown on various substrates, in which the nanowires grow from seed crystals by the correlations of the geometry and orientation of seed crystals with those of as-grown nanowires. We also present the synthesis of numerous metal silicide and germanide 1D nanostructures. By simply varying reaction conditions, furthermore, nanowires of metastable phase, such as $Fe_5Si_3$ and $Co_3Si$, and composition tuned cobalt silicides (CoSi, $Co_2Si$, $Co_3Si$) and iron germanides ($Fe_{1.3}Ge$ and $Fe_3Ge$) nanowires are synthesized. Such developments can be utilized as advanced platforms or building blocks for a wide range of applications such as plasmonics, sensings, nanoelectronics, and spintronics.

Application of SiO2 nanocomposite ferroelectric material in preparation of trampoline net for physical exercise

  • Zhanguo Su;Junyan Meng;Yiping Su
    • Advances in nano research
    • /
    • v.14 no.4
    • /
    • pp.355-362
    • /
    • 2023
  • Physical exercise, especially intense exercise and high intensity interval training (HIIT) by trampoline, can lead to muscle injuries. These effects can be reduced with intelligent products made of nanocomposite materials. Most of these nanocomposites are polymers reinforced with silicon dioxide, alumina, and titanium dioxide nanoparticles. This study presents a polymer nanocomposite reinforced with silica. As a result of the rapid reaction between tetraethyl orthosilicate and ammonia in the presence of citric acid and other agents, silica nanostructures were synthesized. By substituting bis (4-amino phenoxy) phenyl-triptycene in N, N-dimethylformamide with potassium carbonate, followed by catalytic reduction with hydrazine and Pd/C, the diamine monomer bis (4-amino phenoxy) phenyl-triptycene is prepared. We synthesized a new polyaromatic (imide) with triptycene unit by sol-gel method from aromatic diamines and dianhydride using pyridine as a condensation reagent in NMP. PI readily dissolves in solvents and forms robust and tough polymer films in situ. The FTIR and NMR techniques were used to determine the effects of SiO2 on the sol-gel process and the structure of the synthesized nanocomposites. By using a simultaneous thermal analysis (DTA-TG) method, the appropriate thermal operation temperature was also determined. Through SEM analysis, the structure, shape, size, and specific surface area of pores were determined. Analysis of XRD results is used to determine how SiO2 affects the crystallization of phases and the activation energy of crystallization.

Determination of La in $U_3Si/Al$ Spent Nuclear Fuel by Ion Chromatography-Inductively Coupled Plasma-Mass Spectrometry (Ion Chromatography-Inductively Coupled Plasma-Mass Spectrometry에 의한 $U_3Si/Al$ 사용후핵연료 중 La의 분리 및 정량)

  • Han, Sun Ho;Choi, Kwang Soon;Kim, Jung Suk;Jeon, Young Shin;Park, Yang Soon;Jee, Kwang Yong;Kim, Won Ho
    • Analytical Science and Technology
    • /
    • v.13 no.5
    • /
    • pp.601-607
    • /
    • 2000
  • Lanthanum has been used as one of the burnup monitor in spent nuclear fuel. $U_3Si/Al$ spent nuclear fuel contains small amount of La in high concentration of U and Al. Therefore, chemical separation of La is required to remove matrix elements. At first, ion chromatography (IC) and inductively coupled plasma systems were installed in radiation shielded glove box to handle the radioactive samples. Retention behavior of uranium, aluminum, lanthanum and some interesting fission products (Sr, Zr, Y, Mo, Ru, Pd, Rh, Cs, Ba, Ce, Pr, Nd, Sm, Eu and Cd) was investigated using the CG10 column and ${\alpha}$-HiBA eluent. As all elements were eluted earlier than lanthanum in 0.2 M ${\alpha}$-HiBA eluent, a portion of U and Al was directly passed to waste using a three way valve between the column and the nebulizer. Thus it was possible to determine the lanthanum in a high concentration of U and Al matrix. Retention time of La was about 12 minutes in this separation condition. Optimum range for the determination of La in $U_3Si/Al$ spent nuclear fuel was $1-10{\mu}g/L$ (ppb) with this system and detection limit was $0.25{\mu}g/L$ in case of $200{\mu}L$ of sample volume.

  • PDF

Carbon-free Hydrogen Production Using Membrane Reactors (막촉매반응기를 이용한 수소생산)

  • Do, Si-Hyun;Roh, Ji Soo;Park, Ho Bum
    • Membrane Journal
    • /
    • v.28 no.5
    • /
    • pp.297-306
    • /
    • 2018
  • This review focused carbon-free hydrogen productions from ammonia decomposition including inorganic membranes, catalysts and the presently studied reactor configurations. It also contains general information about hydrogen productions from hydrocarbons as hydrogen carriers. A Pd-based membrane (e.g. a porous ceramic or porous metallic support with a thin selective layer of Pd alloy) shows its efficiency to produce the high purity hydrogen. Ru-based catalysts consisted of Ru, support, and promoter are the efficient catalysts for ammonia decomposition. Packed bed membrane reactor (PBMR), Fluidized bed membrane reactor (FBMR), and membrane micro-reactor have been studied mainly for the optimization and the improvement of mass transfer limitation. Various types of reactors, which contain various combinations of hydrogen-selective membranes (i.e. Pd-based membranes) and catalysts (i.e. Ru-based catalysts) including catalytic membrane reactor, have been studied for carbon-free hydrogen production to achieve high ammonia conversion and high hydrogen flux and purity.

The effect of lateral wedge on postural sway in Parkinson's disease

  • Yoon, Ji-Yeon;Park, Jinse;Park, Kang Min;Ha, Sam Yeol;Kim, Sung Eun;Shin, Kyong Jin;Kim, Si Eun;Jo, Geunyeol
    • Annals of Clinical Neurophysiology
    • /
    • v.20 no.1
    • /
    • pp.31-35
    • /
    • 2018
  • Background: Although postural instability is one of the major symptoms of Parkinson's disease (PD), dopaminergic treatment is ineffective for treating postural instability. Recent reports have shown that somatosensory deficit is associated with postural instability, and that somatosensory input improved postural instability. The purpose of this study is to evaluate the effects of lateral wedges for quiet standing postural control in people with PD. Methods: Twenty-two patients who were diagnosed with PD were enrolled in this study. The participants stood on a force plate under two conditions (wedge and no wedge) with or without having their eyes open or closed. The center of pressure (COP) range and velocity were analyzed using a two-way repeated-measures analysis of variance. Results: The range and velocity of COP in the anterioposterior and mediolateral (ML) directions were significantly improved after the patients stood on the lateral wedge with their eyes closed (p < 0.05). The range in ML direction and velocity in both directions of COP were significantly decreased when their eyes were open (p < 0.05). Conclusions: Regardless of vision, standing on lateral wedges improved postural sway in people with PD.