• Title/Summary/Keyword: Pd(0)

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Effect of Alginic Acid-Added Functional Drink(HAEJOMIIN)in Brown Angae(Undaria pinnatifida) on Obesity and Biological Activity of SD Rats (미역(Undaria pinnatifida)의 알긴산-첨가 기능성 음료(해조미인)가 흰쥐의 비만 및 생리활성에 미치는 영향)

  • 최진호;김동우
    • Journal of Life Science
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    • v.7 no.4
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    • pp.361-370
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    • 1997
  • Sprague-Dawley male rats were fed experimental diet, and also were orally daministerred with 3.0% ultra low viscosity (ULV) sodium alginate-added functional drink(AL-3.0% group : HAEJOMIN), 5.0% polyedxtrose(PD)-added drink(PD-5.0group) and 2.5% polydextrose-added drink(PD-2.5 group) for 8 weeks. Effect of rhese dietary fiber-added functional drinks on body weight, feed and gross efficincies, triglyceride and cholesterol levels, LDL- cholesterol levels, hydroxyl radical and malondialdehyde levels, and superoxide dismutase (SOD) activity in serum of SD rats were evaluated. Administration of AL-3.0 drink and PD-5.0 drink resulted in a marked inhibition in increase of body weight compared with control and PD-2.5 groups for 8 weeks. Inhibition effect in body weight in 3.0% alginic acid-added drink )AL-3.0 froup_ showed a same trend in 5.0% polydextrose(PD)-added drink (PD-5.0 group)(p<0.001). Therefore, it is found that inhibition effects of obesity in 3.0% alginic acid-added drink were higher 2 times than that in same concentration of polydextrose(PD)-added drink. Triglyceride and cholesterol levels in AL-3.0 and PD-5.0 groups significantly decreased to 25$\sim$30% compared with control group(p<0.01$\sim$0.001), but there were no significant differences in these drinks. LDL-cholesterol levels in AL-3.0 group significantly decreased about 15% compared with PD-5.0 group, but atherogenic index in AL-3, 0 group showed a similar trend to that in PD-5.0 group. Hydroxyl radical formations and lipid peroxide(LPO) levels in AL-3, 0 and PD-5.0 groups significantly decreased to 15% and 20%, respectively, compared with control group(p, 0.05$\sim$0.01), but there were no significant differences in these drinks. Superoxide, dismutase(SOD) activity in AL-3.0 group significantly higher (about 255) than those in control and PD-5.0 groups(p<0.01). These results suggest that administration of ULV-sodium alginate-added functional drink(HAEJOMIIN) effectively can not only inhibit obesity, but also can intervent chronic degenerative disease and aging process.

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Effects of Pd Addition on Electrode properties of Metal Hydride (Pd 첨가가 금속수소화물 전극 특성에 미치는 영향)

  • Choi, Jeon;Lee, Kyung-Ku
    • Transactions of the Korean hydrogen and new energy society
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    • v.10 no.2
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    • pp.141-149
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    • 1999
  • Recently the Ni/MH secondary battery has been studied extensively to achieve higher energy density, longer cycle life and faster charging-discharging rate etc. In this work, the electrode properties of $(LM)Ni_{4.49}Co_{0.1}Mn_{0.205}Al_{0.205}$ alloy and $Ti_{0.6}Zr_{0.4}V_{0.6}Ni_{1.4}$ alloy with addition of Pd were investigated. These alloys did not show any change in XRD pattern by Pd addition. As Pd was added as alloy element, the activation behavior was not affected significantly in both $AB_2$ type and $AB_5$ type electrodes and, On charging and discharging in high current density, Discharge capacity with increasing of Pd content was more decreased. But cycle life was showed increasing. Especially the electrode of $Ti_{0.6}Zr_{0.4}V_{0.6}Ni_{1.4}+0.5wt%$ Pd alloy was not almost decreased discharge capacity for 400cycles.

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Electrochemical Oxidation of Hydrogen at Palladium Electrode (팔라디움 전극에서의 전기화학적 수소산화반응)

  • Oh, M.H.;Paik, C.H.;Cho, B.W.;Yun, K.S.;Min, B.C.;Ju, J.B.;Sohn, T.W.
    • Transactions of the Korean hydrogen and new energy society
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    • v.7 no.1
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    • pp.45-54
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    • 1996
  • Electrochemical oxidation of hydrogen on PdOx and Pd electrodes were investigated in aqueous 30% KOH solution at different temperatures and hydrogen concentrations(partial pressures). Anodic reaction by hydrogen on PdOx electrode was mainly due to the oxidation of adsorbed hydrogen at -0.8V~-0.5V(vs. Hg/HgO). For Pd electrode, the anodic reaction was participated by the adsorbed hydrogen on surface, as well as by the metal hydride formed from direct reaction between Pd and hydrogen at -0.5V~0.0V(vs. Hg/HgO). With the increase of hydrogen concentration the charge transfer resistance decreased and the exchange current increased. The transfer coefficient of PdOx and Pd electrodes were found to be 0.78 and 0.72 respectively, which shows the superior reactivity of Pd electrode. The activation energies of PdOx and Pd electrodes decreased with the increase of overpotential and were found to be 23.9~20.3 kJ/mole and 7.2~3.0kJ/mole, respectively.

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New Packaging and Characteristics of PIN PD for CWDM Transmission (저밀도 파장분할 다중화용 PIN PD 제작 및 특성)

  • Kang, Jae-Kwang;Chang, Jin-Heyon
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.4 s.37
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    • pp.323-330
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    • 2005
  • We fabricate PIN PD (Positive Intrinsic Negative Photo-Diode) for CWDM optical repeater and optical transmission system, and analyze theoretically the characteristics to verify the capability of device fabricated. Furthermore, we integrate CWDM filter into PD package to enhance the cost and the performance when compared to the conventional system, in which CWDM filter and PD package are linked by optical fusion splicing. The integrated CWDM PD is fabricated by three steps as follows: CWDM filter design, PD packaging, and product assembly and test. The results of measurement for PD fabricated reveal 0.5 dB bandwidth of 17 nm, isolation over 60 dB at transmission port and over 20 dB at reflection port. Also, the IMD3 for wireless communication is over 63 dBc, and the responsivity of PD presents over 0.9 A/W for 20 samples of the total 23 PD. The total insertion loss reduces about 0.4${\~}$0.7 dB due to the integrated assembly of CWDM and PD.

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Separation of Palladium Precipitate Formed by Ascorbic Acid in a Simulated Radioactive Liquid Waste (모의 방사성 폐액에서 아스코르빈산에 의한 Pd의 침전 분리)

  • Hwang, Doo-Seong;Kwon, Seon-Kil;Lee, Kue-Il;Park, Jin-Ho;Yoo, Jae-Hyung;Park, So-Jin
    • Applied Chemistry for Engineering
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    • v.9 no.2
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    • pp.243-248
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    • 1998
  • This study investigated the separation and the property of palladium precipitate formed by ascorbic acid in a simulated radioactive liquid waste, which was composed of 10 elements((Pd, Ru, Rh, Nd, Cs, Sr, Fe, Ni, Zr, Mo). Pd was separated selectively by using reduction characteristics of metal ions contained in the simulated waste with ascorbic acid. When the nitric acid concentration was 0.5 M, the Pd over 99.5% was precipitated by adding 0.04 M ascorbic acid. Nitric acid concentration is important at the reduction reaction of Pd ion. The precipitation yield of Pd was decreased as the concentration of nitric acid was increased. The Pd precipitate was re-dissolved in reaching at an equilibrium when the concentration of nitric acid was high and ascorbic acid was added with a small amount. The Pd precipitate formed by ascorbic acid was Pd metal and was aggregated by particles less than $1.0{\mu}m$.

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Magnetoresistance Effect of [Pd/Co] Spin-valve with Perpendicular Anisotropy (수직자기이방성을 갖는 [Pd/Co] Spin Valve 구조에서 자기저항효과)

  • Choi, Jin-Hyup;Lee, Ky-Am
    • Journal of the Korean Magnetics Society
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    • v.16 no.3
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    • pp.173-177
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    • 2006
  • We have investigated the magnetoresistance (MR) effect of the spin valve structures composed of perpendicularly magnetized Pd/Co multilayers, with changing the space layer (Pd or Cu) thickness, the stacking number of the Pd/Co multilayers, and the Co insertion-layer thickness. The Cu space layer showed larger MR ratio than the Pd space layer. The Co insertion-layer between Cu layer and pinned layer enhanced the MR ratio about three times. The maximum MR ratio of 7.4 % was established in the sample with the Co insertion-layer thickness of 0.62 and 1.01 nm.

Microstructure Observation of Pd-Ga System Dental Alloy for Metal-Ceramic Restorations (치과 도재용 Pd-Ga계 합금의 미세조직 관찰)

  • 김기주;이진형
    • Journal of Biomedical Engineering Research
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    • v.21 no.6
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    • pp.537-542
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    • 2000
  • Ga이 함유된 Pd-Ga계 합금은 우수한 기계적 성질, 심미성 및 생체적합성등으로 차세대 치과 도재용 합금으로 주목 받고 있다. 본 연구에서는 상용 77.3%Pd-6.0%Ga계 합금을 원심주조법으로 주조하고, 탈개스, 세라믹소성처리한 후 미세조직을 광학현미경, X-선 회절기, 투과전자현미경으로 관찰하였다. X-선 회절분석 및 투과전자현미경 관찰 결과, Pd고용체와 미세한 석출물에 의해 나타나는 줄무늬를 확인하였다. 공정점 86$0^{\circ}C$에서 5시간 유지시킨 상평형 열처리조건에서는 Pd고용체와 금속간화합물 Pd(sub)2Ga에 해당하는 보다 명확한 제한시야회절도형을 얻었다. 이러한 결과로 77.3%Pd-6.0%Ga계 합금은 Pd고용체와 미세한 구형의 금속간화합물 Pd(sub2)Ga으로 구성되었음을 알 수 있었다.

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Neonatal indirect hyperbilirubinemia and glucose-6-phosphate dehydrogenase deficiency

  • Isa, Hasan M.;Mohamed, Masooma S.;Mohamed, Afaf M.;Abdulla, Adel;Abdulla, Fuad
    • Clinical and Experimental Pediatrics
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    • v.60 no.4
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    • pp.106-111
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    • 2017
  • Purpose: This study aimed to determine the prevalence of glucose-6-phosphate dehydrogenase (G6PD) deficiency among infants with neonatal indirect hyperbilirubinemia (NIH); compare G6PD-deficient and G6PD-normal patients regarding hyperbilirubinemia and need for exchange transfusions (ET); and assess risk factors for ET and kernicterus. Methods: This is a case-control retrospective study. Medical records of NIH patients admitted to the Pediatric Department, Salmaniya Medical Complex, Bahrain, between January 2007 and June 2010 were reviewed. Data on sex, age at presentation, hospitalization duration, need for ET, hemoglobin (Hb) level, reticulocyte count, direct Coombs test, serum total and indirect bilirubin levels, thyroid function, blood and urine cultures, G6PD status, and blood groups were collected and compared between the G6PD-deficent and G6PD-normal patients. Results: Of 1,159 NIH patients admitted, 1,129 were included, of whom 646 (57%) were male. Among 1,046 patients tested, 442 (42%) were G6PD deficient, 49 (4%) needed ET, and 11 (1%) had suspected Kernicterus. The G6PD-deficient patients were mainly male (P<0.0001), and had lower Hb levels (P<0.0001) and higher maximum bilirubin levels (P=0.001). More G6PD-deficient patients needed ET (P<0.0001). G6PD deficiency (P=0.006), lower Hb level (P=0.002), lower hematocrit count (P=0.02), higher bilirubin level (P<0.0001), higher maximal bilirubin level (P<0.0001), and positive blood culture result (P<0.0001) were significant risk factors for ET. Maximal bilirubin level was a significant risk factor for kernicterus (P=0.021) and independently related to ET (P=0.03). Conclusion: G6PD deficiency is an important risk factor for severe NIH. In G6PD-deficent neonates, management of NIH should be hastened to avoid irreversible neurological complications.

Evaluation of circulating PD-1 and PD-L1 as diagnostic biomarkers in dogs with tumors

  • Song, Doo-Won;Ro, Woong-Bin;Park, Hee-Myung
    • Journal of Veterinary Science
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    • v.22 no.5
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    • pp.75.1-75.10
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    • 2021
  • Background: Programmed cell death protein-1 (PD-1) and programmed cell death ligand-1 (PD-L1) have important roles in tumor evasion of the immune system. Objectives: This study aimed to assess the diagnostic utility of circulating PD-1 and PD-L1 levels in healthy dogs and dogs with tumors. Methods: Circulating PD-1 and PD-L1 levels in the serum of 71 dogs with tumors were compared with those of 52 healthy dogs by performing enzyme-linked immunosorbent assay (ELISA). Results: The ELISA results revealed higher circulating PD-1 and PD-L1 levels in dogs with tumors (2.9 [2.2-3.7] ng/mL; median [IQR] and 2.4 [1.4-4.4] ng/mL, respectively) than in healthy dogs (2.4 [1.9-3.0] ng/mL; p = 0.012 and 1.4 [0.9-2.1] ng/mL; p < 0.001, respectively). Especially, there was a significant difference in circulating PD-1 levels between healthy dogs and dogs with malignant epithelial tumors (2.4 [1.9-3.0] ng/mL and 3.1 [2.6-4.4] ng/mL, respectively; p < 0.01). In addition, there was a significant difference in circulating PD-L1 levels between healthy dogs and dogs with lymphomas (1.4 [0.9-2.1] ng/mL and 2.7 [1.6-5.8] ng/mL, respectively; p < 0.001). Conclusion: This study indicates that circulating PD-1 and PD-L1 have potential as tumor diagnostic biomarkers in dogs with tumors.

Electrochemical Corrosion Characteristics of Dental Prostheses High-Palladium Alloys (치과용 고-Pd계 합금의 부식특성)

  • 김기주;이진형
    • Journal of Biomedical Engineering Research
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    • v.22 no.6
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    • pp.511-518
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    • 2001
  • In vitro corrosion resistance of the commercially used 76.5wt.%Pd-17.6%Cu-7.2%Ga and 77.3%Pd-6.0%Ga dental Prostheses high-Palladium system alloys in cast, degassing and porcelain-firing heat treatment conditions were evaluated by the potentiodynamic polarization technique in the de-aerated 0.9%NaCl and a modified Fusayama electrolyte. From the corrosion rate experimental results, we found that there is a small difference in the corrosion resistance depending on the microstructure. However. it was so small that there is no significant problem as a dental material. The 77.3%Pd-6.0%Ga showed better corrosion resistance than the 76.5%Pd-11.6%Cu-7.2%Ga dental Prostheses high-palladium system alloys. These experimental observations in 76.5%Pd-11.6%Cu-7.2%Ga alleys are mainly due to a rapid quenching and Cu in the alloy which accelerate the eutectic reaction with a segregation and Precipitates in the microstructure. On the ocher hand, 77.3%Pd-6.0%Ga alloys, which are solid-solution matrix, show much better col·lesion resistance compared with that of 76.5%Pd-11.6%Cu-7.2%Ga alloys.

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