• Title/Summary/Keyword: PbU

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Microstructural Properties of (Pb)(La,Ce)$TiO_3$ ceramics as a function of $MnO_2$ addition ($MnO_2$ 첨가에 따른 (Pb)(La,Ce)$TiO_3$ 세라믹스의 미세구조특성)

  • Oh, D.U.;Min, S.K.;Yoon, K.H.;Yoo, J.H.;Park, C.Y.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.442-445
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    • 2001
  • In this study, microstructural and dielectric properties of $Pb_{0.83}(La_{0.2}Ce_{0.8})_{0.08}TiO_3$(PCT) ceramics as a function of $MnO_2$ addition were investigated for 30MHz ceramic resonator application. Grain size was gradually increased according to the increase of $MnO_2$ addition amount and showed the highest value of $1.502{\mu}m$ at the 0.9wt% $MnO_2$. Moreover, density showed the highest value of $7.582 g/cm^3$ at the 0.7wt% $MnO_2$.All the composition ceramics,curie temperature was nearly constant around $330^{\circ}C$

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Superconducting phenomena of the $(Bi_{1-x}Pb_x)_2Sr_2Ca_2Cu_{3.6}O_y$ systems ($(Bi_{1-x}Pb_x)_2Sr_2Ca_2Cu_{3.6}O_y$ 소결체의 초전도 현상)

  • 박용필;황교영;이준웅
    • Electrical & Electronic Materials
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    • v.4 no.3
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    • pp.201-210
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    • 1991
  • 본 논문에서는 (B $i_{1-x}$ P $b_{x}$)$_{2}$S $r_{2}$C $a_{2}$C $u_{3.6}$ $O_{y}$ (x=0~0.5)로 조성된 분말의 최적 하소온도를 결정하고 시편의 최적 소결온도를 규명하기 위하여 열분석을 하였다. 또 단일상의 고온 초전도체를 제작하기 위하여 열처리 온도, 시간 및 Pb 함량 변화에 따라 제작된 시편의 미세구조, 조성, 전기저항 및 전류밀도를 측정하여 상호 연관성을 종합적으로 분석, 검토하여 상변이에 관한 원인을 규명하고자 하였다. 또한 실용화 전 단계로서 임계특성 해석을 위하여 성형조건을 변화시켜 시편을 제작, 전류밀도값을 측정하였다.였다.다.

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Resonant Properties of $Pb(La,Ce)TiO_3$ System Ceramics (레조네이터용 $Pb(La,Ce)TiO_3$ 계 세라믹스의 공진특성)

  • Min, S.K.;Ohe, D.U.;Yoon, K.H.;Yoo, J.H.;Hong, J.I.;Kim, J.S.;Yoon, H.S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05c
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    • pp.19-24
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    • 2001
  • In this study, Pb(La Ce)$TiO_3$ composition ceramics were manufactured for 20 MHz resonator application. Electromechanical coupling factor, mechanical quality factor and dynamic range of thickness vibration mode were measured as the variations of L/T(length/thickness) ratio of ceramic substrats. Mechanical quality factor and dynamic range of third overtone thickness vibration mode showed the highest value of 2,773 and 52.22 dB at specimen S4(l/t=12), respectively. The excellent temperature stability of resonant frequency suitable for resonator application was shown, regardless of thermal shock.

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Structural and Dielectric Properties of Pb[(Zr,Sn)Ti]NbO3 Thin Films Deposited by Radio Frequency Magnetron Sputtering

  • Choi, Woo-Chang
    • Transactions on Electrical and Electronic Materials
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    • v.11 no.4
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    • pp.182-185
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    • 2010
  • $Pb_{0.99}[(Zr_{0.6}Sn_{0.4})_{0.9}Ti_{0.1}]_{0.98}Nb_{0.02}O_3$ (PNZST) thin films were deposited by radio frequency magnetron sputtering on a $(La_{0.5}Sr_{0.5})CoO_3$ (LSCO)/Pt/Ti/$SiO_2$/Si substrate using a PNZST target with an excess PbO of 10 mole%. The thin films deposited at the substrate temperature of $500^{\circ}C$ crystallized to a perovskite phase after rapid thermal annealing (RTA). The thin films, which annealed at $650^{\circ}C$ for 10 seconds in air, exhibited good crystal structures and ferroelectric properties. The remanent polarization and coercive field of the fabricated PNZST capacitor were approximately $20uC/cm^2$ and 50 kV/cm, respectively. The reduction of the polarization after $2.2\;{\times}\;10^9$ switching cycles was less than 10%.

STUDY ON DYNAMIC BEHAVIOUR IN 3PB DUCTILE STEEL SPECIMEN APPLIED BY THE IMPACT LOAD

  • HAN M. S.;CHO J. U.;BERGMARK A.
    • International Journal of Automotive Technology
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    • v.6 no.3
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    • pp.229-234
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    • 2005
  • The dynamic crack growth in ductile steel is investigated by means of the impact loaded 3 point bending (3PB) specimens. Results from experiments and numerical simulations are compared to each other. A modified 3PB specimen designed with the reduced width at its ends has been developed in order to avoid the initial compressive loading of the crack tip and also to avoid the uncertain boundary conditions at the impact heads. Numerical simulations of the experiments are made by using a finite element method (FEM) code, ABAQUS. The high speed photography is used to obtain the crack growth and the data of the crack tip opening displacement (CTOD). The direct measurements of the relative rotations of two specimen halves are made by using the Moire interference pattern.

Geochemistry of Uranium and Thorium Deposits from the Kyemyeongsan Pegmatite (계명산층 페그마타이트에 수반되는 우라늄·토륨 광상의 지구화학적 특성)

  • Park, Maeng-Eon;Kim, Gun-Soo
    • Economic and Environmental Geology
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    • v.31 no.5
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    • pp.365-374
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    • 1998
  • Economic U- and Th-bearing pegmatite deposits occur in the Kyemyeongsan Formation, and are spatially closely associated with the Carboniferous alkali granite. The pegmatite is lithochemically alkaline and peralumious, and consists mainly of potassic feldspar and quartz with allanite and U- and Th-bearing minerals. Paragenetic stages of mineralization in the pegmatite are divided as follows: early silicate mineralization, main rare metal mineralization, and late silicate mineralization. Thorite, euxenite, fergusonite and uranpyrochlore are the predominant U- and Th-bearing minerals. Both the enrichments of Nb, Y, Th, U, and Ta and the depletions of Hf, Ba, and Rb in the pegmatite were resulted from magmatic differentiation. The increases of Na and Ca in uranpyrochlore, of Th and U in fergusonite, of Si, Th, U and Pb in thorite, and of Nb and Y in euxenite were possibly resulted from both later internal fractionation and hydrothermal alteration. The variation of chemical composition in a mineral species reflects the different pysico-chemical conditions during the crystallization.

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Studies on the Separation and Preconcentration of Metal Ions by XAD-16-[4-(2-thiazolylazo)] orcinol Chelating Resin (XAD-16-[4-(2-thiazolylazo)]orcinol 킬레이트 수지에 의한 금속이온의 분리 및 농축에 관한 연구)

  • Lee, Won;Seol, Kyung-Mi;An, Hye-Sook;Lee, Chang-Heon;Lim, Jae-Hee
    • Analytical Science and Technology
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    • v.10 no.4
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    • pp.282-290
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    • 1997
  • The sorption and desorption properties of U(VI), Th(IV), Zr(IV), Cu(II), Pb(II), Ni(II), Zn(II), Cd(II) and Mn(II) ions on XAD-16-[4-(2-thiazolylazo)orcinol] (TAO) chelating resin were studied by elution method. The effect was examined with respect to overall capacity of each metal ion, separation of mixed metal ions, flow rate and concentration of buffer solution for optimum condition of sorption. The overall capacities of some metal ions on this chelating resin were 0.35nmol U(VI)/g resin, 0.49nmol Th(IV)/g resin, 0.41nmol Cu(II)/g resin, and 0.31nmol Zr(IV)/g resin, respectively. The elution order of metal ions obtained from breakthrough capacity and overall capacity at pH 5.0 was Th(IV)>Cu(II)>U(VI)>Zr(IV)>Pb(II)>Ni(II)>Zn(II)>Mn(II)>Cd(II). The group separation of mixed metal ions was possible by increasing pH in pH range 2~5 at a flow rate of 0.28mL/min. Characteristics of desorption were investigated with desorption agents such as $HNO_3$, HCl, $HClO_4$, $H_2SO_4$, and $Na_2CO_3$. It was found that 2M $HNO_3$ showed high desorption efficiency to most of metal ions except Zr(IV) ion. Also, desorption and recovery of Zr(IV) ion were successfully performed with 1M $H_2SO_4$. Recovery of trace amount of U(VI) ion from artificial sea water was over 94%. The chelating resin, XAD-16-TAO was successfully applied to group separation of rare earth metal ions from U(VI) by using 2M $HNO_3$ as an eluent.

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The Design of Intelligent Agent for Personal Finance Management System on Ubiquitous Environments (유비쿼터스 환경에서 개인자산관리 서비스를 위한 지능형 에이전트의 설계)

  • Shin, Kyung-Shik;Kim, Nam-Hee
    • Journal of Intelligence and Information Systems
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    • v.15 no.4
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    • pp.65-78
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    • 2009
  • The rapid changes of financial environment have increased the need and demand for personal financial advisory service from financial experts. In particular, as the individual customers want to get more customized financial services, the financial institutions created the private banking (PB) sector and have constantly expanded their PB services. However, it remains still problematic that the private banking system requires high costs so that the number of eligible customers who can have proper PB services is quite limited. To solve this problem, we propose an intelligent agent that can provides specialized and customized personal financial advisory services to the customers with low costs. The proposed agent systemizes and structures the information and knowledge of financial experts in private banking services so that individual customers can easily access to high-quality PB services when they need. On the first attempt we develop a framework of U-smart PB, an intelligent agent for personal financial management based on different scenarios related to personal financial decisions, and derive its core services. This system not only provides information simply, but also proposes to support personal investment decisions technically as an intelligent agent that embodies real-time customized financial management in a ubiquitous environment, regardless of time and place.

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Dielectric properties of low temperature firing glass reacted (Ba, Sr)$TiO_3$$ ceramic capacitors (저온소결용 (Ba, Sr)$TiO_3$-Glass계 세라믹스의 유전특성)

  • Gu, Ja-Won;Seol, Yong-Geon;Choe, Seung-Cheol
    • Korean Journal of Materials Research
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    • v.5 no.2
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    • pp.151-156
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    • 1995
  • Low temperature firing $(Ba, Sr)TiO_{3}$ dielectrics were successfully prepared with lead based glass and those electrical properties were investigated. Different amount of PbO content glass materials were added to dielectrics to investigate the sinterability and its dielectric properties. Also, various compositions of ceramic capacitors were prepared to applicate in multilayer ceramic capacitors. A large amount of experiment has been done with various Pb contented glasses and different sintering temperatures. The sintering temperature of $(Ba,Sr)TiO_{3}$can be reduced from $1350^{\circ}C$to as low as $1050^{\circ}C$ with 4wt% addition of $PbO-ZnO-B_{2}O_{2}$ glass materials. Its dielectric constant at room temperature was up to 8100 with low dielectric loss, 0.005. This ceramic capacitor showed fully fired microstructures with its grain size of 1-3$\mu \textrm{m}$. The sintered body which was sintered at $1150^{\circ}C$ for 2hr with 4wt% $PbO-ZnO-B_{2}O_{2}$ glass material addition satisfied the Z5U specification of the EIAS.

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Geochemical Characteristics and Pollution Level of Heavy Metals of Asian Dust in Daejeon Area, 2007 (spring season) (2007년 봄철 대전지역에서 발생한 황사 및 대기부유물의 지구화학적 특성 및 중 금속의 오염도)

  • Lee, Pyeong-Koo;Youm, Seung-Jun;Bae, Beob-Geun
    • Economic and Environmental Geology
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    • v.45 no.3
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    • pp.217-235
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    • 2012
  • We evaluated the geochemical characteristics and their potential pollution of Asian Dusts in Daejeon, Korea during spring 2007. Compared with the chemical compositions of soils in source area of Asian Dust, those of aerosols in Daejeon were enriched with trace elements (ten to hundred fold), inferring that pollutants from China have affected on local environment in adjoining country such as Korea. Chemical analysis of aerosols during Asian dust showed that fine particles ($PM_{2.5}$) contained high contents of trace elements such as Cr, Cu, Pb, Zn, V, S, As, Cd, Co, Ni, Mo, Sb, Cs, Rb, Th, Sc and Y. In the case of TSP (Total Suspended Particle), Zr, Sr, Ba, Li, Th and U were contained much more than other trace elements. The contents of some elements (i.e. Li, Cs, Co, U, Cr, Ni, Rb, V, Th, Y, Sr and Sc) in aerosols collected in Asian Dust period, which are not likely enriched by air pollutants, were higher (2 - 4.2 fold) than those in Non Asian Dust period, indicating that these elements could be used as indicator elements for determining the occurrence of Asian Dust phenomena (especially, Sr, V, Cr & Li). In the case of Asian Dust coming through the big cities and/or industrial areas of China, the domestic aerosols had higher contents of trace elements (such as S, Cd, Zn, Pb, Cu, Mo and As) than those from Northeastern China via North Korea, indicating that the transportation courses of air mass are very important to determine the pollution degrees. Using the enrichment factors of trace elements in aerosols during Asian Dust and Non Asian Dust, we identified that some elements (i.e. S, Zn, Cu, Pb, As, Mo and Cd) were most problematic in terms of environmental hazard aspects, and these elements could affect adverse effects on human health as well as ecosystem and surface environment (soil and water) through long-lived precipitation.