• Title/Summary/Keyword: Pb addition

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The Effect of Nb2O5 Addition on Properties of PZT Ceramics Prepared by Partial Oxalate Method (부분수산법으로 제조한 PZT세라믹스의 특성에 미치는Nb2O5 첨가효과)

  • 김태주;남효덕;이준형
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.1
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    • pp.33-38
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    • 2003
  • Highly homogeneous PZT powder was prepared by a partial oxalate method using chemicals of (Z $r_{0.53}$ $Ti_{0.47}$) $O_2$, Pb(N $o_3$)$_2$and (COOH)$_2$ㆍ2$H_2O$. N $b_2$ $O_{5}$ addition effect on microstructure and electrical properties of PZT ceramics was investigated. When the precursors were calcined at 71$0^{\circ}C$, a single perovskite phase was obtained. After sintering at 110$0^{\circ}C$, X-ray diffraction Patterns showed coexistence of rhombohedral and tetragonal phases regardless of the N $b_2$ $O_{5}$ content. As the content of N $b_2$ $O_{5}$ increased, grain size decreased but sintered density increased. The electromechanical coupling factor of kp and the piezoelectric constant of $d_{31}$ increased linearly with the content of N $b_2$ $O_{5}$, and those values reached 0.7 and -200, respectively, when 1.2 mol% of N $b_2$ $O_{5}$ is added. is added.ded.

Yield, Nutritional Content, and Antioxidant Activity of Pleurotus ostreatus on Corncobs Supplemented with Herb Residues

  • Jin, Zhiqiang;Li, Yunling;Ren, Jiahong;Qin, Nan
    • Mycobiology
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    • v.46 no.1
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    • pp.24-32
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    • 2018
  • Improper disposal of herb residues in China has caused severe problems to the surrounding environment and human safety. Three herb residues, i.e., compound Kushen injection residues (CKI) and part one and part two of Qizhitongluo Capsule residues (QC1 and QC2, respectively), were used for the cultivation of Pleurotus ostreatus. The effect of the supplementation of corncobs (CC) with different herb residues on yield, nutritional composition, and antioxidant activity of P. ostreatus was investigated. Compared to the control, the higher mycelial growth rate was observed on substrates CC +30% CKI and CC +30% QC1, while the higher yield was obtained from substrates CC +30% QC2 and CC +30% CKI. Moreover, chemical analysis of fruit bodies revealed that the addition of herb residues to CC significantly increased proteins, amino acids, ashes, minerals (Na and Ca), and total phenolic contents but significantly reduced carbohydrates and $IC_{50}$ values of DPPH radicals. In addition, no heavy metals (Pb, Cd, and As) were detected in the fruiting bodies harvested from different substrate combinations. These results demonstrated that mixtures of CC with herb residues might be utilized as a novel, practical, and easily available substrate for the cultivation of P. ostreatus, which is beneficial for the effective management of herb residues.

Optical Properties of Metal Halide Perovskite Nanocrystals with Addition of Metal Bromide (금속 브롬화물의 첨가에 따른 금속 할라이드 페로브스카이트 나노결정의 광학적 특성 변화)

  • Yun, Seokjin;Choi, Jihoon
    • Journal of the Korean institute of surface engineering
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    • v.52 no.6
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    • pp.334-341
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    • 2019
  • Organometal halide perovskite materials have attracted much attention in the photovoltaic and light emitting devices due to the compositional flexibility with AMX3 formula (A is an organic amine cation; M is a metal ion; X is a halogen atom). The addition of homovalent or heterovalent metal cations to the bulk organohalide perovskites has been performed to modify their energy band structure and the relevant optoelectronic properties by ligand-assisted ball milling. Here, we report CH3NH3Pb1-xMxBr3 nanocrystals substituted by metallic cations (M is Sn2+, In3+, Bi3+; x = 0, 0.01, 0.02, 0.05, 0.1, 0.2). Photoluminescence and quantum yield was significantly reduced with increasing metallic cations content. These quenching effect could be resulted from the metal cations that behave as a non-radiative recombination center.

Effects of Polyethylene Addition in Particleboard (파티클보드에 폴리에틸렌 첨가의 효과)

  • Oh, Yong-Sung
    • Journal of the Korean Wood Science and Technology
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    • v.28 no.2
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    • pp.25-31
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    • 2000
  • Low-density polyethylene (LDPE) powder was investigated as a hydrophobic additive component in particleboard (PB). PBs were manufactured using southern pine particles with a liquid phenolic resin binder at two press temperatures. LDPE at three application rates was used. PBs were tested for physical properties and water soak dimensional stability per the procedure ASTM D 1037. The results indicated that as the LDPE addition level and hot-press temperature were increased, the panel water absorption and thickness swell values decreased. However, the panel's physical properties were affected negatively by increased LDPE application rates. These results indicated that LDPE could be used only in limited amounts to improve the panel's water soak dimensional properties.

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Effect of MnO2 and CuO Addition on Microstructure and Piezoelectric Properties of 0.96(K0.5Na0.5)0.95Li0.05Nb0.93Sb0.07O3-0.04BaZrO3 Ceramics

  • Cho, Kyung-Hoon
    • Korean Journal of Materials Research
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    • v.29 no.3
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    • pp.150-154
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    • 2019
  • This study investigates the effect of MnO2 and CuO as acceptor additives on the microstructure and piezoelectric properties of $0.96(K_{0.5}Na_{0.5})_{0.95}Li_{0.05}Nb_{0.93}Sb_{0.07}O_3-0.04BaZrO_3$, which has a rhombohedral-tetragonal phase boundary composition. $MnO_2$ and CuO-added $0.96(K_{0.5}Na_{0.5})_{0.95}Li_{0.05}Nb_{0.93}Sb_{0.07}O_3-0.04BaZrO_3$ ceramics sintered at a relatively low temperature of $1020^{\circ}C$ show a pure perovskite phase with no secondary phase. As the addition of $MnO_2$ and CuO increases, the sintered density and grain size of the resulting ceramics increases. Due to the difference in the amount of oxygen vacancies produced by B-site substitution, Cu ion doping is more effective for uniform grain growth than Mn ion doping. The formation of oxygen vacancies due to B-site substitution of Cu or Mn ions results in a hardening effect via ferroelectric domain pinning, leading to a reduction in the piezoelectric charge coefficient and improvement of the mechanical quality factor. For the same amount of additive, the addition of CuO is more advantageous for obtaining a high mechanical quality factor than the addition of $MnO_2$.

Genetic Analysis of the 2019 Swine H1N2 Influenza Virus Isolated in Korean Pigs and Its Infectivity in Mice (2019년 국내에서 분리한 H1N2 돼지 인플루엔자바이러스 유전자 분석 및 이의 마우스에 대한 감염성)

  • Jang, Yunyueng;Seo, Sang Heui
    • Journal of Life Science
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    • v.30 no.9
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    • pp.749-762
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    • 2020
  • Influenza A viruses are circulating in a variety of hosts, including humans, pigs, and poultry. Swine influenza virus is a zoonotic pathogen that can be readily transmitted to humans. The influenza viruses of the 2009 H1N1 pandemic were derived from swine influenza viruses, and it has been suggested that the 1957 H2N2 pandemic and the 1968 H3N2 pandemic both originated in pigs. Pigs are regarded as a mixing vessel in the creation of novel influenza viruses since they are readily infected with human and avian influenza viruses. We isolated three novel H1N2 influenza viruses from pigs showing respiratory symptoms on a Korean farm in 2019. These viruses were reassortants, containing PA and NP genes from those of the 2009 H1N1 influenza virus in addition to PB2, PB1, HA, NA, M, and NS genes from those of triple-reassortant swine H3N2 and classical swine H1N2 influenza viruses circulating in Korean pigs. Mice infected with the isolated H1N2 influenza virus lost up to 17% body weight and exhibited interstitial pneumonia involving infiltration of many inflammatory cells. Results suggest that close surveillance to detect emerging influenza viruses in pigs is necessary for the health of both pigs and humans.

Characteristics of PLT Thin Films on MgO Substrates and Fabrication of Infrared Sensor (MgO 기판 위에 올린 PLT 박막의 특성과 적외선 센서의 제작)

  • Cho, Sung-Hyun;Jung, Jae-Mun;Lee, Jae-Gon;Kim, Ki-Wan;Hahm, Sung-Ho;Choi, Sie-Young
    • Journal of Sensor Science and Technology
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    • v.6 no.3
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    • pp.188-193
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    • 1997
  • The lanthanum-modified lead titanate (PLT) thin films on (100) cleaved MgO single crystal substrate have been prepared by RF magnetron sputtering method using PbO-rich target with varing La contents. The substrate temperature, working pressure, $Ar/O_{2}$, and RF power density of PLT thin films were $580^{\circ}C$ 10mTorr, 10/1, and $1.7W/cm^{2}$, respectively. In these conditions, the c-axis growth and tetragonality of the PLT thin films decreased for addition of La content and the PLT thin films showed diffuse phase transition from high temperature XRD patterns. The infrared sensor was fabricated. The remanent polarization was above $1.71{\mu}C/cm^{2}$ and the pyroelectric voltage was above 500mV with 10:1 signal to noise ratio.

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The Leaching and Recovery of Au from Scrap of PCBs (PCBs의 스크랩으로부터 Au 용출과 회수)

  • You, Don-Sang;Park, Cheon-Young
    • Journal of the Korean earth science society
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    • v.35 no.4
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    • pp.259-266
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    • 2014
  • This study was carried out to find an environmental friendly and effective way to leach Au and Ag from scrap of Printed Circuit Boards (PCBs) using sodium-hypochlorite solution. In an EDS analysis, valuable metals such as Cu, Sn, Sb, Al, Ni, Pb and Au were all found in PCBs. The highest leaching rates obtained were 1% of pulp density with a chlorine:hypochlorite of 2:1 and a concentration of NaCl at 2M. The highest Au recovery was observed with the addition of sodium metabisulfite to make a 3M solution. It is confirmed that the leaching agent (chlorine-hypochlorite) could effectively leach Au and Ag from Printed Circuit Boards (scrap parts) and the additive reagent sodium metabisulfite could easily precipitate Au from the chlorine-hypochlorite solution.

Removal of Chlorine from Fly Ash in Municipal Solid Waste Incineration Ash by Water Washing (수세에 의한 생활폐기물 소각재 중 비산재로부터 염소성분의 제거)

  • 안지환;한기천;김형석
    • Resources Recycling
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    • v.10 no.5
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    • pp.36-43
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    • 2001
  • The chlorine component in fly ash from municipal solid waste incineration ash was removed by water washing for the purpose of recycling fly ash as a raw material of ordinary portland cement. The samples were a different kind of 리y ashes using $Ca(OH)_2$and NaOH as media of wet scrubber for flue gas cleaning. The content of soluble salts of fly ash using $Ca(OH)_2$and NaOH was 32.8%, 50.1% and the content of chlorine component, 22.9% and 26.0% respectively, which was KCl, NaCl, CaC1OH mainly. When each fly ash was washed using water under conditions of a agitation speed of 300 rpm, a liquid to solid ratio of 10, most soluble salts in fly ash were dissolved within 30 minutes and the content of chlorine component in ash was diminished to the content of 4.4%, 2.O% at $20^{\circ}C$ and 1.7%, 0.8% at $50^{\circ}C$ respectively. And the main compound of residual chlorine component in ash after water washing was friedel`s salt ($3CaO.A1_2$$O_3$.$CaCl_2$.$10H2$O). From analysis results of water quality for wastewater by water washing, the components exceeding discharged wastewater standard were only Pb and Cd. But As pH was controlled to 10 with addition of $CO_2$(g) or $Na_2$$_CO3$in water, the concentration of heavy metals such as Pb and Cd was also under discharged wastewater standard.

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Detection of Heavy Metal Ions by the Cuvette Assay Measuring Urease Inhibitory Activity (Urease 저해활성 측정 cuvette assay에 의한 중금속 이온 검출)

  • Kim, Dong-Kyung;Park, Kyung-Rim;Kang, Eun-Mi;Park, In-Seon;Kim, Nam-Soo
    • Applied Biological Chemistry
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    • v.46 no.2
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    • pp.74-78
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    • 2003
  • To determine the urease inhibitory activity of various heavy metal ions, a photometric cuvette assay for measuring ammonia production was developed. In this assay, the absorbance values at 630 m were linearly increased according to the ammonia concentrations up to 3.0 mg/l (r : 0.998). The urease inhibitions upon addition of a single species of heavy metal ions were in the decreasing order of Hg(II) > Pb(II) > Cu(II) > Cd(II) > Zn(II) ions. As expected, the urease inhibitions at a fixed concentration of a single species and at varying concentrations of other species occurred in the additive way. The above results show the applicability of the current method to the selective detection on Hg(II) ions as well as the screening of heavy metal ions possibly present at various samples.