• Applied Biological Chemistry
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• v.4
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• pp.23-28
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• 1963

Various species of the genus Capsicum contain in their fruits an intensively sharp and pungent substance, Capsaicin, which was first isolated in an almost pure state by Thresh. Containing the pungent principle, Capsicums are used extensively in food as a spice and in medicine as a rubefacient and carminative. Numerous methods have been proposed for the isolation, the chemical structure and the quantitative determination of Capsaicin. Modifying the several methods described before, the Capsaicin contents in various species of the genus Capsicum were determined as follows. (1) The isolation of pure Capsaicin was the essential first step for the determination of Capsaicin contents. Powdered cayenne pepper was extracted with acetone. By the method of ether alkali partition extraction slightly modified at this laboratory and by the recrystallization with light petroleum ether that was repeated ten times, the pure crystalline Capsaicin was obtained. Using this Capsaicin, the standard absorption curve was drawn with Beckman spectrophotometer model DU for the quantitative determination of Capsaicin. 92) The powdered sample was extracted in a Soxhlet extractor with ether-acetone solvent system(3:1) for 25 hours. Capsaicin in this ether-acetone extracts was efficiently separated in a pure state by paper partition chromatography using 58% methanol solution as developing agent. It was found that 58% methanol was one of the most valuable solvent to separate Capsaicin from impurities such as sterols, fatty acids, waxes and carotenoid pigments. (3) The colorimetric method modifying the Schulte-Kruger's method which consists of measuring the red color produced with diazobenzenesulphonic acid was used. Capsaicin in various species of the genus Capsicum was determined quantitatively with use of Beckman spectrophotometer model DU at $480\;m{\mu}$.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2008.04a
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• pp.276-279
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• 2008

In order to measure sound transmission loss (STL) of a shipboard window of small size, a special partition is built into the test opening between two reverberation rooms and the specimen is placed in that partition. For high sound insulation, the filler wall often has multi-layered structure such as double-brick wall or buckhead structure with thick steel plate, absorptive material, and sandwich panels. This paper discusses the installation method of a multi-layered filler wall that consist of gypsum boards, lead plates, and glass wool. The experimental results of various wall structures are introduced. The comparison between the results show that the sound bridge effect plays a significant role in lowering the maximum STL of the filler wall. It is also found that the higher the sound insulation performance of the filler wall is, the more important the franking transmission through other side wall of the test facility is.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.12 no.10
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• pp.1794-1800
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• 2008

This paper presents a method of constructing the digital logic switching functions using PLA. First of all, we propose a MIN and MAX algebra arithmetic operation based on the Post algebra. And we discuss the T-gate which is used for realization of the MIN and MAX algebra arithmetic operation. Next, we discuss the MIN array and MAX array which are basic circuit of the PLA, also we discuss the literal property. For the purpose of the design for the digital logic switching functions using PLA, we Propose the variable partition, modular structure design, literal generator, decoder and invertor. The proposed method is the more compactable and extensibility.

• Journal of environmental and Sanitary engineering
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• v.10 no.3
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• pp.78-84
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• 1995

Cationic surfactants can be used to modify surface of solids to promote adsorption of hydrophobic organic compounds. This behavior is due to the surfactant forming aggregate structure on the solid surface. Partition coefficients are commonly used to quantify the distribution of organic pollutants between the aqueous and particulate phases of aquatic system Partitioning of hydrophobic compounds to cetyltrimethylammonium bromide ( CTAB ) coated silicate has been investigated as a function of surfactant surface coverage at I=0 and 0.1 ionic strength. Toluene, Xylene, TCI sorption experiments demonstrated that the CTAB coated silicate was able to remove these hydrophobic organic compounds from solution The hydrophobic organic compound with the higher Kow had higher removals than lowest Kow hydrophobic organic compound.

• Journal of the Korean Chemical Society
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• v.15 no.6
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• pp.285-293
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• 1971

The statistical thermodynamical properties of heavy water are calculated according to the transient state theory of significant liquid structure. The calculated values are shown to be in good agreement with the observed ones. The grand canonical ensemble partition function for the adsorbed phase of heavy water on graphite surface is derived using the theory. The adsorption isotherm, the surface pressure, the molar entropy and the molar internal energy for the adsorbed phase and then the molar heat of adsorption are calculated according to the derived partition function. The thermodynamic properties of the adsorbed water are also calculated and the results are compared with those of heavy water and discussed in view of the experimentally observed phenomena.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2004.05a
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• pp.699-704
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• 2004

As being inconvenient to apply reinforced concrete structure to high-rise buildings, it is applied steel structured system. Therefore light-weight wall systems are applied as partition wall to reduce the self-load of the building. But, the required performances of a light-weight wall are not evaluated systematically. As a field survey result, partition walls of house-to-house were not showed their respected performances, so the dwellers are feel so worse the quality of the whole building. In steel-structured high-rise buildings especially, occupant's dissatisfaction concerned indoor noise was high because curtain wall systems having a high air-tight performance isolate the outdoor noise making masking effect. Therefore wall systems which have high performances of sound insulation and air-tightness are required in high-rise buildings. As a result, a new drywall system was presented and the performance was verified with field test.

• Bulletin of the Korean Chemical Society
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• v.2 no.3
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• pp.90-96
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• 1981

The significant structure theory of liquids has been successfully applied to the sodium ammonia solution. In applying the theory to sodium ammonia solution, we assumed there were four species in solution, i.e., sodium cation, solvated electron, triple ion, and free electron and equilibria existed between them. Based on these assumptions, we set up the model explaining the anomalous properties of sodium ammonia solution. The partition function for sodium ammonia solution is composed of the partition functions for the above four species and also for the Debye-Huckel excess free energy term. Agreements between calculated and experimental values of the thermodynamic quantities, such as molar volume, vapor pressure, partial molar enthalpy and entropy, and chemical potential as well as viscosity are quite satisfactory.

• Bulletin of the Korean Chemical Society
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• v.33 no.5
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• pp.1527-1535
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• 2012

Selection of the most informative molecular descriptors from the original data set is a key step for development of quantitative structure activity/property relationship models. Recently, mutual information (MI) has gained increasing attention in feature selection problems. This paper presents an effective mutual information-based feature selection approach, named mutual information maximization by replacing collinear variables (MIMRCV), for nonlinear quantitative structure-property relationship models. The proposed variable selection method was applied to three different QSPR datasets, soil degradation half-life of 47 organophosphorus pesticides, GC-MS retention times of 85 volatile organic compounds, and water-to-micellar cetyltrimethylammonium bromide partition coefficients of 62 organic compounds.The obtained results revealed that using MIMRCV as feature selection method improves the predictive quality of the developed models compared to conventional MI based variable selection algorithms.

• Bulletin of the Korean Chemical Society
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• v.24 no.8
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• pp.1207-1210
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• 2003

The effect of solvent structure on the slope in the plot of ln K vs. solute carbon number was examined. It was found that the free energy of methylene group transfer from the gas phase into a solvent was always negative and that the absolute magnitude of interaction free energy between the methylene group and the solvent was always larger than the absolute magnitude of cavity formation free energy of the methylene group in the solvent. Thus, the slope in the plot of ln K vs. solute carbon number was always positive and its value decreases with increase of solvent polarity since the cavity formation energy of the CH₂ unit increases with increase of solvent polarity while the dispersive interaction energy of the CH₂ unit is virtually invariant. We also examined the effect of sequential addition of CH₂ unit to a solvent molecule upon ln K for three homologous series of solvents: n-alkanes, n-alcohols, and n-nitriles. Characteristic trends in the plots of ln K vs. solvent carbon number were observed for individual solvent groups. A decrease of ln K with solvent carbon number was observed for n-alkanes. An abrupt increase in ln K followed by levelling off was observed for n-alcohols while a final slight decrease in ln K after an abrupt increase followed by rapid levelling off was noted for n-nitriles. All of theses phenomena were found related to variation in cavity formation energy. It was clearly shown that a structural change of a polar solvent by sequential addition of CH₂ units causes an abrupt polarity decrease initially, then gradual levelling off, and finally, conversion to a virtually nonpolar solvent if enough CH₂ units are added.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.9
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• pp.1032-1041
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• 2004

In this study we decompose the 3-dimensional velocity field of isotropic turbulent flow into the coherent and the incoherent structure using the discrete wavelet. It is shown that the coherent structure, 3% wavelet modes, has 98% energy and 88% enstrophy and its statistical characteristics are almost same as the original turbulence structure. And it is confirmed that the role of the coherent structure is that it produces the turbulent kinetic energy at the inertia range then transfers energy to the dissipation range. The incoherent structure, with residual wavelet modes, is uncorrelated and has the Gaussian probability density function but it dissipates the kinetic energy in dissipation range. On the procedure, we propose a new but easy way to get the threshold by applying the energy partition percentage concept about coherent structure. The vorticity field extracted from the wavelet-decomposed velocity field has the same structure as the result of the precedent studies which decomposed vorticity field directly using wavelet. Therefore it has been shown that velocity and vorticity field are on the interactive condition.