• Journal of Korean Society for Atmospheric Environment
• /
• v.29 no.5
• /
• pp.601-614
• /
• 2013

The commercial charcoal kiln was projected the largest source of biomass burning sector in Korea. Commercial charcoal kiln was operated to emit air pollutants into the air without any air pollution prevention equipment. The object of this field survey was to understand characteristics of air pollutants concentration and emission factors and to provide preliminary data for effective processor from oak charcoal manufacturing process. As result of field survey, TSP, $PM_{10}$ and $PM_{2.5}$ concentration from charcoal kiln were 400~37,000 $mg/m^3$. These values were over the 100 $mg/m^3$ in TSP, this value was effluent quality standard of Clean Air Conservation Act. The average concentration of CO, $SO_2$ and TVOC were 2~5%. 0~110 ppm and 820~10,000 ppm respectively. The emission factors were 42.4 g-PM/kg-oak in TSP, 40.3 g-PM/kg-oak in $PM_{10}$, 38.2 g-PM/kg-oak in $PM_{2.5}$, 182.5 g-CO/kg-oak, 1.0 g-NO/kg-oak, $SO_2$ 0.2 g-$SO_2/kg$-oak and 104.4 g-TVOC/kg-oak. The part of commercial charcoal kiln had air pollution prevention equipment but it was difficult to work properly. Much wood tar excreted in exhaust emissions from oak charcoal manufacturing process. This wood tar was cause of many troubles sticking in the air pollutant prevention equipment. For handling particulate matters and gaseous air pollutants from oak charcoal manufacturing process in biomass burning, air pollutant prevention equipment design and management needs preprocessor for removal wood tar.

• Journal of environmental and Sanitary engineering
• /
• v.18 no.4
• /
• pp.24-35
• /
• 2003

Recent epidemiologic studies revealed that the concentration of air pollutants and fine particulated matter have some effects on health status and are associated with increased mortality and morbidity. The purpose of this study was to characterize background mass concentration of fine particle (PM2.5) and metallic composition from September 2001 to August 2002 in comparison with a medium city, Asan and metropolitan city, Seoul. Conclusively, proper management for fine particles was required in a medium city, Asan, considering the concentrations of metallic elements in fine particles in Asan were relatively higher than those in Seoul. The results were as followed. 1. Average mass concentrations of fine particles in Asan and Seoul were 37.70(${\pm}18.41{\;}{\mu}g/\textrm{m}^3$) and 5.83(${\pm}38.50$) ${\mu}g/\textrm{m}^3$, respectively. When the weather conditions were classified as normal and yellow-sand, measured average mass concentrations of fine particles in yellow-sand weather condition was significantly higher than those of normal weather condition in both cities (p<0.05). 2. Depending on seasons, measured average mass concentrations of fine particles in Asan and Seoul in spring were 47.76(${\pm}19.07$) ${\mu}g/\textrm{m}^3$m and 61.53 (${\pm}4.37$) ${\mu}g/\textrm{m}^3$, respectively. In summer, the average mass concentrations of fine particles in Asan and Seoul were 29.44(${\pm}9.85$) ${\mu}g/\textrm{m}^3$ and 25.42(${\pm}8.10$) ${\mu}g/\textrm{m}^3$, respectively. Especially, the concentration was the highest in spring and the lowest in summer among four seasons. 3. Average concentrations of manganese(Mn), iron(Fe), chromium(Cr), cadmium(Cd), lead(Pb) and silicon(Si) in fine particles in Asan were significantly higher in Seoul (p<0.05). Average concentration of Si in fine particle in Asan was statistically higher than that of Seoul during yellow -sand condition (p<0.05). 4. Considering the characterization of four seasons, average Pb concentration of fine particle in Asan is significantly higher than that of Seoul in spring(p<0.01). In summer, average Mn and Cr concentrations of fine particle in Asan is higher than those of Seoul (p<0.05). Average Mn, Fe. Cr and Si concentrations in fall (p<0.05), and average Mn, Fe, Cr, Pb, and Si concentrations in winter (p<0.05) in Asan were higher than those of Seoul, respectively. 5. Mass concentrations of each Mn, Fe, Cd and Si in fine particles were significantly correlated with both cities. In normal weather condition, Mn, Cu and Si concentrations are statistically significant in Asan, while Mn, Fe, Cu and Si concentrations are statistically significant in Seoul. Mn, Fe and Si concentrations in both cities were statistically significant during yellow-sand weather.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.36 no.11
• /
• pp.1065-1072
• /
• 2012

Due to its oxygen (O) content, biodiesel (BD) is advantageous in that it lowers PM emissions in CI engines. Therefore, BD is considered one of the best candidates for low temperature combustion (LTC) operation because its use can extend the regime for simultaneous reduction of PM and $NO_x$. Thus, in this study, LTC operation was realized using BD and diesel with a 5~7% $O_2$ fraction. Engine test results show that the use of BD increased the efficiency and reduced emissions such as PM, THC, and CO; furthermore, IMEP reduced by 10~12% owing to the lower LHV of the fuel. In particular, smoke was suppressed by up to 90% because O atoms in the BD enhanced the soot oxidation reaction. To compensate the IMEP loss, turbocharging (TC) was then tested, and the results showed that the power output increased and PM was reduced further. Moreover, TC in BD engine operation allowed a similar level of reduction in both $NO_x$ and PM at 11~12% $O_2$ fraction, suggesting that there is a potential to widen the operating range by the combination of TC and BD.

• Journal of the Korean earth science society
• /
• v.36 no.1
• /
• pp.36-50
• /
• 2015

The purpose of this study is to assign emission source profiles of volatile organic compounds (VOCs) and particulate matters (PMs) for chemical speciation, and to correct the temporal allocation factor and the chemical speciation of source profiles according to the source classification code within the sparse matrix operator kernel emission system (SMOKE) in the Seoul metropolitan area. The chemical speciation from the source profiles of VOCs such as gasoline, diesel vapor, coating, dry cleaning and LPG include 12 and 34 species for the carbon bond IV (CBIV) chemical mechanism and the statewide air pollution research center 99 (SAPRC99) chemical mechanism, respectively. Also, the chemical speciation of PM2.5 such as soil, road dust, gasoline and diesel vehicles, industrial source, municipal incinerator, coal fired, power plant, biomass burning and marine was allocated to 5 species of fine PM, organic carbon, elementary carbon, $NO_3{^-}$, and $SO_4{^2-}$. In addition, temporal profiles for point and line sources were obtained by using the stack telemetry system (TMS) and hourly traffic flows in the Seoul metropolitan area for 2007. In particular, the temporal allocation factor for the ozone modeling at point sources was estimated based on $NO_X$ emission inventories of the stack TMS data.

• Journal of Korean Society for Atmospheric Environment
• /
• v.32 no.1
• /
• pp.67-81
• /
• 2016

In order to examine the variation characteristics of chemical compositions in accordance with the different meteorological conditions, $PM_{10}$ and $PM_{2.5}$ were collected at Gosan site of Jeju Island in 2014, and then their ionic and elemental species were analyzed. The concentrations of nss-$SO{_4}^{2-}$ and $NH_4{^+}$ were respectively 4.3 and 3.3 times higher in fine particle mode ($PM_{2.5}$) compared to coarse particle mode ($PM_{10-2.5}$), however $NO_3{^-}$ concentration was 1.6 times higher in coarse mode compared to fine particle mode. During Asian dust days, the concentrations of nss-$Ca^{2+}$ and $NO_3{^-}$ increased highly as 7.7 and 4.5 times in coarse particle mode, and 3.0 and 4.9 times higher in fine particles, respectively. Especially, the concentrations of the crustal species (Al, Fe, Ca, K, Mn, Ba, Sr, etc.) indicated a noticeable increase during the Asian dust days. For the haze days, the concentrations of secondary pollutants increased 2.2~2.7 and 2.9~6.0 times in coarse and fine particles, respectively, and they were 0.8~1.1 and 1.8~2.4 times, respectively, during the mist days. The aerosols were acidified largely by sulfuric and nitric acids, and neutralized mainly by ammonia in fine particle mode during the haze days, but neutralized by calcium carbonate in coarse particle mode during the Asian dust days. The clustered back trajectory analysis showed that the concentrations of nss-$SO{_4}^{2-}$, $NO_3{^-}$, and $NH_4{^+}$ were relatively high when the inflow pathway of air mass was from the southern part of China.

• Journal of Korean Society of Transportation
• /
• v.34 no.5
• /
• pp.377-393
• /
• 2016

Vehicle emissions have been known as a critical factor to give a negative impact on the public health. In particular, particulate matters(PM) and NOx are highly related with respiratory diseases such as asthma. This study aimed at analyzing spatio-temporal patterns of PM and NOx generated from urban freeway traffic. MOVES, which is a well-known emission analysis tool presented by US Environmental Protection Agency(EPA), was applied to estimate PM and NOx based on traffic volume and speed data obtained from Seoul Outer Ring Expressway during January~June, 2012. K-means clustering analysis was used for categorizing the Level of Vehicle Emissions(LOVE) to support more systematical identification of the significance of emissions. Then, spatio-temporal analyses of estimated emissions were conducted by LOVE. Finally, this study proposed a set of strategies to reduce both PM and NOx to enhance public health based on analysis results.

• Journal of Environmental Science International
• /
• v.12 no.6
• /
• pp.665-676
• /
• 2003

To investigate the chemical characteristics of PM$\_$2.5/ in Seoul, Korea, atmospheric particulate matters were collected using a PM$\_$10/ dichotomous sampler including PM$\_$10/ and PM$\_$2.5/ inlet during the period of October 2000 to September 2001. The Inductively Coupled Plasma-Mass Spectromety (ICP-MS), ion Chromatography (IC) methods were used to determine the concentration of both metal and ionic species. A statistical analysis was performed for the heavy metals data set using a principal component analysis (PCA) to derived important factors inherent in the interactions among the variables. The mean concentrations of ambient PM$\_$2.5/ and PM/sub10/ were 24.47 and 45.27 $\mu\textrm{g}$/㎥, respectively. PM$\_$2.5/ masses also showed temporal variations both yearly and seasonally. The ratios of PM$\_$2.5/PM$\_$10/ was 0.54, which similar to the value of 0.60 in North America. Soil-related chemical components (such as Al, Ca, Fe, Si, and Mn) were abundant in PM$\_$10/, while anthropogenic components (such as As, Cd, Cr, V, Zn and Pb) were abundant in PM2s. Total water soluble ions constituted 30∼50 % of PM$\_$2.5/ mass, and sulfate, nitrate and ammonium were main components in water soluble ions. Reactive farms of NH$_4$$\^$+/were considered as NH$_4$NO$_3$ and (NH$_4$)$_2$SO$_4$ during the sampling periods. In the results of PCA for PM$\_$2.5/, we identified three principal components. Major contribution to PM$\_$2.5/ seemed to be soil, oil combustion, unidentified source. Further study, the detailed interpretation of these data will need efforts in order to identify emission sources.

• Journal of the Korean earth science society
• /
• v.35 no.7
• /
• pp.543-553
• /
• 2014

The environmental behavior of $SO_2$ was investigated in terms of the factors affecting the temporal variabilities by analyzing the data sets obtained from the Yongsan district in Seoul from 2004 till 2013. To this end, the relationship between $SO_2$ and relevant parameters including particulate matters (such as $PM_{2.5}$, $PM_{10}$, and TSP (total suspended particulates)) and gaseous components ($CH_4$, CO, THC (total hydrocarbon), NMHC (non-methane hydrocarbon), NO, $NO_2$, NOx, and $O_3$) was investigated in several aspects. Over a decade, the annual mean concentrations of $SO_2$ varied in the range of $4.36-5.86nmole\;mole^{-1}$ (min-max) which was about five times lower than the regulation guideline set for the air quality management in Korea. In fact, this pattern greatly contrasts with some other air pollutants of which concentrations exceeded their guideline values significantly. According to our analysis, $SO_2$ was strongly correlated to the temperature and other relevant parameters. The overall results of this study confirm that the administrative regulation of $SO_2$ levels has been made effectively relative to other airborne pollutants.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.20 no.1
• /
• pp.88-94
• /
• 2012

One of the effective ways to reduce both $NO_x$ and PM at the same time in a diesel CI engine is to operate the engine in low temperature combustion (LTC) regimes. In general, two strategies are used to realize the LTC operation-dilution controlled LTC and late injection LTC - and in this study, the former approach was used. In the dilution controlled regime, LTC is achieved by supplying a large amount of EGR to the cylinder. The significant EGR gas increases the heat capacity of in-cylinder charge mixture while decreasing oxygen concentration of the charge, activating low temperature oxidation reaction and lowering PM and $NO_x$ emissions. However, use of high EGR levels also deteriorates combustion efficiency and engine power output. Therefore, it is widely considered to use increased intake pressure as a way to resolve this issue. In this study, the effects of intake pressure variations on performance and emission characteristics of a single cylinder diesel engine operated in LTC regimes were examined. LTC operation was achieved in less than 8% $O_2$ concentration and thus a simultaneous reduction of both PM and $NO_x$ emission was confirmed. As intake pressure increased, combustion efficiency was improved so that THC and CO emissions were decreased. A shift of the peak Soot location was also observed to lower $O_2$ concentration while $NO_x$ levels were kept nearly zero. In addition, an elevation of intake pressure enhanced engine power output as well as indicated thermal efficiency in LTC regimes. All these results suggested that LTC operation range can be extended and emissions can be further reduced by adjusting intake pressure.

• Journal of the Korean earth science society
• /
• v.31 no.6
• /
• pp.600-607
• /
• 2010

In 2008, multiple episodes of large-scale transport of natural airborne particles and anthropogenically affected particles from different sources in the East Asian continent were identified in the National Oceanic and Atmospheric Administration (NOAA) satellite RGB-composite images and the mass concentrations of ground level particulate matters. To analyze the aerosol size distribution during the large-scale transport of atmospheric aerosols, both aerosol optical depth (AOD; proportional to the aerosol total loading in the vertical column) and fine aerosol weighting (FW; fractional contribution of fine aerosol to the total AOD) of Moderate resolution Imaging Spectroradiometer (MODIS) aerosol products were used over the East Asian region. The six episodes of massive natural airborne particles were observed at Cheongwon, originating from sandstorms in northern China, Mongolia and the loess plateau of China. The $PM_{10}$ and $PM_{2.5}$ stood at 70% and 16% of the total mass concentration of TSP, respectively. However, the mass concentration of $PM_{2.5}$ among TSP increased as high as 23% in the episode in which they were flowing in by way f the industrial area in east China. In the other five episodes of anthropogenically affected particles that flowed into the Korean Peninsula from east China, the mass concentrations of $PM_{10}$ and $PM_{2.5}$ among TSP reached 82% and 65%, respectively. The average AOD for the large-scale transport of anthropogenically affected particle episodes in the East Asian region was measured at $0.42{\pm}0.17$ compared with AOD ($0.36{\pm}0.13$) for the natural airborne particle episodes. Particularly, the regions covering east China, the Yellow Sea, the Korean Peninsula, and the east Korean sea were characterized by high levels of AOD. The average FW values observed during the event of anthropogenically affected aerosols ($0.63{\pm}0.16$) were moderately higher than those of natural airborne particles ($0.52{\pm}0.13$). This observation suggests that anthropogenically affected particles contribute greatly to the atmospheric aerosols in East Asia.