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http://dx.doi.org/10.5572/KOSAE.2016.32.1.067

Influences of Asian Dust, Haze, and Mist Events on Chemical Compositions of Fine Particulate Matters at Gosan Site, Jeju Island in 2014  

Song, Jung-Min (Faculty of Chemistry and Cosmetics, Jeju National University)
Bu, Jun-Oh (Faculty of Chemistry and Cosmetics, Jeju National University)
Yang, Seung-Hyuk (Faculty of Chemistry and Cosmetics, Jeju National University)
Lee, Jae-Yun (Faculty of Chemistry and Cosmetics, Jeju National University)
Kim, Won-Hyung (Faculty of Chemistry and Cosmetics, Jeju National University)
Kang, Chang-Hee (Faculty of Chemistry and Cosmetics, Jeju National University)
Publication Information
Journal of Korean Society for Atmospheric Environment / v.32, no.1, 2016 , pp. 67-81 More about this Journal
Abstract
In order to examine the variation characteristics of chemical compositions in accordance with the different meteorological conditions, $PM_{10}$ and $PM_{2.5}$ were collected at Gosan site of Jeju Island in 2014, and then their ionic and elemental species were analyzed. The concentrations of nss-$SO{_4}^{2-}$ and $NH_4{^+}$ were respectively 4.3 and 3.3 times higher in fine particle mode ($PM_{2.5}$) compared to coarse particle mode ($PM_{10-2.5}$), however $NO_3{^-}$ concentration was 1.6 times higher in coarse mode compared to fine particle mode. During Asian dust days, the concentrations of nss-$Ca^{2+}$ and $NO_3{^-}$ increased highly as 7.7 and 4.5 times in coarse particle mode, and 3.0 and 4.9 times higher in fine particles, respectively. Especially, the concentrations of the crustal species (Al, Fe, Ca, K, Mn, Ba, Sr, etc.) indicated a noticeable increase during the Asian dust days. For the haze days, the concentrations of secondary pollutants increased 2.2~2.7 and 2.9~6.0 times in coarse and fine particles, respectively, and they were 0.8~1.1 and 1.8~2.4 times, respectively, during the mist days. The aerosols were acidified largely by sulfuric and nitric acids, and neutralized mainly by ammonia in fine particle mode during the haze days, but neutralized by calcium carbonate in coarse particle mode during the Asian dust days. The clustered back trajectory analysis showed that the concentrations of nss-$SO{_4}^{2-}$, $NO_3{^-}$, and $NH_4{^+}$ were relatively high when the inflow pathway of air mass was from the southern part of China.
Keywords
Asian dust; Haze; Mist; $PM_{10}$; $PM_{2.5}$; Gosan site;
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1 Lee, D.-E., W.-H. Kim, E.-K. Jo, J.-H. Han, C.-H. Kang, and K.-H. Kim (2011) Acidification and Neutralization Characteristics of Atmospheric Fine Particles at Gosan Site of Jeju Island in 2008, J. Korean Soc. Atmos. Environ., 27(5), 603-613. (in Korean with English abstract)   DOI
2 Lee, H.-D., G.-H. Lee, I.-D. Kim, J.-S. Kang, and K.-J. Oh (2013) The Influences of Concentration Distribution and Movement of Air Pollutants by Sea Breeze and Mist around Onsan Industrial Complex, Clean Technology, 19(2), 95-104. (in Korean with English abstract)   DOI
3 Lee, H.-S., C.-M. Kang, B.-W. Kang, and H.-K. Kim (1999) A Study of Concentration Characteristics of Acidic Air Pollutants During the Summer and Winter Seasons in Seoul, J. Korean Soc. Atmos. Environ., 15 (2), 113-120. (in Korean with English abstract)
4 Lee, K.Y., Y.J. Kim, C.H. Kang, J.S. Kim, L.S. Chang, and K.H. Park (2015) Chemical characteristics of longrange-transported $PM_{2.5}$ at Gosan, Jeju Island, in the spring and fall of 2008, 2009, 2011, and 2012, J. Air & Waste Management Assoc., 65(4), 445-454.   DOI
5 Lee, S.-B., G.-N. Bae, Y.P. Kim, H.-C. Jin, Y.-S. Yoon, and K.-C. Moon (2002) Aerosol Characteristics at Tokchok Island in the Yellow Sea, J. Korean Soc. Atmos. Environ., 18(4), 305-316. (in Korean with English abstract)
6 Lee, S.H., B.W. Kang, I.J. Yeon, J.R. Choi, H.P. Park, H.S. Lee, and B.Y. Cho (2012) Analysis of $PM_{2.5}$ Case Study Burden at Chungju City, J. Korean Soc. Atmos. Environ., 28(5), 595-605. (in Korean with English abstract)   DOI
7 Lee, Y.-J., S.-A. Jung, M.-R. Jo, S.-J. Kim, M.-K. Park, J.-Y. Ahn, Y.-S. Lyu, W.-J. Choi, Y.-d. Hong, J.-S. Han, and J.-H. Lim (2014) Characteristics of PM Chemical Component during Haze Episode and Asian Dust at Gwang-ju, J. Korean Soc. Atmos. Environ., 30(5), 434-448. (in Korean with English abstract)   DOI
8 Mainey, A. and T. William (1999) Compendium of Methods for the Determination of Inorganic Compounds in Ambient Air: (Chapter IO-3) Chemical Species Analysis of Filter-Collected Suspended Particulate Matter, US Environmental Protection Agency EPA/625/R-96/010a, 1-27.
9 Masiol, M., S. Squizzato, D. Ceccato, G. Rampazzo, and B. Pavoni (2012) Determining the influence of different atmospheric circulation patterns on $PM_{10}$ chemical composition in a source apportionment study, Atmos. Environ., 63, 117-124.   DOI
10 McMurry, P., M. Shepherd, and J. Vickery (2004) Particulate Matter Science for Policy Makers; a NARSTO Assessment (Chapter 3), Cambridge University Press, U.K.
11 Na, D.J. and B.K. Lee (2000) A Study on the Characteristics of $PM_{10}$ and Air-borne Metallic Elements Produced in the Industrial City, J. Korean Soc. Atmos. Environ., 16(1), 23-35. (in Korean with English abstract)
12 NIER (National Institute of Environmental Research, 2011) 2010 The Annual report for operating result of air pollution intensive monitoring stations.
13 Park, J.-S., C.-H. Kim, J.-J. Lee, J.-H. Kim, U.-H. Hwang, and S.-D. Kim (2010) A Study on The Chemical Mass Composition of Particle Matter in Seoul, Journal of Korean Society of Urban Environment, 10 (3), 293-303. (in Korean with English abstract)
14 Park, S.M., K.J. Moon, J.S. Park, H.J. Kim, J.Y. Ahn, and J.S. Kim (2012) Chemical Characteristics of Ambient Aerosol during Asian Dusts and High PM Episodes at Seoul Intensive Monitoring Site in 2009, J. Korean Soc. Atmos. Environ., 28(3), 282-293. (in Korean with English abstract)   DOI
15 Rengarajan, R., A.K. Sudheer, and M.M. Sarin (2011) Wintertime $PM_{2.5}$ and $PM_{10}$ carbonaceous and inorganic constituents from urban site in western India. Atmos. Res., 102(4), 420-431.   DOI
16 Shin, S.A., J.S. Han, Y.D. Hong, J.Y. Ahn, K.J. Moon, S.J. Lee, and S.D. Kim (2005) Chemical Composition and Features of Asian Dust Observed in Korea (2000-2002), J. Kor. Soc. Atmos. Environ., 21(1), 119-129. (in Korean with English abstract)
17 Roth, B. and K. Okada (1998) On the Modification of Sea-Salt Particles in the Coastal Atmosphere, Atmos. Environ., 32, 1555-1569.   DOI
18 Seinfeld, J.H. and S.N. Pandis (1998) Atmospheric Chemistry and Physics, John Wiley & Sons, New York, U.S.A., 408.
19 Shin, H.J., T.J. Lee, and D.S. Kim (1996) A Study on the Size Distribution of Trace Metals Concentrations in the Ambient Aerosols, J. Korean Soc. Atmos. Environ., 12(1), 67-77. (in Korean with English abstract)
20 Sokolik, I.N., D.M. Winker, G. Bergametti, D.A. Gillette, G. Carmichael, Y.J. Kaufman, L. Gomes, L. Schuetz, and J.E. Penner (2001) Introduction to Special Section: Outstanding Problems in Quantifyinf the Radiative Impacts of Mineral Dust, J. Geophys. Res., 106, 18015-18027.   DOI
21 Sun, Y., G. Zhuang, A. Tang, Y. Wang, and Z. An (2006) Chemical characteristics of $PM_{2.5}$ and $PM_{10}$ in hazefog episodes in Beijing, Environ. Sci. Technol., 40(10), 3148-3155.   DOI
22 Szigeti, T., V.G. Mihucz, M. Ovari, A. Baysal, S. Atilgan, S. Akman, and G. Zaray (2013) Chemical characterization of $PM_{2.5}$ fractions of urban aerosol collected in Budapest and Istanbul, Microchemical Journal, 107, 86-94.   DOI
23 Wang, Y., G. Zhuang, A. Tang, H. Yuan, Y. Sun, S. Chen, and A. Zheng (2005) The ion chemistry and the source of $PM_{2.5}$ aerosol in Beijing, Atmos. Environ., 39, 3771-3784.   DOI
24 Yeatman, S.G., L.J. Spokes, and T.D. Jickells (2001) Comparisons of coarse-mode aerosol nitrate and ammonium at two polluted coastal sites, Atmos. Environ., 35, 1321-1335.   DOI
25 Wang, Y., G. Zhuang, X. Zhang, K. Huang, C. Xu, A. Tang, J. Chen, and Z. An (2006) The ion chemistry, seasonal cycle, and source of $PM_{2.5}$ and TSP aerosol in Shanhai, Atmos. Environ., 40, 2935-2952.   DOI
26 Wolff, G.T., P.E. Korsog, N.A. Kelly, and M.A. Ferman (1985) Relationships between fine particulate species, gaseous pollutants and meteorological parameters in detroit, Atmos. Environ., 19(8), 1341-1349.   DOI
27 Wurzler, S., T.G. Reisin, and Z. Levin (2000) Modification of Mineral Dust Particles by Cloud Processing and Subsequent Effects on Drop Size Distributions, J. Geophys. Res., 105, 4501-4512.   DOI
28 Zhang, R., Z. Shen, T. Cheng, M. Zhang, and Y. Liu (2010) The Elemental Composition of Atmospheric Particles at Beijing during Asian Dust Events in Spring 2004, Aerosol and Air Quality Research, 10, 67-75.
29 Zhuang, L. and B.J. Huebert (1996) Lagrangian analysis of the total ammonia budget during Atlantic Stratocumulus Transition Experiment/Marine Aerosol and Gas Exchange, J. Geophys. Res., 101, 4341-4350.   DOI
30 Calvo, A.I., C. Alves, A. Castro, V. Pont, A.M. Vicente, and R. Fraile (2013) Research on aerosol sources and chemical composition: Past, current and emerging issues, Atmos. Res., 120-121, 1-28.   DOI
31 Choi, G.H., K.H. Kim, C.H. Kang, and J.H. Lee (2003) The influence of the Asian dust on the metallic composition of fine and coarse particles fractions, J. Korean Soc. Atmos. Environ., 19(1), 45-56. (in Korean with English abstract)
32 Choi, H. (2011) Characteristics of hourly variation of gaseous pollutant concentration at Gangneung, Korea for Yellow Sand Event period in winter-case study of February 14-16, 2005, Journal of Climate Research, 6(1), 59-76.
33 Chun, Y., J.-Y. Lim, and B.-C. Choi (2003) The Features of Aerosol in Seoul by Asian Dust and Haze during Springtime from 1998 to 2002, J. Atmo. Sci., 39 (4), 459-474. (in Korean with English abstract)
34 Han, J.S., Y.M. Kim, J.Y. Ahn, B.J. Kong, J.S. Choi, S.U. Lee, and S.J. Lee (2006) Spatial Distribution and Variation of Long-range Transboundary Air Pollutants Flux during 1997-2004, J. Korean Soc. Atmos. Environ., 22(1), 99-106. (in Korean with English abstract)
35 Dentener, F.J., G.R. Carmichael, Y. Zhang, J. Lelieveld, and P.J. Crutzen (1996) Role of Mineral Aerosol as a Reactive Surface in the Global Troposphere, J. Geophys. Res., 101, 22869-22889.   DOI
36 Draxler, R.R and G.D. Rolph (2013) HYSPLIT (HYbrid Single-Particle Lagrangian Integrated Trajectory) Model access via NOAA ARL READY Websit (http://ready.arl.noaa.gov/HYSPLIT_traj.php).
37 Galloway, J.N. and W.C. Keene (1989) Processes controlling the concentrations of $SO_4\;^{2-}$, $NO_3\;^-$, $NH_4\;^+$, $H^+$, $HCOO_T$ and $CH_3COO_T$ in precipitation on Bermuda, Tellus, 41B, 427-443.   DOI
38 Hatakeyama, S., K. Murano, F. Sakamaki, H. Mukai, H. Bandow, and Y. Komazaki (2001) Transport of atmospheric pollutants from East Asia, Water, Air and Soil Pollution, 130, 373-378 (2001).   DOI
39 Huebert, B., T. Bates, P. Russell, J. Seinfeld, M. Wang, M. Uematsu, and Y.J. Kim (2003) An overview of ACE-Asia; Strategies for quantifying the relationships between Asian aerosols and their climatic impaets, J. Geophys. Res., 108, 18361-18370.
40 Hyeon, D.-R., J.-M. Song, K.-J. Kim, W.-H. Kim, C.-H. Kang, and H.-J. Ko (2014) Compositions of haze aerosols and their variation by inflow pathway of air mass at Gosan site in Jeju Island during 2012-2013, Anal. Sci. Technol., 27(4), 213-222. (in Korean with English abstract)   DOI
41 Jo, H.-Y. and C.-H. Kim (2010) Characteristics of East Asia synoptic meteorological conditions in association with haze phenomena, Atmosphere, 20(2), 161-172. (in Korean with English abstract)
42 Kim, K.-J., S.-H. Lee, D.-R. Hyeon, H.-J. Ko, W.-H. Kim, and C.-H. Kang (2014) Composition comparison of $PM_{10}$ and $PM_{2.5}$ fine particulate matter for Asian dust and haze events of 2010-2011 at Gosan site in Jeju Island, Anal. Sci. Technol., 27(1), 1-10. (in Korean with English abstract)   DOI
43 Jo, H.-Y. and C.-H. Kim (2011) Characteristics of Air Quality over Korean Urban Area due to the Long-range Transport Haze Events, J. Korean Soc. Atmos. Environ., 27(1), 73-86. (in Korean with English abstract)   DOI
44 Jung, J.-H. and Y.-J. Han (2008) Study on Characteristics of $PM_{2.5}$ and Its Ionic Constituents in Chuncheon, Korea, J. Korean Soc. Atmos. Environ., 24(6), 682-692. (in Korean with English abstract)   DOI
45 Kang, C.H., W.H. Kim, H.J. Ko, and S.B. Hong (2009) Asian Dust effect on Total Suspended Particulate (TSP) compositions at Gosan in Jeju Island, Korea, Atmos. Res., 94(2), 345-355.   DOI
46 Kim, N.K., Y.P. Kim, C.H. Kang, and K.C. Moon (2004) Characteristics of Nitrate Concentration Measured at Gosan: Measurement Data of $PM_{2.5}$ and TSP between 1998 and 2002, J. Korean Soc. Atmos. Environ., 20(1), 119-128.
47 Kim, S. and S. Lee (2013) The Analysis of the Weather Characteristics by Source Region of the Asian Dust Observed in South Korea, Journal of the Korean Geographical Society, 48(2), 167-183. (in Korean with English abstract)
48 Lee, D., J. Park, B. Kong, S. Lee, H. Kim, J. Park, H. Jeon, and S. Seo (2010) The Characteristics of the Air Pollutants Distribution and Concentration at the Baengnyeong Island (III), National Institute of Environmental Research.