• 제목/요약/키워드: Particles

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수열합성법에 의한 Zinc Selenide 나노 분말 합성 및 미세구조 특성 연구 (Fabrication and Characterization of Nano-Sized ZnSe Powders by Hydrothermal Process)

  • 김미소;홍현선
    • 한국재료학회지
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    • 제27권9호
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    • pp.459-465
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    • 2017
  • Nano-sized Zinc selenide (ZnSe) powder was successfully synthesized using Zn and Se precursors in a hydrothermal process. Temperature for the synthesis was varied from $95^{\circ}C$ to $180^{\circ}C$ to evaluate its influence on the microstructural properties of the synthetic particles. ZnSe powder thus fabricated was characterized using various analytical tools such as SEM, XRD, TEM and UV-Vis methods. Two types of ZnSe particles, that is, the precipitated particle and the colloidal particles, were identified in the analysis. The precipitated particles were around 100 nm in average size, whereas the average size of the colloidal particles was around 20 nm. The precipitated particles made at $150^{\circ}C$ and $180^{\circ}C$ were found to be a single phase of ZnSe; however, an inhomogeneous phase was obtained at the lower synthesis temperature of $95^{\circ}C$, suggesting that the temperature for the synthesis should be over $100^{\circ}C$. The precipitated particles were inactive in the UV-Vis absorption investigation, whereas the colloidal particles showed that absorptions occurred at 380 nm in the UV-Vis spectrum.

에틸렌/공기 역확산 화염에서의 초기 매연 입자의 성장 특성 (The evolution characteristics of incipient soot particles in ethylene/air inverse diffusion flame)

  • 오광철;이은도;신현동;이의주
    • 한국연소학회지
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    • 제9권2호
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    • pp.38-44
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    • 2004
  • The evolution of incipient soot particles has been examined by high resolution electron microscopy (HRTEM) and elemental analyzer in ethylene-air inverse diffusion flames. Laser Induced Incandescence(LII) and laser scattering methods were introduced for examining the soot volume fraction and morphological properties in combustion generated soot qualitatively. Soot particles, collected by thermophoretic sampling, were analyzed by using HRTEM to examine the nano structure of precursor particles. HRTEM micrographs apparently reveal a transformation of condensed phase of semitransparent tar-like material into precursor particles with relatively distinct boundary and crystalline which looks like regular layer structures. During this evolution histories, C/H analysis was also performed to estimate the chemical evolution of precursor particles. The changes of C/H ratio of soot particles with respect to residence time can be divided into two parts: one is a very slowly increasing regime where tar-like materials are transformed into precursor particles (inception process) the other is an increasing region with constant rate where surface growth affects the increase of C/H ratio dominantly (surface growth process). These results provide a clear picture of a transition to mature soot from precursor materials.

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이성분 나노유체 (NH3/H2O + 나노입자)의 열전달 및 흡수성능 촉진실험 (Experiment on Heat Transfer and Absorption Performance Enhancement for Binary Nanofluids (NH3/H2O + Nano-Particles))

  • 이진기;정청우;강용태
    • 대한기계학회논문집B
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    • 제32권9호
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    • pp.669-675
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    • 2008
  • The objectives of this paper are to examine the effect of nano-particles on the pool type absorption heat transfer enhancement and to find the optimal conditions to design a highly effective compact absorber for ammonia/water absorption system. The effect of $Al_2O_3$ nano-particles and carbon nanotube(CNT) on the absorption performance is studied experimentally. The experimental ranges of the key parameters are 20% of ammonia concentration, $0{\sim}0.08\;vol%$ (volume fraction) of CNT particles, and $0{\sim}0.06 \;vol%$ of $Al_2O_3$ nano-particles. For the ammonia/water nanofluids, the heat transfer rate and absorption rate with 0.02 vol% $Al_2O_3$ nano-particles were found to be 29% and 18% higher than those without nano-particles, respectively. It is recommended that the concentration of 0.02 vol% of $Al_2O_3$ nano-particles be the best candidate for ammonia/water absorption performance enhancement.

실내환기 방식이 재채기 토출입자의 거동특성에 미치는 영향 (Effect of Ventilation Type on the Trajectory of Coughed Particles in a Hospital Ward)

  • 권순박;송지한;조영민;정우태;박덕신
    • 한국입자에어로졸학회지
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    • 제9권2호
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    • pp.59-67
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    • 2013
  • One of purposes in this study was to confirm the behavior of coughed particles under different ventilation conditions. Three types of ventilation systems were applied for this experiment and the properties of coughed particles were measured using computational fluid dynamics (CFD) in an intensive care unit. The changes of total airborne particles for each case showed different trends according to the ventilation type and time, but the deposited particles were similar in all conditions. Although the time taken for 50% of the particles to be deposited was the fastest in case 2, the portion of deposited particles after 300 seconds was only 5% in all conditions. In case 1, a relatively small number of particles were deposited on the wall, but the particle exhaust and deposition on the occupants were the highest. In case 3, the downward ventilation was applied as that recommended by the US Center for Disease Control and Prevention (CDC) and showed different exhaust efficiencies according to the particle size.

분무열분해법에 의한 푸른색 발광 BAM 형광체 분말의 형태 조절 (Morphology control of blue-emitting BAM phosphor particles by the spray pyrolysis)

  • 강윤찬;노현숙
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.566-569
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    • 1999
  • The blue emitting BAM Phosphor Particles with various compositions were Prepared by the spray Pyrolysis. The effect of composition on the morphology of BAM particles was Investigated. In the case of BaMgAl$_{10}$ /O$_{22}$ : Eu$^{2+}$, the morphology of particles with sphericity and non-aggregation characteristics disappeared after post-treatment at 1400 $^{\circ}C$ for 3 hrs. On the other hand, the ocher composition particles except BaMgAl$_{10}$ /O$_{22}$ : Eu$^{2+}$ maintained their original morphology after post-treatment, even if the particles were prepared at low temperatures in the spray pryrolysis. The BAM particles with MgAl$_{2}$/O$_4$as intermediate material at low post-treatment temperature had high thermal stability and maintained sphericity of particles after post-treatment. All the samples had main omission peak at 450 nm, which corresponds to blue emission. The optimum post-treatment temperature of BAM:Eu$^{2+}$ particles for the maximum PL(photoluminescence) intensity in the spray pylolysis was 1200 $^{\circ}C$ because of high crystallinity, Phase-Purity, and good morphology.ology.

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차량 주행 과정에서 타이어와 도로의 마찰에 의해서 발생하는 도로입자의 특성연구 (Properties of Roadway Particles from the Interaction between Tire and Road Pavement)

  • 이석환;김홍석;박준혁;우세종;곽지현
    • 한국자동차공학회논문집
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    • 제20권6호
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    • pp.24-32
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    • 2012
  • A large fraction of urban $PM_{10}$ concentrations is due to non-exhaust traffic emissions including road dust, tire wear particles, and brake lining particles. Although potential health and environmental impacts associated with tire wear debris have been increased, few environmentally and biologically relevant studies of actual tire wear debris have been conducted. Tire wear particles (TWP) are released from the tire tread as a result of the interaction between the tire and the pavement. Roadway particles (RP), meanwhile, are particles on roads composed of a mixture of elements from tires, pavements, fuels, brakes, and environmental dust. The main objective of present study is to identify the contribution of tires to the generation of RP and to assess the potential environmental and health impacts of this contribution. First, a mobile measurement system was constructed and used to measure the roadway particles on asphalt road according to vehicle speed. The equipment of the mobile system provides $PM_{10}$ concentrations by Dusttrak DRX and number density & size distribution measurements of fine and ultra-fine particles by a fast mobility particle sizer (FMPS) and an aerosol particle sizer (APS). When traveling on an asphalt road at constant speed, there is a clear tendency for PM10 concentration to increase slightly in accordance with an increase in the vehicle speed. It was also found that considerable brake wear particles and particles from tire/road interface were generated by rapid deceleration of the vehicle. The morphology and elements of the roadway particles were also analyzed using SEM-EDX technique.

입자 퇴적이 승용차용 정전 필터의 미세 입자 포집 특성에 미치는 영향 (Effect of Particle Loading on the Collection Performance of an Electret Cabin Air Filter for Submicron Particles)

  • 지준호;강석훈;황정호;배귀남
    • 대한기계학회논문집B
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    • 제26권8호
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    • pp.1102-1114
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    • 2002
  • An electret filter is composed of permanently charged electret fibers and is widely used in applications requiring high collection efficiency and low-pressure drop. In this work, the collection efficiency of the filter media used in manufacturing cabin air filters was investigated by using poly-disperse particles when submicron particles were loaded. Long-term experiments were conducted by applying two different charging states, which were spray electrification and charge equilibrium by bipolar ionization. In order to investigate the effect of particle loading in filter media, NaCl particles were generated from 0.1% and 1% solutions by an atomizer. Liquid DOS particles were used to evaluate the effect of liquid particles on the collection efficiency of an electret filter. The results show significant effect of charge amount and size distribution of loading particles on the collection performance of a filter media in submicron region. Smaller particles loaded in electret fibers cause a more rapid degradation in collection efficiency and have lower minimum efficiency with time. The pressure drop of a filter media do rarely increase when the collection efficiency decreases to the minimum value. For the larger particles charged by spray electrification, which have charge amounts more than that of Boltzmann equilibrium charge distribution, the pressure drop of a filter media slowly increases in comparison with that of equilibrium charged particles. For DOS particles it is shown that the charging level of an electret filter severely decreases and the collection efficiency is below 10% in some particle size range.

An Orchestrated Attempt to Determine the Chemical Properties of Asian Dust Particles by PIXE and XRF Techniques

  • Ma, Chang-Jin;Kim, Ki-Hyun;Choi, Sung-Boo;Kasahara, Mikio;Tohno, Susumu
    • Asian Journal of Atmospheric Environment
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    • 제4권3호
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    • pp.189-197
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    • 2010
  • An orchestrated attempt was made to analyze samples of bulk and individual particulate matters (PM) collected at the Gosan ground-based station on the west coast of Jeju, Korea. A two-stage filter pack sampler was operated to collect particles in both large (> $1.2\;{\mu}m$) and small size fractions (< $1.2\;{\mu}m$) between the Asian dust (hereafter called "AD") storm event and non-Asian dust period. Elemental components in bulk and individual particles were determined by PIXE and synchrotron XRF analysis systems, respectively. To assess the transport pathways of air parcels and to determine the spatial distribution of PM, the backward trajectories of the Meteorological Data Explorer (Center for Global Environmental Research, 2010) and the NOAA's HYSPLIT dispersion-trajectory models were applied. In line with general expectations, Si and other crustal elements in large size particles showed considerably higher mass loading on AD days in comparison with non-AD days. Computation of the crustal enrichment factors [(Z/Si)$_{particle}$/(Z/Si)$_{desert}$ sand] of elements in large size particles (> $1.2\;{\mu}m$) allowed us to estimate the source profile and chemical aging of AD particles as well as to classify the soil-origin elements. On the basis of a single particle analysis, individual AD particles are classified into three distinct groups (neutralized mineral particles, S-rich mineral particles, and imperfectly neutralized particles).

합성 조건이 분무열분해 공정에 의해 합성되는 Co3O4 분말의 특성에 미치는 영향 (The Effect of Preparation Conditions on the Characteristics of Co3O4 Particles Prepared by Spray Pyrolysis)

  • 김도엽;주서희;구혜영;홍승권;강윤찬
    • 한국재료학회지
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    • 제16권1호
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    • pp.11-18
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    • 2006
  • [ $Co_3O_4$ ] particles with non-aggregation characteristics were prepared by various conditions such as preparation temperature, flow rate of carrier gas, and concentration of spray solution using spray pyrolysis. The morphology and crystallinity of the preformed particles obtained by spray pyrolysis at various conditions affected the mean size and morphology of the post-treated $Co_3O_4$ particles. The preformed particles with hollow and porous morphology obtained from spray solution with citric acid and ethylene glycol turned to $Co_3O_4$ particles with nano size, regular morphology and non-aggregation characteristics after post-treatment at $800^{\circ}C$. On the other hand, the preformed particles obtained by the preparation conditions of short residence time of particles inside hot wall reactor and high reactor temperature turned to $Co_3O_4$ particles with aggregated morphology after post-treatment. The mean crystallite size and particle size of the $Co_3O_4$ particles prepared from optimum preparation conditions were 47 nm and 210 nm at post-treatment temperature of $800^{\circ}C$.

고무상입자가 치과용 복합레진의 물리적 성질에 미치는 영향 (EFFECT OF CORE-SHELL PARTICLES ON PHYSICAL PROPERTIES OF DENTAL COMPOSITES)

  • 최경규
    • Restorative Dentistry and Endodontics
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    • 제23권2호
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    • pp.690-700
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    • 1998
  • Rubber-toughened particles which are used in the field of chemical engineering are used to increase the fracture toughness of thermoset resin. The application of Core-Shell particles, one of rubber-toughened particles, as a filler for dental composite or restoration have not been examined. The purpose of this study was to evaluate possible use of Core-Shell particles for dental composite, and the hypothesis was that additional toughening mechanisms are activated by the addition of Core-Shell particles. After blending 50vol% quartz with Bis-GMA/TEGDMA resin matrix, the experimental resins were made by the addition of Core-Shell particles with varied content level as 0, 2.5, 5, 7.5, 10, 12.5, 15, and 20wt%. Fracture toughness was determined on three-point bending specimen with single-edge notch according to ASTM-E 399. Also, flexural properties, that is, strength and modulus were measured by three-point bending testing. Fractogragh of fracture toughness specimen was observed using SEM (JEOL 6400 SEM, MA). The following results from this study were obtained ; 1. Fracture toughness of composite resin added 2.5wt% Core-Shell particles was significantly higher than control group ($p{\leq}0.05$). 2. Flexural properties were decreased with increasing Core-Shell particle content, which showed a correlation statistically ($p{\leq}0.05$). 3. A toughening mechanism such as lamination and microcrack was observed in specimen determined high fracture toughness. 4. The dispersion of Core-Shell itself and quartz filler particles was limited present high content of Core-Shell particles, which decreased a resulting mechanical properties of composites. These results suggest that adequate Core-Shell particles can be used to enhance mechanical properties included toughening for dental composites.

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