• Title/Summary/Keyword: Particle-in-cell method

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Synthesis of Carbon-Supported Pt-Ru Catalysts using a Flame Spray Pyrolysis Method for Fuel Electrode of Low Temperature Fuel Cell (화염분무열분해 공정을 이용한 저온 연료전지 연료전극용 탄소담지 Pt-Ru 촉매의 제조)

  • Lee, Hyun-Min;Lee, Dong-Geun
    • Particle and aerosol research
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    • v.8 no.2
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    • pp.69-74
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    • 2012
  • This study describes how successfully a conventional flame aerosol synthesis was used to continuously synthesize Pt-Ru catalysts supported by carbon agglomerates. Nearly spherical catalysts produced in the flame were mainly composed of metallic Pt and Ru with the molar ratio of 1:1 and those sizes were controllable from ~1.5 nm to ~2.0 nm. Nevertheless, only Pt peaks were found from X-ray diffraction experiments, suggesting that amorphous-like Ru was well mixed in the crystalline Pt lattices. It was found from Cyclo-voltamograms and CO stripping experiments that the electrochemical properties of the catalysts are at least comparable to that of a conventional commercial sample.

Microfluidic cell sizing using hydrophoretic size-based separation (유체영동 기반의 입자분리현상을 이용한 세포 크기 측정방법)

  • Choi, Sung-Young;Park, Je-Kyun
    • Journal of Sensor Science and Technology
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    • v.17 no.4
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    • pp.245-249
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    • 2008
  • This paper presents a microfluidic cell sizing method using hydrophoretic size-based separation. By exploiting slanted obstacles in a microchannel, we can generate a lateral pressure gradient so that microparticles can be deflected and arranged along lateral flows induced by the gradient. Using such movement of particles, we discriminated 8 to 15 μm-sized beads. We measured the size of U937 cells by comparing the hydrophoretic response of the cells to those of the size-standard beads whose diameters are known. Due to its simple design and fabrication, the sizing method can be easily integrated with other microfluidic components such as cell culture chambers conducting on-chip sizing and sorting.

A Study on the Characteristics of the Flow around a Sunken Vessel (침선어초 주위의 유동특성에 관한 연구)

  • 양찬규;김현주
    • Journal of Ocean Engineering and Technology
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    • v.14 no.4
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    • pp.9-16
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    • 2000
  • This paper deals with the numerical and experimental study on the characteristics of the flow around a sunken vessel. Numerical simulation of the two dimensional steady flow on the midship section are carried out by the CFD code which is developed by using finite volume method and which includes the standard $textsc{k}$-$\varepsilon$ model with standard wall function. A experimental study is also carried out for the 1/100 scale model in circulating water channel. A velocity fields around the ship are measuremed by using particle image velocimetry technique. And the fluid forces acting on the ship hull by uniform current are measured by two axis load cell. The computed and measured velocity fields on the midship section are compared with each other in the view point of velocity dstribution and reattachement length, which shows good agreement in quality. The drag force on the vessel also showed the same tendency in both computational and experimental results. However, the quantitative disagreements are shown due to the three dimensional effect of the experiment. The result are used to determine the functional efficiency and stability of the vessel as a artificial reef.

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Preparation of electro-catalysts supported on the bimodal porous carbon for polymer electrolyte fuel cell (Bimodal 다공성 탄소지지체에 담지된 고분자전해질연료전지용 전극촉매 제조)

  • Hwang, So-hee;Park, Gu-Gon;Yim, Sung-Dae;Park, Seok-Hee;Kim, Han-Sung;Yang, Tae-Hyun;Kim, Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.652-655
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    • 2009
  • The bimodal porous carbons were synthesized by using imprinting method with templates of SBA-15 particle and silica sphere and applied as supporting materials for the electro-catalyst of polymer electrolyte fuel cell (PEFC). The silica spheres with diameter size of 100 nm and SBA-15 particle having 200 nm -250 nm diameter and 700 nm -900 nm length were synthesized in this work. The bimodal porous carbons (S100) were prepared by using the silica spheres and SBA-15 as templates and mesophase pitch as a carbon source. The PtRu nanoparticle of ca. 1.9 nm were supported on the bimodal porous carbon support and the resulting PtRu/S100 catalysts was tested by the cyclic voltammetry. The use of bimodal porous carbon showed in comparable electro-catalytic activities with commercial catalyst. Though unclear effects of bimodal porosity of supports could be obtained in the scope of this study, morphological advantage in electrical conductivity can be considered on the electro-catalytic activity.

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Development of Energy Harvesting Hybrid system consisted of Electrochromic Device and Dye-Sensitized Solar Cell using Nano Particle Deposition System (나노 입자 적층 시스템(NPDS)을 이용한 염료 감응 태양전지 - 전기 변색 통합 소자 및 에너지 하베스팅 시스템에 대한 연구)

  • Kim, Kwangmin;Kim, Hyungsub;Choi, Dahyun;Lee, Minji;Park, Yunchan;Chu, Wonshik;Chun, Dooman;Lee, Caroline Sunyong
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.2
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    • pp.65-71
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    • 2016
  • In this study, Antimony Tin Oxide (ATO) ion storage layer and $TiO_2$ working electrode were fabricated using Nano Particle Deposition System. NPDS is the cutting-edge technology among the dry deposition methods. Accelerated particles are deposited on the substrate through the nozzle using NPDS. The thicknesses for coated layers were measured and layer's morphology was acquired using SEM. The fabricated electrochromic cell's transmittance was measured using UV-Visible spectrometer and power source at 630 nm. As a result, the integrated electrochromic/DSSC hybrid system was successfully fabricated as an energy harvesting system. The fabricated electrochromic cell was self-operated using DSSC as a power source. In conclusion, the electrochromic cell was operated for 500 cycles, with 49% of maximum transmittance change. Also the photovoltaic efficiency for DSSC was measured to be 2.55% while the electrochromic cell on the integrated system had resulted in 26% of maximum transmittance change.

Analysis of Measuring Error for Particle Size Analysis by Laser Diffraction Spectrometer (입자크기분석을 위한 레이저회절 분광계의 측정오차 분석)

  • Ha, Sang-An;Son, Heui-Jeong
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.713-722
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    • 2000
  • This study analysed error of measurement and reproducibility for particle size analysis by the laser diffraction spectrometer. Laser diffraction spectrometers has become a very important method of particle size analysis. This measuring method has the advantage of simple operation, good reproducibility and rapid analysis. A feeding and dispersing system have been developed, which allows mass throughputs between 0.1~23 g/min in flowing air and 1.4~35% in flowing liquid. It has been used as a feeder unit for wet and dry particle size analysis from diffraction patterns. Relevant parameters, such as particle shape, particle size, dispersion, flow rate, concentration were analysed for measuring error. And system parameters of instruments for measurement of dynamic processes, eg, measuring time, focal plane, injection pressure drop and dispersion effect by the ultrasonic and mixing of preliminary treatment, were also discussed.

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Analysis of Pedestrian Flow Characteristics in Subway Station (지하역사 기본 모델에 대한 여객 유동 특성 해석)

  • Nam Seong-Won
    • Journal of the Korean Society for Railway
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    • v.9 no.3 s.34
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    • pp.271-276
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    • 2006
  • Insight into behaviour of pedestrians as welt as tools to assess passenger flow condition is important in such instances as planning and geometric design of railway station under regular and safety-critical circumstances. Algorithm for passenger flow analysis based on DEM (Discrete Element Method) is newly developed. There are lots of similarity between particle-laden two phase flow and passenger flow. The velocity component of 1st phase corresponds to the unit vector of calculation cell, each particle to passenger, volume fraction to population density and the particle velocity to the walking velocity, etc. And, the walking velocity of passenger is also represented by the function of population density. Key algorithms are developed to determine the position of passenger, population density and numbering to each passenger. To verify the effectiveness of new algorithm, passenger flow analysis for the basic models of railway station is conducted.

Synthesis of $Li_xNi_(0.85)Co_(0.15)O_2$ by the PVA-procursor Method and the Effect of Air Flow During the Pyrolysis

  • 권호진;김근배;김수주;송미영;박선희;권혜영;박동곤
    • Bulletin of the Korean Chemical Society
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    • v.20 no.5
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    • pp.508-516
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    • 1999
  • Polycrystalline powder of LixNi0.85Co0.15O2 was synthesized by pyrolyzing a powder precursor obtained by the PVA-precursor method. Coin cells of lithium-ion rechargeable battery were assembled, whose the cathodes were fabricated from the crystalline powders of LixNi0.85Co0.15O2 synthesized by the method. The effect of synthetic variation on the property of the cell was tested by carrying out 100 consecutive cycles of charge-dis-charge on the cells. The property of the cell was largely influenced by the pyrolysis conditions applied for the synthesis of the LixNi0.85Co0.15O2. Depending on whether the pyrolysis was carried out in standing air or in the flow of dry air, the discharge capacity and cycle-reversibility of the cell varied in large extent. When the powder precursor was pyrolyzed in standing air, a minor phase of lithium carbonate was remained in the LixNi0.85Co0.15O2. The carbon containing powder precursor had to be pyrolyzed in the flow of dry air to eliminate the minor phase. In the flow of dry air, the lithium carbonate in the precursor was eliminated over 500-700。C without any prominent heat event. By controlling the flow of air over the precursor during its pyrolysis, particle size could also be altered. The effect of flowing dry air, during first step pyrolysis or during second step heat treatment, on the property of the cell was discussed.

The Effect of Fabrication Process on the Characteristics of $LiCoO_2$ Cathode for Molten Carbonate Fuel Cell (용융탄산염 연료전지용 $LiCoO_2$ 산화전극의 제조방법에 따른 특성)

  • 임준혁;김태근
    • Journal of Environmental Science International
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    • v.5 no.4
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    • pp.535-544
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    • 1996
  • In the development of Molten Carbonate Fuel Cell, one of the serious problems is the dissolution of cathode material. Therefore, the development of the alternative cathode which is stable in molten carbonate is needed. In this research, the licoo, was chosen as alternative cathode material. $LiCoO_2$ powder was synthesized by high temperature calcination method and by citrate sol-gel method. And its structure and physical iharacteristics were analyzed by XRD, 1 R, TCA and porosimeter. The conductivity and solubility of $LiCoO_2$ electrode were also measured. Homogeneous $LiCoO_2$ Powder was obtained by citrate sol-Rel method at 445$^{\circ}C$, however, obtained above 75$0^{\circ}C$ by high temperature calcination method. Homogeneous particle size distribution and fine powder were obtained by the citrate sol-Rel method. $LiCoO_2$ electrode showed higher electric conductivity ($1.7 $\Omega$^{-1}cm^{-1}$) than NiO (0.1 $\Omega$^{-9} cm^{-1}) at $650^{\circ}C$. The solubilities of $LiCoO_2$ electrode in electrolyte were varies 0.6 to 1.0 ppm during 200 hours. So, the solubilities of $LiCoO_2$ were much lower than that of NiO.

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Numerical Analysis on Passenger Flow for the Model of Railway Station (철도 역사 모델에 대한 여객 유동 해석)

  • Kwon, Hyeok-Bin;Cha, Chang-Hwan;Nam, Seong-Won
    • Proceedings of the KSR Conference
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    • 2006.11b
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    • pp.387-391
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    • 2006
  • Insight into behaviour of pedestrians as well as tools to assess passenger flow conditions are important in for instance planning and geometric design of railway station under regular and safety-critical circumstances. Algorithm for passenger flow analysis based on DEM(Discrete Element Method) is newly developed. There are lots of similarity between particle-laden two phase flow and passenger flow. The velocity component of 1st phase corresponds to the unit vector of calculation cell, each particle to passenger, volume fraction to population density and the particle velocity to the walking velocity, etc. And, the walking velocity of passenger is also represented by the function of population density. Key algorithms are developed to determine the position of passenger, population density and numbering to each passenger. To verify the effectiveness of new algorithm, passenger flow analysis for the basic models of railway station is conducted.

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