• Title/Summary/Keyword: Particle-in-cell method

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Fabrication and Characterization of High-activity Pt/C Electrocatalysts for Oxygen Reduction

  • Lim, Bo-Rami;Kim, Joung-Woon;Hwang, Seung-Jun;Yoo, Sung-Jong;Cho, Eun-Ae;Lim, Tae-Hoon;Kim, Soo-Kil
    • Bulletin of the Korean Chemical Society
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    • v.31 no.6
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    • pp.1577-1582
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    • 2010
  • A 20 wt % Pt/C is fabricated and characterized for use as the cathode catalyst in a polymer electrolyte membrane fuel cell (PEMFC). By using the polyol method, the fabrication process is optimized by modifying the carbon addition sequence and precursor mixing conditions. The crystallographic structure, particle size, dispersion, and activity toward oxygen reduction of the as-prepared catalysts are compared with those of commercial Pt/C catalysts. The most effective catalyst is obtained by ultrasonic treatment of ethylene glycol-carbon mixture and immediate mixing of this mixture with a Pt precursor at the beginning of the synthesis. The catalyst exhibits very uniform particle size distribution without agglomeration. The mass activities of the as-prepared catalyst are 13.4 mA/$mg_{Pt}$ and 51.0 mA/$mg_{Pt}$ at 0.9 V and 0.85 V, respectively, which are about 1.7 times higher than those of commercial catalysts.

Numerical Simulation for an Air-Solid Two-Phase Flow in a Vertical Pipe (기체 흐름에 고체입자가 섞인 파이프 내의 이상유동에 대한 수치 해석)

  • Pak S. I.;Chang K. S.
    • 한국전산유체공학회:학술대회논문집
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    • 2002.10a
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    • pp.41-46
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    • 2002
  • A numerical simulation was made to determine the motion of particles in the fluid. The simulation is based on the Eulerian-Lagrangian method. The fluid motion was solved using a PISO-based finite-element method and a $\kappa-\epsilon$ model of turbulence. In the Lagrangian method for the solid phase, the trajectories of particles are calculated by integrating the equations of motion of a single Particle, and the collision between particles are taken into account. The influence of particles on the fluid phase is taken into account by introducing source terms in the Eulerian equations govering the fluid flow. It is known as the particle-source-in-cell (PSIC) method. Also, the turbulent effect in the particles and fluid notion is considered. The numerical results were compared with the experiment for a two-phase flow in a vertical pipe.

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A Study on the Homogeneity of Powder Mixture (분말약품 혼합의 균일성에 관한 연구)

  • 김길수;이민화
    • YAKHAK HOEJI
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    • v.21 no.2
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    • pp.95-100
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    • 1977
  • The effects of the particle size on the homogeneity of mixing and segregation of caffeine-lactose (1:99) mixture were studied. Using the two kinds of caffein, milled and unmilled caffein, V-type blender, the degree of mixing according to the particle size was predicted and the experiment on the change of mixedness by mixing time was carried out by the method derived from mixing index theory by Poole et al. and Hersey. the results could be summarized as follows; (1) The homogeneity of mixing was greatly affected by the particle size and the particle size should be reduced to the adepuate level to attain the desirable mixedness. (2) The homogeneity was not proportional to the mixing time and optimum mixing time for caffein-lactose was about 10 minutes. (3) Segregation tendency was increased by the particle size increase and greatly affected by the flow time in the segregation cell.

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A Study on Electrode Preparation for Alkaline Fuel Cell (알칼리 연료전지 전극제조에 관한 연구)

  • Hong, Jin Ki;Lee, Kyung Ju;Lee, Wha Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.2 no.1
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    • pp.57-67
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    • 1990
  • This study is proposed to investigate the effect of electrode preparation method for Alkaline Fuel Cell using NaOH as an electrolyte on the Fuel Cell performance. The materials used for the preparation of electrode are Pt and Ag on Vulcan XC-72. Surface area of Vulcan XC-72 have different values according to the pretreatment conditions and the dispersion of Pt is dependent on the impregnation Particle size of Pt impregnated on unpretreated carbon was observed to be $20{\sim}40{\AA}$ and that on pretreated carbon in $N_2$ stream at $950^{\circ}C$ was found to be finely dispersed less then $15{\AA}$. The electrode performance was affected by the particle size of metals and operating temperature. It was revealed from this study that the optimum particle size about $30{\AA}$ and optimum temperature range is between $90{\sim}100^{\circ}C$.

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전기 저항법을 이용한 Micro Particle Counter Micro Fluidic Device 개발

  • Lee Jun;Yun Deok-Won;Chae Ho-Cheol;Han Chang-Su
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2005.05a
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    • pp.134-138
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    • 2005
  • Recently many researches related with biotechnology are processed and it is the situation that research about micro fluidic devices is active. Micro fluidic devices has been one of the most widely used devices for the analysis in biotechnology because they have many advantages, flexibility, transparency, thermal and electrical stability, nontoxic, etc. In this study, micro fluidic device with PDMS is developed for particle counter which separates a small quantity of particles, The principle of micro particle counter is electrical-impedance method, and it was also applied hydrodynamic flow focusing. It is more efficient method to analyzing particles furthermore it can be applied to cell count ins for biotechnology.

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Development and Test of 2.5-Dimensional Electromagnetic PIC Simulation Code

  • Lee, Sang-Yun;Lee, Ensang;Kim, Khan-Hyuk;Seon, Jongho;Lee, Dong-Hun;Ryu, Kwang-Sun
    • Journal of Astronomy and Space Sciences
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    • v.32 no.1
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    • pp.45-50
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    • 2015
  • We have developed a 2.5-dimensional electromagnetic particle simulation code using the particle-in-cell (PIC) method to investigate electromagnetic phenomena that occur in space plasmas. Our code is based on the leap-frog method and the centered difference method for integration and differentiation of the governing equations. We adopted the relativistic Buneman-Boris method to solve the Lorentz force equation and the Esirkepov method to calculate the current density while maintaining charge conservation. Using the developed code, we performed test simulations for electron two-stream instability and electron temperature anisotropy induced instability with the same initial parameters as used in previously reported studies. The test simulation results are almost identical with those of the previous papers.

Investigating the effect of changing parameters in the IEC device in comparative study

  • H. Ghammas;M.N. Nasrabadi
    • Nuclear Engineering and Technology
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    • v.56 no.1
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    • pp.292-300
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    • 2024
  • Kinetic simulations have been performed on an Inertial Electrostatic Confinement Fusion (IECF) device. These simulations were performed using the particle-in-cell (PIC) method to analyze the behavior of ions in an IEC device and the effects of some parameters on the Confinement Time (CT). CT is an essential factor that significantly contributes to the IEC's performance as a nuclear fusion device. Using the PIC method, the geometry of a two-grided device with variable grid radius, the number of cathode grid rings, variable pressure and different dielectric thickness for the feed stalk was simulated. In this research, with the development of previous works, the interaction of particles was simulated and compared with previous results. The simulation results are in good agreement with the previous results. In these simulations, it was found that with the increase of the dielectric thickness of the feed stalk, the electric field was weakened and as a result, the confinement time was reduced. On the other hand, with the increase of the cathode radius, the confinement time increased. Using the results, an IEC device can be designed with higher efficiency and more optimal CT for ions.

Development of an Analysis Program for Pedestrian Flow based on the Discrete Element Method (이산요소법을 이용한 보행류 해석 프로그램 개발)

  • Nam, Seong-Won;Kwon, Hyeok-Bin
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.3197-3202
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    • 2007
  • An analysis program for pedestrian flow has been developed to investigate the flow patterns of passenger in railway stations. Analysis algorithms for pedestrian flow based on DEM(Discrete Element Method) are newly developed. There are lots of similarity between particle-laden two phase flow and passenger flow. The velocity component of 1st phase corresponds to the unit vector of calculation cell, each particle to passenger, volume fraction to population density and the particle velocity to the walking velocity, etc. And, the walking velocity of passenger is also represented by the function of population density. Key algorithms are developed to determine the position of passenger, population density and numbering to each passenger. By using the developed program, we compared the simulation results of the effects of the location and size of exit and elapsed time.

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Toward the computational rheometry of filled polymeric fluids

  • Hwang, Wook-Ryol;Hulsen Martien A.
    • Korea-Australia Rheology Journal
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    • v.18 no.4
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    • pp.171-181
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    • 2006
  • We present a short review for authors' previous work on direct numerical simulations for inertialess hard particle suspensions formulated either with a Newtonian fluid or with viscoelastic polymeric fluids to understand the microstructural evolution and the bulk material behavior. We employ two well-defined bi-periodic domain concepts such that a single cell problem with a small number of particles may represent a large number of repeated structures: one is the sliding bi-periodic frame for simple shear flow and the other is the extensional bi-periodic frame for planar elongational flow. For implicit treatment of hydrodynamic interaction between particle and fluid, we use the finite-element/fictitious-domain method similar to the distributed Lagrangian multiplier (DLM) method together with the rigid ring description. The bi-periodic boundary conditions can be effectively incorportated as constraint equations and implemented by Lagrangian multipliers. The bulk stress can be evaluated by simple boundary integrals of stresslets on the particle boundary in such formulations. Some 2-D example results are presented to show effects of the solid fraction and the particle configuration on the shear and elongational viscosity along with the micro-structural evolution for both particles and fluid. Effects of the fluid elasticity has been also presented.

Analysis of Viscous Flow Around an Impulsively Started Marine Propeller Using VIC(Vortex In Cell) Method (VIC(Vortex In Cell) 방법을 이용한 순간 출발하는 프로펠러 주위의 점성유동 해석)

  • Lee, Jun-Hyeok;Kim, Yoo-Chul;Lee, Youn-Mo;Suh, Jung-Chun
    • Journal of the Society of Naval Architects of Korea
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    • v.49 no.1
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    • pp.26-32
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    • 2012
  • The 3-D unsteady viscous flow around an impulsively started rotating marine propeller is simulated using VIC(Vortex-In-Cell) method which is adequate to analyze the strong vortical flow around complicatedly-shaped body. The computational procedure is governed by the vorticity transport equation in Lagrangian form. In order to solve the equation, a regular grid which is independent to the shape of a body is introduced and each term of the equation is evaluated numerically on the grid by applying immersed boundary concept. In this paper, the overall algorithm including the formulation of governing equations and boundary conditions is described and some computational results are presented with discussing their physical validity.