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Adsorption of Cadmium Ion by Wood Charcoal Prepared with Red oak (Quercus mongolica) (신갈나무 목탄의 카드뮴(Cd)이온 흡착 특성)

  • Jo, Tae-Su;Lee, Oh-Kyu;Choi, Joon-Weon;Byun, Jae-Kyung
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.3
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    • pp.93-100
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    • 2008
  • For investigation of adsoption properties of cadmium elimination by wood charcoal, $25m{\ell}$ aqueous cadmium solutions in various concentrations were treated with 0.2 g wood charcoal of Red Oak (Quercus mongolica) for 280 minutes. Almost 100% of cadmium elimination ratio was obtained in the solutions with initial concentration of 20 and 40 ppm in the treatment, whereas they were 75 and 50% in those of 80 and 160 ppm. In the effect of treatment time, the highest amount of cadmium ions was eliminated during the first ten minutes in each solution so that the elimination ratio of each case was over 70% of the maximum elimination value. From the analysis of adsorptive cadmium adsorption mechanism using the Langmuir adsorption isotherm, it was suggested that cadmium ion molecules were adsorbed at the active sites on the charcoal particle in form of one layer. The Gibbs free energy of the adsorption process was calculated in negative value for each solution. This means the adsorption processes are spontaneous which do not require the extra input energy.

FREE-FLOATING PLANETS, THE EINSTEIN DESERT, AND 'OUMUAMUA

  • Gould, Andrew;Jung, Youn Kil;Hwang, Kyu-Ha;Dong, Subo;Albrow, Michael D.;Chung, Sun-Ju;Han, Cheongho;Ryu, Yoon-Hyun;Shin, In-Gu;Shvartzvald, Yossi;Yang, Hongjing;Yee, Jennifer C.;Zang, Weicheng;Cha, Sang-Mok;Kim, Dong-Jin;Kim, Seung-Lee;Lee, Chung-Uk;Lee, Dong-Joo;Lee, Yongseok;Park, Byeong-Gon;Pogge, Richard W.
    • Journal of The Korean Astronomical Society
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    • v.55 no.5
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    • pp.173-194
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    • 2022
  • We complete the survey for finite-source/point-lens (FSPL) giant-source events in 2016-2019 KMTNet microlensing data. The 30 FSPL events show a clear gap in Einstein radius, 9 𝜇as < 𝜃E < 26 𝜇as, which is consistent with the gap in Einstein timescales near tE ~ 0.5 days found by Mróz et al. (2017) in an independent sample of point-source/point-lens (PSPL) events. We demonstrate that the two surveys are consistent. We estimate that the 4 events below this gap are due to a power-law distribution of free-floating planet candidates (FFPs) dNFFP/d log M = (0.4 ± 0.2) (M/38 M)-p/star, with 0.9 ≲ p ≲ 1.2. There are substantially more FFPs than known bound planets, implying that the bound planet power-law index 𝛾 = 0.6 is likely shaped by the ejection process at least as much as by formation. The mass density per decade of FFPs in the Solar neighborhood is of the same order as that of 'Oumuamua-like objects. In particular, if we assume that 'Oumuamua is part of the same process that ejected the FFPs to very wide or unbound orbits, the power-law index is p = 0.89 ± 0.06. If the Solar System's endowment of Neptune-mass objects in Neptune-like orbits is typical, which is consistent with the results of Poleski et al. (2021), then these could account for a substantial fraction of the FFPs in the Neptune-mass range.

Physicochemical Characteristics and Ginsenosides Compositions of Makgeolli Added with Mountain Ginsengs (장뇌삼 첨가 탁주의 이화학적 특성 및 Ginsenosides 함량)

  • Choi, Kang Hyun;Sohn, Eun-Hwa;Kim, Sung Jun;Lee, Je-Hyuk;Jang, Ki-Hyo
    • Journal of the East Asian Society of Dietary Life
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    • v.23 no.4
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    • pp.437-443
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    • 2013
  • Rice wine (makgeolli) containing various amounts of mountain ginsengs (MG) are being prepared with nuruk and yeasts, and the physicochemical characteristics and contents of ginsenosides in MG-makgeolli were analyzed. Average particle size of MG powder is $29.1{\mu}m$. MG slice (20 g) or powder (0~20 g) and rice (3,000 g) were used for 12 days fermentation of makgeolli, makgeolli containing slice of MG (SW-makgeolli), makgeolli containing 2 g (PW1-makgeolli), 10 g (PW2- makgeolli), 20 g (PW3-makgeolli) of powder of MG, respectively. Soluble solids and pH levels show no differences between five kinds of makgeolli groups, whilst the presence of high amounts of MG (PW3-makgeolli) caused decreases in ethanol and acidity. Major free amino acids in MG-makgeolli are glutamic acid and arginine. Total contents of 14 ginsenosides are approximately 2.5 g/100 g of dried MG powder and major ginsenoside were ginsenosides Re, Rb1, Rb2, Rg1, Rc and Rf. During the propagation of makgeolli containing MG, the ginsenosides Rb1, Rb2, Rb3, and Rc decreased, whilst ginsenosides Rg3 and compound K increased highly. It indicates that ginsenosides in MG are metabolized to different forms of ginsenosides by brewing microorganisms.

Fundamental Studies on Sinyewon Clays (新禮院粘土에 관한 基礎的 硏究)

  • Park, Soon-Za;Ann, Nam-Soon;Kim, Yoon-Ho
    • Journal of the Korean Chemical Society
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    • v.10 no.2
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    • pp.67-75
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    • 1966
  • Four kinds of clays from Sinyewon mine which is located in Chungchoungnam-Do district and two kinds of Japanese clays (Gairome, Kibushi) were selected and studied on the fundamental properties of these clays and those which are refined by the elutriation method. Chemical analysis, grading analysis such as refractoriness, specific gravity, color, fired color and plasticity, particle size distribution, various thermal tests, X-ray diffraction analysis and electron microscopic survey were carried out on these clays. The comparison of domestic clays with Japanese clays was made. 1. In chemical composition and physical properties, these four kinds of Sinyewon clays are almost similar to each other and also to Gairome and Kibushi clays. In refractoriness, Gairome and Kibushi clays have relatively high value such as SK 34 and 35, while Sinyewon clays have the value of about SK 32. Especially Sinyewon clay B has the low refractoriness (SK 18) and plasticity. Refined clays have the tendency of somewhat higher value than crude ones in refractoriness. 2. When burnt up to $900^{\circ}C$, the coefficients of contraction of Sinyewon clays were under 1.5%, Gairome under 1.3%, Kibushi under 3.0%. Only Sinyewon clay B showed expansion (1.0%) instead of contraction. 3. X-ray diffraction analysis and electron micrography showed that all of four Sinyewon clays and two Japanese clays are mainly composed of poorly crystallized kaolin, containing small amount of halloysite, sericite and considerable amount of quartz and feldspar. Sinyewon clay B contains especially large amount of quartz and feldspar. In general, it has been found out that the refined clays were free from large amount of iron oxide, quartz and feldspar.

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Synthesis and characterization of carbon doped TiO2 photocatalysts supported on stainless steel mesh by sol-gel method

  • Tijani, JO.;Fatoba, OO.;Totito, TC.;Roos, WD.;Petrik, LF.
    • Carbon letters
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    • v.22
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    • pp.48-59
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    • 2017
  • This study synthesized pure anatase carbon doped $TiO_2$ photocatalysts supported on a stainless steel mesh using a sol-gel solution of 8% polyacrylonitrile (PAN)/dimethylformamide (DMF)/$TiCl_4$. The influence of the pyrolysis temperature and holding time on the morphological characteristics, particle sizes and surface area of the prepared catalyst was investigated. The prepared catalysts were characterized by several analytical methods: high resolution scanning electron microscopy (HRSEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), and X-ray photoelectron spectroscopy (XPS). The XRD patterns showed that the supported $TiO_2$ nanocrystals are typically anatase, polycrystalline and body-centered tetragonal in structure. The EDS and XPS results complemented one another and confirmed the presence of carbon species in or on the $TiO_2$ layer, and the XPS data suggested the substitution of titanium in $TiO_2$ by carbon. Instead of using calcination, PAN pyrolysis was used to control the carbon content, and the mesoporosity was tailored by the applied temperature. The supported $TiO_2$ nanocrystals prepared by pyrolysis at 300, 350, and $400^{\circ}C$ for 3 h on a stainless steel mesh were actual supported carbon doped $TiO_2$ nanocrystals. Thus, $PAN/DMF/TiCl_4$ offers a facile, robust sol-gel related route for preparing supported carbon doped $TiO_2$ nanocomposites.

Numerical investigation of the impact of geological discontinuities on the propagation of ground vibrations

  • Haghnejad, Ali;Ahangari, Kaveh;Moarefvand, Parviz;Goshtasbi, Kamran
    • Geomechanics and Engineering
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    • v.14 no.6
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    • pp.545-552
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    • 2018
  • Blast-induced ground vibrations by a significant amount of explosives may cause many problems for mining slope stability. Geological discontinuities have a significant influence on the transmission of dynamic pressure of detonation and according to their position relative to the slope face may have damaging or useful impacts on the slope stability. In this study, the effect of geological discontinuities was investigated by modelling a slope with geological discontinuities through applying the dynamic pressure in three-dimensional discrete element code (3DEC). The geological discontinuities in four states that generally apperceived in mine slopes are considered. Given the advantages of the pressure decay function defined by some researcher, this type of function was used to develop the pressure-time profile. The peak particle velocities (PPV) values were monitored along an axis by utilization of Fish programming language and the results were used as an indicator to measure the effects. As shown in the discontinuity-free model, PPV empirical models are reliable in rocks lacking discontinuities or tightly jointed rock masses. According to the other results, the empirical models cannot be used for the case where the rock mass contains discontinuities with any direction or dip. With regard to PPVs, when the direction of discontinuities is opposite to that of the slope face, the dynamic pressure of detonation is significantly damped toward the slope direction at the surface of discontinuities. On the other hand, when the discontinuities are horizontal, the dynamic pressure of detonation affects the rock mass to a large distance.

Virtual pencil and airbrush rendering algorithm using particle patch (입자 패치 기반 가상 연필 및 에어브러시 가시화 알고리즘)

  • Lee, Hye Rin;Oh, Geon;Lee, Taek Hee
    • Journal of the Korea Computer Graphics Society
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    • v.24 no.3
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    • pp.101-109
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    • 2018
  • Recently, the improvement of virtual reality and augmented reality technologies leverages many new technologies like the virtual study room, virtual architecture room. Such virtual worlds require free handed drawing technology such as writing descriptions of formula or drawing blue print of buildings. In nature, lots of view point modifications occur when we walk around inside the virtual world. Especially, we often look some objects from near to far distance in the virtual world. Traditional drawing methods like using fixed size image for drawing unit is not produce acceptable result because they generate blurred and jaggy result as view distance varying. We propose a novel method which robust to the environment that produce lots of magnifications and minimizations like the virtual reality world. We implemented our algorithm both two dimensional and three dimensional devices. Our algorithm does not produce any artifacts, jaggy or blurred result regardless of scaling factor.

A Comparison between Various CFD Solvers for Analysis on Thermal Load in Smart Farm(Fluent, Open-FOAM, Blender) (스마트팜 열부하 분석을 위한 CFD 해석 도구 비교)

  • Lee, Jun-Yeob;Oh, Jong-woo;Lee, DongHoon
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2017.04a
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    • pp.170-170
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    • 2017
  • 기후변화 따른 스마트팜 돈사 외부 환경의 변화에 대응하고, 사육 환경을 능동적으로 개선하기 위한 연구가 수행 중이다. 돈사 내 열전달 요소 간 상호 역학성 분석을 위해서 고려해야할 사항은 입기구, 보온 등, 열풍기, 단열제, 위치, 방향, 돈사의 연평균 온도, 습도, 연중 일사량, 가축의 열복사 등 상호 복잡하게 연관되어 있는 물리량이다. 돈사 전체 열손실, 자연발생 에너지량, 강제발생 에너지량, 난방용량 등을 고려한 순간 열부하 산정을 위한 여러 방법 중 우선적으로 CFD(Computational Fluid Dynamics)를 이용하였다. 순간 열부하 산정을 위한 해석 도구 선정에 있어서 다양한 유체 및 기체 전산 유체역학 Solver(Fluent, Open-FOAM, Blender)를 고려하였다. 공간 Mech를 수행하기 위한 도구로는 공개 소프트웨어 인 FreeFem++ 3.51-4 (http://www.freefem.org)를 이용하였다. 이 과정에서 일부 기체 (암모니아)의 농도를 난수로 변화시키는 기법을 적용하여 가상적으로 돈사의 환경을 Pseudo 시뮬레이션 하였다. 결과적으로 Fluent에 비하여 OpenFOAM을 이용하여 얻은 열유동의 방향(속도)과 크기 백터가 상대적으로 크게 나타났다. Fluent가 시계열 상에서 혼합 기체 물리량 변화를 무시할 수 있는 안정되고 균일한 환경에 적합하기 때문인 것으로 판단되었다. Blender의 경우 Lattice Boltzmann methods 과 Smoothed-particle hydrodynamics 방법을 이용한 유체/입자 동력학 모델링을 제공함에 있어 시각적 효과를 강조하는 기능에 중점을 두었다. Fluent와 Blender에서 제공하는 해석 연산 모듈의 정확성 검증을 위해선 공간 분해능을 높인 정밀 계측 시스템을 이용하여 검증할 필요가 있다. Open-FOAM를 이용한 열부하 분석 수행이 상대적으로 높은 절대값을 보이는 특성은 열부하 제어 시스템의 Overshoot를 유발할 가능성이 있으므로 이에 대한 해석 모델의 보정이 추가적으로 필요할 것이다. CFD의 한계인 시간 복잡도를 낮추고 상대적으로 높은 시계열 분해능을 확보할 경우 돈사 내 환기시스템에 맞는 소요 환기량 실시간 산정이 가능해지고 외부기상 및 돈사내부 복사열을 활용함과 동시에 돈군 순환에 상응하는 실시간 열부하 관리 시스템 도출이 가능할 것이다.

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Immunohistochemical and Electron Microscopical Studies on the Initial Skin Lesions Induced Experimentally by Very Virulent Strain of Marek`s Disease Virus in Chickens (마렉병 바이러스 강독주의 실험 접종에 의해 유발된 닭의 초기 피부 병변에 대한 면역조직화학적 및 전자현미경적 연구)

  • 조경오
    • Journal of Veterinary Clinics
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    • v.18 no.1
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    • pp.55-60
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    • 2001
  • Immunohistochemical and Electron Microscopical Studies on the Initial Skin Lesions Induced Experimentally by Very Virulent Strain of Marek\`s Disease Virus in Chickens Marek\`s disease virus (MDV), which is an avian herpesvirus, causes malignant CD3+CD4+CD8-T cell lymphomas at many sites including visceral organs, muscles, peripheral nerves and skin. In the early skin lesions induced by MDV, corelationship between the translational activity of MDV early gene, pp38 and demonstration of MDV particles in the lymphoid cells are not well studied. Therefore, skin biopsies taken at weekly intervals for 2 weeks from the same specific-pathogen free chicknes inoculated with Md/5 MDV were examined immunohistochemically and electron microscopically. In the skin biopsies sampled at 1 week and 2 weeks post inoculation (PI), feather follicle epithelium (FFE) exhibited usually strong positive reaction for pp38, whereas only few lymphoblasts, which were infiltrated around FFE revealed positive reaction. Electron microscopically, small lymphocytes were detectable in the dermis and subcutaneous skin tissues sampled at 1 week PI. The number of small lymphocytes was increased and pleomorphic lymphoblasts, which were medium to large in size were scattered among the small lymphocytes at 2 weeks PI. Some of lymphoblasts revealed degenerative and necrotic changes. FFE contained a lot of MDV particles in the nucleus including mature and immature ones. Infrequently, immature virus particles were observed not only in the degenerative and necrotic lymphoblasts, but also rarely in the health lymphoblasts. From the present results, spontaneous MDV activation including translational activity of MDV pp38 gene and formation of MDV particles was occurred in the lymphoblasts of early MD skin lesions.

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Instrumentation of a Thermal-Optical Carbon Analyzer and Its Sensitivity in Organic and Elemental Carbon Determination to Analysis Protocols

  • Lim, Ho-Jin;Sung, Su-Hwan;Yi, Sung-Sin;Park, Jun-Hyun
    • Journal of Environmental Science International
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    • v.21 no.1
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    • pp.1-9
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    • 2012
  • A thermal-optical transmittance carbon analyzer has been developed to determine particulate organic (OC) and elemental (EC) carbon. Several analysis factors affecting the sensitivity of OC and EC determination were investigated for the carbon analyzer. Although total carbon (TC) is usually consistent in the determination, OC and EC split is sensitive to adopted analysis protocol. In this study the maximum temperature in oxygen-free He in the analysis was examined as a main cause of the uncertainty. Prior to the sensitivity analysis consistency in OC-EC determination of the carbon analyzer and the uniformity of carbonaceous aerosol loading on a sampled filter were checked to be in acceptable range. EC/TC ratios were slightly decreased with increasing the maximum temperature between $550-800^{\circ}C$. For the increase of maximum temperature from $500^{\circ}C$ to $800^{\circ}C$, the EC/TC ratio was lowered by 4.65-5.61% for TC loading of 13-44 ${\mu}g/cm^2$ with more decrease at higher loading. OC and EC determination was not influenced by trace amount of oxygen in pure He (>99.999%), which is typically used in OC and EC analysis. The facing of sample loaded surface to incident laser beam showed negligible influence in the OC-EC split, but it caused elevated PC fraction in OC for forward facing relative to backward facing.