• Title/Summary/Keyword: Particle polarization

Search Result 102, Processing Time 0.029 seconds

A New Mechanish of Bright Plating on the Ground of Analysis of Rate Nucleafion and Growth (결정의 발생속도식과 송장속도식의 해석에 지초한 광택니켈도금의 새로운 메카니즘)

  • 박병각;송재설;김창진
    • Journal of the Korean institute of surface engineering
    • /
    • v.21 no.2
    • /
    • pp.76-82
    • /
    • 1988
  • The bright nickel electroplatings were carried out the Watt bath containg a solobel saccharin as class I brightner and para substituted benzaldehydes as class II one. Extended Huckel MO calculation was done and polarization was measured to examine between $\pi$-electron density and the brightness. The correlation is also investigated between $\pi$-electron density of oxygen atom of aldehyde group and slope of polarization curve. As a result of the analysis of rate equation of nucleation, the surface energy of the deposited particle was obtained from the slope of the plot of $\ell$nI against 1/η2, and also the reat equation of nucleation found to influnced on the leveling on the basis of adsorption theory. We have proposed the general electroplating mechanism that is applied other to all other electroplating but nickel one. The above elucidated mechanism can be extended can be extended to the all electroplating other than bright nickel electroplating.

  • PDF

Numerical Analysis of Thermally stimulated current of Ionic Space charge Polarijation by Hopping Model (Hopping 모델에 의한 이온 공간전하분극 숙련재전류의 수치해석)

  • 김의균;국상훈
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1990.10a
    • /
    • pp.91-94
    • /
    • 1990
  • The behavior of charged particle in dielectrics have a many effects on characteristics of the insulating materials. In this paper, numerical analysis method by hopping model was investigated application of TSC. As the results, there was a difference between characteristics of TSC by dipole polarization. Physical constant of movable ion corresponding to the experimental results was evaluated and also. Numerical calculations of unsaturated TSC and I-V characteristics were carried out by was of hopping model.

Ultra Broadband Absorption of SPPs Enhanced Dual Grating Thin Film CIGS Solar Cell Enabled by Particle Swarm Optimization

  • Le, DuyKhanh;Tran, QuyetThang;Lee, Sangjun;Kim, Sangin
    • Journal of the Optical Society of Korea
    • /
    • v.18 no.5
    • /
    • pp.429-435
    • /
    • 2014
  • We examined the effective utilization of Particle Swarm Optimization (PSO) to enhance the light absorption performance in thin CuIn1-xGaxSe2 (CIGS) solar cells with dual (top and bottom) gratings. The PSO tuned structure was demonstrated to be capable of achieving high and ultra broadband absorption spectra due to well-spaced and well-defined absorption peaks, which were SPPs and photonic modes induced by the metal and dielectric gratings. For only TM polarization and both polarizations, the fully optimized net absorptions exhibit 85.6% and 78.1%, which correspond to ~35.4% and ~23.5% improvement compared to optimized flat structures, respectively.

Surface Discharge Characteristics in Dry-Air on Laminated Epoxy Solid Dielectrics and Conductive Particle (적층된 에폭시 고체유전체와 도전성 파티클에 대한 Dry-Air의 연면방전특성)

  • Lim, Dong-Young;Jeon, Jong-Cheul;Bae, Sungwoo;Lee, Kwang-Sik;Park, Won-Zoo
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
    • /
    • v.30 no.2
    • /
    • pp.93-101
    • /
    • 2016
  • This paper presents the surface discharge characteristics in Dry-Air on laminated epoxy solid dielectrics and conductive particles in order to provide the valuable information for the insulation design of eco- friendly gas insulated switchgear. To improve insulation performance, the three types of the laminated epoxy solid dielectrics were proposed, and it was revealed that their surface discharge characteristics were similar to the bakelite dielectrics of same-laminated types. From the surface discharge characteristics of dry air, it was demonstrated that the effect of conductive particles on surface discharge voltage was dominant when there are this particles at the shortest electrode gap and that the degradation of insulation performance on the conductive particles was evident in epoxy than teflon. These phenomena were interpreted in terms of particle-triggered discharge mechanism and electric field of triple junction, respectively.

Conformational Change of Escherichia coli Signal Recognition Particle Ffh Is Affected by the Functionality of Signal Peptides of Ribose-Binding Protein

  • Ahn, Taeho;Ko, Ju Hee;Cho, Eun Yi;Yun, Chul-Ho
    • Molecules and Cells
    • /
    • v.27 no.6
    • /
    • pp.681-687
    • /
    • 2009
  • We examined the effects of synthetic signal peptides, wild-type (WT) and export-defective mutant (MT) of ribose-binding protein, on the conformational changes of signal recognition particle 54 homologue (Ffh) in Escherichia coli. Upon interaction of Ffh with WT peptide, the intrinsic Tyr fluorescence, the transition temperature of thermal unfolding, and the GTPase activity of Ffh decreased in a peptide concentration-dependent manner, while the emission intensity of 8-anilinonaphthalene-1-sulfonic acid increased. In contrast, the secondary structure of the protein was not affected. Additionally, polarization of fluorescein-labeled WT increased upon association with Ffh. These results suggest that WT peptide induces the unfolded states of Ffh. The WT-mediated conformational change of Ffh was also revealed to be important in the interaction between SecA and Ffh. However, MT had marginal effect on these conformational changes suggesting that the in vivo functionality of signal peptide is important in the interaction with Ffh and concomitant structural change of the protein.

Experimental Techniques for Surface Science with Synchrotron Radiation

  • Jonhnson, R.L.;Bunk, O.;Falkenberg, G.;Kosuch, R.;Zeysing, J.
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 1998.02a
    • /
    • pp.17-17
    • /
    • 1998
  • Synchrotron radiation is produced when charged particles moving with relativistic velocities a are accelerated - for example, deflected by the bending magnets which guide the electron or p positrons in circular accelerators or storage rings. By using special focusing magnetic lattices i in the particle accelerators it is possible to make the dimensions of the particle beam very small with a hi맹 charge density which results in a light source with high b디lIiance. Synchrotron light h has important properties which make it ideal for a wide range of investigations in surface s science. The fact that the spectrum of electromagnetic radiation emitted in a bending magnet e extends in a continuum from the 얹r infra red region to hard x-rays means that it is id않I for a v variety of spectroscopic studies. Since there are no convenient lasers, or other really bright l light sources, in the vacuum ultraviolet and soft x-ray re.밍ons the development of synchrotron r radiation has enabled enormous advances to be made in this di펌C비t spectr따 re밍on. P Polarization-dependent measurements, for ex없nple ellipsometry or circular dichroism studies a are possible because the radiation has a well-defined polarization - linear in the plane of orbit w with additional right-circular, or left-circular, components for emission an생es above, or below, t the horizontal, respectively. Since the synchrotron light is emitted from a bunch of charge c circulating in a ring the light is emitted with a well-defined time structure with a short flash of l light every time a bunch passes an exit port. The time structure depends on the size of the ring a and the number and sequence of filling of the bunches. A pulsed light source enables time¬r resolved studies to be performed which provide direct information on the lifetimes and decay m modes of excited states and in addition opens up the possibility of using time of flight t techniques for spectroscopic studies. The fact that synchrotron radiation is produced in a clean u ultrahi야 vacuum environment is of gr않t importance for surce science studies. The current t비rd generation synchrotron light sources provide exceptionally high baliance and stability a and open up possibilities for experiments which would have been inconceivable only a short time ago.

  • PDF

Experimental Study and Modelling on Membrane Fouling in Taylor Vortex Flow Microfiltration (테일러 와류 정밀여과에서 막오염의 실험적 연구 및 모델링)

  • 박진용;김현우;최창균
    • Membrane Journal
    • /
    • v.13 no.2
    • /
    • pp.88-100
    • /
    • 2003
  • A change of filtrate flux in Taylor vortex flow filtration was investigated experimentally by rotating speed of inner cellulose ester membrane cylinder (average pore size: 1.2 ${\mu}m$), slurry concentration, and particle size. The filtrate flux was a direct proportion relation with TMP, but an inverse relation with resistances. A change of cake resistance with time was examined by rotating speed, slurry concentration, and particle size. Initial resistance increased dramatically as raising slurry concentration, and the pseudo-steady state was maintained at high resistance value. However, times to reach the pseudo-steady state did not depend on slurry concentration. The resistance was larger as smaller particle size, because possibility of pore blocking inside membrane could be higher and shear effect should be lower as smaller particle size. A model equation suggested in this study was composed of particle deposition and removal terms, and could confirm well experimental data using average values of experimental coefficients.

Preparation and Electrochemical Performance of CNT Electrode with Deposited Titanium Dioxide for Electrochemical Capacitor

  • Kim, Hong-Il;Kim, Han-Joo;Morita, Masayuki;Park, Soo-Gil
    • Bulletin of the Korean Chemical Society
    • /
    • v.31 no.2
    • /
    • pp.423-428
    • /
    • 2010
  • To reduce polarization of electrochemical capacitor based on carbon nanotube, titanium oxide nanoparticles were deposited by ultrasound. The pore distribution of $TiO_2$/CNT nanoparticle exhibited surface area of $341\;m^2g^{-1}$ when $TiO_2$ content was 4 wt %, which was better than that of pristine CNT with surface area of $188\;m^2g^{-1}$. The analyses indicated that titanium oxide (particle diameter < 20 nm) was deposited on the CNT surface. The electrochemical performance was evaluated by using cyclic voltammetry (CV), impedance measurement, and constant-current charge/discharge cycling techniques. The $TiO_2$/CNT composite electrode showed relatively better electrochemical behaviors than CNT electrode by increasing the specific capacitance from $22\;Fg^{-1}$ to $37\;Fg^{-1}$ in 1 M $H_2SO_4$ solution. A symmetric cell assembled with the composite electrodes showed the specific capacitance value of $11\;Fg^{-1}$ at a current loading of $0.5\;mAcm^{-2}$ during initial cycling.

Fabrication of LaySr1-yFexTi1-xO3-based Nanocomposite Solid Oxide Fuel Cell Anodes by Infiltration (Infiltration법을 이용한 LaySr1-yFexTi1-xO3계 나노복합 연료극 제조)

  • Yoon, Jong-Seol;Choe, Yeong-Ju;Hwang, Hae-Jin
    • Journal of the Korean Ceramic Society
    • /
    • v.51 no.3
    • /
    • pp.224-230
    • /
    • 2014
  • Nano-sized gadolinium-doped ceria (GDC)/nickel particle-dispersed $La_ySr_{1-y}Ti_{1-x}Fe_xO_3$ (LSFTO)-based composite solid oxide fuel cell anodes were fabricated by an infiltration method and the effects of the GDC/Ni nanoparticles on the anode polarization resistance and cell performance were investigated in terms of the infiltration time and nickel content. The anodic polarization resistance of the LSFTO anode was significantly enhanced by GDC and/or Ni infiltration and it decreased with increasing infiltration time and Ni content, respectively. It is believed that the observed phenomena are associated with enhancement of the ionic conductivity and catalytic activity in the nanocomposite anodes by the addition of GDC and Ni. Power densities of cells with the LSFTO and LSFTO-GDC/Ni nanocomposite anodes were 150 and $300mW/cm^2$ at $800^{\circ}C$, respectively.

A Study on the Photon Energy Characteristics of ZnO Thin Film According to Coating Thickness (ZnO 박막의 증착 두께에 따른 Photon Energy 특성에 관한 연구)

  • Lee, Jung-Il;Seo, Jang-Soo;Jung, Sung-Gyo;Kim, Byung-In
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2003.05b
    • /
    • pp.75-81
    • /
    • 2003
  • This study evaporates ZnO layer thickness differently with RF sputtering method on Si Wafer(n-100). This study is performed to examine the characteristics of photon energy and dielectric loss according to the thickness of ZnO and increase the reliability and reproduction of ZnO thin film. It is confirmed that the variation of electric Permittivity by frequency is resulted from the formation of particles within thin film, the particle size and the polarization on grain boundary. Peak of electric Permittivity value of thin film has slower and less value in early low wavelength by the coulomb force involved in carrier combination according to the increase of frequency. Reversal of electric Permittivity values is induced by dipole polarization shown in the dielectric of thin film. Complex electric constant $({\varepsilon}_1{\varepsilon}_2)$ has larger peak values as it’s thickness is thinner and then it is larger according to the increase of frequency. Electric Permittivity by photon energy has large value in imaginary number and is reduced exponentially by the increase of carrier density according to that of photon energy.

  • PDF