• 제목/요약/키워드: Particle electrode

검색결과 389건 처리시간 0.028초

백금 무전해 도금 방법의 변화에 따른 이온성 고분자 및 금속 복합체 액추에이터의 특성 분석 (Characterization of Ionic-Polymer Metal Composite Actuators Varying Electroless Plating Method of Platinum)

  • 차승은;김병목;조성환;이승기;박정호;김병규
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제51권12호
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    • pp.601-607
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    • 2002
  • IPMC(Ionic Polymer Metal Composite)actuators were optimized for producing improved forces by changing multiple parameters including repetition of number of plating, surface electroding and additive(PVP)-treatment on reduction. The platinum electrode is deposited on the surface of the material where platinum particle stay in a dense form that appears to introduce a significant level of surface electrode resistance. Actuation tests were performed for such IPMC actuators under a low voltage. The test results show that the lower surface-electrode resistance generates higher actuation capability in the IPMC actuators. In order to investigate relaxation behavior of bending and repeatability in dry condition, the IPMC was coated by$rubber(KRATON^{TM})$to minimize the effect of water evaporation from IPMC. This actuator can be used in air with surface coating to avoid membrane drying.

Electrocatalysis of Oxygen Reduction by Au Nanoparticles Electrodeposited on Polyoxometalate-Modified Electrode Surfaces

  • Choi, Kyung-Min;Choi, Su-Hee;Kim, Jong-Won
    • 전기화학회지
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    • 제12권1호
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    • pp.75-80
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    • 2009
  • The effect of polyoxometalate monolayers on the electrodeposition of Au nanoparticles (AuNPs) on glassy carbon (GC) surfaces was examined by electrochemical and scanning electron microscope techniques. The presence of $SiMo_{12}O^{4-}_{40}$-layers resulted in average particle sizes of ca. 60 nm, which is larger than AuNPs deposited on bare GC surfaces. AuNPs electrodeposited on $SiMo_{12}O^{4-}_{40}$-modified GC surfaces for 20 s exhibited the best electrocatalytic activity for oxygen reduction. This system exhibited similar or slightly better efficiency for oxygen reduction than a bare Au electrode. Rotating disk electrode experiments were also performed and revealed that the catalytic reduction of oxygen on AuNPs deposited on $SiMo_{12}O^{4-}_{40}$-modified GC electrodes is a two-electron process.

3전극형 반사형 디스플레이의 단일컬러 구현 및 구동방법 (Single Color Realization and Driving Method of Three-Electrode Type Reflective Display)

  • 이상일;김영조
    • 한국전기전자재료학회논문지
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    • 제28권2호
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    • pp.109-114
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    • 2015
  • We realize a color reflective display without any color filter and sub-pixelation concept, by which the full or single color realization is basically impossible. In this study, we use a 3-electrode on the lower substrate with indium tin oxide (ITO) glass. The width of a rib is $30{\mu}m$, a cell size is $150{\mu}m{\times}150{\mu}m$, and the space of lower electrodes is $10{\mu}m$. To get the single color, we drive this panel by a identical algorithm based on the movement of charged particle in color fluid within a cell with hermetic seal. According to the driving method, the lifetime of panel is different.

전기사이클론 성능특성에 관한 실험적 연구 (An Experimental Study on the Performance Characteristics of Electrocyclone)

  • 홍진일;한정균;오장근;김윤제
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2005년도 동계학술발표대회 논문집
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    • pp.552-557
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    • 2005
  • In order to get the high collection efficiency of the electrocyclone. the effect of inlet and electrode shapes must be well grasped. In this study, performance characteristics of electrocyclone with different inlet and electrode shapes were experimentally investigated and compared as a function of particle size. Experimental results indicated that the helical inlet and tooth electrode have effect on significantly increasing collection efficiency.

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The Effect of Surface Modification with La-M-O (M = Ni, Li) on Electrochemical Performances of Li[Ni0.8Co0.15Al0.05]O2 Cathode

  • Ryu, Jea-Hyeok;Kim, Seuk-Buom;Park, Yong-Joon
    • Bulletin of the Korean Chemical Society
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    • 제30권3호
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    • pp.657-660
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    • 2009
  • The surface of $Li[Ni_{0.8}Co_{0.15}Al_{0.05}]O_2$ cathode particle was modified by lanthanum based oxide to improve electrochemical property and thermal stability. The XRD pattern of surface layer was indexed with that of $La_4NiLiO_8$. The discharge capacity of modified electrode was higher than that of pristine sample, specially at fast charge-discharge rate and high cut-off voltage. In the DSC profile of the charged sample, the generation of heat by exothermic reaction was decreased by surface modification. Such enhancement may by attributed to the presence of stable lanthanum based oxide, which effectively suppressd the reaction between electrode and electrolyte on the surface of $Li[Ni_{0.8}Co_{0.15}Al_{0.05}]O_2$ electrode.

Carbon Corrosion at Pt/C Interface in Proton Exchange Membrane Fuel Cell Environment

  • Choi, Min-Ho;Beom, Won-Jin;Park, Chan-Jin
    • Corrosion Science and Technology
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    • 제9권6호
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    • pp.281-288
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    • 2010
  • This study examined the carbon corrosion at Pt/C interface in proton exchange membrane fuel cell environment. The Pt nano particles were electrodeposited on carbon substrate, and then the corrosion behavior of the carbon electrode was examined. The carbon electrodes with Pt nano electrodeposits exhibited the higher oxidation rate and lower oxidation overpotential compared with that of the electrode without Pt. This phenomenon was more active at $75^{\circ}C$ than $25^{\circ}C$. In addition, the current transients and the corresponding power spectral density (PSD) of the carbon electrodes with Pt nano electrodeposits were much higher than those of the electrode without Pt. The carbon corrosion at Pt/C interface was highly accelerated by Pt nano electrodeposits. Furthermore, the polarization and power density curves of PEMFC showed degradation in the performance due to a deterioration of cathode catalyst material and Pt dissolution.

입자법을 이용한 와이어.이온.플라즈마원의 해석 (Numerical Analysis of Discharge in Wire ion Plasma Source)

  • 송태헌;고광철;강형부
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 추계학술대회 논문집
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    • pp.369-372
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    • 1997
  • Wire Ion Plasma Source (WIPS) is a plasma device which has a thin wire anode, a coaxially-set cylindrical cathode and electrodes located in both ends of the cylinder. The potential between the anode and cathode changes logarithmically by this electrode configuration. This electrode configuration enables high-density plasma to produce even at a low anode voltage. Since the electrode configuration is axially symmetric and long. plasma with axially uniform number density can be produced. Using particle-in-cell(PIC) and Monte Carlo collision(MCC), we investigate the traiectory of electrons and the characteristics of D.C. discharge in Wire ton Plasma Source.

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PEMFC에서 막 열화가 전극 열화에 미치는 영향 (Effect of Membrane Degradation on the Electrode Degradation in PEMFC)

  • 송진훈;정재진;정재현;김세훈;안병기;고재준;박권필
    • Korean Chemical Engineering Research
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    • 제51권3호
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    • pp.325-329
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    • 2013
  • 실제 고분자 전해질 연료전지(PEMFC) 운전조건에서는 전극과 전해질 막은 동시에 열화된다. 그런데 고분자전해질 연료전지의 전극 열화와 전해질 열화의 상호 작용에 대해 연구되지 않았다. 본 연구에서는 전해질 막 열화가 전극 열화에 미치는 영향에 대해 연구하였다. 전해질 막 열화 후 전극을 열화시켜 전해질 막 열화없이 전극을 열화시켰을 때와 비교하였다. 열화전후의 I-V 성능, 수소투과전류, 순환 전압측정(CV), 임피던스, TEM 등을 측정하였다. 전해질 막열화에 의해 수소투과도가 증가하고, 이에 따라 백금 입자 성장속도가 감소함으로써 전극 열화속도가 감소함을 보였다.

이중 페로브스카이트 촉매 PrBaMn2O5+δ의 고온전기분해조(Solid Oxide Electrolysis Cell) 연료극 촉매로 적용 가능성에 대한 연구 (Study on Possibility of PrBaMn2O5+δ as Fuel Electrode Material of Solid Oxide Electrolysis Cell)

  • 권영진;김동연;배중면
    • 한국군사과학기술학회지
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    • 제20권4호
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    • pp.491-496
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    • 2017
  • The hydrogen($H_2$) is promising energy carrier of renewable energy in the microgrid system such as small village and military base due to its high energy density, pure emission and convenient transportation. $H_2$ can be generated by photocatalytic water splitting, gasification of biomass and water electrolysis driven by solar cell or wind turbine. Solid oxide electrolysis cells(SOECs) are the most efficient way to mass production due to high operating temperature improving the electrode kinetics and reducing the electrolyte resistance. The SOECs are consist of nickel-yttria stabilized zirconia(NiO-YSZ) fuel electrode / YSZ electrolyte / lanthanum strontium manganite-YSZ(LSM-YSZ) air electrode due to similarity to Solid Oxide Fuel Cells(SOFCs). The Ni-YSZ most widely used fuel electrode shows several problems at SOEC mode such as degradation of the fuel electrode because of Ni particle's redox reaction and agglomeration. Therefore Ni-YSZ need to be replaced to an alternative fuel electrode material. In this study, We studied on the Double perovskite $PrBrMnO_{5+{\delta}}$(PBMO) due to its high electric conductivity, catalytic activity and electrochemical stability. PBMO was impregnated into the scaffold electrolyte $La_{0.8}Sr_{0.2}Ga_{0.85}Mg_{0.15}O_{3-{\delta}}$(LSGM) to be synthesized at low temperature for avoiding secondary phase generated when it exposed to high temperature. The Half cell test was conducted at SOECs and SOFCs modes.

An Analysis of Particle-clumping Phenomena of a Charged Particle-type Reflective Electronic Display

  • Kim, Young-Cho
    • Transactions on Electrical and Electronic Materials
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    • 제13권4호
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    • pp.212-214
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    • 2012
  • Both the electrically positive and negative particles in a cell of quick response-liquid powder display (QR-LPD) are surrounded by conductive electrodes on the upper and lower substrate and the dielectric materials of the barrier ribs. Particles in a cell are attached to or detached from the other materials by image force, electric field, Coulomb's force, and Van der Waals' force. Through these forces, the moving particles form an image but induce clumping phenomena. Particles having a large kinetic energy by a large q/m value crash into the opposite electrode with high speed at a large driving voltage and quickly lose electrically charged material. As a result, these particles are clumped and degrade panel performance. The clumped particles in a cell are observed by microscopic photographs and ascertained by a response time. When the bias voltage is increased to 0.68-0.76 $V/{\mu}m$, particle clumping occurs abruptly and the response time increases sharply. This particle clumping is similarly observed after the number of driving times at the driving voltage (0.42-0.64 $V/{\mu}m$).