• 분석과학
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• 제32권3호
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• pp.77-87
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• 2019

High viscosity carbon black dispersions are used in various industrial fields such as color cosmetics, rubber, tire, plastic and color filter ink. However, carbon black particles are unstable to heat due to inherent characteristics, and it is very difficult to keep the quality of the product constant due to agglomeration of particles. In general, particle size analysis is performed by dynamic light scattering (DLS) during the dispersion process in order to select the optimum dispersant in the carbon black dispersion process. However, the existing low viscosity analysis provides reproducible particle distribution analysis results, but it is difficult to select the optimum dispersant because it is difficult to analyze the reproducible particle distribution at high viscosity. In this study, dynamic light scattering (DLS) and asymmetrical flow field-flow fractionation (AsFlFFF) analysis methods were compared for reproducible particle size analysis of high viscosity carbon black. First, the stability of carbon black dispersion was investigated by particle size analysis by DLS and AsFlFFF according to milling time, and the validity of analytical method for the selection of the optimum dispersant useful for carbon black dispersion was confirmed. The correlation between color and particle size of particles in high viscosity carbon black dispersion was investigated by using colorimeter. The particle size distribution from AsFlFFF was consistent with the colorimetric results. As a result, the correlation between AsFlFFF and colorimetric results confirmed the possibility of a strong analytical method for determining the appropriate dispersant and milling time in high viscosity carbon black dispersions. In addition, for nanoparticles with relatively broad particle size distributions such as carbon black, AsFlFFF has been found to provide a more accurate particle size distribution than DLS. This is because AsFlFFF, unlike DLS, can analyze each fraction by separating particles by size.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 춘계학술대회
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• pp.1851-1856
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• 2003

A new Lagrangian stochastic dispersion model is developed by combining the GLM(generalized Langevin model) and the elliptic relaxation method. Under the physically plausible assumptions a simple analytical solution of elliptic relaxation is obtained. To compare the performance of our model with other model, the statistics of particle velocity as well as concentration are investigated. Numerical simulation results show good agreement with available experimental data.

• 대한기계학회논문집B
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• 제27권7호
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• pp.867-876
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• 2003

The Lagrangian dispersion of fluid particles in inhomogeneous turbulence is investigated by a direct numerical simulation of turbulent channel flow. Four points Hermite interpolation in the homogeneous direction and Chebyshev polynomials in the inhomogeneous direction is adopted to simulate the fluid particle dispersion. An inhomogeneity of Lagrangian statistics in turbulent boundary layer is investigated by releasing many particles at several different wall-normal locations and tracking those particles. The fluid particle dispersions and Lagrangian structure functions of velocity are scaled by the Kolmogorov similarity. The auto-correlations of velocity and acceleration are shown at the different releasing locations. Effect of initial particle location on the dispersion is analyzed by the probability density function at the several downstreams and time instants.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 추계학술대회 논문집
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• pp.251-251
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• 2009

The generation of energy and the cooling of system using thermoelectric semiconductor material have been in spotlight. Thermoelectric effect increases with the decrease of the thermal conductivity. In the thermoelectric devices, thermal conductivity is related to phonon scattering. Therefore, few studies have been conducted in the thermoelectric materials dispersed nano oxide particle for increasing the phonon scattering. However, core-shell structure which nano particle disperses in solvents and then which thermoelectric materials coated on the nano oxide particles has not been reported. In this study, we selected commercial nano powder such as $Al_2O_3$. This nano particle was about 20nm and was crushed aggregate by mechanical treatment. We have developed the effect of the dispersant and the solvent. The properties of particles were evaluated by SEM, TEM, particle size analysis, and BET. Dispersion and dispersion stability were evaluated by electronic microscope and turbidity.

• 한국대기환경학회지
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• 제20권1호
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• pp.47-58
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• 2004

The $textsc{k}$-$\varepsilon$ algebraic stress model (KEASM) was applied to atmospheric dispersion simulation using the Lagrangian particle dispersion model and was compared with the most popular turbulence closure model in the field of atmospheric simulation, the Mellor-Yamada (MY) model. KEASM has been rarely applied to atmospheric simulation, but it includes the pressure redistribution effect of buoyancy due to heat and momentum fluxes. On the other hand, such effect is excluded from MY model. In the simulation study, the difference in the two turbulence models was reflected to both the turbulent velocity and the Lagrangian time scale. There was little difference in the vertical diffusion coefficient $\sigma$$_{z}$. However, the horizontal diffusion coefficient or calculated by KEASM was larger than that by MY model, coincided with the Pasquill-Gifford (PG) chart. The applicability of KEASM to atmospheric simulations was demonstrated by the simulations.s.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.899-904
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• 2003

A new model for dense gas dispersion is formulated within the Lagrangian framework. In several accidental released situations, denser-than-air vapour clouds are formed which exhibit dispersion behavior markedly different from that observed for passive atmospheric pollutants. For relevant prediction of dense gas dispersion, the gravity and entrainment effects need to implemented. The model deals with negative buoyancy which is affected by gravity. Also, the model is subjected to entrainment. The mean downward motion of each particle was accounted for by considering the Langevin equation with buoyancy correction term.

• 반도체디스플레이기술학회지
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• 제10권2호
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• pp.91-95
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• 2011

Ni-CNT(carbon nanotubes) composite coating is often used for the surface treatment of electronic/mechanical devices to improve the properties of the exisiting Ni electroplating. For this, the dispersion of CNT particle is a critical process. In this study, ball milling and additive called sodium dodecyl sulfate(SDS) are employed for dispersion. Electroplated Ni-CNT films were examined by SEM-EDX, AES, microhardness tester, 4-point probe and contact angle measurement to find the optimum dispersion conditions. Ni-CNT coatings formed by ball milling for 9 hrs and with addition of SDS 12 times of CNT contents showed the highest hardness, reasonable resistivity and non-stick characteristics.

• 반도체디스플레이기술학회지
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• 제22권4호
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• pp.1-6
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• 2023

In CO₂ laser surface machining of plastic films in modern display manufacturing, scattering of fume particles could be a major source of well-recognized film surface contamination. This computational fluid dynamics research investigates the suction air flow patterns over a film surface as well as the dispersion of micron-sized fume particles with low-Reynolds number particle drag model. The numerical results show the recirculatory flow patterns near laser machining point on film surface and also over the surface of vertical suction slot, which may hinder the efficient removal of fume particles from film surface. The dispersion characteristics of fume particles with various particle size have been tested systematically under different levels of suction flow intensity. It is found that suction removal efficiency of fume particles heavily depends on the particle size in highly nonlinear manners and a higher degree of suction does not always results in more efficient particle removal.

• 한국대기환경학회지
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• 제19권3호
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• pp.249-261
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• 2003

A three-dimensional mesoscale atmospheric dispersion modeling system consisting of the Lagrangian particle dispersion model (LPDM) and the meteorological mesoscale model (MM5) was employed to simulate the transport and dispersion of non-reactive pollutant during the nuclear spill event occurred from Sep. 31 to Oct. 3, 1999 in Tokaimura city, Japan. For the comparative analysis of numerical experiment, two more sets of foreign mesoscale modeling system; NCEP (National Centers for Environmental Prediction) and DWD (Deutscher Wetter Dienst) were also applied to address the applicability of air pollution dispersion predictions. We noticed that the simulated results of horizontal wind direction and wind velocity from three meteorological modeling showed remarkably different spatial variations, mainly due to the different horizontal resolutions. How-ever, the dispersion process by LPDM was well characterized by meteorological wind fields, and the time-dependent dilution factors ($\chi$/Q) were found to be qualitatively simulated in accordance with each mesocale meteorogical wind field, suggesting that LPDM has the potential for the use of the real time control at optimization of the urban air pollution provided detailed meteorological wind fields. This paper mainly pertains to the mesoscale modeling approaches, but the results imply that the resolution of meteorological model and the implementation of the relevant scale of air quality model lead to better prediction capabilities in local or urban scale air pollution modeling.

• 한국환경과학회지
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• 제13권10호
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• pp.891-902
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• 2004

In order to predict air pollution and Yellow-sand dispersion precisely, it is necessary to clarify the sensitivity of meteorological field input interval. Therefore numerical experiment by atmospheric dynamic model(RAMS) and atmospheric dispersion model(PDAS) was performed for evaluating the effect of temporal and spatial resolution of meteorological data on particle dispersion. The results are as follows: 1) Base on the result of RAMS simulation, surface wind direction and speed can either synchronize upper wind or not. If surface wind and upper wind do not synchronize, precise prediction of Yellow-sand dispersion is strongly associated with upwelling process of sand of particle. 2) There is no significant discrepance in distribution of particle under usage of difference temporal resolution of meteorological information at early time of simulation, but the difference of distribution of particles become large as time goes by. 3) There is little difference between calculated particles distributions in dispersion experiments with high temporal resolution of meteorological data. On the other hand, low resolution of meteorological data occur the quantitative difference of particle density and there is strong tendency to the quantitative difference.