• Title/Summary/Keyword: Particle deposition

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Oxidation Behavior of Oxide Particle Spray-deposited Mo-Si-B Alloys

  • Park, J.S.;Kim, J.M.;Kim, H.Y.;Perepezko, J.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.20 no.6
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    • pp.299-305
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    • 2007
  • The effect of spray deposition of oxide particles on oxidation behaviors of as-cast Mo-14.2Si-9.6B (at%) alloys at $1200^{\circ}C$ up to for 100 hrs has been investigated. Various oxide powders are utilized to make coatings by spray deposition, including $SiO_2,\;TiO_2,\;ZrO_2,\;HfO_2$ and $La_2O_3$. It is demonstrated that the oxidation resistance of the cast Mo-Si-B alloy can be significantly improved by coating with those oxide particles. The growth of the oxide layer is reduced for the oxide particle coated Mo-Si-B alloy. Especially, for the alloy with $ZrO_2$ coating, the thickness of oxide layer becomes only one fifth of that of uncoated alloys when exposed to in air for 100 hrs. The reduction of oxide scale growth of the cast Mo-Si-B alloy due to oxide particle coatings are discussed in terms of the change of viscosity of glassy oxide phases that form during oxidation at high temperature.

Reduction Characteristics of Mass Produced Particle for Chemical-Looping Combustor with Different Fuels (매체순환식 가스연소기용 대량생산입자의 연료별 환원반응특성)

  • Ryu, Ho-Jung;Kim, Kyung-Su;Lee, Seung-Yong;Park, Yeong-Seong;Park, Moon-Hee
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.4
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    • pp.348-358
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    • 2008
  • Reduction reactivity and carbon deposition characteristics of mass produced oxygen carrier particle(OCN-650) have been investigated by using hydrogen, methane, syngas, and natural gas as fuels. For all fuels, the maximum conversion and oxygen transfer capacity increased as the temperature increase. The reduction rate and the oxygen transfer rate increased as the temperature increase for methane. However, those values showed maximum at 900$^{\circ}C$ for hydrogen, syngas, and natural gas. To explain consistently the change of maximum conversion, reduction rate, oxygen transfer capacity, oxygen transfer rate and degree of carbon deposition for different fuels, new parameters such as reactive carbon contents and require oxygen per input gas were adopted.

Modeling of the Ignition and Combustion of Single Aluminum Particle (단일 알루미늄 연료 입자의 점화 및 연소 모델링)

  • Yang, Hee-Sung;Lim, Ji-Hwan;Kim, Kyung-Moo;Lee, Ji-Hyung;Yoon, Woong-Sup
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.05a
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    • pp.187-192
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    • 2008
  • A simplified model for an isolated aluminum particle burning in air is presented. Burning process consists of two stages, ignition and quasi-steady combustion (QSC). In ignition stage, aluminum which is inside of oxide film melts owing to the self heating called heterogeneous surface reaction (HSR) as well as the convective and radiative heat transfer from ambient air until the particle temperature reaches melting point of oxide film. In combustion stage, gas phase reaction occurs, and quasi-steady diffusion flame is assumed. For simplicity, 1-dimesional spherical symmetric condition and flame sheet assumption are also used. Extended conserved scalar formulations and modified Shvab-Zeldovich functions are used that account for the deposition of metal oxide on the surface of the molten aluminum. Using developed model, time variation of particle temperature, masses of molten aluminum and deposited oxide are predicted. Burning rate, flame radius and temperature are also calculated, and compared with some experimental data.

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Effects of the Block Arrangement on the Collection Efficiency in the Two-Stage Electrostatic Precipitator with Charging Plate (평판형 방전판을 갖는 2단식 전기집진기의 집진판 블록배열이 집진효율에 미치는 영향)

  • 박성호;박청연;김태권
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.6
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    • pp.641-652
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    • 2000
  • The effect of block arrangement has been investigated on the particle deposition in the specified collecting cell of two-stage electrostatic precipitator by numerical analysis. Recirculation zone existed at the downstream of the block in the collecting cell, and the particles entering the recirculation zone were deposited on the collecting plate. Particle trajectory and deposition had considerably different phenomenon according to electrostatic and inertial effect, which depended on inlet mean velocity, electrostatic number, and particle diameter in the collecting cell. The total collection efficiency reached a minimum value through an interaction of electrostatic and inertial effect. In the computational domain, total collection efficiency for the case of two blocks in the computational domain was more than that of one block at the relative small electrostatic number. However as the block distance and inertial effect increased, the difference between the collection efficiency of two cases decreased. In the range of relatively small particle size total collection efficiency was always superior to particle collection efficiency that was predicted by Deutsch equation.

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Effect of Ventilation Type on the Trajectory of Coughed Particles in a Hospital Ward (실내환기 방식이 재채기 토출입자의 거동특성에 미치는 영향)

  • Kwon, Soon-Bark;Song, Ji-Han;Cho, Young-Min;Jeong, Woo-Tae;Park, Duck-Shin
    • Particle and aerosol research
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    • v.9 no.2
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    • pp.59-67
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    • 2013
  • One of purposes in this study was to confirm the behavior of coughed particles under different ventilation conditions. Three types of ventilation systems were applied for this experiment and the properties of coughed particles were measured using computational fluid dynamics (CFD) in an intensive care unit. The changes of total airborne particles for each case showed different trends according to the ventilation type and time, but the deposited particles were similar in all conditions. Although the time taken for 50% of the particles to be deposited was the fastest in case 2, the portion of deposited particles after 300 seconds was only 5% in all conditions. In case 1, a relatively small number of particles were deposited on the wall, but the particle exhaust and deposition on the occupants were the highest. In case 3, the downward ventilation was applied as that recommended by the US Center for Disease Control and Prevention (CDC) and showed different exhaust efficiencies according to the particle size.

Molecular Dynamics Study of the Energetic Aluminum Cluster Impact and Deposition (운동에너지를 가지는 알루미늄 덩어리 충돌 및 증착에 관한 분자동력학 연구)

  • 강정원;황호정
    • Journal of the Korean Vacuum Society
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    • v.10 no.3
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    • pp.283-288
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    • 2001
  • We have investigated aluminum cluster deposition using a classical molecular dynamics simulations. We studied the variations of the cluster momentum and the impulse force during collisions, and found that the close-packed cluster impact has some of properties of the single particle collision and the linear atomic chain collisions. We also simulated the series of energetic cluster deposition with energy Per atom. When energy Per atom in cluster has some eV rather than very low, the intermixing occurred easily in growth film and we can obtain a good film without subsequent annealing process.

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Effect of Catalyst Preparation on the Selective Hydrogenation of Biphenol over Pd/C Catalysts

  • Cho, Hong-Baek;Park, Jai-Hyun;Hong, Bum-Eui;Park, Yeung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.29 no.2
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    • pp.328-334
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    • 2008
  • The effects of catalyst preparation on the reaction route and the mechanism of biphenol (BP) hydrogenation, which consists of a long series-reaction, were studied. Pd/C catalysts were prepared by incipient wetness method and precipitation and deposition method. The reaction behaviors of the prepared catalysts and a commercial catalyst along with the final product distributions were very different. The choice of the catalyst preparation conditions during precipitation and deposition including the temperature, pH, precursor addition rate, and reducing agent also had significant effects. The reaction behaviors of the catalysts were interpreted in terms of catalyst particle size, metal distribution, and support acidities.

Modelling of Carbon Plume by Laser-ablation Method (레이저 용삭법에 의한 플라즈마의 진전 모델링)

  • So Soon-Youl;Lee Jin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.5
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    • pp.492-497
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    • 2006
  • The study on laser-ablation plasmas has been strongly interested in fundamental aspects of laser-solid interaction and consequent plasma generation. In particular, this plasma has been widely used for the deposition of thin solid films and applied to the semiconductors and insulators. In this paper, we developed and discussed the generation of carbon ablation plasmas emitted by laser radiation on a solid target, graphite. The progress of carbon plasmas by laser-ablation was simulated using Monte-Carlo particle model under the pressures of vacuum, 1 Pa, 10 Pa and 66 Pa. At the results, carbon particles with low energy were deposited on the substrate as the pressure becomes higher However, there was no difference of deposition distributions of carbon particles on the substrate regardless of the pressure.

A Numerical Study on Coughed Particle Dispersion and Deposition in Negative Pressure Isolation Room according to Particle Size (음압격리병실에서의 기침 토출입자의 입경에 따른 확산 및 침적에 대한 수치해석 연구)

  • Jung, Minji;Hong, Jin Kwan
    • Journal of The Korea Institute of Healthcare Architecture
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    • v.24 no.2
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    • pp.37-44
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    • 2018
  • Purpose: This study investigates the influences of coughing direction and healthcare worker's location on the transport characteristics of coughed particles in airborne infection isolation room (AIIR), which is commonly called negative pressure isolation room, with a downward ventilation system. Methods: Computational Fluid Dynamics (CFD) was used to simulate the airflow and for tracing the behavior of particles. Results: The results show that the airflow pattern and coughing direction have a significant influence on the characteristics of particle dispersion and deposition. When healthcare workers are in the isolation room with the patient who is lying on the bed, it is recommended to be located far from the anteroom to reduce the exposures from infectious particles. And when the patient is lying, it is more effective in removing particles than when the patient is in Fowler's position. Although it is an isolation room that produces unidirectional flow, coughing particles can spread to the whole room and a large number of particles can be deposited onto patient, bed, side rails, healthcare worker, ceiling, floor, and sidewall. Implications: Following the patients' discharge or transfer, terminal cleaning of the vacated room, furniture, and all clinical equipment is essential. Also, it is necessary to establish detailed standard operating procedure (SOP) in order to reduce the risk of cross-contamination.

Development of Particle Deposition System for Cleaning Process Evaluation in Semiconductor Fabrication (반도체 세정 공정 평가를 위한 나노입자 안착 시스템 개발)

  • Nam, Kyung-Tag;Kim, Young-Gil;Kim, Ho-Joong;Kim, Tae-Sung
    • Journal of the Semiconductor & Display Technology
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    • v.6 no.4
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    • pp.49-52
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    • 2007
  • As the minimum feature size decrease, control of contamination by nanoparticles is getting more attention in semiconductor process. Cleaning technology which removes nanoparticles is essential to increase yield. A reference wafer on which particles with known size and number are deposited is needed to evaluate the cleaning process. We simulated particle trajectories in the chamber by using FLUENT. Charged monodisperse particles are generated using SMPS (Scanning Mobility Particle Sizer) and deposited on the wafer by electrostatic force. The Experimental results agreed with the simulation results well. We calculate the particles loss in pipe flow theoretically and compare with the experimental results.

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