• 제목/요약/키워드: Particle Volume Concentration

검색결과 198건 처리시간 0.021초

마이크로캡슐의 제조와 그 응용(폴리락티드 마이크로캡슐) (Preparation of Microcapsules and Their Application (Poly (L-lactide) Microcapsule))

  • 홍기정;박수민
    • 한국염색가공학회지
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    • 제10권2호
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    • pp.29-36
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    • 1998
  • Poly(L-lactide) microcapsules containing hydrophilic penetrate were prepared by interfacial precipitation method through solvent evaporation from w/o/w emulsion. Effect of four determinative process parameters on the particle size distributions, morphologies, and release properties of microcapsules coated with poly(L-lactide) was investigated. Moreover, susceptible functional cotton fabrics treated with the mentioned microcapsules were prepared and laundry test up to 15 times were done to determine fastness properties. As a result, the prepared poly(L-lactide) microcapsules with a more sharp-distributive, rounder, and more permeable membranes could be prepared by means of protective colloid concentration, solution volume and stirring rate.

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다각주사법에 대한 비대칭 분무 구조의 토모그래피 재구성 (Tomographic Reconstruction of Asymmertic Liquid Spray from Multi-angular Scanning)

  • 이충훈;정석호
    • 한국자동차공학회논문집
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    • 제4권1호
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    • pp.177-186
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    • 1996
  • A convolution alogorithm combined with Fourier transformation is applied to the tomographic reconstruction of the asymmetric spray structure to identify the local drop size and volume concentration. The line of sight intergrated data from Malvern particle analyzer with multiangular scanning form a basic information for the deconvolution. Linear interpolation is tested to obtain the effect of increasing number of scanning angles. This transformation method predicts well the structure of asymmetric spray. The tehnique can be extended to other line of sight combustion diagnostics.

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External and Internal Glucose Mass Transfers in Succinic Acid Fermentation with Stirred Bed of Immobilized Actinobacillus succinogenes under Substrate and Product Inhibitions

  • Galaction, Anca-Irina;Rotaru, Roxana;Kloetzer, Lenuta;Vlysidis, Anestis;Webb, Colin;Turnea, Marius;Cascaval, Dan
    • Journal of Microbiology and Biotechnology
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    • 제21권12호
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    • pp.1257-1263
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    • 2011
  • This paper is dedicated to the study on the external and internal mass transfers of glucose for succinic acid fermentation under substrate and product inhibitions using a bioreactor with stirred bed of immobilized Actinobacillus succinogenes cells. By means of the substrate mass balance for a single particle of biocatalysts, considering the kinetic model adapted for both inhibitory effects, specific mathematical models were developed for describing the profiles of the substrate concentration in the outer and inner regions of biocatalysts and for estimating the substrate mass flows in the liquid boundary layer surrounding the particle and inside the particle. The values of the mass flows were significantly influenced by the internal diffusion velocity and rate of the biochemical reaction of substrate consumption. These cumulated influences led to the appearance of a biological inactive region near the particle center, its magnitude varying from 0 to 5.3% of the overall volume of particles.

디젤엔진에서 배출되는 미세 입자의 크기 분포 (Submicrometer Particle Size Distribution of Emissions from Diesel Engines)

  • 김민철;권순박;이규원;김종춘;류정훈;엄명도
    • 한국대기환경학회지
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    • 제15권5호
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    • pp.657-665
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    • 1999
  • Particulate matter produced by diesel engines is of concern to cngine manufactures because of its environmental impact. The majority of diesel particles are in the range of smaller than 1 ${\mu}{\textrm}{m}$. Because of their tiny volume, ultrafine diesel particles contribute very little to the total mass concentration which is currently regulated for automobile emissions. Ultrafinc particles are known to have deleterious effects upon human health cspecially because they penetrate deeply human respiratory tract and have negative effects on the health. In this study, the engine exhaust gas was diluted in a dilution tunnel and the particle size distribution was measured using the scanning mobility particel sizer system. Measurements of the number and the mass concentrations of the diesel exhaust were made under different engine ooperating conditions. The dilution sampling system provided a common basis for collection of the exhaust by cooling and diluting the source emission prior to the measurement. The measurement results showed that the particle size distributions of the exhaust from the diesel vehicles equipment with either heavy-duty or lignt-duty diesel engines, were similar in the particle size range of 0.08~0.2${\mu}{\textrm}{m}$.

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PFOA Free 불소 고분자 및 실리카 나노졸을 이용한 self cleaning 표면 가공에 관한 연구 (A Study on the Self-cleaning Surface Finishing Using PFOA Free Fluoric Polymer and Silica Nano-sol)

  • 박성민;권일준;김란;염정현;윤남식;이경남
    • 한국염색가공학회지
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    • 제21권6호
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    • pp.1-11
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    • 2009
  • Super-hydrophobic surface, with a water contact angle greater than $150^{\circ}$, has a self cleaning effect termed 'lotus effect'. We introduced super-hydrophobicity onto aramid/rayon mixture fabric with dual-scale structure by assembling silica nano-sol. Mixture fabric was treated with silica nano-sol, fluoric polymer using various parameters such as particle size, concentration. Silica nano-sol size were measured using particle size analyzer. Morphological changes by particle size were observed using field emission scanning electron microscopy(FE-SEM), contact angle measurement equipment. The contact angle of water was about $134.0^{\circ}$, $137.0^{\circ}$, $143.0^{\circ}$, $139.5^{\circ}$ and $139.0^{\circ}$ for mixture fabric coated with 100.2nm, 313.7nm, 558.2nm, 628.5nm and 965.4nm silica nano-sol, compared with about $120.0^{\circ}$ for mixture fabric coated with fluoric polymer. When we mixed particle sizes of 100.2nm and 558.2nm by 7:3 volume ratio, the contact angle of water was about $146.2^{\circ}$. And we mixed particle sizes of 313.7nm and 558.2nm by 7:3 volume ratio, the contact angle of water was about $141.8^{\circ}$. Also we mixed particle sizes of 558.2nm and 965.4nm by 7:3 volume ratio, the best super-hydrophobicity was obtained. In this paper, we fabricated the water-repellent surfaces with various surface structures by using four types of silica nano-sol, and we found that the dual-scale structure was very important for the super-hydrophobicity.

The Critical Pigment Volume Concentration Concept for Paper Coatings: II. Later-Bound Clay; Ground Calcium Carbonate, and Clay- carbonate Pigment Coatings

  • Lee, Do-Ik
    • 펄프종이기술
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    • 제34권5호
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    • pp.18-38
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    • 2002
  • A previous study on the model coatings based on latex-bound plastic pigment coatings (1) has been extended to latex-bound No. 1 clay, ultra-fine ground calcium carbonate (UFGCC), and clay-carbonate pigment mixture coatings, which are being widely used in the paper industry. The latex binder used was a good film-forming, monodisperse S/B latex or 0.15$\mu\textrm{m}$. No. 1 clay was representative of plate-like pigment particles, whereas UFGCC was of somewhat rounded rhombohedral pigment particlel. Both of them had negatively skewed triangular particle size distributions having the mean particle suet of 0.7${\mu}{\textrm}{m}$ and 0.6$\mu\textrm{m}$, respectively. Their packing volumes were found to be 62.5% and 657%, respectively. while their critical pigment volume concentrations (CPVC's) were determined to be 52.7% and 50.5% ( average of 45% caused by the incompatibility and 55.9% extrapolated) by coating porosity, respectively. Each pigment/latex coating system has shown its unique relationship between coating properties and pigment concentrations, especially above its CPVC. Notably, the clay/latex coating system hat shown higher coating porosity than the UFGCC/latex system at high pigment concentrations above their respective CPVC's. It was also found that their coating porosity and gloss were inter-related to each other above the CPVC's, as predicted by the theory. More interestingly, the blends of these two pigments have shown unique rheological and coating properties which may explain why such pigment blends are widely used in the industry. These findings have suggested that the unique structure of clay coatings and the unique high-shear rheology of ground calcium carbonate coatings can be judiciously combined to achieve superior coatings. Importantly, the low-shear viscosity of the blends was indicative of their unique packing and coating structure, whereas their high-shear rheology was represented by a common mixing rule, i.e., a viscosity-averaging. Transmission and scanning electron and atomic force microscopes were used to probe the state of pigment / latex dispersions, coating surfaces, freeze fractured coating cross-sections, and coating surface topography. These microscopic studies complemented the above observations. In addition, the ratio, R, of CPVC/(Pigment Packing Volume) has been proposed as a measure of the binder efficiency for a given pigment or pigment mixtures or as a measure of binder-pigment interactions. Also, a mathematical model has been proposed to estimate the packing volumes of clay and ground calcium carbonate pigments with their respective particle size distributions. As well known in the particle packing, the narrower the particle size distributions, the lower the packing volumes and the greater the coating porosity, regardless of particle shapes.

용융 알루미늄내에서 개재물의 크기분포 및 농도측정에 관한 연구 (A Study on the Measurement of the Concentration and the Size Distribution of Inclusions in the Molten Aluminum)

  • 안정;문광호;이광학
    • 한국주조공학회지
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    • 제14권1호
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    • pp.62-74
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    • 1994
  • The concentration and particle size distribution of non-metallic inclusions which suspended in the molten aluminum at $700^{\circ}C$ were measured by using LiMCA apparatus. The result revealed that the number of inclusions increased with increasing the applied current or decreasing the orifice diameter, while decreased with increasing the purity of aluminum. And also, it was found that the number of inclusions increased with increasing the amount of boron added to molten aluminum. This was found to be attributed to the formation of the inclusions of TiB and $V_3B_2$. It was investigated that the average concentration of inclusions in a constant volume of 20ml of molten aluminum was increased in the order of pure molten aluminum, molten aluminum containing 20ppm of boron and molten aluminum used repeatly in the experimental casting in this study.

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쿨터카운터(Coulter Counter)를 이용한 극지 눈시료 중 광물성 먼지의 입자크기분포 분석 (Particle Size Distribution Analysis of Mineral Dust in Polar Snow Using a Coulter Counter)

  • 강정호;황희진;홍상범;허순도
    • Ocean and Polar Research
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    • 제36권4호
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    • pp.319-326
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    • 2014
  • Mineral dust in the polar snow plays an important role both in the climate system of the Earth and in global biogeochemical cycles. Analysis of the concentration and the particle size distribution of mineral dust has been carried out in the snow from the Antarctic surface snow and the Greenland snowpit. Among the various particle size determination techniques, a Multisizer 3 Coulter Counter in a class 100 clean bench counted all particles between 1.1 and $30.0{\mu}m$ with a $50{\mu}m$ aperture tube. The aperture tube size, the concentration of electrolytes and the accuracy of the particle size distribution were determined in this study. The number concentrations from the Antarctic surface snow were 81,843 particles $mL^{-1}$, but those from the Greenland snowpit were 10,666 particles $mL^{-1}$. In the volume distribution, the distributions of mineral dust in both the Antarctic surface snow and the Greenland snowpit showed lognormal distribution in the size interval 1.1 to $6.0{\mu}m$ with the mode, 3.562 and $3.836{\mu}m$, respectively. The analysis technique using a coulter counter for mineral dust could be used for reconstructing paleoclimates from polar ice cores.

수직관내 유리알-물 유동의 압력손실 및 열전달 성능 (Pressure Loss and Heat Transfer Characteristics of the Glass Bead - Water Flow in a Vertical Tube)

  • 김내현;김정식;이윤표
    • 한국에너지공학회:학술대회논문집
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    • 한국에너지공학회 1996년도 춘계학술발표회 초록집
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    • pp.121-131
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    • 1996
  • Recently, circulating liquid fluidized bed heat exchangers are widely used in a number of places - chemical, process, food concentration, waste water treatment facilities, etc. In a circulating heat exchanger, solid particles circulate with the liquid, thereby increase the heat transfer and reduce the fouling potential of the heat exchanger. In this study, glass beads were circulated through a vertical tube. The pressure loss and the heat transfer coefficient were measured. At low flow velocities, glass beads enhanced the heat transfer considerably. The enhancement increased as the volume fraction of the glass beads increased. It also increased as the particle diameter increased. The pressure loss showed a similar trend. From the observed particle behavior near tube wall, a possible explanation of the trend is provided.

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고효율 냉각용 나노분말/절연유 분산액의 제조 및 열전달특성 (Preparation and Heat Transfer Properties of Nanoparticle-in-Transformer Oil Dispersions as Advanced Energy-efficient Coolants)

  • 최철;오제명
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.81-82
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    • 2006
  • The purposes of the present study are to produce a high thermal efficient of oil-based nanofluids which can be used as ultra-high voltage transformer oil, and to investigate their thermal and physical properties under static and dynamic conditions. Three kinds of nanofluids are prepared by dispersing $Al_2O_3$ or AlN nanoparticles in transformer oil. The thermal conductivities of the nanoparticles-oil mixtures increase with temperature, particle volume concentration and thermal conductivity of solid particle itself. It was quite important to eliminate $H_2O$ as byproducts of esterification and excess oleic acid which did not form stable chemical bonds with powder surface to get high dispersion stability.

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