• Title/Summary/Keyword: Particle Morphology

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A new description of the fractal dimension of particle aggregates in liquid medium

  • Xing, Jun;Ding, Shiqiang;Liu, Zhengning;Xu, Jirun
    • Particle and aerosol research
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    • v.11 no.4
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    • pp.99-105
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    • 2015
  • The possible existence forms of particle aggregates in liquid medium are classified into four different types according to their morphological characteristics, including the single particles that are separated from each other, the linear aggregates in which all component particles are located in a line, the planar aggregates where all particles are arranged on a plane, and the volumetric aggregates where all particles forms a three-dimensional space. These particle aggregates with different space morphologies have different fractal dimensions and different influence on the rheological phenomena of the solid-liquid system. The effects of various aggregates on the suspension viscosity are analyzed and related with the particle concentration, and then a mathematical model is presented to determine the fractal dimensions of various aggregates by measuring the apparent viscosity of the solid-liquid system. In the model, the viscous fractal dimension is developed as a new concept, the fractal dimensions of different aggregates can be obtained separately and then the relative components of various aggregates experimentally analyzed.

Impact of Biochar Particle Shape and Size on Saturated Hydraulic Properties of Soil

  • Lim, Tae-Jun;Spokas, Kurt
    • Korean Journal of Environmental Agriculture
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    • v.37 no.1
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    • pp.1-8
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    • 2018
  • BACKGROUND: Different physical and chemical properties of biochar, which is made out of a variety of biomass materials, can impact water movement through amended soil. The objective of this research was to develop a decision support tool evaluating the impact of the shape and the size distribution of biochar on soil saturated hydraulic conductivity ($K_{sat}$). METHODS AND RESULTS: Plastic beads of different size and morphology were compared with biochar to assess impacts on soil $K_{sat}$. Bead and biochar were added at the rate of 5% (v/w) to coarse sand. The particle size of bead and biochar had an effect on the $K_{sat}$, with larger and smaller particle sizes than the original sand grain (0.5 mm) decreasing the $K_{sat}$ value. The equivalent size bead or biochar to the sand grains had no impact on $K_{sat}$. The amendment shape also influenced soil hydraulic properties, but only when the particle size was between 3-6 mm. Intra-particle porosity had no significant influence on the $K_{sat}$ due to its small pore size and increased tortuosity compared to the inter-particle spaces (macro-porosity). CONCLUSION: The results supported the conclusion that both particle size and shape of the amended biochar impacted the $K_{sat}$ value.

Film Coating and Micro - Pattering Process of Nano-particle Conductive Ink System by Using ESD Method

  • Yang, Jong-Won;Jo, Sang-Hyeon;Sin, Na-Ri;Kim, Jin-Yeol
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.238.1-238.1
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    • 2011
  • 본 연구에서는 non-contact deposition method의 일환인 ESD (electroctatic deposition)의 박막공정을 이용하여 Conductive layer 위에 Gold nanoparticles 및 Silver nanoparticles 등 organic/inorganic nano particle conductive ink system의 단분산 2D 박막을 제조를 연구하였다. ESD head를 통해 여러가지 organic / inorganic nano particle conductive ink system을 Deposition하였으며 분산도가 높고 균일한 단분산의 2차원 박막 구조를 얻을 수 있었으며, 전도성 PEDOT과의 Hybridization을 통해 균일상의 표면 Morphology를 갖는 고 전도성 투명 필름을 제작하였다. ESD technique를 이용하는 박막공정 기술은 나노입자 및 나노구조물의 박막화 패턴화를 포함하는 새로운 Deposition 기술로써 이를 응용하여 금속 나노입자의 2차원의 패턴화된 박막 구현을 통해 유기반도체 및 전자소자에의 응용성을 증거할 수 있었다.

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A Simulation Method for Modeling the Morphology and Characteristics of Electrospun Polymeric Nanowebs

  • Kim Hyungsup;Kim Dae-Woong;Seo Moon Hwo;Cho Kwang Soo;Haw Jung Rim
    • Macromolecular Research
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    • v.13 no.2
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    • pp.107-113
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    • 2005
  • We developed an algorithm to simulate the generation of virtual nanowebs using the Monte Carlo method. To evaluate the pore size of the simulated multi-layered nanoweb, an estimation algorithm was developed using a ghost particle having zero volume and mass. The penetration time of the ghost particle through the virtual nanoweb was dependent on the pore size. By using iterative ghost particle penetrations, we obtained reliable data for the evaluation of the pore size and distribution of the virtual nanowebs. The penetration time increased with increasing number of layers and area ratio, whereas it decreased with increasing fiber diameter. Dimensional analysis showed that the penetration time can be expressed as a function of the fiber diameter, area ratio and number of layers.

Simulation of particle filtration by Brownian dynamics (Brownian dynamics 를 이용한 입자 포집 모사)

  • Bang, Jong-Geun;Yoon, Yoong-Sup
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.1922-1927
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    • 2008
  • In the present study, deposition of discrete and small particles, which diameter is less than $1{\mu}m$, on a filter element was simulated by stochastic method. Trajectory of each particle was numerically solved by Langevin equation and Brownian random motion was treated by Brownian dynamics. Lattice Boltzmann method (LBM) was used to solve flow field around the filter collector and deposit layer. Interaction between flow field and deposit layer was obtained from a converged solution from an inner-loop calculation. Simulation method is properly validated and collection efficiency due to different filtration parameters are examined and discussed. Morphology of deposit layer and its evolution was visualized in terms of the particle size. The particle loaded effect on collection efficiency was also discussed.

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Study of Incipient Soot Particles with Measuring Methodologies (입자 측정방법을 통한 초기 수트입자 연구)

  • Lee Eui Ju
    • Journal of the Korean Society of Visualization
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    • v.2 no.1
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    • pp.12-17
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    • 2004
  • The physical characteristics of soot near the soot inception point were investigated with various measurements. In-situ measurements of particle size and volume fraction were introduced based on time resolved laser-induced incandescence (TIRE-LII) and laser-induced ion mobility (LIIM). The one has more convenience and accuracy than conventional LII technique and the other works best for particle sizes of a few nanometers at high concentrations in a uniform concentration field. A complementary ex-situ measurement of particle size is nano differential mobility analyzer (Nano-DMA), which recently developed for measuring particle sizes between 2nm and 100nm and provides high-resolution size information for early soot. Particles will be also collected on transmission electron microscope (TEM) grids using rapid thermophoretic sampling and analyzed for morphology. These measurements will allow fresh and original insight into the characterizing soot inception process. The measured physical properties of incipient soot will clarify the controlling growth mechanism combined with chemical ones, and the dominant mechanism for soot modeling can be deduced from the information.

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Influence of the degradation of MgO protective layer on the Surface profiles and discharge characteristics in AC-PDP.

  • Lee, Soo-Beom;Jeoung, J.M.;Ko, B.D.;Oh, P.Y.;Moon, M.W.;Lee, J.H.;Lim, J.E.;Lee, H.J.;Han, Y.G.;Yoo, N.L.;Jeoung, S.H.;Son, C.G.;Choi, E.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1207-1210
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    • 2005
  • The MgO protective layer provides protection from the discharge, lowers the discharge voltage and prolongs the AC-PDP lifetime. We have investigated the characteristics of degradation of MgO protective layer, which correlates to the image-sticking[1] and the lifetime in AC-PDP. The degraded MgO have been changed the surface morphology of MgO. It was found that panel lifetime depended on degradation of MgO protective.

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Synthesis of Porous TiO2-SiO2 Particles by Self-assembly of Nanoparticles (나노입자들의 자기조립에 의한 TiO2-SiO2 다공체 제조)

  • Oh, Kyoung Joon;Kim, Sun Kyung;Chang, Hankwon;Jang, Hee Dong
    • Particle and aerosol research
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    • v.7 no.3
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    • pp.79-85
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    • 2011
  • Porous $TiO_2-SiO_2$ particles were synthesized by co-assembly of nanoparticles of $TiO_2$ and $SiO_2$ in evaporating aerosol droplets. Poly styrene latex (PSL) particles were employed as a template of porous particles. Flowrate of dispersion gas, weight ratio of $TiO_2/SiO_2$ and $SiO_2$ concentration in the precursor, and PSL size were chosen as process variables. The morphology, crystal structure, chemical bonding, and pore size distribution were analyzed by FE-SEM, XRD, FT-IR, BET. The morphology of porous $TiO_2-SiO_2$ particles was spherical and the average particle size range were from 1 to $10{\mu}m$. The particles were composed of meso and macro pores. The average particle diameter and pore volume of the as prepared particles were dependant on process variables. It was found that UV-Vis absorption of the porous particles was comparable with pure $TiO_2$ nanoparticles even though $TiO_2/SiO_2$ ratio is low in the porous particles.

Control of Size and Morphology of Particles Using CO2 Laser in a Flame (화염증 CO2 Laser를 이용한 입자의 크기 및 형상 제어)

  • Lee, Donggeun;Lee, Seonjae;Choi, Mansoo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.11
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    • pp.1379-1389
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    • 1999
  • A new technique for control of size and shape of flame-made particles is Introduced. The characteristic sintering time can be controlled Independently of collision time by heating the particles with irradiation of laser because the sintering time strongly depends on temperature. A coflow oxy-hydrogen diffusion flame burner was used for $SiCl_4$ conversion to silica particle. Nanometer sized aggregates irradiated by a high power CW $CO_2$ laser beam were rapidly heated up to high temperatures and then were sintered to approach volume-equivalent spheres. The sphere collides much slower than the aggregate, which results in reduction of sizes of particles maintaining spherical shape. Light scattering of Ar ion laser and TEM observation using a local sampling device were used to confirm the above effects. When the $CO_2$ laser was irradiated at low position from the burner surface, particle generation due to gas absorption of laser beam occurred and thus scattering intensity increased with $CO_2$ laser power. At high irradiation position, scattering intensity decreased with $CO_2$ laser power and TEM image showed a clear mark of evaporation and recondensation of particles for high $CO_2$ laser power. When the laser was irradiated between the above two positions where small aggregates exist, average size of spherical particles obviously decreased to 58% of those without $CO_2$ laser irradiation with the spherical shape. Even for increased carrier gas flow rate by a factor of three, TEM photograph also revealed considerable reduction of particle size.

Morphological Study on PNIPAAm Hydrogel Microspheres Prepared by Using SPG Membrane Emulsification and UV Photopolymerization (SPG 막유화 및 UV 광중합법에 의해 제조된 PNIPAAm 하이드로젤 입자의 형태학에 관한 연구)

  • Lee, Yun Jig;Kim, Mi Ri;Cheong, In Woo
    • Journal of Adhesion and Interface
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    • v.16 no.2
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    • pp.76-82
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    • 2015
  • W/O emulsions were prepared from the aqueous solution containing NIPAAm, MBA, and APS in the continuous phase of toluene and mineral oil mixture with HMP and Span80 by using SPG membrane emulsification, and followed by the formation of PNIPAAm hydrogel microspheres through UV photopolymerization. As the ratio of mineral oil to toluene increased in the continuous phase, both particle size of the hydrogel increased and density of PNIPAAm polymer in the hydrogel particle increased, and which significantly affected swelling/deswelling ratio ($V/V_o$) with temperature change around VPTT. When the polymerization temperature was below LCST ($20^{\circ}C$), PNIPAAm hydrogel showed filled particle morphology; however, it was turned out to hollow particle morphology with thick shell layer with $40^{\circ}C$. Both density of PNIPAAm and gel content of the hydrogel increased with the increase in MBA concentration.