• Journal of the Korean institute of surface engineering
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• v.40 no.4
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• pp.190-196
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• 2007

Dye sensitized solar cells(DSSC) are the most promising future energy resource due to their high energy efficiency, low production cost, and simple manufacturing process. But one problem in DSSC is short life time compared to silicon solar cells. This problem occurred from photocatalytic degradation of dye material by nanometer sized $TiO_2$ particles. To prevent dye degradation as well as to increase its life time, the transparent coating film is needed for UV blocking. In this study, we synthesized nanometer sized $TiO_2$ particles in sols by increasing its internal pressure up to 200 bar in autoclave at $120^{\circ}C$ for 10 hrs. The synthesized $TiO_2$ sols were all formed with brookite phase and their particle size was several nm to 30 nm. Synthesized $TiO_2$ sols were coated on the backside of fluorine doped tin oxide(FTO) glass by ink jet printing method. With increasing coating thickness by repeated ink jet coating, the absorbance of UV region (under 400 nm) also increases reasonably. Decomposition test of titania powders dispersed in 0.1 mM amaranth solution covered with $TiO_2$ coating glass shows more stable dye properties under UV irradiation, compared to that with as-received FTO glass.

• Analytical Science and Technology
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• v.32 no.3
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• pp.77-87
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• 2019

High viscosity carbon black dispersions are used in various industrial fields such as color cosmetics, rubber, tire, plastic and color filter ink. However, carbon black particles are unstable to heat due to inherent characteristics, and it is very difficult to keep the quality of the product constant due to agglomeration of particles. In general, particle size analysis is performed by dynamic light scattering (DLS) during the dispersion process in order to select the optimum dispersant in the carbon black dispersion process. However, the existing low viscosity analysis provides reproducible particle distribution analysis results, but it is difficult to select the optimum dispersant because it is difficult to analyze the reproducible particle distribution at high viscosity. In this study, dynamic light scattering (DLS) and asymmetrical flow field-flow fractionation (AsFlFFF) analysis methods were compared for reproducible particle size analysis of high viscosity carbon black. First, the stability of carbon black dispersion was investigated by particle size analysis by DLS and AsFlFFF according to milling time, and the validity of analytical method for the selection of the optimum dispersant useful for carbon black dispersion was confirmed. The correlation between color and particle size of particles in high viscosity carbon black dispersion was investigated by using colorimeter. The particle size distribution from AsFlFFF was consistent with the colorimetric results. As a result, the correlation between AsFlFFF and colorimetric results confirmed the possibility of a strong analytical method for determining the appropriate dispersant and milling time in high viscosity carbon black dispersions. In addition, for nanoparticles with relatively broad particle size distributions such as carbon black, AsFlFFF has been found to provide a more accurate particle size distribution than DLS. This is because AsFlFFF, unlike DLS, can analyze each fraction by separating particles by size.

• Particle and aerosol research
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• v.8 no.1
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• pp.37-43
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• 2012

In this study, we designed a 'spark in liquid' system. The spark discharge between two electrodes were used to generate particles by using sufficient temperature to evaporate a part of electrodes. The power supply system provides a continuous spark discharge by discharging of the capacitor to ionize the electrodes in liquid. The DC spark discharge system operates with 1-10 kV voltage. Processed copper and graphite rods were used to both electrodes with 1-3 mm diameter. There are several variables which can control the particle size and concentration such as gap distance between electrodes, applied voltage, operating liquid temperature, electrode type and liquid type. So we controlled these variables to confirm the change of particle size distribution and concentration of particles contained in liquid as wt%. 'spark in liquid' system is expected to apply nanoink by control of concentration with analysis of characteristics.

• Korea-Australia Rheology Journal
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• v.15 no.4
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• pp.179-185
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• 2003

Associating polymers act as flocculants in colloidal suspensions, because the hydrophobic groups (hydrophobes) can adsorb onto particle surfaces and create intermolecular cross-linking. The steady-shear viscosity and dynamic viscoelasticity were measured for suspensions flocculated by multichain bridging of associating polymers. The effects of surfactant on the suspension rheology are studied in relation to the bridging conformation. The surfactant molecule behaves as a displacer and the polymer chains are forced to desorb from the particle surfaces. The overall effect of surfactant is the reduction of suspension viscosity. However, the additions of a small amount of surfactant to suspensions, in which the degree of bridging is low, cause a viscosity increase, although the number of chains forming one bridge is decreased by the forced desorption of associating polymer. Since the polymer chains desorbed from one bridge can form another bridge between bare particles, the bridging density over the system is increased. Therefore, the surfactant adsorption leads to a viscosity increase. The surfactant influences the viscosity in two opposing ways depending on the degree of bridging.

• Particle and aerosol research
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• v.13 no.3
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• pp.111-118
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• 2017

Electrohydrodynamic (EHD) printing with the aid of strong electric fields can generate and pattern droplets that are smaller than droplets by other printing technologies. Conventional EHD printing has created two-dimensional (2D) patterns by moving its nozzle or a substrate in X and Y directions. In this study, we aimed to develop an EHD system that can create 2D patterns using a multielectrode array (MEA) without moving a nozzle or substrate. In particular, printing ink mixtures of biodegradable polymers and model dyes was patterned on a thin film made of another biodegradable polymer. Without movement of a nozzle and substrate, stable 2D patterning of minimum $6{\mu}m$ size over a range of about 1 mm away from the nozzle position was achieved by MEA control only. We also demonstrated the possibility of denser 2D pattering of the ink mixtures by moving a target substrate relative to MEA position.

• Korean Journal of Materials Research
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• v.14 no.11
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• pp.807-812
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• 2004

The uniformity of emission mage and field emission properties of carbon nanotube(CNT) cathodes dependence on CNT particle dispersion were investigated for field emission displays. We used multi-walled carbon nanotubes (MWNTs) synthesized by CVD method as the field emitter materials. CNT dispersion in CNT ink was carried out by ultrasonication and shaking methods. According to CNT dispersion conditions, the uniformity of emission image and field emission properties of CNT cathodes were greatly affected. The smaller particles of filler materials and CNT powders provide the better properties of the CNT cathodes.

• Textile Coloration and Finishing
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• v.31 no.2
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• pp.77-87
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• 2019

To improve rubbing fastness of the printed fabrics, the binder polymers for Digital Textile Printing(DTP) pigment inks were synthesized with miniemulsion polymerization using various acrylic monomers, which are MMA(Methyl methacrylate), BA(Butyl acrylate), and Self-crosslinking monomers, such as NEA(N-Ethylol acrylamide) and MAA (Methacrylic acid). The acrylic monomer compositions were varied when synthesizing the binder polymers and their particle size distributions, average molecular weights, and Tgs were investigated. The prepared binder polymers were applied to prepare Cyan, Black, Yellow and Magenta pigment ink for DTP and the prepared inks were used to dye cotton fabrics. Then, color strength, and rubbing fastness were also investigated to study the effect of the comonomer compositions of the binder polymer on the color strength and rubbing fastness of the resulting pigment inks.

• Particle and aerosol research
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• v.17 no.2
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• pp.21-27
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• 2021

We developed non-metallic electrodes that can replace metallic electrodes of the electrostatic precipitator(ESP) for the purpose of light weight, corrosion resistance, cost reduction. We manufactured three types of collection electrodes made of stainless steel (M), Carbon ink coating layer-Plastic sheet-Carbon ink coating layer (CPC), and Plastic sheet-Carbon ink coating layer-Plastic sheet (PCP). We studied the collection efficiency of a two-stage ESP using oil mist particles with and without collection stage by changing the flow rate, the material of collection electrode, and the applied voltage of the pre-charger module and the collection module. Here we measured concentrations of particles at diameters of 0.45 ㎛ (CMD; count median diameter) and 3.0 ㎛ (MMD : mass median diameter), as well as PM_2.5 and PM₁₀. As a result of the experiment, two-stage ESP had 22~25% higher collection efficiency in PM_2.5 than one-stage ESP at the same applied voltage. The difference in collection efficiency by varying the materials of collection electrodes was less than 5%. The weight of the non-metallic electrode was only one eighth the weight of the metal electrode. CPC electrode had a thickness of 0.27 mm, which was 1.5 times thinner than a thickness of PCP electrode, so when the flow rate increased, the CPC electrodes couldn't be kept at equal intervals due to the fluttering unlike PCP electrodes. In addition, the PCP-CPC collection module of the present experiment followed the theoretical efficiency based on Deutsch equation and Cochet's charging theory.

• Journal of the Semiconductor & Display Technology
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• v.9 no.4
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• pp.87-91
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• 2010

Charged micro-particles are widely used as the key components for many electrical applications such as an e-paper, a touch panel, a printer toner and an electronic ink. Among them, the e-paper is an emerging reflective type display using the charged particles that has the advantages of the extremely low power consumption and sunlight readability. To create images on the e-paper, we confine black positively-charged and white negatively-charged particles between bottom and top electrodes and selectively apply the electric field. When the Coulomb force by an applied electric field is greater than the adhesion force between the charged particle and the electrode, the particles' transition happens resulting in the change of color between black and white. Therefore, the adhesion force is a very important factor for designing and estimating e-paper's operation. In this study, we constructed a basic model for particle's transition and an adhesion force equation describing particle's transition with three different forces: electrostatic image force, Van der Waals force and gravitational force. The simulation results showed that the gravitational force is negligible for the interesting range for the charge and the radius, and the adhesion force can be strongly dependent on the particle's charge and radius.

• Journal of the Korean Society of Visualization
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• v.15 no.1
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• pp.53-63
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• 2017

Sonic and supersonic jets include many complicated flow physics associated with shock waves, shear layers, vortices as well as strong interactions among them, and have a variety of engineering applications. Much has been learned from the previous researches on the sonic and supersonic jets but quantitative assessment of these jets is still uneasy due to the high velocity of flow, compressibility effects, and sometimes flow unsteadiness. In the present study, the sonic jets issuing from a convergent nozzle were measured by PIV and Schlieren optical techniques. Particle Image Velocimetry (PIV) with Olive oil particles of $1{\mu}m$ was employed to obtain the velocity field of the jets, and the black-white and color Schlieren images were obtained using Xe ramp. A color filter of Blue-Green-Red has been designed for the color Schlieren and obtained from an Ink jet printer. In experiments, two types of sonic nozzles were used at different operating pressure ratios(NPR). The obtained images clearly showed the major features of the jets such as Mach disk, barrel shock waves, jet boundaries, etc.