• Title/Summary/Keyword: Particle Growth

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Vapor deposition and characterization of parylene films

  • Kim, Eui-Jung
    • Journal of Korean Vacuum Science & Technology
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    • v.3 no.1
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    • pp.16-23
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    • 1999
  • Deposition of parylene (PA) films has been explored at substrate temperatures below 2$0^{\circ}C$ and pressures below 4 torr. The film thickness was measured using AFM and the film thickness measured was 3,500-12,000$\AA$ and the growth rate was 20-70$\AA$/min. T도 dielectric constant of the deposited PA films was found to be 2.66 and the dielectric strength was in excess of 2$\times$105V/cm. The growth rate became a maximum at a precursor decomposition temperature of $600^{\circ}C$. It was found that the growth rate decreased with increasing substrate temperature, whereas it increased with increasing pressure. At a precursor decomposition temperature of 75$0^{\circ}C$ or at a deposition pressure above 1 Torr the film surface became rough due to particle formation in the gas phase. The condensation of a p-xylylene monomer on the substrate surface turned out to be a rate-limiting step in the growth of the PA films.

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Numerical Analysis for the Detailed Structure and the Soot Formation Mechanism in Counterflow Ethylene-Air Nonpremixed Flame (대향류 에틸렌/공기 비예혼합 화염의 구조 및 Soot 생성 메커니즘 해석)

  • 임효준;김후중;김용모
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.5
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    • pp.40-54
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    • 1999
  • The flame structure and soot formation in the counterflow Ethylene-Air nonpremixed flame are numerically analyzed. The present soot reaction mechanism involves nucleation, surface growth, particle coagulation, and oxidation steps. The gas phase chemistry and the soot nucleation, surface growth reactions are coupled by assuming that the nucleation and soot mass growth has the certain relationship with the concentration of benzene and acetylene. In terms of the centerline velocity and the soot volume fraction, the predicted results are compared with the experimental data. The detailed discussion has been made for the sensitivity of model constants and the deficiencies of the present model. Numerical results indicated that the acetylene addition to the soot surface plays the dominant role in the soot mass growth for the counterflow nonpremixed flame.

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Effects of Zeolite Particle on Soil Chemical Properties and Rice Growth (Zeolite 입도(粒度)가 토양화학성(土壤化學性) 및 벼 생육(生育)에 미치는 영향(影響))

  • Lim, Soo-Kil;Lee, Chang-Ho;Shin, Kwan-Seop
    • Korean Journal of Soil Science and Fertilizer
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    • v.28 no.4
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    • pp.340-349
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    • 1995
  • Effects of the zeolite particle size on the soil chemical properties and on rice growth was investigated on the pot with the loamy sand (Sadu series) and silty clay loam(Paju series) soils. All the zeolite treatments brought the increase of unhulled grain yield on the both loamy sand and silty clay loam soils. Unhulled grain yield increased with increasing the amount of zeolite applied and with decreasing the amount of particle size of zeolite applied on both soils. Unhulled grain yield increased significantly by 11.1% (22.79g/head) with 2ton/10a of smaller than $106{\mu}m$ size zeolite on the loamy sand soil and on the silty clay loam soil, yield increased by 9.3% (24.98g/head) with 1.5ton/10a of smaller than $106{\mu}m$ size zeolite. CEC, pH and contents of exchangeable cations of the soil after experiment were raised by increasing the amount of zeolite and also by decreasing the particle size of zeolite at both soil. At the heading stage, the zeolite treatments improved the growth of rice plant compared to control. The nutrient contents(T-N, Ca, Mg, K, Na), except phosphorus, in the rice plant grown on the zeolite treated soils were higher than control plot.

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Studies on the Manufacture of Fiber Pot and its Effect for the Good Transplanting (이식용(移植用)Pot의 제조(製造) 및 그 효과(効果)에 관(關)한 연구(硏究))

  • Kim, Ji Moon;Lee, Hwa Hyung;Kwon, Ki Won;Song, Ho Kyong
    • Journal of Korean Society of Forest Science
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    • v.46 no.1
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    • pp.1-9
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    • 1980
  • This study was carried out to examine the substitution possibility into fiber pot instead of Jiffy pot for the good transplanting. Fiber pot was made of fiber, wood waste particle, and bark powder (10% of the particle weight) and also latex was added into the furnish as a binder. The pots were sprayed with just enough urea solution to prevent nitrogen deficiency of pot media coming from the breakdown of wood fiber in the pot wan during the plant growing. The utility of fiber pot was compared with that of Jiffy pot in the service test of two tree species under a green-house condition. The results obtained can be summarized as follows ; 1. Fiber pot made of 30% wood fiber+70% particle including 10% of bark powder, and 3%-latex has shown a good results like that of Jiffy pot in the sp. gr., tear factor and burst factor. For water absorption, fiber pot made of 50% fiber+50% particle, and 3%-latex got the best result. In the consideration of the above physical and mechanical properties of the fiber pot for good root penetration through the pot wall and facile handling, fiber pot made of 30% fiber+70% particle, and 3%-latex may be seemed to be good. 2. There were no harms in sapling growth in fiber pot as well as in Jiffy pot. The root penetration ability through the fiber pot was slightly inferior to that of Jiffy pot, and yet the pot damage through transportation seemed to be slighter in fiber pot than in Jiffy pot.

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Preparation of $Pb(Sc_{1/2}Nb_{1/2})O_3$ powders by the molten salt synthesis method (용융염 합성법에 의한 $Pb(Sc_{1/2}Nb_{1/2})O_3$ 분말의 제조)

  • 박경봉
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.3
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    • pp.400-405
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    • 1997
  • Lead scandium niobate powders were prepared by a molten salt synthesis method using KCl as a flux. Variations in phase formation and particle morphology were investigated for the temperature range $700^{\circ}C$ to $850^{\circ}C$. Pure $Pb(Sc_{1/2}Nb_{1/2})O_3$ perovskite phase was formed at $850^{\circ}C$ after 2hrs and the average particle size of powder was below 0.5 $\mu\textrm{m}$. The results are discussed with respect to DTA, X-ray diffraction, and microstructural characterization data.

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Design of ceramics powder compaction process parameters (Part Ⅰ : Finite element analysis) (세라믹스 분말 가압 성형 공정 변수 설계(1부: 유한요소 해석))

  • Jung S. C.;Keum Y. T.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.1
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    • pp.21-26
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    • 2005
  • In order to simulate the powder compaction process and to assess the effects of packing randomness and particle arrangement 2-dimensional model of rod array compaction using quasi-random multiparticle array is introduced. The elastic modulus of porous ceramics is computed by the homogenization method. With 3 Al₂O₃ and 3 Al particles the compaction processes associated with the porosities are simulated by the explicit finite element method, based on the elastic modulus found by the homogenization method. The simulation results are compared with both previous analytical ones and experimental measurements. Finally, in order to find the relationship between the friction coefficient of powder particles and the relative density, the sensitivity analysis is performed.

Development of transparent dielectric paste for PDP (플라즈마 디스플레이용 투명 유전체 페이스트의 개발)

  • Kim, Hyung-Jong;Chung, Yong-Sun;Joo, Kyoung;Auh, Keun-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.1
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    • pp.50-54
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    • 1999
  • Plasma display panel is a potential candidate for HDTV, due to the fact that the screen size can easily be increased by a thick film technology. In this study, transparent dielectric materials which satisfied the requirements of dielectrics for PDP was developed using lead alumina borosilicate glasses. The Paste which had thixotropic behavior suitable for screen printing was made of this glass composition. the paste became more thixotropic as the particle size decreased. After firing, the cross sectional area of the thick film was analyzed by SEM. The voids in the thick film were removed using bimodal particle system. The dielectric thick film showed good adhesion characteristics.

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Preparation of Au fine particle dispersedf $TiO_{2}$ film by sol-gel and photoreduction process (Sol-Gel and photoreduction 공정에 의한 Au 미립자분산 $TiO_{2}$ 박막 제조)

  • 현부성;김병일;강원호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.1
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    • pp.23-28
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    • 1999
  • Au fine particles dispersed $TiO_{2}$ film was prepared on silica glass substrate by sol-gel dipping and firing process. The $TiO_{2}$ films were fabricated from the system of titanium tetraisopropoxide-EtOH-HCl-$H_{2}O$-hydrogen tetrachloroaurat (III) tetrahydrate. The conditions for the formation of clear solution and dissolving high concentration of Au compound were examined. Photoreduction process was adopted to control the size of gold metal particles. Phase evolution of matrix $TiO_{2}$ and variation of Au particle with UV irradiation were investigated by XRD, SEM, TEM and UV-visible spectrophotometer. The effect of CPCl (Cetylpyridinium chloride monohydrate) as a dispersion agent was evaluated.

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A Study on the CVD Deposition for SiC-TRISO Coated Fuel Material Fabrication (화학증착법을 이용한 삼중 코팅 핵연료 제조에 관한 연구)

  • Kim, Jun-Gyu;Kum, E-Sul;Choi, Doo-Jin;Kim, Sung-Soon;Lee, Hong-Lim;Lee, Young-Woo;Park, Ji-Yeon
    • Journal of the Korean Ceramic Society
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    • v.44 no.3 s.298
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    • pp.169-174
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    • 2007
  • TRISO coated fuel particle is one of the most important materials for hydrogen production using HTGR (high temperature gas cooled reactors). It is composed of three isotropic layers: inner pyrolytic carbon (IPyC), silicon carbide (SiC), outer pyrolytic carbon (OPyC) layers. In this study, TRISO coated fuel particle layers were deposited through CVD process in a horizontal hot wall deposition system. Also the computational simulations of input gas velocity, temperature profile and pressure in the reaction chamber were conducted with varying process variable (i.e temperature and input gas ratios). As deposition temperature increased, microstructure, chemical composition and growth behavior changed and deposition rate increased. The simulation showed that the change of reactant states affected growth rate at each position of the susceptor. The experimental results showed a close correlation with the simulation results.

Shape Control of Platinum Nanoparticles Using a Metal Salt (금속 염을 이용한 백금 나노입자의 형상제어)

  • Kwak, Seoung Yeul;Lee, Jin Ho;Kim, Jin Woo;Jung, Taek Kyun;Kim, Young Do
    • Journal of Powder Materials
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    • v.19 no.6
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    • pp.393-397
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    • 2012
  • $AgNO_3$ has the characteristic is controlling the inhibition or promotion of particle growth by adsorbing onto specific facets of platinum nanoparticles. Therefore, in this study, $AgNO_3$ was added to control the shape of platinum nanoparticles during the liquid phase reduction process. Consequently, platinum cubes were synthesized when $AgNO_3$ of 1.1 mol% (with respect to the Pt concentration) was added into the solution. Platinum octahedrons were synthesized when 32 mol% (with respect to the Pt concentration) was added into the solution. These results demonstrate that the metal salt $AgNO_3$, effectively controlled the relative growth rates of each facet of Pt nano particles.