• Polymer(Korea)
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• v.31 no.2
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• pp.168-176
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• 2007

The sub-micron particles of poly ($\gamma-glutamic$ acid) (PGA) containing lysozyme have been prepared using supercritical antisolvent (SAS) precipitation process at various experimental conditions such as pressure, temperature, inner diameter of nozzle, and concentration. As overall results of the application of SAS process to this system, the smaller size powder has been produced as (i) increasing pressure, (ii) decreasing temperature, (iii) decreasing the inner diameter of nozzle, and (iv) decreasing the concentration of PGA and lysozyme. It is found by means of FT-IR analysis that during SAS process, the composition has changed from the original composition of PGA : lysozyme=50 : 50 into PGA : lysozyme=33 : 67 at final product powder. It means that PGA has higher solubility for the mixed solvent of carbon dioxide and dimethyl sulfoxide (DMSO). Due to such difference of solubility, this particle forms the core-shell structure of which the core consists mainly of lysozyme. It is also found that the residual DMSO amount of $7.8\times10^{-3}wt%$ exists inside the powder.

• The Journal of Engineering Research
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• v.5 no.1
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• pp.73-87
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• 2004

The synthesis and crystallization of amorphous calcium carbonate($CaCO_3$.$nH_2 O$) obtained from gas-liquid reaction between aqueous solution of calcium hydroxide and carbon dioxide at 15~$50^{\circ}C$ are investigated by electrical conductometry, XRD and TEM. The results are as follows: The initial reaction products prior to the formation of precipitated calcium carbonate is amorphous calcium carbonate. The electrical conductivity values in the slurry are decreased during the formation of amorphous calcium carbonate which covers particle surface of calcium hydroxide and retard the dissolution of calcium hydroxide into the solution. that amorphous calcium carbonate is unstable in the aqueous solution and crystallizes finally to calcite by the through-solution reaction. While amorphous calcium carbonate crystallizes into chain-like calcite, the conductivity values are recovered rapidly and the apparent viscosity of slurry containing higher concentration of calcium hydroxide increase. At below pH 9.5, chain-like calcite separates into individual particles to form precipitated calcium carbonate. The formation and synthetic temperature range of amorphous calcium carbonate is most suitable a primary decreasing step(a-step) at $15^{\circ}C$ in the electrical conductometry.

• Journal of the Korean Wood Science and Technology
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• v.37 no.6
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• pp.546-555
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• 2009

To study an effective use of woods, three-ply hybrid laminated woods instead of crosslaminated woods which are composed of spruce in the face and three kinds of wood-based boards (MDF, PB, OSB) in the core were manufactured, and the effect of constitution elements for the core laminae on bending strength performances was investigated. Bending modulus of elasticity (MOE) of hybrid laminated woods had the highest values for the hybrid laminated wood types arranging OSB laminae in the core, and had the lowest values for those arranging MDF laminae in the core. These values were higher than those of various cross-laminated woods. The estimated bending MOEs of the hybrid laminated woods which were composed of perpendicular-direction lamina of spruce in the faces were similar to their measured values, regardless of wood-based boards in the core. However, those of the hybrid laminated woods which were composed of parallel-direction lamina of spruce in the faces had much higher values than those of their measured values, and it was necessary to revise the measured values. Bending modulus of rupture (MOR) of the hybird laminated woods had the highest value for those arranging OSB laminae in the core, and had the lowest values for those arranging PB laminae in the core unlike the bending MOE. By hybrid laminating, the anisotropy of bending strength performances was markedly decreased, and the differences of strength performances among wood-based boards were also considerably decreased.

• Journal of the Korean Wood Science and Technology
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• v.42 no.3
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• pp.309-317
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• 2014

Harvested wood products (HWP) are known as products from the tree such as sawn wood, plywood, particle board, structural lumber, wooden interior material, wooden furniture, and paper products. Because carbon is locked up in the HWP until eventual end-use of HWP, HWP played a role as the carbon storage which has the effect of stabilizing the concentration of carbon dioxide in the atmosphere. For these reasons, the suggestion that it must admit the carbon storage effect of HWP has been constantly raised. In 2011, the 17th session of the Conference of the Parties (COP) to the United Nations Framework Convention on Climate Change (UNFCCC) which was held in Durban, South Africa, assigned "Production Approach" which targets only the HWP producted by using round wood of domestic forestry as a official method for carbon accounting. Therefore, it is necessary that each country has to determine the half-life of wood in order to correspond to the discussions and negotiations between countries in the future and to develop an inventory of product-specific domestic wood. In this study, some countries' examples of the methods and conditions for determining half-life of HWP were investigated, and it was tried to derive the factor and methodology to determine half-life span of domestic HWP appropriately.

• Journal of the Korean Wood Science and Technology
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• v.36 no.3
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• pp.93-100
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• 2008

For investigation of adsoption properties of cadmium elimination by wood charcoal, $25m{\ell}$ aqueous cadmium solutions in various concentrations were treated with 0.2 g wood charcoal of Red Oak (Quercus mongolica) for 280 minutes. Almost 100% of cadmium elimination ratio was obtained in the solutions with initial concentration of 20 and 40 ppm in the treatment, whereas they were 75 and 50% in those of 80 and 160 ppm. In the effect of treatment time, the highest amount of cadmium ions was eliminated during the first ten minutes in each solution so that the elimination ratio of each case was over 70% of the maximum elimination value. From the analysis of adsorptive cadmium adsorption mechanism using the Langmuir adsorption isotherm, it was suggested that cadmium ion molecules were adsorbed at the active sites on the charcoal particle in form of one layer. The Gibbs free energy of the adsorption process was calculated in negative value for each solution. This means the adsorption processes are spontaneous which do not require the extra input energy.

• Journal of Korea Water Resources Association
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• v.44 no.1
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• pp.65-72
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• 2011

Natural streams meander, forming pools at the outer part of bend and riffles at the crossing. Pools are deep at a lower flow velocity, and riffles are shallow at a higher flow velocity. Attentions are being paid to pool-riffle sequences in meandering streams because pool-riffle sequences tend to increase biodiversity of the stream ecosystem. This study investigates the characteristics of distribution of bed sediment particles in the upstream reach of the Gap Stream, which is a tributary of the Geum River in Korea. The upstream part of the Gap Stream, the study reach, is a gravel-bed stream, showing a pool and three riffles due to meandering. The reach also includes pools at the upstream and downstream parts of the weir. The characteristics of bed sediment particles sampled at the wetland and in the side channel are studied, revealing that the median particle diameter in the riffle is about four times larger than that in the pool. In addition, flow simulations are carried out for ordinary discharge and design flood, and such parameters important to sediment transport as velocity, shear stress, dimensionless shear stress (or Shields number), and dimensionless shear velocity are provided to see the mobility of sediment particles in the pool-riffle sequence.

• Journal of Korea Water Resources Association
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• v.49 no.10
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• pp.887-901
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• 2016

Cohesive sediments form flocs through the flocculation process. The size and density of floc are variable whereas those of a fine sediment are always assumed to be constant. The settling velocity, one of main factors of sediment transport, is determined by size and density of particle. Therefore, the flocculation process plays an important role in transport of cohesive sediment. It is of great difficulty to directly measure the density of floc in the field due to technical limitation at present. It is a popular approach to estimate the density of floc by applying the fractal theory. The main assumption of fractal theory is the self-similarity. This study aims to examine the applicability of fractal theory to cohesive sediment in small rivers of Korea. Sampling sediment has been conducted in two different basins of Geum river and Yeongsan river. The results of settling experiments using commercial camera show that the sediment in Geum river basin follows the main concept of fractal theory whereas the sediment in Yeongsan river basin does not have a clear relationship between floc size and fractal dimension. It is known from this finding that the fractal theory is not easily applicable under the condition that the cohesive sediment includes the high content of organic matter.

• Journal of Korea Water Resources Association
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• v.50 no.3
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• pp.201-210
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• 2017

This study proposes a numerical model which is able to simulate turbidity currents intruding into a reservoir and resulting sediment depositions. The proposed model is applied to laboratory experiments by Toniolo and Schultz (2005), and propagation of turbidity currents, morphological change, and trap of suspended sediment are simulated. It is simulated that the turbidity current after plunging at the foreset of the model delta, propagates along the bottom. The thickness of the turbidity current increases significantly after being blocked by the dam, and this effect is propagated in the upstream direction. In addition, it is simulated that the foreset moves in the downstream direction due to both the bedload and suspended load and the thickness of the bottom set increases due to the suspended load. It is found that the height of the intake affects the thickness of the turbidity current and the location of the internal hydraulic jump. The impact of the height of the intake on the trap efficiency is not clear in the experimental results, however, overall trap efficiency is predicted quite successfully by the model. Also, sensitivity analysis is carried out, and the results indicates that the particle size affects the trap efficiency most.

• Korean Journal of Soil Science and Fertilizer
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• v.3 no.1
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• pp.61-66
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• 1970

This study examined the morphology and physical and chemical characteristics of the Changpyeong series developed on gently sloping to rolling relief on dissected old paddiplains and terraces. This soil has dark brown silty clay loam A horizons, very thick dark red to red silty clay or clay Bt horizons, and C horizons of old alluvial materials frequently with strongly weathered round cobbles and pebbles. It is strongly acid with a low organic matter content, relatively low in cation exchange capacity, but with relatively high base-status based on amount of extractable cations. There is no obvious changes in particle size distribution with depth and textural B horizons probably have not been formed by podzolization but formed by mechanical movement of clay. This soil is classified as Typic Hapludalfs in USDA 7th approximation and Brunic Luvisols in FAO classification system.

• Korean Journal of Soil Science and Fertilizer
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• v.38 no.5
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• pp.238-246
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• 2005

We conducted this investigation to observe competitive adsorption phenomena among the heavy metals onto the available sorption sites of soil particle surfaces in sandy clay loam and clay soil collected from Nonsan city, Chungnam and Yoosung, Daejeon in Korea, respectively. Polluted and contaminated soils can often contain more than one heavy metal species, resulting in competition for available sorption sites among heavy metals in soils due to complex competitive ion exchange and specific sorption mechanism. And the adsorption characteristics of the heavy metals were reported that the selectivity for the sorption sites was closely related with electropotential and electro negativity carried by the heavy metals. The heavy metals were treated as single, binary and ternary systems as bulk solution phase. Adsorption in multi-element system was different from single-element system as Cr, Pb and Cd. The adsorption isotherms showed the adsorption was increased with increasing equilibrium concentrations. For binary and ternary systems, the amount of adsorption at the same equilibrium concentration was influenced by the concentration of individual ionic species and valence carried by the respective heavy metal. Also we found that the adsorption isotherms of Cd and Pb selected in this experiment were closely related with electronegativity and ionic potential regardless number of heavy metals in solution, while the adsorption of Cr carried higher valance and lower electro negativity than Cd and Pb was higher than those of Cd and Pb, indicating that adsorption of Cr was influenced by ionic potential than by electronegativity. Therefore adsorption in multi-element system could be influenced by electronegativity and ionic potential and valance for the same valance metals and different valance, respectively. But it still needs further investigation with respect to ionic strength and activity in multi-element system to verify sorption characteristics and reaction processes of Cr, especially for ternary system in soils.