• Title/Summary/Keyword: Partial cavity

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Structure of Tetra-ter-butyl-tetrapropionyloxycalix[4]arene (Tetra-tert-butyl-tstrapropionyloxycalix [4] arene의 구조)

  • 김회진;노광현
    • Korean Journal of Crystallography
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    • v.4 no.1
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    • pp.25-35
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    • 1993
  • Tetra-tert-butyl-tetrapropionycalix (4) arena (C56H7208) is Triclinic, space group Pl, with a=13.664(5), b=17.585(5), c=12.863(2)A, a=109.33(2), B=111.97(2), γ=76.45(3) ˚, Z=2, V=2684.08A3, D, =1.152g/cm3, Dm=1.15g/cm3. The intensity data were collected on an Enraf-Nonius CAD-4 Diffractometer with a graphite monochromated Mo-Ka radiation. The structure was solved by direct methods and refined by leastsquares methods. The final R factor was 0.084 for 2561 observed reflections. The configuration of the molecule from the X-ray crystallographic investigation has the partial cone conformation, three tort-butylphenyls are down and a tort-butylphenyl is up. Three propionyloxy groups direct toward the exterior of the macrocycle cavity.

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Structure of Tetrapropionyloxycalix[4]arene (Tetrapropionyloxycalix[4]arene의 구조에 관한 연구)

  • 박영자;김현희
    • Korean Journal of Crystallography
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    • v.6 no.2
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    • pp.80-87
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    • 1995
  • The structure of Tetrapropionyloxycalix[4]arene(C40H40O8) has been studied by X-ray diffraction method. The crystal is monoclinic a=13.921(3), b=13.552(2), c=19.840(5)Å, β=110.38(2)°, Z=4 T=297K, Dc=1.23gcm-3, F(000)=1376, Systematic absences : hkl none, h0l : h+l=2n, 0k0: k=2n define space group P21/n. The structure was solved by direct method and refined by full-matrix least-squares methods to final R of 0.06 for 2514 observed reflections. The macrocycle exists in partial cone conformation. Three propionyl groups direct toward the exterior of the macrocycle cavity.

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A Study of Thermal and flow Characteristics Induced by Fire in a Partial Enclosure (부분밀폐공간내에서 화재로 야기되는 열 및 유동특성에 관한 연구)

  • 박희용;한철희;박경우
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.5
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    • pp.1288-1300
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    • 1994
  • Mathematical modeling and numerical calculation on the flow and thermal characteristics induced by fire in a partial enclosure are performed. The solution procedures include the Shvab-Zeldovich approximation for the physical transport equations, low Reynolds number k-.epsilon. model for the turbulent fluid flow and Discrete Ordinate method(DOM) to calculate the radiative heat transfer. PMMA(Polymethylmethacrylate) is adopted as a solid fuel. Two different cases are considered : combustions with and without gas radiation occuring in a open cavity for variable pyrolyzing location of PMMA. When the fire source is located at the left-wall, the flow region of flame gas is limited at the left-wall and ceiling and recirculation region of inlet gas is formulated at neat the floor. In case of neglecting the radiative heat transfer, more large flame size and higher temperature is predicted. It is essential to consider the radiative heat transfer for analysis of fire phenomenon.

Manufacturing of metal-framework for maxillary removable partial dentures using milling wax-blocks (Wax-block milling을 이용한 상악 가철성 국소의치 금속구조물 제작 증례)

  • Seo, A-Ra;Kwon, Soon-Suk
    • Journal of Technologic Dentistry
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    • v.44 no.1
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    • pp.24-30
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    • 2022
  • This research introduces the manufacturing process of the metal-framework of one of the maxillary partial dentures, the "obturator", using milling wax-blocks, for patients with palate loss due to oral cancer. It explains the protocol of taking the patient's oral impression, preparation of a working cast, scanning, designing using a computer-aided design program, investing the milling wax-blocks, and completing the obturator. This method does not follow the traditional wax and agar process thereby reducing the errors arising during the manufacturing process and decreasing the time, material, and labor required. Moreover, the retention, stability, and compatibility of the metal framework were observed to be high in both the working cast and oral cavity.

Prosthetic rehabilitation of partially edentulous patient after maxillectomy: A case report (상악골 부분절제술 시행한 부분 무치악 환자에서 폐쇄 장치를 이용한 보철 수복 증례)

  • Heo, Kyung-Hoi;Lim, Young-Jun;Kim, Myung-Joo;Kwon, Ho-Beom
    • The Journal of Korean Academy of Prosthodontics
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    • v.54 no.2
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    • pp.167-171
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    • 2016
  • Patients undergone partial maxillectomy experience post-operative masticatory, phonetic, and swallowing difficulties. They also encounter social and psychological challenges due to changes in their facial appearances. Thus, functional and esthetic recovery through maxillofacial prosthesis becomes significant for these patients. The objective of an appropriate obturator is to restore palate and improve phonetic and swallowing ability by separating the oral cavity, nasal cavity, maxillary sinus, and nasopharynx. In this case report, an obturator was fabricated for a patient who had partial resection from the maxillary posterior region to the pharynx due to squamous cell carcinoma. The purpose of this case study is to describe the results because the patient was successfully improved both functionally and esthetically.

Postoperative Phonetic Evaluation of Two Cases of Verrucous Carcinoma of the Larynx after Partial Laryngectomy with False Vocal Cord Advancement Flap (후두 우상암에서 후두 부분적출술 및 가성대 전진피판에 의한 성대 재건술 전후의 음성변화 : 2례)

  • 정성민;장주애;김윤정
    • Journal of the Korean Society of Laryngology, Phoniatrics and Logopedics
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    • v.9 no.1
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    • pp.86-90
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    • 1998
  • Verrucous carcinoma is a variant of highly differentiated squamous cell carcinoma and has a predilection for the oral cavity and larynx. It is known to be of good prognosis due to its low regional and distant metastatic potential. Peak incidence is at ages 40-69 while predominantly occuring in males and its association with tobacco smoking has been implicated. The verrucous carcinoma have accordingly been treated by radiotherapy or surgical procedures but there has been considerable controversy regarding the effect of radiotherapy due to the possibility of anaplastic transformation Laser surgery and partial resection are among the commonly used surgical procedures but laser surgery has not yet shown results in improving phonetic abilities. Authors experienced two cases of verrucous carcinoma of the larynx treated by partial laryngectomy and false vocal cord advancement flap who showed no recurrence of disease under stroboscopic examination after two year follow up and when compared to preoperative aerodynamic studies, the expiratory air pressure was decreased and mean air flow rate increased which improved glottal efficiency markedly.

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Intracavity frequency doubling of a single-mode Nd:YAG laser using a nonplanar ring cavity (비평면 고리형 공진기를 이용한 단일 모드 Nd:YAG 레이저의 내부 공진기 주파수 배가)

  • 박종락;윤태현
    • Korean Journal of Optics and Photonics
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    • v.14 no.1
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    • pp.85-91
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    • 2003
  • Intracavity frequency doubling of a single-mode Nd:YAG laser by using a nonplanar ring cavity is demonstrated. The nonplanar ring cavity consists of a Brewster-angled Nd:YAG crystal placed in a magnetic field, a KTP crystal, and two spherical mirrors. In this design the Nd:YAG block acts as both a nonreciprocal polarization rotator and a partial polarizer, and the nonplanar portion of the ring cavity, which is formed by a relative twist angle between the Brewster-angled end surfaces of the Nd:YAG block, serves as a reciprocal polarization rotator. An eigenpolarization theory for the cavity configuration is presented and suitable values of the relative twist angle for unidirectional operation are estimated. A single-mode output power of 22 ㎽ at 532 nm and an optical to optical conversion efficiency of 1.8% are obtained with a 1.2 W diode laser at 809 nm.

Numerical Analysis of Axisymmetric Supercavitating Underwater Vehicle with the Variation of Shape Parameters (축대칭 수중 운동체의 형상 변화를 고려한 초월공동 수치해석)

  • Park, Hyun-Ji;Kim, Ji-Hye;Ahn, Byoung-Kwon
    • Journal of the Society of Naval Architects of Korea
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    • v.55 no.6
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    • pp.482-489
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    • 2018
  • Most of the numerical and experimental studies on supercavitating flows are focused on the cavitator only. However, the partial cavity growing into the supercavity is affected by the shape of the body placed behind the cavitator. In this paper, we develope a numerical method which is based on the boundary element method to predict supercavitating flow around three-dimensional axisymmetric bodies. We estimate the influence of the body shape on the supercavity growth. Here, we consider various parameters of the body such as cavitator shape, shoulder length and body diameter, and compare the results with the case of the cavitator only. In summary, it is found that the body may impede the cavity growth, the shoulder mainly affects the cavity length, and the supercavity occurring in the cone type cavitator is strongly influenced rather than that of the disk type cavitator.

Analysis of Flow Field in Cavity Using Finite Analytic Method (F.A.M.을 이용한 공동 내부의 유동해석)

  • 박명규;정정환;김동진
    • Journal of Advanced Marine Engineering and Technology
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    • v.15 no.4
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    • pp.46-53
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    • 1991
  • In the present study, Navier-Stokes equation is numerically solved by use of a Finite analytic method to obtain the 2-dimensional flow field in the square cavity. The basic idea of F.A.M. is the incorporation of local analytic solutions in the numerical solution of linear or non-linear partial differential equations. In the F.A.M., the total problem is subdivided into a number of all elements. The local analytic solution is obtained for the small element in which the governing equation, if non-linear, to be linearized. The local analytic solutions are then expressed in algebraic form and are overlapped to cover the entire region of the problem. The assembly of these local analytic solutions, which still preserve the overall nonlinearity of the governing equations, results in a system of linear algebraic equations. The system of algebraic equations is then solved to provide the numerical solutions of the total problem. The computed flow field shows the same characteristics to physical concept of flow phenomena.

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Elastic Wave Resonance Scattering from a Fluid-filled Cylindrical Cavity (유체가 채워진 실린더형 공동에 의한 탄성파 공명 산란 해석)

  • Huinam Rhee;Park, Youngjin
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2002.05a
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    • pp.208-213
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    • 2002
  • A new method is presented for the isolation of resonances from scattered waves for elastic wave resonance scattering problems. The resonance scattering function consisting purely of resonance information is defined. Elastic wave resonance scattering from a water-filled cylindrical cavity imbedded in an aluminum matrix is numerically analyzed. The classical resonance scattering theory and the new method compute different magnitudes and phases of the resonances from each partial wave, and therefore. their total resonance spectra are quite different. The exact $\pi$ - radians phase shifts through the resonance and anti-resonance frequencies show that the proposed method properly extracts the vibrational resonance information of the scatterer compared to resonance scattering theory.

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