• Title/Summary/Keyword: Parameters Optimization

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Effects of Precursor Concentration and Current on Properties of ZnO Nanorod Grown by Electrodeposition Method (전착법으로 성장된 산화아연 나노막대의 특성에 전구체 농도 및 전착 전류가 미치는 효과)

  • Park, Youngbin;Nam, Giwoong;Park, Seonhee;Moon, Jiyun;Kim, Dongwan;Kang, Hae Ri;Kim, Haeun;Lee, Wookbin;Leem, Jae-Young
    • Journal of the Korean institute of surface engineering
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    • v.47 no.4
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    • pp.198-203
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    • 2014
  • ZnO nanorods have been deposited on ITO glass by electrodeposition method. The optimization of two process parameters (precursor concentration and current) has been studied in order to control the orientation, morphology, and optical property of the ZnO nanorods. The structural and optical properties of ZnO nanorods were systematically investigated by using field-emission scanning electron microscopy, X-ray diffractometer, and photoluminescence. Commonly, the results show that ZnO nanorods with a hexagonal form and wurtzite crystal structure have a c-axis orientation and higher intensity for the ZnO (002) diffraction peaks. Both high precursor concentration and high electrodeposition current cause the increase in nanorods diameter and coverage ratio. ZnO nanorods show a strong UV (3.28 eV) and a weak visible (1.9 ~ 2.4 eV) bands.

Reservoir Management in Flood Period with Chance Constrained LP (위험도제약(危險度制約) 선형계획법(線形計劃法)에 위한 홍수기(洪水期) 저수지운영(貯水池運營))

  • Lee, Kil Seong;Kang, Bu Sik
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.12 no.3
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    • pp.139-151
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    • 1992
  • A reservoir operation model was established under the varying restricted water level(r.w.l.) subject to the inflow distributions in flood period. The optimization model consists of 2 sub-models. One model minimizes deviations of releases from the expected release and the other minimizes capacity requirement for flood control. In order to make deterministic equivalents, the inflow distribution of reservoir is assumed to be 2-parameter Lognormal, and its parameters are estimated by the maximum likelihood method. The model is applied to joint operation of Soyang and Chungju dam. The results show that Soyang was designed for larger flood event than that for Chungju. The operation under the varying r.w.l. turns out to be more effective than one under the uniform r.w.l. Such effect is more obvious at Chungju compared with Soyang. Release pattern shows diminishing and delaying effect in a period of high inflows and larger discharges than actual in a period of low inflows.

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Evaluation of the Applicability of the Poisson Cluster Rainfall Generation Model for Modeling Extreme Hydrological Events (극한수문사상의 모의를 위한 포아송 클러스터 강우생성모형의 적용성 평가)

  • Kim, Dong-Kyun;Kwon, Hyun-Han;Hwang, Seok Hwan;Kim, Tae-Woong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.34 no.3
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    • pp.773-784
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    • 2014
  • This study evaluated the applicability of the Modified Bartlett-Lewis Rectangular Pulse (MBLRP) rainfall generation model for modeling extreme rainfalls and floods in Korean Peninsula. Firstly, using the ISPSO (Isolated Species Particle Swarm Optimization) method, the parameters of the MBLRP model were estimated at the 61 ASOS (Automatic Surface Observation System) rain gauges located across Korean Peninsula. Then, the synthetic rainfall time series with the length of 100 years were generated using the MBLRP model for each of the rain gauges. Finally, design rainfalls and design floods with various recurrence intervals were estimated based on the generated synthetic rainfall time series, which were compared to the values based on the observed rainfall time series. The results of the comparison indicate that the design rainfalls based on the synthetic rainfall time series were smaller than the ones based on the observation by 20% to 42%. The amount of underestimation increased with the increase of return period. In case of the design floods, the degree of underestimation was 31% to 50%, which increases along with the return period of flood and the curve number of basin.

Nonlinear correlation analysis between air and water temperatures in the coastal zone, Korea (우리나라 연안 기온과 수온의 비선형 상관관계 분석)

  • Lee, Khil-Ha
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.19 no.2
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    • pp.128-135
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    • 2007
  • In response to anthropogenic global warming due to a buildup greenhouse gas, the effect of the air temperature on water temperature has been noticed. Therefore, effects have been made to build an air/water temperature relationship at three study regions using the data collected by the Ministry of the Maritime Affairs and Fisheries (MOMAF). The air/water relationship varies with time-scale and weekly time-scale was chosen for the study. The data were fitted to the S-shaped non-linear relationship, and the parameters for the S-curve were derived using a single-criteria multi-parameter optimization scheme. Separate regression curves were fitted to consider seasonal hysteresis at the Masan site. The study results support the S-shaped non-linear relationship is the best fit for the air/water relationship at the Korean coastal zone. This study will contribute to determine the future policy regarding water quality and ecosystem for the decision-driving organization.

An Experimental and Modeling Study on the Oxidation Kinetics of Nitric Oxide over Platinum-based Catalysts (백금계 촉매상에서 산화질소(NO)의 산화반응속도에 관한 실험 및 모델링 연구)

  • Kim, Young-Deuk;Jeong, Soo-Jin;Kim, Woo-Seung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.5
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    • pp.71-80
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    • 2012
  • To improve the $NO_X$ conversion over a SCR (selective catalytic reduction) catalyst, the DOC (diesel oxidation catalyst) is usually placed upstream of the SCR catalyst to enhance the fast SCR reaction ($4NH_3+2NO+2NO_2{\rightarrow}4N_2+6H_2O$) using equimolar amounts of NO and $NO_2$. Here, a ratio of $NO_2/NO_X$ above 50% should be avoided, because the reaction with $NO_2$ only ($4NH_3+4NO+O_2{\rightarrow}4N_2+6H_2O$) is slower than the standard SCR reaction ($4NH_3+4NO+O_2{\rightarrow}4N_2+6H_2O$). In order to accurately predict the performance characteristics of SCR catalysts, it is therefore desired to develop a more simple and reliable mathematical and kinetic models on the oxidation kinetics of nitric oxide over a DOC. In the present work, the prediction accuracy and limit of three different chemical reaction kinetics models are presented to describe the chemicophysical characteristics and conversion performance of DOCs. Steady-state experiments with DOCs mounted on a light-duty four-cylinder 2.0-L turbocharged diesel engine then are performed, using an engine-dynamometer system to calibrate the kinetic parameters such as activation energies and preexponential factors of heterogeneous reactions. The reaction kinetics for NO oxidation over Pt-based catalysts is determined in conjunction with a transient one-dimensional (1D) heterogeneous plug flow reactor (PFR) model with diesel exhaust gas temperatures in the range of 115~$525^{\circ}C$ and space velocities in the range of $(0.4{\sim}6.5){\times}10^5\;h^{-1}$.

A Parametric Study on Optimal Earth-Moon Transfer Trajectory Design Using Mixed Impulsive and Continuous Thrust (혼합 추력 방식의 지구-달 최적 전이궤적 설계인자에 따른 비교연구)

  • Lee, Dae-Ro;No, Tae-Soo;Lee, Ji-Marn;Jeon, Gyeong-Eon
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.39 no.11
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    • pp.1021-1032
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    • 2011
  • This paper presents the results of a parametric study for the design of optimal Earth-Moon transfer trajectory using mixed impulsive and continuous thrust. Various types of the optimal Earth-Moon transfer trajectories were designed by adjusting the relative weight between the impulsive and the continuous thrust, and flight time. Two very different transfer trajectories can be obtained by different combination of design parameters. Furthermore, it was found that all thus designed trajectories permit the ballistic capture by the Moon gravity. Finally, the required thrust profiles are presented and analyzed in detail.

Experimental Study of a Recuperator with Offset Strip Fins (오프셋 스트립 휜을 가지는 리큐퍼레이터에 대한 실험적 연구)

  • Kim, Taehoon;Do, Kyu Hyung;Han, Yong-Shik;Choi, Byung-Il;Kim, Myungbae
    • Journal of Energy Engineering
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    • v.24 no.2
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    • pp.72-78
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    • 2015
  • In the present study, a recuperator to improve the thermal efficiency of a micro gas turbine is considered. The counter flow plate-fin heat exchanger with offset strip fins is chosen as the type of the recuperator. From the optimization study as varying design parameters of the recuperator determined from the ideal cycle analysis, the internal structure of the recuperator is determined. The recuperator is made from stainless steel 304. In order to evaluate performance of the recuperator, experimental investigation is performed. The effects of inlet temperature of hot-side of the recuperator on the thermal performance of the recuperator are investigated. As a result, effectiveness of the recuperator obtained from the experiments is well consistent with that obtained from the correlations.

Optimization of Bioreactor Operation by Mass Transfer Coefficient (물질전달계수를 이용한 생물 반응기 운전 최적화)

  • Kim, Hyung-Soon
    • Journal of the Korean Society of Industry Convergence
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    • v.4 no.3
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    • pp.243-251
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    • 2001
  • The effects of various operating parameters(agitation speed, impeller type, antiform agents, impeller spacing etc.) on air-liquid mass transfer was characterized by volumetric mass transfer coefficient($k_La$). Also, the dual-impeller agitated systems are compared with single-impeller agitated systems with a special focus on its applications for bioreactors, $k_La$ was take over a range of 200~450 rpm of agitation speed, and 0.5~2.5 vvm of air flow rates, for four single impeller and impeller combinations consisting of four impeller types, namely rushton, pitched blade, scaba, intermig were tested. The rushton impeller showed the best $k_La$ as compared with other single impellers. The dual impeller system are found to be superior as compared to single impeller in all aspects, The best combination of the dual impeller was a intermig of axial flow type as an upper impeller and a rushton of radial flow type as a lower part. Also, the control of the DO level with the variation of agitation speed was more efficient than that with an increase in air flow rate. The addition of antiform dropped the $k_La$ very large up to 1g/L regardless the type. PPG was less effect on $k_La$ than other antiforms. The impeller spacing and presence of solute are found very effective on $k_La$. When the $NaNO_3$is presented as solute, the $k_La$ increased approximately 50% then control.

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Unified Model for Performance Analysis of IEEE 802.11 Ad Hoc Networks in Unsaturated Conditions

  • Xu, Changchun;Gao, Jingdong;Xu, Yanyi;He, Jianhua
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.6 no.2
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    • pp.683-701
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    • 2012
  • IEEE 802.11 standard has achieved huge success in the past decade and is still under development to provide higher physical data rate and better quality of service (QoS). An important problem for the development and optimization of IEEE 802.11 networks is the modeling of the MAC layer channel access protocol. Although there are already many theoretic analysis for the 802.11 MAC protocol in the literature, most of the models focus on the saturated traffic and assume infinite buffer at the MAC layer. In this paper we develop a unified analytical model for IEEE 802.11 MAC protocol in ad hoc networks. The impacts of channel access parameters, traffic rate and buffer size at the MAC layer are modeled with the assistance of a generalized Markov chain and an M/G/1/K queue model. The performance of throughput, packet delivery delay and dropping probability can be achieved. Extensive simulations show the analytical model is highly accurate. From the analytical model it is shown that for practical buffer configuration (e.g. buffer size larger than one), we can maximize the total throughput and reduce the packet blocking probability (due to limited buffer size) and the average queuing delay to zero by effectively controlling the offered load. The average MAC layer service delay as well as its standard deviation, is also much lower than that in saturated conditions and has an upper bound. It is also observed that the optimal load is very close to the maximum achievable throughput regardless of the number of stations or buffer size. Moreover, the model is scalable for performance analysis of 802.11e in unsaturated conditions and 802.11 ad hoc networks with heterogenous traffic flows.

Development of a Burnt Beef Flavor by Reaction Flavor Technology (Reaction flavor 기술을 이용한 구운 쇠고기향 개발)

  • Kim, Ki-Won;Baek, Hyung-Hee
    • Korean Journal of Food Science and Technology
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    • v.35 no.6
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    • pp.1045-1052
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    • 2003
  • To develop a burnt beef flavor by reaction flavor technology, hydrolyzed vegetable protein (HVP) was reacted with precursors. Ribose, cysteine, furaneol, thiamin, methionine, garlic powder, and phospholipid were selected as suitable precursors for producing a burnt beef flavor. HVP and the selected precursors were reacted in a high pressure reactor to optimize reaction parameters, such as temperature, time, and water content. Optimum reaction conditions were $130^{\circ}C$, 1 hr, and 7.5% water addition. A burnt beef flavor was generated without pH adjustment. On the basis of an omission test, cysteine, furaneol, thiamin, and garlic powder were evaluated for optimization using response surface methodology. The optimum composition of precursore was determined to be 7.7% cysteine, 7.3% furaneol, 2.1% thiamin, and 6.9% garlic powder. Based on these results, optimum reaction conditions for the production of a burnt beef flavor from HVP were 5% ribose, 5% methionine, 5% phospholipid, 7.7% cysteine, 7.3% furaneol, 2.1% thiamin, 6.9% garlic powder, 7.5% water addition, $130^{\circ}C$ reaction temperature, and 1hr reaction time.