• Applied Biological Chemistry
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• v.34 no.3
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• pp.287-294
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• 1991

The relationships between the quantitative structure of benzotriazoles and their post-emergence growth inhibiting activity$(pI_{50})$ against Oryzae sativa L. and Echinochloa crus-galli were investigated using a generalized quantitative structure activity relationships (QSAR). According to the QSAR analysis, the free radical parameter $(E_R)$ is a very important factor and the growth inhibiting activity values showed parabolic relation to $E_R$ parameter of para-substituents(X). The activity of (3) was superior to those of (4) and (3b) is selected as the most highly effective compound. The optimal values of $E_R$ parameter of the growth inhibiting activity aganist E.crus-galli are $E_R(3)=0.52\;and\;E_R(4)=0.15$, respectively. From the result of molecular design, the substituents(X) of electron withdrawing properties and $E_R$ parameter of optimal value(0.52) were most desirable for high activity of the benzotriazoles. And in view of this, benzotriazoles may also be effective in blocking the photosynthetic electron transfer.

• The Korean Journal of Ceramics
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• v.2 no.1
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• pp.19-24
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• 1996

The phase distribution and interface chemistry by the solid-state reaction between SiC and nickel were studied at temperatures between $550 \;and\; 1250^{\circ}C$ for 0.5-100 h. The reaction with the formation of silicides and carbon was first observed above $650^{\circ}C$. At $750^{\circ}C$, as the reaction proceeded, the initially, formed $Ni_3Si_2$ layer was converted to $Ni_2$Si. The thin nickel film reacted completely with SiC after annealing at $950^{\circ}C$ for 2 h. The thermodynamically stable $Ni_2$Si is the only obsrved silicide in the reaction zone up to $1050^{\circ}C$. The formation of $Ni_2$Si layers with carbon precipitates alternated periodically with the carbon free layers. At temperatures between $950^{\circ}C$ and $1050^{\circ}C$, the typical layer sequences in the reaction zone is determined by quantitative microanalysis to be $SiC/Ni_2$$Si+C/Ni_2$$Si/Ni_2$$Si+C/…Ni_2$Si/Ni(Si)/Ni. The mechanism of the periodic band structure formation with the carbon precipitation behaviour was discussed in terms of reaction kinetics and thermodynamic considerations. The reaction kinetics is proposed to estimate the effective reaction constant from the parabolic growth of the reaction zone.

• Applied Chemistry for Engineering
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• v.27 no.3
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• pp.335-341
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• 2016

In this study, impurity effects on diffusive-convection flow fields by physical vapor transport under terrestrial and microgravity conditions were numerically analyzed for the mixture of $Hg_2Cl_2-I_2$ system. The numerical analysis provides the essence of diffusive-convection flow as well as heat and mass transfer in the vapor phase during the physical vapor transport through velocity vector flow fields, streamlines, temperature, and concentration profiles. The total molar fluxes at the crystal regions were found to be much more sensitive to both the gravitational acceleration and the partial pressure of component $I_2$ as an impurity. Our results showed that the solutal effect tended to stabilize the diffusive-convection flow with increasing the partial pressure of component $I_2$. Under microgravity conditions below $10^{-3}g_0$, the flow fields showed a one-dimensional parabolic flow structure indicating a diffusion-dominant mode. In other words, at the gravitational levels less than $10^{-3}g_0$, the effects of convection would be negligible.

• Journal of Powder Materials
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• v.24 no.4
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• pp.292-297
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• 2017

A metallic oxide layer of a heat-resistant element contributes to the high-temperature oxidation resistance by delaying the oxidation and has a positive effect on the increase in electrical resistivity. In this study, green compacts of Fecralloy powder mixed with amorphous and crystalline silica are oxidized at $950^{\circ}C$ for up to 210 h in order to evaluate the effect of metal oxide on the oxidation and electrical resistivity. The weight change ratio increases as per a parabolic law, and the increase is larger than that observed for Fecralloy owing to the formation of Fe-Si, Fe-Cr composite oxide, and $Al_2O_3$ upon the addition of Si oxide. Si oxides promote the formation of $Al_2O_3$ and Cr oxide at the grain boundary, and obstruct neck formation and the growth of Fecralloy particles to ensure stable electrical resistivity.

• Earthquakes and Structures
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• v.26 no.3
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• pp.239-249
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• 2024

A new layered shear continuum model box was developed to address the dynamic response issues of buried oil and gas pipelines under multi-point excitation. Vibration table tests were conducted to investigate the seismic response of buried pipelines and the surrounding soil under longitudinal multi-point excitation. A nonlinear model of the pipeline-soil interaction was established using ABAQUS finite element software for simulation and analysis. The seismic response characteristics of the pipeline and soil under longitudinal multi-point excitation were clarified through vibration table tests and simulation. The results showed good consistency between the simulation and tests. The acceleration of the soil and pipeline exhibited amplification effects at loading levels of 0.1 g and 0.2 g, which significantly reduced at loading levels of 0.4 g and 0.62 g. The peak acceleration increased with increasing loading levels, and the peak frequency was in the low-frequency range of 0 Hz to 10 Hz. The amplitude in the frequency range of 10 Hz to 50 Hz showed a significant decreasing trend. The displacement peak curve of the soil increased with the loading level, and the nonlinearity of the soil resulted in a slower growth rate of displacement. The strain curve of the pipeline exhibited a parabolic shape, with the strain in the middle of the pipeline about 3 to 3.5 times larger than that on both sides. This study provides an effective theoretical basis and test basis for improving the seismic resistance of buried oil and gas pipelines.

• Horticultural Science & Technology
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• v.28 no.5
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• pp.768-776
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• 2010

This study was conducted to predict number and fresh weight of leaves, and total leaf area of a single-stemmed rose 'Vital' based on the accumulated thermal units, and to develop a model of shoot development for the prediction of the time when the flowering shoot reaches a phenological stage in a plant factory system. The base temperature ($T_b$), optimum temperature ($T_{opt}$), and maximum temperature ($T_{max}$) were estimated by regressing the rate of shoot development against the temperature gradient. The rate of shoot development ($R$, $d^{-1}$) for the phase from cutting to bud break (CT-BB) was best described by a linear model $R_b$ ($d^{-1}$) = -0.0089 + $0.0016{\cdot}temp$. The rate of shoot development for the phase from bud break to harvest (BB-HV) was fitted to the parabolic model $R_h$ ($d^{-1}$) = $-0.0001{\cdot}temp^2$ + $0.0054{\cdot}temp$ - 0.0484. The $T_b$, $T_{opt}$, and $T_{max}$ values were 5.56, 27.0, and $42.7^{\circ}C$, respectively. The $T_b$ value was used in the thermal unit computations for the shoot development. Number of leaves, leaf area (LA), and leaf fresh weight showed sigmoidal curves regardless of the cut time. The shoot development and leaf area model was described as a sigmoidal function using thermal units. Leaf area was described as LA = 578.7 $[1+(thermal units/956.1)^{-8.54}]^{-1}$. Estimated and observed shoot length and leaf fresh weight showed a reasonably good fit with 1.060 ($R^2=0.976^{***}$) and 1.043 ($R^2=0.955^{***}$), respectively. The average thermal units required from cutting to transplant and from transplant to harvest stages were $426{\pm}42^{\circ}C{\cdot}d$ and $783{\pm}24^{\circ}C{\cdot}d$, respectively.

• Applied Biological Chemistry
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• v.33 no.3
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• pp.231-238
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• 1990

The structure-antifungal activity correlations between the structure of fourteen new 1-(phenoxymethyl)benzotriazoles (I) (Y=0), 1-(thiophenoxymethyl)benzotriazoles (ll) (Y=S) and 1-(azidomethyl)benzotriazole (III) derivatives were synthesized, and their activity, fifty percent inhibition of mycelial growth($pI_{50}$), in vitro against Pyricularia oryzae, Fusarium axysporum f.sp sesami, Valsa ceratosperma and Botrytis cinerea were investigated using a generalized QSAR method. The activity of (I) was superior In those of (II) and (III). The effect of the substituents (X) on the phenoxy group (I) was rationalized by a parabolic function of electronic (${\sigma}$), steric ($B_1$) and hydrophobic parameter(${\pi}$), and hydrogen bonding (HB). Where the optimal values of substituent on the fungicidal activity againt P. oryzae and F. axysporum f.sp.sesami are $B_1=1.40A;(H)$ and ${\pi}=0.07{\sim}0.15;(H)$, and those of substituent on the fungicidal activity against V. ceratosperma and B. cinerea are ${\sigma}=0.23{\sim}0.28;\;(C1),\;{\pi}=0.70;$ (C1), respectively. The most effective compound ( I a) and ( I d) were examined in this study.

• Journal of the Korean Applied Science and Technology
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• v.38 no.4
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• pp.1003-1009
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• 2021

A study on the associative properties of sodium hyaluronate (NaHA) and Alkane-bis (dimethylalkylammonium bromide) surfactants in aqueous solution was investigated in relation to the chemical structure of surfactants. As a result of measuring the interfacial tension, a parabolic graph showing the minimum value (c_min) at a specific concentration was shown. Above this minimum concentration the increase in interfacial tension is thought to be related to the formation of aggregates of NaHA chains and dimeric surfactants. The plot of viscosity vs surfactant concentration shows a slight maxium at c_min and a viscosity decrease at high surfactant concentrations. Viscosity nonlinear behavior is related to the size increase due to the complex growth and to the size shrinkage following from the interaction with electrolyte ions and free micelles. The results of surface tension measurements show a broad region of surface tension decrease, indicating the NaHA-surfactant interaction. The increase in surface tension above c_min may be related to the adsorption of clusters, consisting of free NaHA chains and dimeric surfactant. The strong adsorption of surfactant is observed at high concentrations.