• International Journal of Aeronautical and Space Sciences
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• 제2권1호
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• pp.12-19
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• 2001

Study of turbulent mixing layers has been a popular subject from the point of view of both practical application and phenomenological importance in engineering field. Turbulent mixing layers can be applied in many fields where rapid transition to turbulence is desirable in order to prevent boundary layer separation or to enhance mixing. The ability to control mixing, structure and growth of the shear flow would obviously have a considerable impact on many engineering applications. In addition to practical applications, free shear flows are one of the simplest flows to understand the fundamental mechanism in the transition process to turbulence. After the discovery of large-scale vortical structure in free shear flows many researchers have investigated the physical mechanism of generation and dissipation processes of the vortical structure. This study investigated the role of the large-scale vortical structures in the turbulent mixing layer using LES(Large-Eddy Simulation). The result shows that the pairing interaction of the vortical structure plays an important role in the growth rate of a mixing layer. It is found that the turbulence quantities depend strongly on the velocity ratio. It is also found that the vorticity in the high-velocity-side can extract energy from the mean flow, while the vorticity in the low-velocity-side lose energy by the viscous dissipation. Finally the results suggest the guideline to obtain the desired flow by control of the velocity ratio.

• Bulletin of the Korean Chemical Society
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• 제7권1호
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• pp.1-5
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• 1986

The influences of $LiNO_3\;and\;AgNO_3$ on the N-C(O) rotational barrier of N,N-dimethylacetamide and N,N-dimethylpropionamide have been investigated. The rotational activation free energy $({\Delta}G^{\neq})\;for\;Li^{+}$-amide complexes is found to increase with increasing salt concentration. On the other hand, that for $Ag^+$-amide complexes increases in the presence of $Ag^+$ ion up to 0.25 M ion concentration and then decreases as the concentration of $Ag^+$ ion is further increased. Such an unusual behavior of $Ag^+$-amide complexes has been interpreted in terms of ion-pairing and diluent effect on the amides. However, $^{13}C$ nmr chemical shift data for the amides have shown that both of these ions interact primarily with the carbonyl group in amides.

• IEIE Transactions on Smart Processing and Computing
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• 제2권3호
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• pp.168-175
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• 2013

Key escrow is a default property that is inherent in identity-based cryptography, where a curious private key generator (PKG) can derive a secret value shared by communicating entities in its domain. Therefore, a dishonest PKG can encrypt and decrypt ciphers or can carry out any attack on the communicating parties. Of course, the escrow property is not completely unwanted but is acceptable in other particular applications. On the other hand, in more civil applications, this key escrow property is undesirable and needs to be removed to provide maximum communication privacy. Therefore, this paper presents an escrow-free identity-based key agreement protocol that is also applicable even in a distinct PKG condition that does not use pairings. The proposed protocol has comparable computational and communicational performance to many other protocols with similar security attributes, of which their security is based on costly bilinear pairings. The protocol's notion was inspired by McCullagh et al. and Chen-Kudla, in regard to escrow-free and multi-PKG key agreement ideas. In particular, the scheme captures perfect forward secrecy and key compromise impersonation resilience, which were lacking in McCullagh et al.'s study, as well as all other desirable security attributes, such as known key secrecy, unknown key-share resilience and no-key control. The merit in the proposed protocol is the achievement of all required security requirements with a relatively lower computational overhead than many other protocols because it precludes pairings.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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• pp.213.1-213.1
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• 2015

Field effect transistors (FETs)를 기반으로 한 바이오센서는 빠른 응답속도, 저비용, label-free 등을 이유로 각광받고 있다. 그러나 3D 구조를 기반으로 한 FETs 바이오센서의 낮은 sensitivity의 한계점을 지니며, 이를 극복하기 위해 1D 구조의 나노튜브 등을 활용하였으나 여전히 높은 sensitivity의 확보는 힘들다. 최근에는 이러한 문제점을 극복하기 위해 이차원 반도체 물질 중 하나인 Transition metal dichalcogenide (TMD)를 이용하여, 700 이상의 sensitivity를 지니는 pH센서 및 100 이상의 sensitivity를 지니는 바이오센서가 보고되었다. 하지만 이보다 더 높은 정확성 및 반응성을 높이기 위한 연구는 부족한 실정이다. 우리는 DNA 템플릿을 이용하여, TMD FET 기반 pH 및 바이오센서의 반응성을 극대화시키는 연구를 선보인다. DNA는 7~8정도의 유전상수 (K)를 가지는 물질로 기존 $SiO_2$(K=3.9)보다 높은 유전상수를 가지며 두께를 0.7 nm로 매우 얇게 형성할 수 있는 장점이 있다. 이는 FET 기반 바이오센서의 표면 캐패시턴스를 높여 sensitivity를 극대화할 수 있으며, 기존에 사용된 high-k 기반 바이오센서와 비교하여도 약 10배 이상의 sensitivity 향상을 노릴 수 있다. 또한, TMD 물질로 우리는 $WSe_2$를 선택하였으며, pH 용액의 receptor로써 우리는 3-Aminopropyltriethoxysilane (APTES)를 활용하였고, 템플릿으로 사용된 DNA는 DX tile 및 Ring type의 두 가지를 사용하였다. 추가로, DNA의 phosphate backbone을 중성화시키고 DNA의 base pairing의 charge 안정화를 위해 구리 이온($Cu^{2+}$) 및 란타넘족($Tb^{3+}$)을 추가하였다. 완성된 바이오센서의 pH 센싱을 위해 우리는 pH 6,7,8의 표준 용액을 사용하였으며, 재현성 및 반복성의 확인하였다.

• 대한기계학회논문집B
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• 제24권3호
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• pp.373-381
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• 2000

The flow and heat transfer characteristics on the impingement surface can be controlled by the change of vortex with the acoustic excitation, because the flow characteristics of an impinging jet are affected strongly by the vortices formed at the jet exit. To investigate the effects of acoustic excitation, we measured the velocity, turbulent intensity distributions for the free jet and local heat transfer coefficients on a impingement surface. As the acoustic excitation, subharmonic frequency of excited frequency plays an important role to the control of the jet flow. If the vortex pairings are promoted by the acoustic excitation, turbulence intensity of the jet flow is increased quickly. On the other hand if the vortex pairings are suppressed, the jet flow has low turbulence intensity at the center of the jet. Therefore, the low heat transfer rates are obtained on the impingement plate for a small nozzle-to-plate distance. However, it has high heat transfer rates at a large distance between the nozzle and plate due to the increasing of potential-core length.

• 대한기계학회논문집B
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• 제27권6호
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• pp.693-700
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• 2003

The effect of the configuration of the nozzle and the impinging surface on the characteristics of the hole-tones has been experimentally investigated. It is found that the plate-tone is a special case of hole-tones, where the hole diameter is zero. The jet velocity range for hole-tones is divided into the low velocity region associated with laminar jet and the high velocity region with turbulent jet. The frequency of the tone is that for the shear layer instability at the nozzle exit or that attainable by a cascade of vortex pairing process with increase of the impinging distance. When the distance is longer than one diameter the frequency decreases to the terminal value near the preferred frequency of the column mode instability, in the range 0.23< $St_d$<0.53, where $St_d$ is the Strouhal number defined by $fd/U_J$, f the frequency, d the nozzle diameter, and $U_J$ the exit velocity. While the convection speed of the downstream vortex, in the present study, is almost constant at low-speed laminar jet, it increases with distance at high-speed turbulent jet. As the frequency increases, the convection speed decreases in the low frequency range corresponding to the preferred mode, in agreement with the existing experimental data for a free jet.

• Archives of Pharmacal Research
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• 제19권5호
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• pp.396-399
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• 1996

High-performance liquid chromatographic method with UV detecction was developed for the determination of theophylline and its metabolites in human urine using ${beta}$-hydroxyethyl theophylline$({beta} -HET)$ as an internal standard. For extraction of urine sample, quality control sample and xanthine-free blank urine were mixed with decylamine (ion-paring reagent) and ${beta}$-HET. After saturation with ammonium sulfate, the mixture was then extracted with organic solvent at pH values of 4.0-4.5. All separations were performed with ion-pair chromatography using decylamine as an ion-pairing reagent and 3mM sodium acetate buffered mobile phase (pH 4.0) containing 1% (v/v) acetonitrile and 0.75 mM decylamine. The detection limits of theophylline, 1, 3-DMU, 1-MU, 3-MX and 1-MX in human urine were 0.17, 0.17, 0.39, 0.19 and 0.19 ${\mu}g$/ml, based on a signal-to-noise ratios of 3.0. The mean intraday coefficients of variation (C.V.s) of each compound on nine replicates were lower than 2.0%, while mean interday C.V.s on three days were lower than 1.6%. All separations were finished within 40miutes.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 1997년도 제9회 학술강연회논문집
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• pp.8-9
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• 1997

산업의 발달과 환경에 대한 관심이 높아짐에 따라 고효율, 저공해인 가스터빈의 응용범위가 넓어지고 있는 추세이다. 가스터빈 기관의 효율을 높이기 위해서는 터빈 입구온도를 높이는 것이 필수적인데 이는 재질에 의해 제한 받게 되고 이 때문에 효과적인 냉각방법의 필요성이 대두되었다 충돌제트는 국소적으로 높은 열/물질 전달 효과를 얻을 수 있어서 터빈 블레이드 냉각과 연소기 벽면 냉각에 효과적으로 응용 될 수 있다. 이러한 충돌제트의 냉각효과는 제트출구의 초기조건에 매우 민감한데 Kelvin-Helmholts 불안정은 불안정한 자유전단층에서 자연적인 와류생성(roll up)과 개개의 와류고리 형성의 원인이 되고 이 고리의 성장과 병합(pairing)은 제트의 유동특성에 상당히 영향을 미친다. 제트주위에 생성되는 이러한 와류에 의해 제트중심에서 속도와 난류강도가 변하게 된다. 이러한 제트초기의 불안정성은 하류에서의 와류성장에 영향을 끼치기 때문에 와류의 조절에 의한 충돌 면에의 열 전달 효과 상승을 기대할 수 있다. 이 조절방법은 크게 두 가지로 나눌 수 있는데 하나는 제트주의 환형관에 이차유동을 가하여 와류를 직접 제어함으로써 자유전단류(free shear layer flow)의 안정성 원리를 이용하여 열 전달을 촉진하는 것이고 다른 하나는 음향여기(acoustic exitation)를 사용하여 제트주위의 와류형성을 조절하는 것인데, 자연적으로 형성되는 와류의 주파수(와류의 고유주파수)나 부조화 주파수(subharmonic)로 음향여기 시키는 경우 제트 주위 와류는 더욱 증폭되고 그렇지 않은 경우 제트주위 와류의 형성이 억제되어 더 긴 제트코어의 길이 및 제트코어 주위에서 작은 크기의 와류들이 형성된다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2010년도 제39회 하계학술대회 초록집
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• pp.279-279
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• 2010

Smart gels have recently associated with photonic crystals to form photonic gels. Since these photonic gels are capable of reversibly converting the volume change of gels induced in response to external chemical or electric stimuli into characteristic optical signals, they have been considered not only as a good platform for label-free chemical or biological detection, actuators or optical switches but also as a good model system to investigate gel swelling behaviour. Recently, we reported block copolymer photonic gels self-assembled from polystyrene-b-poly(2-vinyl pyridine) (PS-b-P2VP) block copolymers, and demonstrated that selective swelling of lamellar structure allows extremely large tunability of the photonic stop band from UV region to IR region ($\lambda$ peak=350~1,600 nm). Herein we report block copolymer photonic gels which exhibit strong tunable optical hysteresis and their applications. As nonlinear responses in swelling of hydrogels were often observed, photonic gels exhibit optical hysteresis with change of external pH. We demonstrate such optical hysteresis can be precisely programmed by controlling ion-pairing affinity. We anticipate that photonic gels with carefully tunned optical hysteresis are applicable to optical memory devices.

• Bulletin of the Korean Chemical Society
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• 제22권7호
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• pp.669-672
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• 2001

Pseudo-first-order rate constants have been measured spectrophotometrically for the title reactions. The plot of kobs vs the concentration of alkali metal ethoxides is linear for the reactions performed in the presence of complexing age nt, 18-crown-6 ether, but curved upwardly for the corresponding reactions performed in the absence of the complexing agent, indicating that the alkali metal ions studied in this study behave as a catalyst. The catalytic effect was found to increase in the order Li+ << K+ ${\leq}$ Na+. Second-order rate constants were determined for the reactions with dissociated free ethoxide (kEtO-) and with ion paired alkali metal ethoxides (kEtO-M+ ) from ion pairing treatments. The magnitude of catalytic effect (kEtO-M+/kEtO-) was found to be 2.3, 9.5 and 8.7 for the reaction of 8-(5-nitroquinolyl) 2-furoate, while 1.4, 3.6 and 4.2 for that of 4-nitrophenyl 2-furoate, indicating that the catalytic effect is larger in the reaction of the former substrate than in that of the latter one. The larger catalytic effect was attributed to two possible complexing sites with alkali metal ions in the former substrate.