• 보존과학연구
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• s.7
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• pp.278-291
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• 1986

In this report the practical case of Viking ship's conservation in Denmarke specially among the Eurpoean nations is introduced. The contents of it are summarized as follows :From 1957 to 1962 the Danish National Museum Salvaged five Viking ships from the bottom of Roskilde Fjord, Which were composed of the pieces of timber whose surface was soft because they had lain on the sea bed for about a thousand years. Excavation had been carried out in the same way as in the field by driving down a sheet piling around the wrecks and pumping the water out. These pieces of the wreck ships were packed in airtight plastic bags one by one to be transported for Brede and then immidiately had to go through the treatment for conservation. The conservation treatment process for the pieces includes three steps ; the preliminary process prior to the hardening treatment, the hardening and the assemble of the ships. In the first step ; the preliminary process, all remains of mud and shells from the fjord bed are washed off, and measuring followed ; every single piece of wreckage was drawn so that the form and size of the piece, nail holes, and breaks were registered before conservation. In the second ; the hardening treatment step, the pieces of the woreckage were filled with P.E.G. This Polyethylene Glycol method was the best to handle in the subsequent mounting of the ships in the museum. In the final, the Glycol-treated pieces were pieced together to spips with support of a system of reinforcements. They were to fit in place after corrections of the form were made several times.

• Journal of Environmental Science International
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• v.10 no.4
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• pp.287-292
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• 2001

A packed bed of volcanic rock was used as deodorizing material to remove hydrogen sulfide($H_2$S) from air in a laboratory-scale column, and was inoculated with Thiobacillus sp. as $H_2S$ oxidizer. The effects of volcanic rock particle size distribution on system pressure drop were examined. Various tests have been conducted to evaluate the effect of $H_2S$ inlet concentration and CBCT(Empty Bed Contact Time) on $H_2S$ elimination. The pressure drop for particles of size range from 5.6 to 10 mm was 14 mm$H_2S$/m at a representative gas velocity of 0.25m/s. Biofilter using scoria and Thiobacillus sp. could get the stable removal efficiencies more than 99.9% under $H_2S$ inlet concentrations in the range from 30 to 1,100ppm at a constant gas flow rate of $15.2{\ell}$/min. $H_2S$ removal efficiencies greater than 99% were observed as long as EBCT was longer than 8sec at the 250ppm of $H_2S$ inlet concentration. When EBCT was reduced to 5.5 sec, $H_2S$ removal efficiency decreased by about 12 percent. The maximum $H_2S$ elimination capacity was determined to be 269g-$H_2S/m^3{\cdot}hr$.

• Journal of Environmental Health Sciences
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• v.33 no.6
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• pp.488-492
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• 2007

The influence of additive materials including saw dust and cow manure in the ripening of leather sludge for the efficient vermisabilization was studied. The ripening characteristics of the leather sludge, the growth of earthworms in the growth bed and the by-products like cast were observed according to the mixing ratio of additive materials. When the mixed leather sludge of which the additive materials contents were over 20% were ripened for 50 days, the values of ORP and alkalinity were changed to the favorable ranges for earthworms, the positive (+) and below 1,000 mg/l as $CaCO_3$, respectively. The velocity of ripening improving the characteristics of the leather sludge was faster in the sludge mixed with cow manure than saw dust. This results could also be verified from the monitoring of the states of earthworm growth using the survival rate, the increase rate of lifeweight and the hatching rate of earthworm cocoon in the their growth bed packed with the ripened sludge. The values of CEC in cast, the vermi-stabilized sludge, were increased with the mixing ratio of additive materials, but the content of heavy metals was drcreased by the dilution effect and accumulation in the earthworm body. Above results show that the leather sludge might be efficiently stabilized by earthworms through the ripening for 50 days using additive materials. Cow manure can be used as a good additive materials for leather sludge as much as saw dust, and the optimum content of additive materials in the well-ripened leather sludge was about 30%.

• Environmental Engineering Research
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• v.11 no.1
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• pp.1-13
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• 2006

In this study, conventional biofilters packed with flexible synthetic polyurethane (PU) foam carriers were operated to remove toluene from a contaminated air stream. PU foams containing various adsorbents (e.g., zeolite, sepiolite, dolomite and barite) were synthesized for the biofilter media and their adsorption characteristics of toluene were determined. Adsorption capacity of PU-adsorbent foam was in the order of PU-dolomite ${\approx}$ PU-zeolite > PU-sepiolite > PU-barite. During the biofiltration experiment, influent toluene concentration was in the range of 0-160 ppm and EBRT (i.e., empty bed residence time) was 45 seconds. Pressure drop of the biofilter bed was 4-5 mm $H_2O/m$ column height. The maximum removal capacity was in the order of PU-dolomite > PU-zeolite > PU-sepiolite > PU-barite, while the complete removal capacity was in the order of PU-dolomite > PU-sepiolite > PU-zeolite > PU-barite. The better biofiltration performance in PU-dolomite foam was because PU-dolomite foam had lower density and higher porosity than the others providing favorable conditions for microbial growth. The results of biodegradation kinetic analysis showed that PU-dolomite foam had higher maximum removal rate ($V_m\;=\;11.04\;g$ toluene/kg dry material/day) and saturation constant ($K_s\;=\;26.57\;ppm$) than the other PU foams. This supports that PU-dolomite foam was better than the others for biofilteration of toluene.

• Polymer(Korea)
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• v.26 no.1
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• pp.121-127
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• 2002

We investigated uranium adsorption and adsorption process characteristics in brine water, changing column bed height packed with amidoximated polypropylene-g- acrylonitrile (AOPP-g-AN) fibrous ion-exchanger. Swelling ratios of AOPP-g-AN in fibrous ion-exchanger were 8.54g/g $H_2O_2$ and 8.87 g/g for $H_2O_2$ solvent respectively. Ion exchange capacity increased with degree of graft and showed the maximum, 3.99 meq/g at 100% degree of graft. In batch process, uranium adsorption had reached an initial equilibrium in 10 min with the adsorption rate of 9.5 mg/min. Finial adsorption capacity was 3.95 meq/g, and pH effect could not be observed. In continuous process, adsorption capacity depended on various packing ratios and showed the maximum, 3.92 meq/g at L/D=1. In L/D<2, breakthrough curve was shown two step by channeling flow and ununiform adsorption. Breakthrough time and adsorption capacity were 26 min and 3.63 meq/g, respectively, in brine water adsorption. When compared with actual brine water and model solution, there was no significant difference of adsorption characteristics.

• Membrane Journal
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• v.28 no.5
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• pp.297-306
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• 2018

This review focused carbon-free hydrogen productions from ammonia decomposition including inorganic membranes, catalysts and the presently studied reactor configurations. It also contains general information about hydrogen productions from hydrocarbons as hydrogen carriers. A Pd-based membrane (e.g. a porous ceramic or porous metallic support with a thin selective layer of Pd alloy) shows its efficiency to produce the high purity hydrogen. Ru-based catalysts consisted of Ru, support, and promoter are the efficient catalysts for ammonia decomposition. Packed bed membrane reactor (PBMR), Fluidized bed membrane reactor (FBMR), and membrane micro-reactor have been studied mainly for the optimization and the improvement of mass transfer limitation. Various types of reactors, which contain various combinations of hydrogen-selective membranes (i.e. Pd-based membranes) and catalysts (i.e. Ru-based catalysts) including catalytic membrane reactor, have been studied for carbon-free hydrogen production to achieve high ammonia conversion and high hydrogen flux and purity.

• Journal of Korean Society of Water and Wastewater
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• v.19 no.2
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• pp.149-154
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• 2005

Conventionally used flocculation tanks require large space and high energy requirement for mixing. Static flocculators using gravel bed filter operate at a lower flow rate ($5-10m^3/m^2{\cdot}h$). Further, the cleaning of this system is difficult. A novel high rate static flocculator/filter developed at UTS packed with buoyant media such as polystyrene, polypropylene has been found to operate at higher filtration rates (30-45 $5-10m^3/m^2{\cdot}h$). They can easily be cleaned with minimal energy. Detailed experiments conducted with an artificial kaolin clay solution show that buoyant media is an excellent static flocculator in producing uniform filterable microflocs (12-15 m) even when it is operated at a high rate of 30-40 m/h. Detailed filtration experiments were conducted in a wastewater treatment plant to treat the biologically treated effluent with a floating media of depth of 120 cm. This filter was able to remove majority of phosphorus and remaining solids. It reduced significantly the fecal coliforms and fecal streptoccoci, thus requiring less amount of chlorine for disinfection. The advantage of this system is the low energy and water requirement for cleaning of filter bed. The periodic backwash adopted 30 seconds air and water and 30 seconds water cleaning every 90 minutes filter operation. Thisis equivalent to 1-2% of filtered water production. Mechanical cleaning system on the other hand, requires very low energy requirement (<1% of filtered water production).

• Biotechnology and Bioprocess Engineering:BBE
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• v.10 no.3
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• pp.236-241
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• 2005

A decolorization process using ion exchange chromatography was developed to refine rhEGF as a cosmetic ingredient. A macroreticular resin (D314) was selected, with respect to its high decolorization rate and recovery yield of rhEGF, and the operational conditions of the decolorization process optimized. The optimum conditions were as follows: the rhEGF effluent was ion exchanged at a flow rate of 60.0mL/h, with an effluent pH 5.0, using a chromatographic column (i.d. 16mm) packed with D314, with a 7.5cm in bed height. The decolorization process was carried out under the optimum conditions, and halted when the effluent volume reached 350mL, giving a decolorization rate and recovery yield of rhEGF higher than 67 and $80\%$, respectively. When the decolorization rate exceeded $67\%$, the final product turned out to be white or light yellowish, which was to the satisfaction of the cosmetic standard.

• Journal of Microbiology and Biotechnology
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• v.6 no.1
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• pp.36-42
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• 1996

The production of sorbitol by permeabilized cells of Zymomonas mobilis immobilized in $\kappa$-carrageenan was investigated. Cetyltrimethylammoniumbromide (CTAB) permeabilized cells were treated with glutaraldehyde prior to immobilization for cross-linking of enzymes, glucose-fructose oxidoreductase (GFOR) in cells. Rigidity of the immobilized beads was increased two-fold with 90$\%$ conversion efficiency by the additions of 40$\%$ (w/v) polyols (glycerol 25 g + propylene glycol 15 g) to 60$\%$ (w/v) distilled water containing 2.5$\%$ (w/v) $\kappa$-carrageenan as a final concentration, prior to immobilization. $\kappa$-Carrageenan beads entrapping permeabilized cells were dried to improve bead rigidity and storage stability. During s6mi-batch process for 72 h with dry beads, there was an improvement of the loss of enzyme activity (less than 10$\%$). In batch process, the kinetic results of $K_m.fructose$ value for the free cells, wet beads and dry $\kappa$-carrageenan beads were 71.7, 72.4 and 116.7 g/l, respectively. Higher productivity was obtained with two-stage continuous packed bed reactors with both wet and dry $\kappa$-carrageenan beads at 25.00 and 21.15 g/l/h, respectively, when measured at second stage.

• Microbiology and Biotechnology Letters
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• v.21 no.4
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• pp.373-380
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• 1993

When the cells of yeast K35 were immobilized in Ca-alginate gel, cell concentration and viability decreased as alginate concentration increased. Considering the results, 2% (w/v) Ca-alginate concentration would be suitable. Among various concentrations of additives and cross-lin-king agent, the addition of 1.67% (w/v) of bentonite together with 0.33% (v/v) of glutaraldehyde (ABG bead) resulted in the highest ethanol production of 1.8%(w/v), using YPD medium containing 2% glucose. ABG bead seemed to be more resistant to phosphate ion than Ca-alginate bead. 0.33%(w/v) of phosphate was a proper concentration for the ethanol production by ABG bead. Scanning electron microscopic observation depicted that the immobilized cells on the bead surface were coated by alginate gel and that the cells in the internal bead were cross-linked with alginate matrix. When repeated-batch culture was performed with ABG bead for 40 days in a packed-bed reactor, ethanol concentration of about 90~110 g/l-gel was maintained. Cell viability was maintained around 70%, and outgrowing cell concentration was below 6.3% of total cell concentration. Consequently, the results showed that ABG head was a potential carrier for continuous production of ethanol compared to conventional Ca-alginate bead.