• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.11a
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• pp.234-237
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• 2000

In this paper, the structural, dielectric and piezoelectric properties of the Pb[(S $b_{1}$2/N $b_{1}$2/)$_{0.035}$- $_Mn_{1}$3/N $b_{2}$3/)$_{0.065}$-(Z $r_{0.49}$, $Ti_{0.51}$)$_{0.90}$] $O_3$ ceramics were investigated with respect to the variation of the milling time. Grain size was decreased as the increase of milling time. As the milling time is increased, the particle size of the powder was decreased. Dielectric constant and electromechanical coupling factor (Qm)were slowly increased with the increase of milling time. The highest value of Qm was 1,497 at milling time 8 hour. Temperature coefficient of resonant frequency(TC $F_{r}$) was moved to positive side with the increase of milling time.e.e.e.e.e.e.

• Proceedings of the KIEE Conference
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• 1991.11a
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• pp.336-338
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• 1991

Effects of $Nb_2O_5$ addition ranged from 0.0 to 0.75(wt%) on the microstructure and electrical porperties of PZT ceramics have been investigated. The Pb vacancy concentration increases with increasing NbO content. However, the experimental results show the resistivity increases with increasing $Nb^{5+}$ content. This behavior can be explained as a compensation effect and $Nb^{5+}$ can serve as a donar and contribute electrons to the conduction process. According to the law of mass action, this result may reduce the total charge carrier:thus the resistivity increase with NbO content in PZT.

• Smart Structures and Systems
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• v.4 no.3
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• pp.291-304
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• 2008

Piezoelectric materials have been widely used in ultrasonic nondestructive testing (NDT). PZT ceramics can be used to receive and generate surface acoustic waves. It is a common application to attach PZT transducers to the surface of structures for detecting cracks in nondestructive testing. However, not until recently have piezoelectric polymers attracted more and more attention to be the material for interdigitated (IDT) surface and guided-wave transducers. In this paper, an interdigitated gold-on-polyvinylidene fluoride (PVDF) transducer for actuating and sensing Lamb waves has been introduced. A specific etching technology is employed for making the surface electrodes into a certain finger pattern, the spacings of which yield different single mode responses of Lamb waves. Experiments have been performed on steel and carbon fiber composite plates. Results from PVDF IDT sensors have been compared with those from PZT transducers for verification.

• Electrical & Electronic Materials
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• v.6 no.2
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• pp.168-174
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• 1993

두가지 부분수산법, 즉 부분수산법(1)과 수정된 부분수산법에 의해 합성한 미분말을 사용하여 PZT 세라믹스를 저온소성하고 그 전기적 제특성을 조사하였다. 두가지 부분수산법에 의해 합성한 분말의 소결거동을 조사해본 결과 고상반응법보다 훨씬 낮은 소결온도인 950.deg.C에서도 단일상의 페로브스카이트상이 얻어지고 치밀화가 이루어졌을 뿐만 아니라 비유전율, 전기기계 결합계수, 압전정수 등 유전 및 압전특성이 고상반응법에 비해 손색이 없었다. 특히 두가지의 부분수산법에 의해 얻어진 PZT 세라믹스는 물리적 전기적 제특성이 서로 비슷하게 나타났으며 이 결과로부터 부분수산법(1)에서 수반되는 ZTO 분말을 따로 합성하는 공정이 불필요한 수정된 부분수산법이 편리함을 알았다.

• The Korean Journal of Ceramics
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• v.6 no.1
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• pp.68-73
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• 2000

The effects of oxygen annealing on the carbon content in MgO thin films were investigated, MgO thin films were deposited on Si(100) substrate at different temperatures of 400 to $700^{\circ}C$ and different deposition rates of 3.4 to 11.6$\AA$/min. Using rf magnetron sputtering method. Carbon content change on the surface of MgO thin films with the oxygen annealing at different temperatures was investigated using various method. The carbon content decreased as the annealing temperature increased. $Pb(Zr_{0.53}Ti_{0.47})O_3$(PZT) thin films were deposited on the MgO/Si(100) substrates. The effects of carbon content on the phase formation and the electrical properties of PZT thin films were also investigated.

• Journal of the Korean Ceramic Society
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• v.25 no.1
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• pp.7-14
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• 1988

In this paper, piezoelectric composite materials of 1-3 connectivity were prepared by using "dicing-filling" technique with PZT ceramics and epoxy polymers, and the dependence of piezoelectric properties on the thickness of specimens was investigated. In case that the PZT volume percent is 18.1%, according to an increment of thickness, the dielectric constant of composites( 33) is unchangeable, which is about 200, the piezoelectric coefficient (d33) is somewhat increased, which is about 240-280 (PC/N) and the electromechanical coupling factor of thickness mode(kt) is proportioned, but radial mode(kp) is constant.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.11a
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• pp.322-325
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• 2002

In this study, dielectric and piezoelectric properties of PSN-PZT Ceramic were investigated as a function of PNW substitution. With the increase of PNW substitution, teragonality, Curie temperature and mechanical quality factor were decreased but grain size and electromechanical coupling factor(kp) was gradully increased. At 4 mol [%] PNW substitution. maximum kp of 0.567 was shown.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.08a
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• pp.35-38
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• 2003

In this paper, we investigated the electric and acoustic properties of piezoelectric composites, which were fabricated using polymer and piezoelectric ceramics, when the volume fraction of PZT varies. Practically, the shrinkage rate of polymer is an important factor in ultrasonic transducer fabrication. When 10 wt% filler A was added into polymer(Epofix), the lowest shrinkage was resulted. The electromechanical coupling factor($k_t$) of the fabricated piezoelectric composites showed its highest when the volume fraction PZT was 0.6. It decreased if the volume fraction was higher than the value. The relative permittivity and acoustic impedance of piezoelectric composites decreased linearly when PZT volume fraction was decreased. The lowest acoustic impedance was 3.2 when the volume fraction of PZT was 0.2.

• The Korean Journal of Ceramics
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• v.3 no.3
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• pp.191-194
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• 1997

Epitaxial Pb(Zr, Ti)O3(PZT) thin films were prepared on MgO(100) substrates by dipping-pyrolysis (DP) process using metal naphthenates as starting materials, and effects of pyrolysis and final heat-treatment conditions on the film's orientation were investigated. Solid-state epitaxial growth of PZT proceeds at lower temperature around 650℃ from the precursor pyrolyzed at 350 and 500℃. The in-plane alignment of the PZT films depends not only on the final heat-treatment temperature but on the pyrolysis conditions; the films, pyrolyzed at a higher temperature for a short time, i.e., at 500℃ for 10 min, exhibited stronger orientation after the same final heat treatment at 650°∼750℃. The PZT films with the strongest orientation were prepared by pyrolysis under the above conditions followed by final heat treatment at 750℃.

• The Journal of the Acoustical Society of Korea
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• v.5 no.2
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• pp.29-38
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• 1986

본 논문은 분극처리된 PZT 압전 세라믹 소자의 물리, 음향학적 제 특성이 시간의 함수로 나타 나는 시효현상을 다루고 있다. SrCO\sub 3\, NiO 및 Fe\sub 2\O\sub 3\를 소량 첨가하여 직접 제조한 PZT 세라믹은 분극처리 후, f\sub r\ 은 증가하는 시효현상을 보여주었다. 시효현상 기구의 이해를 위하 여 이중 포텐샬우물 모델을 이용하였으며, 외부에서 가한 응력, 역방향 전장 및 온도상승에 따라 분극현 상을 나타내었다. 시효현상의 주 원인은 분극처리시 전장 방향으로 분역들이 정렬되면서 내부에 저장되 었던 잔유응력의 이완에 의한 분역계면의 운동에 있음을 간접적으로 확인하였다. 이러한 분역계면의 운 동은 열적 활성화 에너지를 갖는 시간에 의존하는 운동으로써 분극의 감소를 유발하며, 이것이 시효현 상으로 나타나는 것으로 사료된다.