• Title/Summary/Keyword: PW

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DFT Conformational Study of Calix[6]arene: Hydrogen Bond

  • Kim, Kwang-Ho;Choe, Jong-In
    • Bulletin of the Korean Chemical Society
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    • v.30 no.4
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    • pp.837-845
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    • 2009
  • We have performed DFT calculations to investigate the conformational characteristics and hydrogen bonds of the calix[6]arene (1) and p-tert-butylcalix[6]arene (2). The structures of various conformers of 1 were optimized by using the B3LYP/6-31G(d,p) and /6-31+G(d,p) methods followed by single point calculation of MPW1PW91/ 6-31G(d,p). The relative stability of the conformers of 1 is in the following order: cone (pinched: most stable) > partial-cone > cone (winged) $\sim$ 1,2-alternate $\sim$ 1,2,3-alternate > 1,4-alternate > 1,3-alternate > 1,3,5-alternate. The structures of different conformers of 2 were optimized by using the B3LYP/6-31G(d,p) method followed by single point calculation of MPW1PW91/6-31G(d,p). The relative stability of the conformers of 2 is in the following order: cone (pinched) > 1,2-alternate > cone (winged) > 1,4-alternate $\sim$ partial-cone > 1,2,3-alternate > 1,3,5alternate > 1,3-alternate. One of the important factors affecting the relative stabilities of the various conformers of the 1 and 2 is the number and strength of the intramolecular hydrogen bonds.

A Case of Prader-Willi Syndrome with Bilateral Butch Diverticula Associated with Vesicoureteral Reflux (Prader-Willi 증후군에서 방광요관 역류를 동반한 양측성 Hutch 게실 1례)

  • Han Seung-Jeong;Lee Tack Lee;Kim Won-Hong;Hong Young-Jin;Jun Yong-Hun;Lee Ji-Eun
    • Childhood Kidney Diseases
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    • v.9 no.1
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    • pp.112-116
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    • 2005
  • Our patient is the first reported case of Prader-Willi syndrome(PWS) with bilateral Hutch's diverticula. We believe that hypotonia in PWS is associated with multiple bladder diverticula and vesicoureteral reflux. We conclude that PWS can be considered a possible associated syndrome in patients with multiple bladder diverticula.

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Effect of activated carbon modified with oxalic acid on the production of IPA from MX catalyzed by H3PW12O40@carbon and cobalt

  • Fang, Zhou-wen;Liu, Hua-jie;Wang, Zhi-hao;Wen, Di;Long, Xiang-li
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.87-98
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    • 2018
  • The production of IPA from the oxidation of MX is completed under the catalysis of $H_3PW_{12}O_{40}$ (HPW) loaded on carbon and cobalt. Oxalic acid is tried to modify the carbon to upgrade the catalytic activity of HPW@C catalyst. The experiments show that the best carbon is acquired by carbonizing the carbon at $450^{\circ}C$ for 2 h in $N_2$ after being soaked in a $0.20mol\;l^{-1}$ oxalic acid solution for 16 h. The IPA produced by the HPW@C catalysts prepared with the carbon modified is 58.9% over that obtained by the catalysts prepared with the original carbon.

The Physiological Activities of Ripe Fruit of Poncirus trifoliata (완숙된 탱자(Poncirus trifoliata Ripe Fruit)의 부위별 생리활성에 관한 연구)

  • Lee, Yang-Suk;Yoon, Hong-Gun;Kim, Nam-Woo
    • Food Science and Preservation
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    • v.17 no.5
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    • pp.698-705
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    • 2010
  • Ripe fruits of Poncirus trifoliata were examined with a view to development of functional foods and physiological activities were assessed. The flavonoid compound of the sarcocarp extract (SC), at 20.39 mg/g, was the highest of all extracts studied, whereas that in fruit juice extract (FJ) was 18.72 mg/g. The total polyphenol content of pericarp ethanol (PE) and water (PW) extracts were 60.54 mg/g and 45.91 mg/g, respectively. The nitrite scavenging ability of PW (2.0 mg/mL) was 52.27% at pH 1.2. The tyrosinase inhibitory activity of PE (2.0 mg/mL) was 23.23%, but SW showed no such activity at any tested concentration. The electron donating abilities of PW, SC, and FJ were greater than 50% when tested at 0.5 mg/mL. Notably, the $IC_{50}$ of PW was 147.73 ${\mu}g$/mL. Inhibition of xanthine oxidase by PW and SE (0.5 mg/mL) were more than 90%, whereas the $IC_{50}$ of SC was 18.28 ${\mu}g$/mL. These results indicate that P. trifoliate ripe fruits may potentially serve as components of valuable new functional foods.

Evaluation of Surface Dose for Field-in-Field (FIF) Technique in Breast Radiotherapy (유방암 방사선치료에서 Field-in-Field (FIF) 기법의 조사면 주변 선량 분석)

  • Il-Hoon, Cho;Daehong, Kim
    • Journal of the Korean Society of Radiology
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    • v.16 no.7
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    • pp.851-856
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    • 2022
  • The purpose of this study is to confirm the effect of reducing the surface dose around the radiation field in breast cancer radiotherapy using the Field-in-Field (FIF) technique. X-ray was exposed from a linear accelerator (Linac) was used for irradiation, and the surface dose was measured with a glass dosimeter. The source-to-surface distance (SSD) was 90 cm, the field size is 10 × 10 cm2, and the X-ray energy was 6 MV and 10 MV, respectively. The surface dose of the FIF was compared with the dose measured in the physical wedge (PW) and dynamic wedge (DW). Wedge angles of 15° and 30° were used in the PW and DW, respectively. Surface dose was measured at 1 cm, 3 cm, and 5 cm from the center of the field size, respectively. According to the results, FIF showed lower surface dose compared to PW and DW regardless of the energy of the X-ray beam, wedge angle, and dose measurement point. Since FIF could reduce the radiation dose in periphery of the field size in breast cancer treatment, it is expected to be able to reduce the secondary damage caused by the radiation beam as well as to obtain a uniform dose distribution on the target.

Effect of Different Levels of Applications of Illite on the Growth of Red Pepper (Capsicum annuum L.) in Bed Soil (상토에서 일라이트의 혼합비율에 따른 고추 육묘시 생육효과)

  • Lee, Seok-Eon;Kim, Hong-Ki;Kwon, Sang-Moon;Kim, Hee-Jung;Yoo, Ri-Bi;Baek, Ki-Tae;Lee, Moon-Soon;Woo, Sun-Hee;Park, Man;Chung, Keun-Yook
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.6
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    • pp.852-857
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    • 2010
  • This study was performed to explore the effect of the clay mineral illite on the improvement of bed soil and plant growth. Red pepper (Capsicum annuum L.) was used as a model vegetable crop. The experiment was performed during the whole six weeks in the glass house of the Chungbuk National University. Its seedlings were cultivated in the bed soil normally used for horticultural purpose. Of the seedlings cultured, the healthy and regular size of seed were selected and cultivated in the pots. They were treated with two forms of illite, particulate (PA) and powder (PW), at the following application rates: standard application[P1 (PA1, PW1), 1:20 (w/w)], two times[P2 (PA2, PW2), 1:10 (w/w)], and four times[P4 (PA4, PW4), 1:5 (w/w)] of standard application. Untreatment (P0) was used as a control pot. At six weeks of cultivation, their growth lengths were correspondingly increased as the application rate was increased ranging from P0, P1, P2, and to P4. Their growth length was a little greater on the application of powder illite (PW) than on the particulate illite (PA). Based on the plant analysis for the root, leaf, stem of red pepper, the uptake amounts of K, Ca, and Mg, were correspondingly increased, as the application rate was increased ranging from P0, P1, P2, and to P4, respectively. At the same application rate, their amounts taken up in the respective parts were higher on the application of PW illite than on the PA one. Especially the amounts of Ca and Mg were higher in the stem, leaf than root. Consequently, it appears that the illite treatment, especially, PW form of illite, enhance the growth of red pepper in the glass house during the whole six weeks of experiment.

A System Unauthorized Access using MAC Address and OTP (MAC Address와 OTP를 이용한 비인가 접근 거부 시스템)

  • Shin, Seung-Soo;Jeong, Yoon-Su
    • Journal of Digital Convergence
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    • v.10 no.3
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    • pp.127-135
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    • 2012
  • This study improves the existing user identification method using user ID and password. The new protocol protecting unauthorized access is designed and developed using user's ID, password, and OTP for user certification as well as MAC address for computer identification on networks. The safety on trials of unauthorized certification is tested and analyzed for four types following the criterion of information acquisition.