• Title/Summary/Keyword: PVC composite

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Parametric Study on the Design of Sandwich Beams and Plates for Machine Tool Structures (공작기계를 위한 보와 평판의 샌드위치 구조 설계에 관한 파라메트릭 연구)

  • Kim, Dae-Il;Chang, Seung-Hwan
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.15 no.1
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    • pp.39-48
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    • 2006
  • In this paper, polymer composites based sandwich structures like beams and plates are optimised by using parametric study. The structures are composed of fibre reinforced composites for facial material and resin concrete and PVC foam for core materials. The stacking sequences and thickness of the composites are controlled as major parameters to find out the optimal condition for machine tool components. For the plate structure of machine tool bed composites-skined sandwich structure which has several ribs are proposed to enhance bending stiffnesses in two major directions at the same time. Dynamic robustness of a machine tool structure is investigated using modal analysis. From the results optimal configuration and materials for high precesion machine tools are proposed. And the plate was made of fiber reforced composite material and PVC foam.

Preparation of Poly(vinyl chloride)-graft-poly(styrene sulfonic acid) Composite Nanofiltration Membranes (폴리비닐클로라이드-그래프트-폴리스티렌 술폰산 복합 나노막 제조)

  • Kim, Jong-Hak;Park, Jung-Tae;Koh, Joo-Hwan;Roh, Dong-Kyu;Seo, Jin-Ah
    • Membrane Journal
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    • v.18 no.2
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    • pp.132-137
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    • 2008
  • Nanofiltration membranes were prepared based on coating a sulfonated comb-like copolymer layer on top of a poly(vinylidene fluoride) (PVDF) support. The comb-like copolymer comprising poly(vinyl chloride) backbone and poly(styrene sulfonic acid) side chains, i.e. PVC-g-PSSA was synthesized by atom transfer radical polymerization (ATRP) using direct initiation of the secondary chlorines of PVC. The successful synthesis of graft copolymers were confirmed by nuclear magnetic resonance ($^1H$-NMR), FT-IR spectroscopy and wide angle X-ray scattering (WAXS). Composite nanofiltration membranes consisting PVC-g-PSSA as a top layer exhibited the increase of both rejections and solution flux with increasing PSSA concentration. This performance enhancement is presumably due to the increase of SO3H groups and membrane hydrophilicity. The rejections of composite membranes containing 71 wt% of PSSA were 88% for $Na_2SO_4$ and 33% for NaCl, and the solution flux were 26 and $34L/m^2h$, respectively, at 0.3 MPa pressure.

A Study on the Micro-deformation of Plain Weave Carbon/Epoxy Composite-Polymer Foam Sandwich Structures during Curing (평직 탄소섬유 복합재료-고분자 포움 샌드위치 구조의 성형 중 미소변형에 관한 연구)

  • Kim Yong-Soo;Chang Seung-Hwan
    • Composites Research
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    • v.17 no.6
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    • pp.28-36
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    • 2004
  • Micro-tow deformation during forming of PVC foam-fabric composite sandwich structure is investigated to find out the correlation between forming condition and material deformation. The foams used in this research are PVC foams which have 4 different densities and the fabric composite is Carbon/epoxy prepreg which is plain weave (3k) as a skin material. Tow parameters such as crimp angle and tow amplitude are measured using microscope and a proper image tool and are compared with each other. In order to find out the effect of foam deformation during forming on tow deformation the compressive tests of foams are performed in three different environmental temperatures ($25^{\circ}C$, $80{\circ}C$, $125^{\circ}C$). The microscopic observation results show that the micro tow deformations are quite different from each other with respect to the foam density and forming pressure.

The Effect of Titanate Coupling Agents on the Electrical and Mechanical Properties of PVC-Ni Composite Systems (PVC-Ni 복합재의 전기적 ${\cdot}$ 기계적 성질에 미치는 Titanate Coupling Agent 의 영향)

  • Tak Jin Moon;Mi Kyung Lee;Sun Ho Kim
    • Journal of the Korean Chemical Society
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    • v.29 no.3
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    • pp.319-327
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    • 1985
  • The effect of titanate coupling agents on the electrical and mechanical properties of conductive poly (vinyl chloride)-nickel composite was studied as functions of filler concentration, the variation of the amount of titanate coupling agents and the type of titanate coupling agents. It was found that the electrical and mechanical properties of PVC-Ni system were improved by the treatment of titanate coupling agents, but the excessive use of titanate coupling agents influenced to give worse properties.

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A study on the Impact Characteristics for Rubber Toughened polymeric Materials under Low Velocity Impact (고무보강 폴리머 재료의 저속 충격 해석)

  • 구본성;박명균;박세만
    • Proceedings of the Safety Management and Science Conference
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    • 2004.05a
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    • pp.219-231
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    • 2004
  • The Charpy and Izod impact tests are the most prevalent techniques used to characterize the effects of high impulse loads on polymeric materials. An analysis method for rubber toughened PVC is suggested to evaluated critical dynamic strain energy release rates(G$_c$) from the Charpy impact tester was used to extract ancillary information concerning fracture parameters in additional to total fracture energies and maximum critical loads. The dynamic stress intensity factor KID was computed for varying amounts of rubber contents from the obtain maximum critical loads and also toughening effects were investigated as well. The fracture surfaces produced under low velocity impact for PVC/MBS composites were investigated by SEM. The results show that MBS rubber is very effective reinforcement material for toughening PVC.

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Axial behavior of square CFST encased seawater sea-sand concrete filled PVC/GFRP tube columns

  • Rong Su;Xian Li;Ziwei Li
    • Steel and Composite Structures
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    • v.47 no.6
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    • pp.781-794
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    • 2023
  • In order to directly apply seawater and sea sand in construction without desalination, a type of square concrete-filled steel tube (CFST) encased with prefabricated seawater sea-sand concrete filled Polyvinyl Chloride (PVC)/Glass Fiber Reinforced Polymer (GFRP) tube column was proposed. Twenty short columns were tested under uniaxial loads, and the test parameters included inner tube types, seawater sea-sand concrete replacement ratios, concrete strength, the wrapping area of Carbon Fiber Reinforced Polymer (CFRP) strips and the thickness of GFRP tube. The effects of the parameters on failure modes, loading capacity, ductility and strain responses were discussed. All the tested specimens failed with serious buckling of the steel tubes and fracture of the inner tubes. The specimens had good residual bearing capacity corresponding to 64% to 88.9% of the peak capacity. The inner GFRP tubes and PVC tubes wrapped by CFRP strips provided stronger confinement to the core concrete, and were good choices for the proposed columns. Moreover, an analytical model for the composite column with different inner tube types was proposed.

Effect of Synthetic MSW Leachate on Chemical Compatibility of PVC Geomembrane (PVC 지오멤브레인의 화학적 적합성에 합성 MSW 침출수가 미치는 영향분석)

  • Choi, Hangseok
    • Journal of the Korean Geosynthetics Society
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    • v.5 no.2
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    • pp.39-44
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    • 2006
  • The resistance of flexible PVC geomembranes to leachate chemicals is an important factor when PVC geomembranes are being considered as a barrier layer in a composite liner system. This paper describes laboratory test results that evaluate the chemical compatibility of a 0.76 mm (30 mil) thick flexible PVC geomembrane exposed to a synthetic municipal solid waste (MSW) leachate. Changes in dimensional, physical, and mechanical properties were measured after exposure to the synthetic MSW leachate at $23^{\circ}C$ and $50^{\circ}C$ for 30, 60, 90, and 120 days. Although some variability of the test results is observed due to experimental factors and product variability, the synthetic MSW leachate did not significantly degrade the physical or mechanical properties of the flexible PVC geomembrane. As a result, this paper will conclude the PVC geomembranes are not adversely affected by the synthetic MSW leachate.

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Characteristics of Structural Behavior of Unplasticized Polyvinyl Chloride (PVC-U) Pipe Buried Underground (지중매설 경질폴리염화비닐관의 구조적 거동)

  • Kim, Sun-Hee;Cheon, Jinuk;Kim, Eung-Ho
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.6 no.4
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    • pp.16-23
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    • 2015
  • The industrialization and urbanization forced to increase the density of pipelines such as water supply, sewers, and gas pipelines. The materials used for the existing pipe lines are mostly composed of concretes and steels, but it is true that the development for more durable and efficient materials has been continued performed to produce long lasting pipe lines. Recently, underground pipes serve in diverse applications such as sewer lines, drain lines, water mains, gas lines, telephone and electrical conduits, culverts, oil lines, etc. In this paper, we present the result of investigation pertaining to the structural behavior of unplasticized polyvinyl chloride (PVC-U) flexible pipes buried underground. In the investigation of structural behavior such as a ring deflection, pipe stiffness, 4-point bending test, experimental and analytical studies are conducted. In addition, pipe stiffness is determined by the parallel plate loading tests and the finite element analysis. The difference between test and analysis is about 8% although there are significant variations in the mechanical properties of the pipe material. In addition, it was found by the 4-point bending test there is no problem in the connection between the pipes by coupler.

Electrochemical Properties of Carbon Composites Prepared by Using Graphite Ball-milled in Argon and Air Atmosphere

  • Lee, Kyoung-Muk;Oh, Seh-Min;Lee, Sung-Man
    • Bulletin of the Korean Chemical Society
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    • v.29 no.6
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    • pp.1121-1124
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    • 2008
  • A carbon composite was synthesized by mechanical mixing of ball-milled graphite and PVC powders, followed by pyrolysis reaction of PVC. Natural graphite ball milled under atmosphere of argon or air leads to a disordered structure. It appears that the electrochemical lithium intercalation reaction is dependent on the atmosphere in which the graphite is ball milled. The carbon composite obtained using air-milled graphite shows a high reversible capacity and high initial coulombic efficiency compared to argon-milled graphite. This is attributed to the enhanced thermal stability of a disordered structure in the air milled sample. For the one with air-milled graphite, the disordered structure is maintained during heat treatment, while argon-milled graphite is partially crystallized.

Preparation and Characterization of a Surface Renewable Solid State Hg/HgO Reference Electrode Utilizing Gold Amalgam

  • Kim, Won;Park, Jong-Man
    • Bulletin of the Korean Chemical Society
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    • v.28 no.3
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    • pp.439-442
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    • 2007
  • A solid state Hg(Au)/HgO reference electrode was prepared utilizing gold amalgam solid particles. Solid fine powder of the gold amalgam was prepared by chemical reduction of Au(III) with NaBH4 followed by reduction of Hg(II) in the presence of gold fine particles. The solid content in the suspension of the gold amalgam particles and fine mercury oxide particles in DMF containing PVC was precipitated by the addition of a large amount of water to give solid Hg(Au)/HgO/PVC mixture. After drying, the mixture was pressure-molded to a physically stable Hg(Au)/HgO composite reference electrode material. The electrochemical characteristics of the electrode as a reference electrode were very similar to an ordinary Hg/HgO reference electrode. The electrode material can be molded and fabricated in any desired shape and size. The surface can be renewed by a simple polishing process whenever contaminated or deactivated. The applicability of the electrode in the electrochemical detection of carbohydrates after anion exchange separation was evaluated.