• Title/Summary/Keyword: PVA

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The Effect of PVA-Al(III) Complex on the Pore Formation and Grain Growth of UO$_2$ Sintered Pellet (PVA-Al(III) 착물이 UO$_2$ 소결체의 기공형성과 결정립성장에 미치는 영향(I))

  • 이신영;김형수;노재성
    • Journal of the Korean Ceramic Society
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    • v.35 no.8
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    • pp.783-790
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    • 1998
  • The characterization of the complexation reaction of PVA and Al(III) ion at different pH and the sint-ering behaviour of UO2 containing the PVA-Al(III) complexes were investigated. Compared with pure PVA powder the complexed PVA-Al(III) powder had compacter shape and lower decomposition temperature The major phase of PVA-Al(III) complex decomposed at 90$0^{\circ}C$ was $\alpha$-Al2O3 The PVA-Al(III) complex formed at pH 9 had the lowest relative viscosity the highest Al content of 36% and the smallest particle size of 19${\mu}{\textrm}{m}$ While the pure UO2 pellet appeared with bimodal one. The grain size of the pure UO2 pellet was 7${\mu}{\textrm}{m}$ but that of the PVA-Al(III) complex added UO2 pellet was increased up to 36${\mu}{\textrm}{m}$ The largest grain size was ob-tained when the PVA-Al(III) complex formed at pH9 was added and the PVA-Al(III) complex formed at pH 11 had the greatest effect on increasing pore size.

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Heat-Treated Polyvinyl Alcohol/Cellulose Nanocrystal Film with Improved Mechanical Properties and Water Resistance (내수성 및 기계적 물성이 향상된 열처리된 폴리비닐알코올/셀룰로오스 나노결정 필름)

  • Nguyen, Son Van;Lee, Bong-Kee
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.11
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    • pp.1-8
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    • 2021
  • In this study, the water resistance and mechanical properties of heat-treated polyvinyl alcohol (PVA)/cellulose nanocrystal (CNC) films were investigated. PVA is the most commonly used synthetic biodegradable polymers owing to its excellent properties. However, the water/moisture sensitivity and relatively poor mechanical properties of PVA limits its applications. Although heat treatment is a conventionally used method to improve the mechanical strength and water resistance of PVA, the effectiveness of this method is insufficient. Therefore, CNC was used to further improve the mechanical properties and water resistance of the heat-treated PVA film. PVA/CNC nanocomposites containing CNC contents of 0, 1, 3, 5, and 10 wt% were fabricated using solvent casting and subsequent heat treatment. The mechanical properties and water resistance of PVA/CNC films were significantly improved. The tensile strength and wet strength of the PVA/CNC film with a CNC content of 5 wt% (PVA/CNC 5%) were 184.5% and 136.0% higher than those of the untreated PVA, respectively. In addition, the water absorption and solubility of PVA/CNC 5% were 56.6% and 68.2% lower than those of the untreated PVA.

Characteristics of the symbionts Pseudomonas sp. J2W strain and Xanthomonas sp. J2Y strain which utilize polyvinyl alcohol (Polyvinyl alcohol 이용 공생균 Pseudomonas sp. J2W와 Xanthomonas sp. J2Y의 특성)

  • Jo, Youn-Lae
    • Applied Biological Chemistry
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    • v.35 no.1
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    • pp.30-35
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    • 1992
  • Two strains J2W and J2Y which were isolated from soil can utilize polyvinyl alcohol(PVA) as a sole carbon source. PVA was utilized symbiotically by the mixed culture of these two strains which could not utilize PVA in each respective pure culture. Effect of degree of PVA polymerization on the its utilization was examed, and there was remarkable difference among three kind of PVA(PVA 500, 1500 and 2000). The reconstruction of there two strains was carried out with other symbionts Pseudomonas sp. PW and Pseudomonas sp. G5Y which were able to utilize PVA. PVA utilization occured in each remixed culture of J2Y strain with Pseudomonas sp. PW J2W strain with Pseudomonas sp. G5Y, respectively. Identification of bacteria was based on morphological and biological chatacteristics, J2W and J2Y strain were similar to a strain of Pseudomonas pseudimallei and Xanthomonas campestris, respectively.

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Preparation of High Molecular Weight Atactic Poly(vinyl alcohol) Hydrogel by Electron Beam Irradiation Technique (전자빔 조사를 이용한 고분자량 혼성배열 폴리(비닐 알코올) 수화젤의 제조)

  • Kim, Kyung-Sik;Lee, Young-Jae;Lyoo, Won-Seok;Noh, Seok-Kyun
    • Polymer(Korea)
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    • v.32 no.6
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    • pp.587-592
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    • 2008
  • High molecular weight poly(vinyl alcohol) (PVA) hydrogel to be expected as a candidate material for the wound-dressing was successfully prepared by electron beam (EB) irradiation. To produce PVA hydrogels with various gel fractions, degrees of swelling in water, gel strengths, and elongations, two different number-average degrees of polymerization [($P_n$)s] of PVA were adapted such as 1700 and 4000, and the PVA solution concentration and irradiation dose of EB were controlled to range of 5 $\sim$ 20% and 30 $\sim$ 100 kGy, respectively. The gel fraction and strength of PV A hydrogel were increased with increasing molecular weight of PVA, solution concentration, and irradiation dose of EB. On the contrary, the degree of swelling and elongation of PVA hydrogel were decreased. The thermal property and crystallinity related to degree of crosslinking of PVA hydrogel were examined by the analyses of differential scanning calorimetry and X-ray diffraction.

Fabrication and Characterization of Silk/PVA Hydrogels by Sonication and Freezing-Thawing Technique (초음파와 동결/융해에 의한 실크/PVA 하이드로젤의 제조 및 특성 평가)

  • Lee, Ok Joo;Kim, Jung-Ho;Ju, Hyung Woo;Moon, Bo Mi;Park, Hyun Jung;Sheikh, Faheem A.;Park, Chan Hum
    • Polymer(Korea)
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    • v.37 no.6
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    • pp.717-721
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    • 2013
  • Biomaterials like silk fibroin (SF) and poly(vinyl alcohol) (PVA) have received increasing attention in biomedical applications because of their attractive properties such as hydrophobicity and biocompatibility. In this study, efficient systems consisting of interpenetrating SF/PVA hydrogels were prepared as potential candidate for wound dressing applications. A simple approach consisting of sonication and a freezing-thawing technique was adopted to fabricate the hydrogels. Different blend ratios consisting of SF (100, 75, 50, 25 and 0%) with respect to the weight of PVA were prepared. The produced hydrogels were characterized for physico-chemical investigations using various states of techniques like; FE-SEM, TGA, FTIR and tensile strength. The addition of PVA to SF was proved to be beneficial in terms of reducing the pore size and swelling ratio of hydrogels. The mechanical property of SF had been increased by addition of PVA. These results show that SF/PVA hydrogels may serve as potential candidates for wound dressing application.

Preparation and Characterization of PET/PVA-BA/OPP Multi-layer Films for Seasoned-laver Packaging (조미김 포장을 위한 PET/PVA-BA/OPP 다층필름 제조 및 특성분석)

  • Lim, Mijin;Kim, Dowan;Seo, Jongchul
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.23 no.1
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    • pp.9-15
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    • 2017
  • To identify applicability for packaging material of polyvinyl alcohol (PVA)/boric acid (BA) coating solution with highly-enhanced water vapor and oxygen barrier properties, the PET/PVA-BA/OPP multi-layer films were prepared through comma coating and lamination process. The oxygen and water vapor permeabilities, and tensile strength of as-prepared multi-layer films were investigated before and after pressure cooker test (PCT). Although oxygen and water vapor permeabilites, and mechanical properties of PET/PVA-BA/OPP multi-layer films was decreased after PCT, their properties were highly enhanced as increase of BA contents in PVA matrix. This is strongly related with enhanced cross-linking density in PVA-BA layer. In storage test of seasoned-laver, the PET/PVA-BA/OPP multi-layer films were comparatively effective to suppress the increase in peroxide value originating from oxidation of seasoned-laver. Comparing the commercially available PP/Al-metallized PP for seasoned-laver packaging, however, PET/PVA-BA/OPP multi-layer films did not show any advantage in water activity. This is due to higher water vapor permeation properties of as-prepared multi-layer films. Therefore, further studies are required to enhance the water vapor permeation in PET/PVA-BA/OPP multi-layer films.

Mechanical Property Variations of Handsheets by Mixing Ratios of Sw-BKP, Hw-BKP, and PVA Fibers (Sw-BKP, Hw-BKP, PVA 섬유의 배합비에 따른 수초지의 물성과 파괴인성의 변화)

  • Yoon, Sang-Gu;Park, Jong-Moon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.4
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    • pp.60-65
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    • 2015
  • In order to improve the strength of paper, mixing ratio of Sw-BKP and Hw-BKP and PVA (polyvinyl alcohol) fibers dosage were investigated. When the Sw-BKP fraction was increased, strength properties were increased because of average fibers length increased. When PVA fraction increased, paper strength was increased, but there was dissolution of PVA in water. The reason for improving handsheet strength that contained PVA was due to increased bonding action between the fibers by the PVA. The addition of PVA to kraft pulp would be helpful for packaging paper materials to increase strength and fracture toughness.

A Study on the Preparation of Poly(vinyl alcohol) Polarizing Film (폴리비닐알코올 편광필름 제조에 관한 연구)

  • 김삼수;우화령;류원석
    • Textile Coloration and Finishing
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    • v.16 no.4
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    • pp.19-25
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    • 2004
  • Both poly(vinyl alcohol)$(PVA)-I_2$ and PVA-dye polarizing film were prepared using PVA with number-average degree of polymerization of 1,700, 2,300, 2,600. The optical property of used dye in this study closed to the that of iodine. The PVA-dye polarizing film was prepared through the dyeing process. In comparison of the result of the measurement of the heat and humidity resistance of two types polarizing films, it of PVA-dye polarizing film was higher than that of a conventional $PVA-I_2$polarizing film. The transmittance and the polarization efficiency of PVA-dye polarizing film was significantly influenced by dye concentration, dipping time, salt concentration, and temperature of dye bath. The PVA-dye polarizing film exhibited a high polarization efficiency of 99.3% and a good transmittance of 42.4%.

Analysis on Thixotropy of Cement Paste according to the Addition Timing of PVA and Borax (PVA와 붕사 첨가 시기에 따른 시멘트 페이스트의 요변성 발현 분석)

  • Lee, Yu-Jeong;Kim, In-Tae;Han, Dong-Yeop
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.57-58
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    • 2023
  • This study was proceeded to analyze thixotropy of cement paste according to the addition timing of PVA and borax as a basic study of thixotropy of concrete. According to experiment results, the case added borax first and PVA later is that cement paste shows low thixotorpy, and the case added PVA first and borax later is that cement paste shows thixotropy but in certain mix condition fluidity of decrease due to a chemical bond between PVA and borax. The case add PVA and borax simultaneously is that cement paste was expressed thixotropy in all mix condition. Therefore the case add PVA and borax simultaneously is suitable for expressing thixotropy of cement paste.

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Cell Growing Behavior on the Electrospun PVA/GE nanofibermats.

  • Linh, Nguyen Thuy Ba;Nguyen, Thi-Hiep;Song, Ho-Yeon;Yang, Hun-Mo;Min, Young-Ki;Lee, Byong-Taek
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.41.2-41.2
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    • 2009
  • Electrospinning of Polyvinylalcohol (PVA), Gelatin (GE), and PVA/GE blend solutions in acetic acid were investigated to fabricate biodegradable for tissue engineering. The morphology of the electrospun nanofibers was investigated with a field emission scanning electron microscope. The fibers have average diameters in the range 50-150 nm. The miscibility of PVA/GE blend fibers was examined by differential scanning calorimetry.The PVA and GE were immiscible in the as-spun nanofibrous structure. X-ray diffraction (XRD) determined the crystallinity of the membrane and tensile strength for evaluation physical properties. An in vitro study of PVA/GE blend nanofibers was conducted. To assay the cytocompatibility and cell behavior on the PVA/GE blend nanofibrous scaffolds, cell attachment and spreading of fibroblasts seeded on the scaffolds were studied. Our results indicate that thePVA/GE blend nanofibrous matrix, particularly the one that contained 20% PVA and 80% GE could be a good candidate for tissue engineering scaffolds, because it has an excellent cell attachment and spreading for fibroblast cell.

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