• Title/Summary/Keyword: PUR

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A Study on the Strengths of Polyurethane Morthar Cured under Low Temperature Condition (저온양생한 폴리우레탄 모르타르의 강도특성에 관한 연구)

  • 오종석;정효석;박홍신;조영국;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.337-342
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    • 1999
  • The Purpose of this study is to evaluate the strength characteristics of polyurethane(PUR) mortar cured under low temperature condition. PUR mortars are prepared with various catalyst content, methylene chloride(MC) content as a viscosity reducing agent, and curing age at low temperature condition of $0^{\circ}C$, -5$^{\circ}C$ and -1$0^{\circ}C$, tested for working life, compressive and flexural strengths. From the test results, the catalyst and MC contents affect the degree of hardening and blowing of PUR mortar. Strengths increase with an increasing catalyst content at low temperature. Flexural and compressive strength of PUR mortar are about 177kgf/$\textrm{cm}^2$ and 490kgf/$\textrm{cm}^2$ respectively at curing temperature of -1$0^{\circ}C$ with catalyst content of 0.4%. Therefore, it is apparent that this PUR mortars have a sufficient strengths for repair of concrete structures.

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Effect of the Addition of Pentaerythritol or Sorbitol to the Glycolysis of Waste Polyurethane on Prepared Polyol Functionalities and Polyurethane Mechanical Properties (폐 폴리우레탄의 해중합 시 첨가된 pentaerythritol과 sorbitol이 재생 폴리올의 작용기 및 폴리우레탄의 기계적 물성에 미치는 영향)

  • Myoung, Kyo Lim;Kim, Min Gyu;Ko, Jang Myoun;Chun, Jong Han
    • Korean Chemical Engineering Research
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    • v.46 no.6
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    • pp.1039-1042
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    • 2008
  • In order to increase a functionality, OH value, for a recycled polyol prepared from the glycolysis reaction of a waste polyurethane rigid foam(PUR), the effect of an addition of pentaerythritol(PEN, functionality(f)=4) or sorbitol(SOR, f=6) to the its glycolysis reactor on the prepared polyol functionality and the mechanical properties of the polyurethane prepared using it was investigated. The OH values increased from 2.2 for a virgin to 2.8 for the recycled polyol. There was an increase in the mechanical properties including dimensional stability for PUR prepared using the recycled polyol, in which the increased OHs provided higher crosslinking density during PUR synthesis. In addition, the amount of the recycled polyol in the polyol system increased to from 8 to 20 wt% to give better mechanical properties to the PUR.

Influence of Manufacturing Environment on Delamination of Mixed Cross Laminated Timber Using Polyurethane Adhesive

  • SONG, Dabin;KIM, Keonho
    • Journal of the Korean Wood Science and Technology
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    • v.50 no.3
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    • pp.167-178
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    • 2022
  • To investigate the influence of manufacturing environment on bonding performance of mixed cross laminated wood (CLT) using polyurethane (PUR) adhesive, a boiling water soak delamination test according to the temperature and relative humidity was conducted. The 5-ply mixed CLT consisted of Japanese Larch for external and middle layer and yellow poplar for internal layer. The PUR adhesives with different opening times of 10 and 30 minutes were used. The mixed CLT was manufactured according to pressing times of PUR and manufacturing environments of summer and winter. In case of summer environment, the delamination rate of the mixed CLT with pressing time of 4 hours using a PUR adhesive with open time of 10 minutes met the requirements of KS F 2081. In case of winter environment, the delamination rate of the mixed CLT didn't meet the requirements of KS standard. However, it was possible to confirm the effect of improving the adhesive performance by adjusting the pressing time according to the open time of the adhesive under the manufacturing conditions. The delamination rate of CLT with open time 30 minutes PUR, manufactured by indirect moisture supply methods was 11.2% better than direct moisture supply methods. As a result of delamination test in the same condition of relative humidity and adhesive, it was found that the temperature of manufacturing environment influences the adhesive performance.

Behavior of abrasive wear on counterpart roughness of glass fiber reinforcement polyurethane resin composites (상대재의 거칠기에 따른 GF/PUR 복합재료의 연삭마모거동)

  • Kim, Hyung-Jin;Koh, Sung-Wi;Kim, Jae-Dong
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.47 no.3
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    • pp.267-272
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    • 2011
  • The behavior of abrasive wear on counterpart roughness of glass fiber reinforcement polyurethane resin (GF/PUR) composites were investigated at ambient temperature by pin-on-disc friction test. The friction coefficient, cumulative wear volume and surface roughness of these materials against SiC abrasive paper were determined experimentally. The major failure mechanisms were lapping layers, ploughing, delamination, deformation of resin and cracking by scanning electric microscopy (SEM) photograph of the tested surface. As increasing the counterpart roughness the GF/PUR composites indicated higher friction coefficient. The surface roughness of the GF/PUR composites was increased as the sliding velocity was higher and the counterpart roughness was rougher in wear test.

A study on abrasive wear characteristics of side plate of FRP ship (온도변화에 따른 유리섬유/폴리우레탄 복합재료의 충격파괴거동)

  • Kim, Byung-Tak;Koh, Sung-Wi
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.45 no.3
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    • pp.188-193
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    • 2009
  • The present study was undertaken to evaluate the effect of temperature on the results of Charpy impact test for glass fiber reinforced polyurethane(GF/PUR) composites. The Charpy impact test were conducted in the temperature range from -50$^{\circ}$ to 50$^{\circ}$. The impact fracture toughness of GF/PUR composites was considerably affected by temperature and it was shown that the maximum value was appeared at room temperature. It is believed that sensitivity of notch on impact fracture energy were increased with decrease in temperature of specimen. As the GF/PUR composites exposed in low temperature, impact fracture toughness of composites decreased gradually owing to the decrease of interface bonding strength caused by difference of thermal expansion coefficient between the glass fiber/polyurethane resin. And decrease of interface bonding strength of composites with decrease in specimen temperature was ascertained by SEM photographs of Charpy impact fracture surface.

Intramolecular DNA Triplexes in Escherichia. coli (Methylase를 사용한 Escherichia coli에서 Triplex 존재에 관한 연구)

  • Rhim, Hyangshuk;Kim, Sungjo;Kang, Seongman
    • Korean Journal of Microbiology
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    • v.34 no.4
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    • pp.231-235
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    • 1998
  • We have introduced a genetic assay to study the existence of intramolecular triplexes in Escherichia coli. A plasmid containing the gene that encodes a temperature-sensitive EcoRI methylase was cotransformed with different plasmids containing inserts, $(G)_9AATTC(G)_9$ and $(GAA)_9TTC(GAA)_8$, that are able to form intramolecular triplexes in vitro. Inhibition of methylation in vivo was found for $(G)_9AATTC(G)_9$ and $(GAA)_9TTC(GAA)_8$, suggesting that the pur pyr sequences adopt unusual strucures in E. coli. In addition, experiments using two dimensional gel electrophoresis confirmed that intramolecular triplexes are formed for the pur pyr sequences under negative supercoiling. These results demonstrate the existence of intramolecular triplexes in E. coli.

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Characteristics of Wear on Sliding Speed of Glass Fiber Reinforcement Composites (유리섬유강화 복합재료의 미끄럼 속도변화에 따른 마모 특성)

  • Kim, Hyung Jin;Koh, Sung Wi
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.48 no.3
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    • pp.277-283
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    • 2012
  • The characteristics of abrasive wear on sliding speed of glass fiber reinforcement (GF/PUR) composites were investigated at ambient temperature by pin-on-disc friction test. The cumulative wear volume, friction coefficient and surface roughness of these materials on sliding speed were determined experimentally. The major failure mechanisms were lapping layers, deformation of resin, ploughing, delamination, and cracking by scanning electric microscopy (SEM) photograph of the tested surface. As increasing the sliding speed the GF/PUR composites indicated higher friction coefficient. The surface roughness of the GF/PUR composites was increased as the sliding speed was higher in wear test.

Robotic Microsurgery Optimization

  • Brahmbhatt, Jamin V.;Gudeloglu, Ahmet;Liverneaux, Philippe;Parekattil, Sijo J.
    • Archives of Plastic Surgery
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    • v.41 no.3
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    • pp.225-230
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    • 2014
  • The increased application of the da Vinci robotic platform (Intuitive Surgical Inc.) for microsurgery has led to the development of new adjunctive surgical instrumentation. In microsurgery, the robotic platform can provide high definition $12{\times}-15{\times}$ digital magnification, broader range of motion, fine instrument handling with decreased tremor, reduced surgeon fatigue, and improved surgical productivity. This paper presents novel adjunctive tools that provide enhanced optical magnification, micro-Doppler sensing of vessels down to a 1-mm size, vein mapping capabilities, hydro-dissection, micro-ablation technology (with minimal thermal spread-$CO_2$ laser technology), and confocal microscopy to provide imaging at a cellular level. Microsurgical outcomes from the use of these tools in the management of patients with infertility and chronic groin and testicular pain are reviewed. All these instruments have been adapted for the robotic console and enhance the robot-assisted microsurgery experience. As the popularity of robot-assisted microsurgery grows, so will its breadth of instrumentation.

Effect of load upon the abrasive wear characteristics of glass fiber reinforced polyurethane composites (하중변화에 따른 GF/PUR 복합재료의 연삭마모특성)

  • Koh, Sung-Wi
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.46 no.4
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    • pp.495-502
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    • 2010
  • The effect of load and sliding speed on abrasive wear characteristics of glass fiber/polyurethane (GF/PUR) composites were investigated at ambient temperature by pin-on-disc friction test. The friction coefficient, cumulative wear volume and surface roughness of these materials against SiC abrasive paper were determined experimentally. Experimental results showed that the surface roughness of the GF/PUR composites was increased as applied load was higher in wear test. The cumulative wear volume tended to increase nonlinearly with increase of sliding distance and depended on applied load and sliding speed for these composites. It could be verified by scanning electric microscopy (SEM) photograph of surface tested that major failure mechanisms were lapping layers, ploughing, delamination, deformation of resin and cracking.