• Elastomers and Composites
• /
• v.50 no.4
• /
• pp.297-303
• /
• 2015

Ammonium polyphosphate-polyurethane foam composite (APP-PUF) was prepared from poly(adipate)diol/ammonium polyphosphate composite (f = 2), polyether polyol (f = 4.6), and PMDI (f = 2.5). As a blowing agent, $H_2O$ was used at various concentrations. The thermal decomposition behavior, morphology, closed-cell content, and density of APP-PUF were characterized. At the $H_2O$ concentrations lower than 3.5 php, the cell size of pure polyurethane foams (PUF) and APP-PUFs were close each other. As the $H_2O$ concentration became greater than 5.0 php, the cell size of the PUFs greatly increased compared to that of APP-PUFs. Addition of 1.5~1.9 wt% ammonium polyphosphate to the PUFs greatly enhanced the thermal stability of the PUFs, so 50 wt% residual temperature of APP-PUFs increased to $380{\sim}488^{\circ}C$, which were $30{\sim}70^{\circ}C$ higher than those of the PUFs. Thermal stability of the PUFs and APP-PUFs increased with $H_2O$ content and then decreased once $H_2O$ content exceeded 5 php.

• Macromolecular Research
• /
• v.17 no.11
• /
• pp.856-862
• /
• 2009

This study examined the effects of liquid and solid additives on the morphological, mechanical and thermal insulating properties of rigid polyurethane foams (PUFs). The PUFs synthesized with tetramethylsilane (TEMS) as a liquid-type additive showed a smaller average cell size and lower thermal conductivity than those with the aerosil 200 and clay 30B as solid-type additives. When TEMS was added, the average cell size of the PUF became more uniform and finer due to the reduced surface tension of the polymer solution, which increased the nucleation rate and number of bubbles produced and reduced cell size. The PUFs with TEMS showed the highest closed cell contents among the PUFs prepared using TEMS, aerosil 200 and clay 30B. This suggests that the insulation properties of PUF can be determined by both the size of the cell structure and the amount of closed cell contents in the system. The compression and flexural strengths of the PUF increased slightly when the aerosil 200, clay 30B and TEMS were added compared those of the neat PUF. The reaction profiles of the PUFs showed a similar gel and tack tree time with the reaction time among the PUFs synthesized with three different additives and neat PUF. This suggests that the nucleating additives used in this study do not affect the bubble growth of the chemical reaction, and the additives may act as nucleating agents during the formation of PUF. From the above results of the cell size, thermal conductivity, closed cell contents and reaction profile of the PUFs, liquid-type nucleating agent, such as TEMS, is more effective in decreasing the thermal conductivity of the PUF than solid-type nucleating agent, such as aerosil 200 and clay 30B.

• Elastomers and Composites
• /
• v.34 no.4
• /
• pp.285-291
• /
• 1999

Effects of catalysts on network structure, hard segment length and distribution of polyurethane foams in the absence of catalysts were investigated. CFC free all MDI-based poly urethane foams were prepared from poly(ethylene adipate)glycol, 4,4'-diphenylmethane diisocyanate, and water. Amino catalysts used were 1,4-diazabicyclo[2,2,2]octane(DABCO), N, N,N',N'-tetramethyl--hexane-1,6-diamine(MR), bis(2-methylamino ethyl)ether(ET), 1,8-diazabicyclo-[5,4,0]-undecene-7(DBU). Dibutyltindilaurate(DBTL) as control was also used. Hard segment components of polyurethane foams were obtained by a selective degradation of polyester chains with 0.01N KOH-methanol solution. The PUFs with DBU catalyst contained more amount of isocyanurate components than other PUFs. On the other hand, the PUFs with ET, MR, DBTL catalysts contained more amount of allophanate and biuret component than the other PUFs.

• Journal of the Korea Institute of Information Security & Cryptology
• /
• v.24 no.1
• /
• pp.241-259
• /
• 2014

A PUF is a technology for distinguishing a device from other devices like biological information such as humans' iris or fingerprints. Over the past decade, many researchers studied various methods for implementing PUFs and utilizing them in identification, random number generation, key distribution and authentication. However, various attacks on the PUFs are the major reason to inhibiting the proliferation of PUF. For the reasons, various technologies are being studied to enhance safety of PUFs. In this paper, we will see several PUF implementations and various attacks on PUFs, and suggest guidelines for securely implementing PUFs. We expect our guidelines would be the foundation for implementing the secure and reliable PUFs.

• The Journal of Korean Institute of Communications and Information Sciences
• /
• v.38B no.6
• /
• pp.492-500
• /
• 2013

The One-Time Password(OTP) Generator is used as a multi-factor authentication method to ensure secure transaction during e-Financial transaction in the bank and securities company. The OTP based e-Financial Transaction Verification Protocol ensures secure e-financial transaction through confirming the user's identity using OTP authentication information and counters not only Man-in-the-Browser(MITB) attacks but also memory hacking attacks. However, it is possible to generate correct OTPs due to potential of stealing sensitive information of the OTP generator through intelligent phishing, pharming, social engineering attacks. Therefore, it needs another scheme to prevent from above threats, and this paper proposes advanced scheme using Physical Unclonable Functions(PUFs) to solve these problems. First, it is impossible to generate the same OTP values because of the hysically unclonable features of PUFs. In addition, it is impossible to clone OTP generator with hardware techniques. Consequently, the proposed protocol provides stronger and more robust authentication protocol than existing one by adding PUFs in the OTP generator.

• Convergence Security Journal
• /
• v.23 no.5
• /
• pp.143-150
• /
• 2023

Applications on physically unclonable circuits (PUFs) for implementing and utilizing security protocols with hardware is on the rise. PUFs have the capability to perform functions such as authentication, prevention of replication, and secure storage of critical information in integrated circuits and security systems. Through the implementation of physically unclonable circuits, a wide range of security features, including confidentiality, integrity, and availability, can be applied. Therefore, PUFs are promising candidate to build secure integrated circuits and hardware systems. However, in order that PUFs possess security features, PUFs should possess characteristics such as unpredictability, uniqueness, and robustness characteristics. This study provides a detailed explanation and introduction of the methods to characterize the PUF properties. By applying the results, it becomes possible to quantitatively evaluate the characteristics of implemented PUFs and assess their availabilities for security system applications.

• Journal of the Korean Institute of Gas
• /
• v.9 no.1 s.26
• /
• pp.16-20
• /
• 2005

CFC-11 and HCFC-l4lb have been used as blowing agents for rigid polyurethane foam insulation of LNG storage tank. But CFC-11 and HCFC- l4lb deplete ozone layer in the stratosphere. So in leading countries, the use of CFC-11 has been prohibited since 1995 and the use of HCFC-l4lb will be prohibited from 2005. Much efforts and studies have been done about alternative blowing agents and insulations blown by alternative blowing agents. This paper deals with polyurethane foams (PUFs) blown by HFC-365mfc, shows their physical and mechanical characteristics and thermal performance. These data are compared with the results of PUFs blown by HCFC-l4lb. From these test results, PUFs blown by HFC-365mfc show good mechanical and thermal characteristics. It is possible to use PUFs blown by HFC-365mfc as main insulation of membrane type LNG storage tank.

• Journal of the Korean Institute of Gas
• /
• v.8 no.2 s.23
• /
• pp.1-7
• /
• 2004

The physical properties of rigid polyurethane foam(PUF) synthesized using various types of blowing agents such as water, HFC-365mfc, HFC-245fa, HCFC-l4lb, CFC-11 and n-pentane were studied. The blending effect of blowing agents were also studied. The thermal conductivity, reaction rate, and cell morphology of the PUF with various blending ratio of blowing agents were investigated. The PUF blown by water shows the highest compressive strength among other single blowing agents. The thermal conductivity of PUFs blown by HFC-245fa and HFC-365mfc are close to that of PUFs blown by CFC-11. When HFC-365mfc was mixed with HFC-245fa(30mo1e$\%$) as coblowing agent, the mechanical property shows the highest value among other coblowing agents. It is that the thermal conductivity of PUFs depends on cell size of PUFs as well as thermal conductivity of blowing agent in gaseous form.

• Proceedings of the Polymer Society of Korea Conference
• /
• 2006.10a
• /
• pp.373-373
• /
• 2006

Rigid polyurethane foams(PUFs) are widely used in most areas of insulations such as storage tank and pipe line for transporting liquefied gas. Glass fiber and nanoclay are used for improvement in mechanical property and thermal insulation of rigid PUF at very low temperature(<$-150^{\circ}C$). These rigid PUFs have been characterized in terms of thermal, mechanical, dynamic mechanical properties and cell morphology. It was found that mechanical properties, thermal conductivity and dimensional stability of rigid PU foams were improved by glass fiber and nanoclay.

• ETRI Journal
• /
• v.42 no.2
• /
• pp.205-216
• /
• 2020

An arbiter physical unclonable function (APUF) has exponential challenge-response pairs and is easy to implement on field-programmable gate arrays (FPGAs). However, modeling attacks based on machine learning have become a serious threat to APUFs. Although the modeling-attack resistance of an MA-APUF has been improved considerably by architecture modifications, the response generation method of an MA-APUF results in low uniqueness. In this study, we demonstrate three design problems regarding the low uniqueness that APUF-based strong PUFs may exhibit, and we present several foundational principles to improve the uniqueness of APUF-based strong PUFs. In particular, an improved MA-APUF design is implemented in an FPGA and evaluated using a well-established experimental setup. Two types of evaluation metrics are used for evaluation and comparison. Furthermore, evolution strategies, logistic regression, and K-junta functions are used to evaluate the security of our design. The experiment results reveal that the uniqueness of our improved MA-APUF is 81.29% (compared with that of the MA-APUF, 13.12%), and the prediction rate is approximately 56% (compared with that of the MA-APUF (60%-80%).