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PU Midsole용 수성세정제의 성능향상을 위한 첨가제의 영향에 관한 연구

  • Jeong, Gap-Seop;Na, Seok-Eun
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2005.05a
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    • pp.316-318
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    • 2005
  • PU midsole세척용 수성세정제로서 Ester구조를 가진 비이온성 계면활성제를 사용하여 limonene을 유화분산하고, 첨가제의 영향을 검토하여 세정효과를 측정한 결과 계면활성제의 사용은 1${\sim}$1.5wt%, limonene은 30wt%의 범위에서 emulsion입경이 최소로서 가장 좋았다. 접착증진제(CR)와 세척향상제(LD)를 합성하고 첨가효과를 검토한 결과 일정 첨가량 이하에서 세정력이 증가하였으며, 두 첨가제를 동시에 적용하여 synergy효과를 확인하였다. 초적의 첨가조건은 CR과 LD를 각각 5wt%와 2wt% 동시 첨가하는 경우로서 세정성능이 40%정도 증가하였다.

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Blood Compatibility of Polyurethane-poly(vinyl alcohol) Polymer Blends (폴리우레탄-폴리비닐알콜 블렌드의 혈액적합성)

  • 김승수;유영미;신재섭;정규식
    • Polymer(Korea)
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    • v.24 no.1
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    • pp.82-89
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    • 2000
  • The blood compatibilities of PU/PVA polymer blends with different mixing ratios were evaluated using various methods, such as fibrinogen adsorption, plasma recalcification time, platelet adhesion, whole blood clotting time, and complement activation. In addition, PVA on the surface of the polymer blends was crosslinked by glutaraldehyde to restrain the mobility of PVA molecules for characterizing the effect of PVA in the polymer blends on blood compatibility. The fibrinogen adsorption on the polymer blends decreased with the increase of PVA amount in the polymer blends. The plasma recalcification times of the polymer blends with 10-50 wt% PVA were longer than those of PU, PVA, and polymer blends with higher amount of PVA. The morphological changes and adhesion of platelets on the polymer blends with 30-50 wt% PVA were less than those on the other materials. The blood clotting times and complement activation on the polymer blends with 30-50 wt% PVA were reduced, compared to the other materials. On the other hand, the blood compatibility of the crosslinked polymer blends was relatively decreased, compared to the non-crosslinked ones. According to these experimental results, the blood compatibility of the polymer blends with 30-50 wt% PVA was better than that of the other materials and such a blood compatibility of the polymer blends might be related to the mobility of PVA molecules on the surface.

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Changing Relation of Science and Public: The Main Approaches to Public Understanding of Science(PUS) (과학과 대중의 관계 변화 - 대중에 대한 인식 변화를 중심으로)

  • Kim Dong-Kwang
    • Journal of Science and Technology Studies
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    • v.2 no.2 s.4
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    • pp.1-23
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    • 2002
  • This Article examines the main approaches to the public understanding of science(PUS) in light of the changing relation of science and public. Traditional approach called deficit model recognizes scientific knowledge as a entity, unidirectionally diffusing to public. This View basically presupposes the gap between science and public. Meanwhile, this approach has an aspiration to reduce the gap. So there is a paradoxical situation in the traditional PUS. Public perception of environmental crisis and risk of science has been risen since late 1980's. And the science technology studies (STS) have criticized traditional approach. STS proposes new approach of constructive PUS. Constructive PUS conceives the public to have heterogeneous, local characteristic. This approach has been very fertile both in theory and practice. But most recently, newly proposed approach, so called heterogeneous PUS, criticizes constructive PUS. Main point of criticism is that constructive PUS has dichotomy between science and public, and romanticizes the public. It is uncertain whether heterogeneous PUS can take place of constructive PUS. But this trend has the implication that the relation of science and public is constantly changing.

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Spatial Correlation Based Fast Coding Depth Decision and Reference Frame Selection in HEVC (HEVC의 공간적 상관성 기반 고속 부호화 깊이 및 참조영상 결정 방법)

  • Lee, Sang-Yong;Kim, Dong-Hyun;Kim, Jae-Gon;Choi, Hae-Chul;Kim, Jin-Soo;Choi, Jin-Soo
    • Journal of Broadcast Engineering
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    • v.17 no.5
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    • pp.716-724
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    • 2012
  • In this paper, we propose a fast decision method of maximum coding depth decision and reference frame selection in HEVC. To reduce computational complexity and encoding time of HEVC, two methods are proposed. In the first method, the maximum depth of each coding unit (CU) in a largest CU (LCU) is constrained by using the maximum coding depth used by adjacent LCUs based on the assumption that the spatial correlation is very high and rate-distortion (R-D) cost. And we constrain the number of reference pictures for prediction unit (PU) performing motion estimation by using the motion information of the upper depth PU. The proposed methods reduce computational complexity of the HEVC encoder by constraining the maximum coding depth and the reference frame. We could achieve about 39% computational complexity reduction with marginal bitrate increase of 1.2% in the comparison with HM6.1 HEVC reference software.

Kinetics of Metolachlor Degradation by Zerovalent Iron (Zerovalent Iron에 의한 Metolachlor의 분해 Kinetics)

  • Kim, Su-Jung;Oh, Sang-Eun;Yang, Jae-E.
    • Korean Journal of Environmental Agriculture
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    • v.26 no.1
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    • pp.55-61
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    • 2007
  • Metolachlor may pose a threat to surface and ground water qualities due to its high solubility in water, Zerovalent iron (ZVI) releases $e^-$ which can degrade the organochlorinated compounds. The objective of this research was to evaluate the kinetics of metolachlor degradation as affected by ZVI sources [Peerless unannealed (PU) and Peerless annealed (PA)] and ZVI levels (1 and 5%) under batch conditions at different metolachlor concentrations (200 and 1000 mg/l) and temperatures (15, 25, and $35^{\circ}C$). The effectiveness of ZVI on metolachlor degradation was assessed by characterizing the dechlorinated metolachlor byproduct molecules. Metolachlor degradation by ZVI followed the first-ordered kinetics with a higher rate constant at higher level of ZVI treatment. At 5% (w/v) of PU and PA treatment, the half-lives of metolachlor degradation were 9.93 and 6.51 h and all of the initial metolachlor were degraded in 72 and 48 h, respectively. Rate constants (k) of metolachlor degradation were higher at the lower initial metolachlor concentration. The metolachlor degradation by ZVI was temperature dependent showing that the rate constant (k) at 15, 25, and $35^{\circ}C$ were 0.0805, 0.1017, and 0.3116 /h, respectively. The ZVI-mediated metolachlor degradation yielded two byproduct molecules identified as dechlorinated metolachlor $(C_{13}H_{18}NO)$ and dechlorinated-dealkylated metolachlor $(C_{12}H_{17}NO)$. The PA ZVI was more effective than PU ZVI in metolachlor degradation.

Antibacterial Properties of PU/$TiO_2$ Hybrid membrane Films after Photodepositing of Silver (은(Ag) 광증착에 의한 폴리우레탄/$TiO_2$ 하이브리드 멤브레인 필름의 항균특성)

  • Cho, Seong-Min;Min, Byung-Gil;Ji, Kwang-Hwan
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.50-50
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    • 2012
  • 투습방수필름으로 많이 사용되고 있는 폴리우레탄(PU)에 광촉매 기능성을 가지고 있는 나노-$TiO_2$(Degussa P25)를 1~10wt% 복합시킨 후, 은(Ag)이온 수용액에서 자외선 조사에 의한 광증착시키는 과정을 거쳐 은이 도핑된 PU/$TiO_2$/Ag 하이브리드 멤브레인 필름을 제조하였다. (주)비에스지에서 제공받은 PU/DMF/MEK 용액에 $TiO_2$를 초음파로 균일하게 분산배합한 후, 필름캐스팅하여 만든 필름을 AgNO3 수용액에 침지시키고 254nm의 자외선을 30~120초 동안 조사하는 광증착법으로 은을 환원시켜 도핑시켰다. 은 도핑된 하이브리드 필름을 Shaking flask method에서 폐렴간균, 황색포도상구균에 대한 항균성을 측정하고, Clear zone method에서 대장균에 대한 항균성을 측정한 결과, $TiO_2$ 함량이 3wt% 이상이고 UV조사시간이 60초 이상인 경우 99.9% 이상의 항균성을 나타내는 것을 확인하였다.

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Devloping Chcory for Forage Crop by New Technology (새로운 기법에 의한 치코리 (Cichorium intybus L.) 의 사료화에 관한 연구)

  • 허삼남;박홍석
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.15 no.4
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    • pp.265-273
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    • 1995
  • Seeds of chicory were collected and selected with good germination, emergence and productivity. To develop chicory as a new forage crop seeds were primed with polyethylene glycol (PEG 6000) and coated with some chemicals, and tested in laboratory and field. The results obtained are summarized as follows: 1. Among the seed lines collected, PUlgAH, PU21TH, PU37CH and PU30TK were germinated more quickly and took less time for germination than the others. 2. PUI8AH was the best in emergence and growth although PU21TH showed superior germinative ability among the lines collected. 3. Chicory seeds primed with 20~25% PEG solution for three days at $10^{\circ}C$, or the seeds treated with 25% PEG solution at $15^{\circ}C$ regardless the treatment period showed good germination performances. 4. Osmotic priming with PEG accelerated the germination of chicory, but not in the field. 5. Coated seeds geminated more slowly in Petridishes but showed superior emergence and growth to those of primed or untreated seeds. Treatment 3 showed the best performances in pot experiment. 6. Coated seeds showed remarkable increase in establishment and dry matter yield especially in sod sowing compared to the other sowing method. 7. Most nutrient contents except iron and manganese of chicory were much higher than those of mixed pasture .

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Critical Factors for Acceptance of Social Commerce: A Case Study in Oman

  • FAROOQUE, Murtaza;ALMARHOON, Shahrazad;ALHARIZI, Shamma;MOHAMMED, Aref
    • The Journal of Asian Finance, Economics and Business
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    • v.8 no.5
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    • pp.657-665
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    • 2021
  • The study aims to assess the acceptance of social commerce and participate in social commerce amongst Omani people. The questions of the survey Instrument were prepared in English later converted into Arabic. The survey instrument was having two parts; the first part sought the demographic information like age, gender, education, occupation etc. The second part of the instrument was related to the variables, which was in 5-point Likert scale, where 5 means strongly agree while 1 meaning strongly disagree. The data was collected using online and offline surveys, making the number of the valid responses to 478. A conceptual model was developed using the following variables. The selected variables such as "Familiarity" (F), "Trust" (T), "Perceived usefulness" (PU), "Perceived ease of use" (PEU), "Intention to Purchase" (IP). The hypothesis was tested using structural equation modelling. The results indicate that all six hypotheses were supported. The F, T and PEU, and PU was found to be positive and significant related to intention to purchase (p-value 0.003, 0.001, 0.000. & 0.007). Amongst the four, p value of F was found to be the lowest and PU was found to be the highest. This indicate F was strong indicator of IP as compared to others. PUE relates to PU, and F was related to IP.

Effect of 3-Isocaynatopropyl Triethoxy Silane on PU Adhesive (3-Isocaynatopropyl Triethoxy Silane이 PU 접착제에 미치는 영향)

  • Ju, Honghee;Jang, Euisub;Park, Chan Young;Lee, Won-Ki;Kim, Taekyun;Chun, Jae-Hwan
    • Journal of Adhesion and Interface
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    • v.14 no.1
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    • pp.36-42
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    • 2013
  • To improve hydrolytic stability of polyurethane (PU) adhesives, a silane coupling agent (SCA) was added. 3-Isocyanatopropyl triethoxy silane (ITS) as a SCA has two functional groups in the main chain and it is used to improve an interfacial interaction between polymer and inorganic material or metal. In this study, PU adhesives with different amounts of ITS from 0 to 1 wt% were synthesized. Pot time, modulus, thermal stablilty, and adhesive force of the obtained samples were measured. The results showed that the adhesives with ITS showed better properties than that of pure one.

Synthesis and Physical Properties of Waterborne Polyurethane Microgels (수분산성 폴리우레탄 마이크로겔의 합성과 물성)

  • Kim, Kong-Soo;Kim, Tae-Kyung;Oh, Geul-Jung;Kim, Sang-Ki
    • Elastomers and Composites
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    • v.35 no.4
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    • pp.281-287
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    • 2000
  • Waterborne polyurethane(PU) microgel dispersions were synthesized with different mole ratio of polytetramethylene glycol(PTMG) to dimethylol propionic acid(DMPA). Particle size distribution, thermal and mechanical properties of the PU microgels were investigated. Particle size of the microgels was distributed in the range of $98{\sim}$680{\mu}m$ and decreased with increasing the mole ratio of DMPA and 1,2,6-hexanetriol. Glass transition temperature and melting temperature of the microgels were in the range of $-79.7 {\sim}-78.1^{\circ}C$, $22{\sim}24^{\circ}C$ respectively. Tensile strength and elongation of the PU microgel films were maximum in the case of 60/40 mole ratio of PTMG/DMPA.

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