• Title/Summary/Keyword: PSC

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ZnO-free Inverted Polymer Solar Cells Based on New Viologen Derivative as a Cathode Buffer Layer (ZnO를 대체 가능한 새로운 Viologen 유도체가 적용된 역구조 고분자 태양전지)

  • Kim, Youn Hwan;Kim, Dong Geun;Kim, Joo Hyun
    • Applied Chemistry for Engineering
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    • v.27 no.5
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    • pp.512-515
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    • 2016
  • A new viologen derivative namely 1,1'-bis(3,4-dihydroxybutyl)-[4,4'-bipyridine]-1,1'-diium bromide (V-Pr-2OH) was synthesized and applied as a cathode buffer layer to inverted polymer solar cells (PSCs) based on the blend of PTB7 : $PC_{71}BM$. PSCs with the structure of ITO/V-Pr-2OH/PTB7 : $PC_{71}BM/MoO_3/Ag$ as the cathode buffer layer showed the power conversion efficiency (PCE) up to 7.28%, which is comparable to that of the PSCs with the structure of ITO/ZnO/PTB7 : $PC_{71}BM/MoO_3/Ag$ (7.44%) in the absence of V-Pr-2OH. This study demonstrates that a highly efficient PSCs without any high temperature heat treatment can be obtained.

Performance Evaluation of Structure Strengthening Using Sprayed FRP Technique (분사식 FRP공법을 이용한 구조물 보강 성능평가)

  • Chang, Chun-Ho;Jang, Kwang-Seok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.13 no.4 s.56
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    • pp.126-136
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    • 2009
  • The sprayed FRP strengthening technique is combining the Glass fiber and Polyester resin in open air and spraying randomly at concrete's surface with high-speed compressed air. Then it strengthens the structures with a new technique evaluated the structural performance. We applied it to concrete beam and tested for flexural strength, depended on Korea Standard(KS F 2408). Then based on the result of flexural strength, the properties were proposed that applying to structures. Based on the experiment, we have evaluated structural performance by the experiment. 1/5 scale prestressed concrete I-beam were made by Korean Highway's typical drawing in 1993. With these test results, 49.8% increased in flexural strength, improvement of the behavior of serviceability state, and strengthening was surely effective for controlling deflection and crack of structure. Consequently, it can be summarized that Sprayed FRP technique has prospect to improve the performance of structure.

Application of Acoustic Emission Technique for Bridge Cable Monitoring (교량 케이블 적용 강연선 모니터링을 위한 음향방출 기법 검토)

  • Kim, Ga-Young;Seo, Dong-Woo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.4
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    • pp.121-125
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    • 2018
  • This paper presents the assessment of 7-wire strand monitoring using acoustic emission technique for bridges. 7-wire strand is widely used construction materials to provide additional tensile force to bridges. PSC (PreStressed Concrete) bridge and cable-stayed bridge are representatives for such cases. However, as the bridge aging progresses recently, corrosion problems of strand are emerging. For this reason, various NDT (Non-Destructive Test) methods for cable inspection are being studied and applied to the field. One of the NDT methods, acoustic emission technique, is known as an effective technique to detect cable damage and breakage. In this study, to evaluate the applicability of acoustic emission technique to bridges, acoustic emission signals according to damage of the strand were acquired and analyzed by tensile test. Moreover, The optimal AE sensor type was selected for field application. As a result, it is considered that the acoustic emission technique will be able to detect corrosion breakage and signs of rupture.

Comparison of Electrical Conductivities in Complex Perovskites and Layered Perovskite for Cathode Materials of Intermediate Temperature-operating Solid Oxide Fuel Cell (중·저온형 고체산화물 연료전지 공기극 물질로 사용되는 이중층 페로브스카이트와 컴플렉스 페로브스카이트의 전기 전도도 비교)

  • Kim, Jung Hyun
    • Journal of the Korean Ceramic Society
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    • v.51 no.4
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    • pp.295-299
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    • 2014
  • Electrical conductivities of complex perovskites, layered perovskite and Sr doped layered perovskite oxides were measured and analyzed for cathode materials of Intermediate Temperature-operating Solid Oxide Fuel Cells (IT-SOFCs). The electrical conductivities of $Sm_{1-x}Sr_xCoO_{3-\delta}$ (x = 0.3 and 0.7) exhibit a metal-insulator transition (MIT) behavior as a function of temperature. However, $Sm_{0.5}Sr_{0.5}CoO_{3-\delta}$ (SSC55) shows metallic conductivity characteristics and the maximum electrical conductivity value compared to the values of $Pr_{0.5}Sr_{0.5}CoO_{3-\delta}$ (PSC55) and $Nd_{0.5}Sr_{0.5}CoO_{3-\delta}$ (NSC55). The electrical conductivity of $SmBaCo_2O_{5+\delta}$ (SBCO) exhibits a MIT at about $250^{\circ}C$. The maximum conductivity is 570 S/cm at $200^{\circ}C$ and its value is higher than 170 S/cm over the whole temperature range tested. $SmBa_{0.5}Sr_{0.5}Co_2O_{5+\delta}$ (SBSCO), 0.5 mol% Sr and Ba substituted at the layered perovskite shows a typically metallic conductivity that is very similar to the behavior of the SSC55 cathode, and the maximum and minimum electrical conductivity in the SBSCO are 1280 S/cm at $50^{\circ}C$ and 280 S/cm at $900^{\circ}C$.

Effect of Self-Assembled Monolayer Treated ZnO on the Photovoltaic Properties of Inverted Polymer Solar Cells

  • Yoo, Seong Il;Do, Thu Trang;Ha, Ye Eun;Jo, Mi Young;Park, Juyun;Kang, Yong-Cheol;Kim, Joo Hyun
    • Bulletin of the Korean Chemical Society
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    • v.35 no.2
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    • pp.569-574
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    • 2014
  • Inverted bulk hetero-junction polymer solar cells (iPSC) composed of P3HT/PC61BM blends on the ZnO modified with benzoic acid derivatives-based self-assembled monolayers (SAM) are fabricated. Compared with the device using the pristine ZnO, the devices with ZnO surface modified SAMs derived from benzoic acid such as 4-(diphenylamino)benzoic acid (DPA-BA) and 4-(9H-carbazol-9-yl)benzoic acid (Cz-BA) as an electron transporting layer show improved the performances. It is mainly attributed to the favorable interface dipole at the interface between ZnO and the active layer, the eective passivation of the ZnO surface traps, decrease of the work function and facilitating transport of electron from PCBM to ITO electrode. The power conversion eciency (PCE) of iPSCs based on DPA-BA and Cz-BA treated ZnO reaches 2.78 and 2.88%, respectively, while the PCE of the device based on untreated ZnO is 2.49%. The open circuit voltage values ($V_{oc}$) of the devices with bare ZnO and SAM treated ZnO are not much different. Whereas, higher the fill factor (FF) and lower the series resistance ($R_s$) are obtained in the devices with SAMs modification.

Verified 20-car Model of High-speed Train for Dynamic Response Analysis of Railway Bridges (검증된 고속철도 차량의 20량편성 정밀모형에 의한 철도교량의 동적응답 분석)

  • 최성락;이용선;김상효;김병석
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.15 no.4
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    • pp.693-702
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    • 2002
  • The aim of this study is to develop a 3-dimensional dynamic analysis model, capable of considering the interaction between vehicles and bridges more accurately. The dynamic analysis model is developed with the high-speed train (KTX) and a 2-span continuous prestressed concrete box girder bridge with a double track. The 20-car model is developed using the moving vehicle model for the regular trainset. Three-dimensional frame elements are used for the bridge model. Using the developed models, a dynamic behavior analysis program is coded. The analytical results are compared with the dynamic field test results and found to be valid to yield quite accurate dynamic responses. Based on the results of this study, the hybrid model, made up of the moving vehicle model for the heaviest power car and the moving force model for the other cars, is quite simple and effective without loosing the accuracy that much. Under the coincidence condition of two trains traveling with resonance velocity in the opposite directions, it is necessary to check not only the dynamic responses of the bridge with one-way traffic but those with two- way coincidence.

The Impacts of Project Governance, Agency Conflicts on the Project Success : From the Perspective of Agency Theory (프로젝트 거버넌스가 대리인 갈등 및 프로젝트 성공에 미치는 영향 : 대리인 이론 관점)

  • Jeong, Eun-Joo;Kim, Bo-Ram;Jeong, Seung-Ryul
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.41 no.3
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    • pp.11-20
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    • 2018
  • Recently companies have increased the new projects to improve and innovate the business process in order to adopt the advanced technologies such as IoT (Internet of Things), Big Data Analysis, Cloud Computing, mobile and artificial intelligence technologies for sustainable competitive advantages under rapid technological and socioeconomic external environmental changes. However, there are obstacles to achieve the project goals, corporate's strategy and objectives due to various kind of risks based on characteristics of projects and conflicts of stakeholders participated on projects. Hence, the solutions are required to resolve the various kind of risks and conflicts of stakeholders. The objectives of this study are to investigate the impact of the project governance, agency conflicts on the project success based on agency theory by using the statistical hypothesis testing the relationship among those variables. As a result of hypothesis testing, we could find that the project governance impacts positively on project success and negatively on the agency conflicts. Further, the agency conflicts impacts negatively on the project success. Finally, we could find that the agency conflicts such as goal conflict, different risk attitude and information asymmetry between project manager and team members impact negatively on the project success. Meanwhile, the project governance impact positively on the project success, negatively impact on the agency conflicts such as goal conflict, different risk attitude and information asymmetry between project manager and project team members. In order to increase the project success rate, the project governance institutions such as PGB (Project Governance Board), EPMO (Enterprise Project Management Office), PSC (Project Steering Committee) are needed to prevent or reduce the agency conflicts between project manager and team members.

Effect of Valproic acid, a Histone Deacetylase Inhibitor, on the Expression of Pluripotency and Neural Crest Specific Marker Genes in Murine Multipotent Skin Precursor Cells

  • Hong, Ji-Hoon;Park, Sang-Kyu;Roh, Sang-Ho
    • International Journal of Oral Biology
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    • v.35 no.4
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    • pp.209-214
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    • 2010
  • Cells that have endogenous multipotent properties can be used as a starting source for the generation of induced pluripotent cells (iPSC). In addition, small molecules associated with epigenetic reprogramming are also widely used to enhance the multi- or pluripotency of such cells. Skinderived precursor cells (SKPs) are multipotent, sphereforming and embryonic neural crest-related precursor cells. These cells can be isolated from a juvenile or adult mammalian dermis. SKPs are also an efficient starting cell source for reprogramming and the generation of iPSCs because of the high expression levels of Sox2 and Klf4 in these cells as well as their endogenous multipotency. In this study, valproic acid (VPA), a histone deacetylase (HDAC) inhibitor, was tested in the generation of iPSCs as a potential enhancer of the reprogramming potential of SKPs. SKPs were isolated from the back skins of 5-6 week old C57BL/6 X DBA/2 F1 mice. After passage 3, the SKPs was treated with 2 mM of VPA and the quantitative real time RT-PCR was performed to quantify the expression of Oct4 and Klf4 (pluripotency specific genes), and Snai2 and Ngfr (neural crest specific genes). The results show that Oct4 and Klf4 expression was decreased by VPA treatment. However, there were no significant changes in neural crest specific gene expression following VPA treatment. Hence, although VPA is one of the most potent of the HDAC inhibitors, it does not enhance the reprogramming of multipotent skin precursor cells in mice.

Runtime Prediction Based on Workload-Aware Clustering (병렬 프로그램 로그 군집화 기반 작업 실행 시간 예측모형 연구)

  • Kim, Eunhye;Park, Ju-Won
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.38 no.3
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    • pp.56-63
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    • 2015
  • Several fields of science have demanded large-scale workflow support, which requires thousands of CPU cores or more. In order to support such large-scale scientific workflows, high capacity parallel systems such as supercomputers are widely used. In order to increase the utilization of these systems, most schedulers use backfilling policy: Small jobs are moved ahead to fill in holes in the schedule when large jobs do not delay. Since an estimate of the runtime is necessary for backfilling, most parallel systems use user's estimated runtime. However, it is found to be extremely inaccurate because users overestimate their jobs. Therefore, in this paper, we propose a novel system for the runtime prediction based on workload-aware clustering with the goal of improving prediction performance. The proposed method for runtime prediction of parallel applications consists of three main phases. First, a feature selection based on factor analysis is performed to identify important input features. Then, it performs a clustering analysis of history data based on self-organizing map which is followed by hierarchical clustering for finding the clustering boundaries from the weight vectors. Finally, prediction models are constructed using support vector regression with the clustered workload data. Multiple prediction models for each clustered data pattern can reduce the error rate compared with a single model for the whole data pattern. In the experiments, we use workload logs on parallel systems (i.e., iPSC, LANL-CM5, SDSC-Par95, SDSC-Par96, and CTC-SP2) to evaluate the effectiveness of our approach. Comparing with other techniques, experimental results show that the proposed method improves the accuracy up to 69.08%.

Parallel Nonlinear Analysis of Prestressed Concrete Frame on Cluster System (클러스터 시스템에서 프리스트레스트 콘크리트 프레임의 병렬 비선형해석)

  • 이재석;최규천
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.14 no.3
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    • pp.287-298
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    • 2001
  • Analysis of nonlinear behavior of prestressed concrete frame structures on PC is a time-consuming computing job if the problem size increase to a certain degree. Cluster system has emerged as one of promising computing environments due to its good extendibility, portability, and cost-effectiveness, comparing it with high-end work-stations or servers. In this paper, a parallel nonlinear analysis procedure of prestressed concrete frame structure is presented using cluster computing. Cluster system is configured with readily available pentium III class PCs under Win98 or Linux and fast ethernet. Parallel computing algorithms on element-wise processing parts including the calculation of stiffness matrix, element stresses and determination of material states, check of material failure and calculation of unbalanced loads are developed using MPL. Validity of the method is discussed through typical numerical examples. For the case of 4 node system, maximum speedup is 3.15 and 3.74 for Win98 and Linux, respectively. Important issues for the efficient use of cluster computing system based un PCs and ethernet are addressed.

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