• Title/Summary/Keyword: PS-7

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Liquefaction Characteristics of HDPE, PP and PS by Isothermal Pyrolysis (HDPE, PP 및 PS의 등온열분해에 의한 액화 특성)

  • Yu, Hong-Jeong;Park, Su-Yul;Lee, Bong-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.3
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    • pp.198-205
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    • 2002
  • Isothermal pyrolysis of high density polyethylene(HDPE), polypropylene(PP) and polystyrene(PS) was performed at $450^{\circ}C$, respectively. The effect of pyrolysis time on yield and product composition was investigated. Conversion and liquid yield obtained during HDPE pyrolysis continuously increased with time up to 80minutes, but those of PP and PS did not largely change after 35minutes. Each liquid product formed during the pyrolysis was classified into gasoline, kerosene, light oil and wax according to the distillation temperature based on the petroleum product quality standard of Korea Petroleum Quality Inspection Institute. The major liquid product of HDPE pyrolysis was light oiH34 wt.% based on the amount of HDPE treated) and the amounts of the other liquid ingredients(gasoline, kerosene and wax) were almost the same. On the other hand, the pyrolysis of PP produced 27 wt.% gasoline, 22 wt.% kerosene, 24 wt.% light oil and 13wt.% wax, and the pyrolysis of PS produced 56 wt.% gasoline, 12 wt.% kerosene, 9 wt.% light oil and 13 wt.% wax.

Structure-Activity Relationships of Peptide Antibiotics with Improved Bacterial Cell Selectivity of Pseudin

  • Lee, Yeongjoon;Jeon, Dasom;Kim, Jin-Kyoung;Kim, Yangmee
    • Journal of the Korean Magnetic Resonance Society
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    • v.21 no.3
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    • pp.78-84
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    • 2017
  • Pseudin is a naturally occurring 24 amino-acid-residue antimicrobial peptide derived from the skin of paradoxical frog Pseud's paradoxa. It shows potency against the bacteria and antibiotic-resistant bacteria strain, but has high cytotoxicity against mammalian cell. In our previous study, substitution of $Pro^{11}$ for Gly (Ps-P) increased bacterial cell selectivity but decreased the antibacterial activity of pseudin. In this study, we designed pseudin analogue, Ps-4K-P with increased cationicity up to +7 in Ps-P by substituting Glu14, Gln10, Gln24, and Leu18 with Lys. Ps-4K-P showed improved potent antibacterial activity with high bacterial cell selectivity. We determined the tertiary structure of Ps-4K-P in the presence of DPC micelles by NMR spectroscopy and it has a hinge structure at $Pro^{11}$ followed by three turn helices from $Pro^{11}$ to $Val^{23}$ at the C-terminus. Amphipathicity with increased cationicity as well as helix-hinge-helix structural motif provided by introduction of a Pro at position $Gly^{11}$ are the crucial factors which confer antibacterial activity with bacterial cell selectivity to Ps-4K-P.

Effect of Incorporation Rate of Polyacrylamide Hydrogel on Changes in Chemical Properties of Root Media (Polyacrylamide 고흡수성 수지의 혼합 비율이 상토의 화학성에 미치는 영향)

  • Wang, Hyun-Jin;Choi, Jong-Myung;Lee, Jong-Suk
    • Journal of Bio-Environment Control
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    • v.14 no.3
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    • pp.190-195
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    • 2005
  • This research was conducted to investigate the changes in soil chemical properties of root media as influenced by incorporation rate of a polyacryl amide hydrogel, Stocksorb C. The pH at 5 weeks after treatment in four root media such as peatmoss + vermiculite (1:1, v/v; PV), peatmoss + composted rice hull (1:1; PR), peatmoss + composted saw dust (1:1; PD) and peatmoss + composted pine bark (1:1; PB) containing STSB were in the range from 7.04 to 7.30, which was too high. Elevated incorporation rate of STSB resulted in increase of EC in soil solution of four root media with linear and quadratic response. The concentrations of $NH_4^+-N,\;NO_3^--N,\;PO_4-P^{3-},\;K^+,\;Ca^{2+}and\;Mg^{2+}$ in four kinds of root media increased as incorporation rates of STSB were elevated. But the $NO_3^-$-N concentrations in PS media were lower than those in other there root media tested. The Fe concentrations in PV, PR and PS media increased as incorporation rates of STSB were elevated, but those in PB medium did not show significant different. The concentrations of $Fe^{2+},\;Mn^{2+},\;Zn^{2+}and\;Cu^{2+}$ in PS media were higher than those in other three root media.

Diminution of Pesticide Residues on Crops and Soil by Accelerated Photolysis (광분해(光分解) 촉진(促進)에 의한 작물(作物) 및 토양중(土壤中) 농약잔유물(農藥殘留物)의 경감(輕減)에 관한 연구(硏究))

  • Lee, Jae-Koo;Jung, In-Sang;Kwon, Jeong-Wook;Ahn, Ki-Chang
    • Korean Journal of Environmental Agriculture
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    • v.17 no.2
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    • pp.107-116
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    • 1998
  • In an effort to reduce artifically the residual pesticides on crop and soil by accelerated photolysis,some 40 among the naturally occurring and synthetic coumpound were screened for photosensitization and/or photocatalysis and six promising chemicals were selected.The fungicides and the four selected photosensitizers and/or photocatalyst (PS) were applied to each crop.The results obtained are summarized as follows. 1. The wavelengths of maximum absortion (${\lambda}$max) and the molar absorptivites (${\varepsilon}$max) of procymidone,vinclozolin,and carbendazim in acentone were all 209 nm and 853,854,and 8740 respectively. 2. Of the 40 naturally-occuring and synthetic compounds screened,six promising ones were selected and designated as PS-1 (aromatic ketone),PS-2(aromatic amine)PS-3(quinone) ,PS-4 (inorganic compound),PS-5(organic acid salt) and PS-6(semiconductor photocatalyst). 3. In the accelerated photolysis of pesticide in soil by applying PS ,procymidone was decoposed rapidly by virtue of PS-2,being 59% of the control 3 days after application. 4. The vinclozolin residue in soil was reduced to 71% and 21% of the control 1 and 15 days,respectively,after PS-2 application. 5. The photolysis of carbendazim in soil was not accelerated by any of the PS tested. 6. The pesticide residues on the crop were prominently reduced by PS application.The procymidone residue on tomato was reduced to 47% of the control 15 days after PS-1 application and that on red pepper reduced to 57% 15 days after PS-2 application. 7. Vincrozolin residus remaining on tomato 1 and 15 days after PS-2 application were 38% and 56% of the control whereas those on the red pepper were 82% and 64%,respectively. 8. PS-2 was the most effective for the accelerated photolysis of carbendazim residues remaining on tomato, whereas on red pepper, the four of PS tested were all effective, but did not make much difference between them. This might be due to the shielding of sunlight by the leaves of red pepper not to exert the photosensitizing effect of PS-2 to the full.

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The Role of Excipients in Iontophoretic Drug Delivery: In vitro Iontophoresis of Isopropamide and Pyridostigmine through Rat Skin and Effect of Ion-pair Formation with Organic Anions

  • Shim, Chang-Koo
    • Journal of Pharmaceutical Investigation
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    • v.23 no.3
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    • pp.41-50
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    • 1993
  • The iontophoretic delivery across rat skin of quaternary ammonium salts (isopropamide: ISP, pyridostigmine: PS), which are positively charged over a wide pH range, was measured ill vitro. The study showed that: (a) iontophoresis significantly enhanced delivery of ISP and PS compared to respective passive transport; (b) delivery of ISP and PS was directly proportional to the applied continuous direct current density over the range of $0-0.69\;mA/cm^2;$ (c) delivery of ISP and PS was also proportional to the drug concentration in the donor compartment over the range of $0-2{\time}l0^{-2}M:$ (d) sodium ion in the donor compartment inhibited the drug transport possibly due to decreasing the electric transference number of the drug; (e) delivery of ISP and PS increased as the pH of the donor solution increased over the pH range 2-7 suggesting permselective nature of the epidermis, and inhibition of the transference number of the drugs by hydronium ion; (f) some organic anions such as taurodeoxycholate, salicylate and benzoate which form lipophilic ion-pair complexes with ISP inhibited the delivery of ISP. The degree of inhibition by the organic anions was linearly proportional to the extraction coefficient $(K_e)$ of ISP from the partition system with each counteranion between phosphate buffer (pH 7.4) and n-octanol. For PS, however, taurodeoxycholate, but not salicylate and benzoate inhibited the iontophoretic delivery. It suggests that not only sodium ion and hydronium ion but also the counteranions which form lipophilic ion-pairs with quaternary ammonium drugs are not favorable components in formulating the donor solution of the drugs to achieve an effective iontophoretic delivery.

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Performance of WDM Signals in Optical Links with Random Distribution of Residual Dispersion Per Span only in Half Transmission Section of Total Length (전송 반 구획에서만 중계 구간 당 분산이 랜덤하게 분포하는 광 링크에서의 WDM 신호의 성능)

  • Lee, Seong-Real
    • Journal of Advanced Navigation Technology
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    • v.16 no.3
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    • pp.440-448
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    • 2012
  • Optimal net residual dispersion (NRD) and effective launching power range of optical transmission links with optical phase conjugator (OPC) and dispersion management (DM) for compensating the distorted wavelength division multiplexing (WDM) signals due to interaction of group velocity dispersion (GVD) and optical nonlinear effects. WDM systems considered in this research have optical links with the random distribution of residual dispersion per span (RDPS) in each single mode fiber (SMF) spans of only one half transmission section for designing the adaptive optical transmission system configurations. It is confirmed that optimal NRD is 10 ps/nm and effective launching power range is obtained to be -8~1 dBm under NRD = 10 ps/nm in optical links with total dispersion controlled by precompensation. And, it is also confirmed that optimal NRD is -10 ps/nm and effective launching power range is obtained to be -7.5~1 dBm under NRD = -10 ps/nm in optical links with total dispersion controlled by postcompensation.

Effects of Blended TIPS-pentacene:ph-BTBT-10 Organic Semiconductors on the Photoresponse Characteristics of Organic Field-effect Transistors (TIPS-pentacene:ph-BTBT-10 혼합 유기반도체가 유기전계효과트랜지스터 광반응 특성에 미치는 영향)

  • Chae Min Park;Eun Kwang Lee
    • Clean Technology
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    • v.30 no.1
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    • pp.13-22
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    • 2024
  • In this study, blended 6,13-Bis(triisopropylsilylethynyl)pentacene (TP):2-Decyl-7-phenyl[1]benzothieno[3,2-b][1] benzothiophene (BT):Poly styrene (PS) TFT at different ratios were explored for their potential application as light absorption sensors. Due to the mixing of BT, both off current reduction and on/off ratio improvement were achieved at the same time. In particular, the TP:BT:PS (1:0.25:1 w/w) sample showed excellent light absorption characteristics, which proved that it is possible to manufacture a high-performance light absorption device. Through analysis of the crystal structure and electrical properties of the various mixing ratios, it was confirmed that the TP:BT:PS (1:0.25:1 w/w) sample was optimal. The results of this study outline the expected effects of this innovation not only for the development of light absorption devices but also for the development of mixed organic semiconductor (OSC) optoelectronic systems. Through this study, the potential to create a multipurpose platform that overcomes the limitations of using a single OSC and the potential to fabricate a high-performance OSC TFT with a fine-tuned optical response were confirmed.

Search of Optimal Contexts for Context-adaptive Coding of Stereo Parameters in Parametric Stereo of Enhanced aacPlus (Enhanced aacPlus의 Parametric Stereo에서 스테레오 파라미터의 컨텍스트 적응 코딩을 위한 최적 컨텍스트 탐색)

  • Pang, Hee-Suk
    • The Journal of the Acoustical Society of Korea
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    • v.31 no.7
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    • pp.435-440
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    • 2012
  • We propose optimal contexts for context-adaptive coding of stereo parameters in parametric stereo (PS) of enhanced aacPlus. For the quantized indexes of stereo parameters, 8 context candidates were proposed based on the index values and their combinations adjacent to a source index in the time-stereo band domain, where the time-stereo band region was further divided into 4 regions based on refresh/non-refresh frames and stereo bands. The optimal contexts for each region were proposed by experiments, which are expected to be used for context-adaptive coding of PS for improved performance.

A Research on Multiple PS QAM for Channel Compensation in Frequency-Selective Rayleigh Fading Channels (주파수 선택적 Rayleigh 페이딩 채널에서 고차 PS QAM 채널 보상에 대한 연구)

  • Kim, Jeong-Su
    • Journal of the Korea Society of Computer and Information
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    • v.18 no.7
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    • pp.79-84
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    • 2013
  • In this paper, the method of multiple PS(pilot symbol) QAM channel compensation is suggested in order to analyze and improve occurring problems in case of delay waves in Frequency-Selective Rayleigh fading channels through Pilot Symbol Assisted Modulation(PSAM) which is a method predicting and compensating fading information, using Pilot Symbol in flat fading channels. This suggested method shows stable improvement in its performance even though it is effected by the level of delay on delay waves while the existing PSAM method has severe malfunction with a small amount of level of delay on delay waves regardless of signal-to-noise ratio(SNR).

Design of Doubly-Clad Optical Fibers with Low Dispersion for $\lambda=1.3, 1.55{\mu}m$ ($\lambda=1.3, 1.55{\mu}m$에서 저분산을 갖는 이중-클래드 광섬유의 설계)

  • 정석원;김창민
    • Korean Journal of Optics and Photonics
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    • v.6 no.2
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    • pp.156-164
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    • 1995
  • Based on the scalar wave equation of optical fibers, the dispersion characteristics of arbitrarily profiled fibers were analyzed. We used the I-D FEM employing quadratic interpolation fucntions to solve the scalar wave equation. We simulated the DC optical fibers as objects, and searched for the refractive index distribution to minimize the total dispersion. In DC fibers, we found the design parameters for which the total dispersion was almost zero at $\lambda=1.3{\mu}m and 1.55{\mu}m$ simultaneously. We also found the design parameters where the dispersion was flattened, less than 1.0 ps/km.nm for$\lambda=1.4~1.7{\mu}m$1. and the dispersion was as low as 0.65 ps/km.nm at $\lambda=1.55{\mu}m$..

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