• Title/Summary/Keyword: PP2A

Search Result 1,076, Processing Time 0.023 seconds

Preparation and Physical Properties of Silicone Softner for PP Finish (PP 가공용 실리콘 유연제의 제조와 물성연구)

  • Im, Wan-Bin;Yang, In-Mo;Jung, Choong-Ho;Hahm, Hyun-Sik;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
    • /
    • v.19 no.2
    • /
    • pp.117-122
    • /
    • 2002
  • A silicone softner (SS-5), a permanent press (PP) finish, was prepared by blending silicone oil KF-96 (as a lubricating component) and beef tallow hardened oil (as a softening component) which was synthesized from fatty polyamide salts. The prepared SS-5 and the PP finishing resin were applied to PP finishing cotton cloth and P/C gingham sample by one-bath method. The properties such as crease recovery, tear strength, and bending resistance were tested. The samples treated with SS-5 and PP finishing resin showed improved properties when comparing with the untreated ones, with the ones treated only with PP finishing resin, with ones treated with commercial PP finishing softners and PP finishing resin. The grades of fabric samples treated with 3% SS-5 were fifth grade in the bending resistance test.

Effect of irradiation and LDPE content on crystal formation of PP (PP의 결정형성에 대한 조사가교와 LDPE 함량의 영향)

  • Dahal, Prashanta;Kim, Youn Cheol
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.15 no.6
    • /
    • pp.4039-4045
    • /
    • 2014
  • The crystallization behavior of irradiated polypropylene (PP) and the blend is an important parameter for polymer processing. Blends of PP/low density polyethylene (LDPE) with different LDPE contents were prepared by melt mixing in a twin screw extruder. The effect of the LDPE content on the irradiation effectiveness of the PP/LDPE blend with trimethylolpropane-trimetacrylate (TMPTMA) as a crosslinking co-agent was investigated in conjunction with the LDPE loading in the blend. The non-isothermal crystallization and crystal structure were measured by DSC, X-ray diffraction (XRD), and polarized optical microscopy (POM). A decrease in the melting temperature of PP was observed due to irradiation, which may be due to the PP chain scissioning effect of irradiation. The Ozawa component n represents a rod shaped, disc shaped and sphere-shaped geometry of the crystal if the value corresponds to 2, 3 and 4, respectively. Based on Ozawa analysis, the values of n were 3.8 and 2.3 for the pure PP and PP blends with 30 wt% LDPE, respectively. The fact that the crystal geometry of PP changed from spherical to disc and rod shaped was confirmed by Ozawa analysis and POM. The ${\beta}$ form XRD peak of the PP/LDPE blend at $16.1^{\circ}$ disappeared after irradiation due to the crosslinking reaction.

Physical and Mechanical Properties of Blast Furnace Cement Concrete with Polypropylene Fiber (폴리프로필렌 섬유를 보강한 고로시멘트 콘크리트의 물리·역학적 특성)

  • Jun, Hyung Soon
    • Journal of The Korean Society of Agricultural Engineers
    • /
    • v.54 no.6
    • /
    • pp.151-158
    • /
    • 2012
  • This study will not only prove experimental dynamic properties which are classified to slump, compressed strength, bending strength and toughness index blast-furnace cement concrete with polypropylene (PP) fiber that refer properties and volume of it, but also establish a basic data in order to use PP fiber reinforced blast-furnace cement concrete. The slump didn't changed by PP fiber volume $5kgf/m^3$ because of flexibility of fiber in despite of loose mixing. The reason why the slump decreased steadily by PP fiber volume $3kgf/m^3$ was rising contact surface of water. The compressed strength indicated a range of 19.49~26.32 MPa. The tensile strength indicated a range of 2.10~2.44 MPa. The bending strength was stronger about 3~16 % in case of mixing with PP fiber volume than normal concrete. The flexure strength indicated a range of 4.30~4.83 MPa. The toughness indicated a range of $0{\sim}19.88N{\cdot}mm$ and was stronger about 6.7 times in case of PP fiber volume $9kg/m^3$ than PP fiber volume $1kg/m^3$. The pavement with PP fiber volume over such a fixed quantity in the roads of a respectable amount load can have a effect to prevent not only resistance against clack but also rip off failures.

Rheology of PP/Clay Hybrid Produced by Supercritical $CO_2$ Assisted Extrusion

  • Lee, Sang-Myung;Shim, Dong-Cheol;Lee, Jae-Wook
    • Macromolecular Research
    • /
    • v.16 no.1
    • /
    • pp.6-14
    • /
    • 2008
  • Polypropylene (PP)-layered silicate nanocomposites were developed using a new processing method involving a supercritical carbon dioxide ($scCO_2$)-assisted co-rotating twin-screw extrusion process. The nanocomposites were prepared through two step extrusion processes. In the first step, the PP/clay mixture was extruded with $CO_2$ injected into the barrel of the extruder and the resulting foamed extrudate was cooled and pelletized. In the second step, the foamed extrudate was extruded with venting to produce the final PP/clay nanocomposites without $CO_2$. In this study, organophilic-clay and polypropylene matrix were used. Maleic anhydride grafted polypropylene (PP-g-MA) was used as a compatibilizer. This study focused on the effect of $scCO_2$ on the dispersion characteristics of the clays into a PP matrix and the rheological properties of the layered silicate based PP nanocomposites. The dispersion properties of clays in the nanocomposites as well as the rheological properties of the nanocomposites were examined as a function of the PP-g-MA concentration. The degree of dispersion of the clays in the nanocomposites was analyzed by X-ray diffraction and transmission electron microscope. Various rheological properties of the nanocomposites were measured using a rotational rheometer. In the experimental results, the $scCO_2$ assisted continuous manufacturing extrusion system was used to successfully produce the organophilic-clay filled PP nanocomposites. It was found that $scCO_2$ had a measurable effect on the clay dispersion in the polymer matrix and the melt intercalation of a polymer into clay layers.

A Study on the Synthesis of ACE/PP-g-AN Hybrid Fibers by Irradiation and Separation of Uranium (방사선 중합에 의한 ACF/PP-g-AN 복합섬유의 합성 및 우라늄 분리에 관한 연구)

  • 황택성;황대성;노영창
    • Polymer(Korea)
    • /
    • v.24 no.2
    • /
    • pp.174-181
    • /
    • 2000
  • The ACF/PP-g-AN copolymers were synthesized by the irradiational grafting of acrylonitrile onto ACF/PP hybrid fabric. The synthesis of the ACF/PP-g-AN copolymer was evidenced by the band of -C=N absorption peak at 2250 $cm^{-1}$ / and amidoximation was evidenced by the band of -OH and -NH$_2$ peak at 3450 $cm^{-1}$ / on FT-IR spectrum. The optimal time for the uranium ion adsorption equilibrium on ACF/PP-g-AN copolymers was 8 days and the optimal pH was 8. The adsorption capacities of ACF/PP-g-AN copolymers increased according to the content of amidoxime and were not varied even after more than 10 times of regeneration.

  • PDF

Phosphorylation on the PPP2R5D B regulatory subunit modulates the biochemical properties of protein phosphatase 2A

  • Yu, Un-Young;Ahn, Jung-Hyuck
    • BMB Reports
    • /
    • v.43 no.4
    • /
    • pp.263-267
    • /
    • 2010
  • To characterize the biochemical properties of the PP2A regulatory B subunit, PPP2R5D, we analyzed its phosphorylation sites, stoichiometry and effect on holoenzyme activity. PPP2R5D was phosphorylated on Ser-53, Ser-68, Ser-81, and Ser-566 by protein kinase A, and mutations at all four of these sites abolished any significant phosphorylation in vitro. In HEK293 cells, however, the Ser-566 was the major phosphorylation site after PKA activation by forskolin, with marginal phosphorylation on Ser-81. Inhibitory tyrosine phosphorylation on Tyr-307 of the PP2A catalytic C subunit was decreased after forskolin treatment. Kinetic analysis showed that overall PP2A activity was increased with phosphorylation by PPP2R5D phosphorylation. The apparent Km was reduced from $11.25\;{\mu}M$ to $1.175\;{\mu}M$ with PPP2R5D phosphorylation, resulting in an increase in catalytic activity. These data suggest that PKA-mediated activation of PP2A is enabled by PPP2R5D phosphorylation, which modulates the affinity of the PP2A holoenzyme to its physiological substrates.

Studies for the Sustainable Management of Oyster Farms in Pukman Bay, Korea: Estimate of Primary Production

  • Jeong, Woo-Geon;Cho, Sang-Man;Lee, Sang-Jun
    • Fisheries and Aquatic Sciences
    • /
    • v.12 no.2
    • /
    • pp.111-117
    • /
    • 2009
  • To develop sustainable management strategies for oyster farms in Pukman Bay, Korea, we estimated primary production using a numerical model. Because oysters are filter feeders, estimations of primary production (PP) are essential in developing management strategies. The daily PP ranged from 0.07 to 1.5 gC/$m^2$/d and showed significant spatial variations. The spatial distribution of PP was strongly associated with hydrodynamic features, and distinct patterns were observed in three different regions. In the inner bay, high PP was directly influenced by urban and agricultural sewage. The middle part of the bay had low PP, whereas PP in the outer area was high. PP was relatively low during the main oyster growth season, from late autumn to early winter. These findings represent important information for developing a management model for oyster farms in Pukman Bay.

Socio-economic disparity in food consumption among young children in eight South Asian and Southeast Asian countries

  • Kang, Yunhee;Park, Chulwoo;Young, Anna Marie Pacheco;Kim, Jihye
    • Nutrition Research and Practice
    • /
    • v.16 no.4
    • /
    • pp.489-504
    • /
    • 2022
  • BACKGROUND/OBJECTIVES: This study examined socio-economic differences in diverse food consumption among children 6-23 months of age in South Asia and Southeast Asian countries. SUBJECTS/METHODS: Data from Demographic and Health Surveys in four countries in South Asia (n = 15,749) and four countries in Southeast Asia (n = 10,789) were used. Survey-design adjusted proportions were estimated for the following 10 food items: grains, legumes, dark green leafy vegetables (DGLV), vitamin A-rich fruits, vitamin A-rich vegetables, other fruits and vegetables (OFV), fish, meat, dairy, and eggs. An equity gap was defined as an arithmetic difference in the proportion of each food item consumed in the past 24-hours between the wealthiest and lowest quintiles and between rural and urban areas, denoted by percentage points (pp). RESULTS: The consumption of most of the 10 food items was higher in the wealthiest quintiles and urban areas across eight countries. The size of equity gaps was greater in Southeast Asia than in South Asia, particularly for vitamin A-rich fruits (3.3-30.0 pp vs. 0.3-19.6 pp), vitamin A-rich vegetables (12.1-26.7 pp vs. 2.4-5.9 pp), meat (17.7-33.4 pp vs. 3.4-13.4 pp), and dairy (14.7-32.5 pp vs. 3.3-11.4 pp). However, the size of equity gap in egg consumption was greater in Southeast Asia than South Asia (11.2-19.8 pp vs. 11.0-26.7 pp). Relatively narrower gaps were seen in the consumption of grains (0.3-12.9 pp), DGLV (0.6-12.4 pp), and fish (0.1-16.8 pp) across all countries. CONCLUSIONS: Equity gaps in food consumption differed by socio-economic status and region. Reducing equity gaps in nutrient-rich foods and utilizing regionally available food resources may increase child dietary quality.

A Study on the Synthesis of ACF/PP-g-AAc Hybrid Fibrous Adsorbent by Irradiation and Their Separation Properties of Heavy Metals (방사선 중합법에 의한 ACF/PP-g-AAc 혼성섬유 흡착제의 합성 및 중금속 분리 특성에 관한 연구)

  • 황택성;황대성;박정기
    • Polymer(Korea)
    • /
    • v.24 no.1
    • /
    • pp.1-7
    • /
    • 2000
  • The ACF/PP-g-AAc copolymers were synthesized by the irradiational grafting of acrylic acid onto ACF/PP fabric. The synthesis of copolymer was evidenced by the bands at 1720, 3600~3100 $cm^{-1}$ / on FT-IR spectrum. After the adsorption of metal ions on ACF/PP-g-AAc copolymers, the morphology with the small deposits on the fiber surface were observed by SEM. The optimal time for the metal ion adsorption equilibrium on ACF/PP-g-AAc copolymers was 24 hrs and their adsorption capacities increased in the order of Mn$^{2+}$>Cu$^{2+}$>Co$^{2+}$>Ni$^{2+}$. The adsorption capacities of ACF/PP-g-AAc copolymers were invariable after more than 10 times of regeneration.eration.

  • PDF

Evaluation of Segment Lining Fire Resistance Based on PP Fiber Dosage and Air Contents (세그먼트 라이닝의 PP섬유 혼입량과 공기량 변화에 따른 화재저항 특성 평가)

  • Choi, Soon-Wook;Kang, Tae Sung
    • Tunnel and Underground Space
    • /
    • v.31 no.6
    • /
    • pp.469-479
    • /
    • 2021
  • As a material for preventing spalling of concrete, the effectiveness of PP fiber has already been confirmed. However, it is necessary to consider the maximum temperature that occurs during a fire, and to solve the mixing problem and the strength reduction problem that occur depending on the mixing amount. In this study, the fire resistance performance of tunnel segment linings according to the PP fiber content and air volume under the RABT fire scenario was investigated. As a result, no spalling or cross-sectional loss occurred in all test specimens, and when the PP fiber content was small, the maximum temperature was relatively high and the maximum temperature arrival time was also fast. On the other hand, no trend was found for the maximum temperature and arrival time according to the difference in air volume. In the internal temperature distribution results for the PP fiber mixing amount of 0.75, 1.0, 1.5, and 2.0 kg/m3, the results of 0.75 and 1.0 kg/m3 showed similar temperature distribution, and the results of 1.5 and 2.0 kg/m3 were similar. It was confirmed that the internal temperature distribution tends to decrease at the same depth when the amount of PP fiber mixed is large, and it was confirmed that a remarkable difference occurred from the results of 1.0 kg/m3 and 1.5 kg/m3 of PP fiber mixed amounts.