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Bond Properties of Nonpolar Macro Synthetic Fiber in Cement Mortar with Maleic Anhydride Grafted Polypropylene Powder (무수말레인산이 그라프트된 폴리프로필렌 분말 첨가에 따른 시멘트 모르타르와 무극성 마크로 합성섬유의 부착 특성)

  • Lee, Jin-Hyung;Park, Chan-Gi
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.2A
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    • pp.137-143
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    • 2011
  • This study evaluated the effects of maleic anhydride grafted polypropylene powder (mPP) contents on the bond properties of cement mortar and nonpolar macro synthetic fibers (macro synthetic fiber). Dog-bone bond tests were performed to evaluate the bond performance of macro synthetic fiber in cement mortar with varying amounts of mPP (0%, 5%, 10%, 15%, 20%, 25%, 30% of cement weight). The bond properties (pullout behavior, pullout load and interface toughness) of macro synthetic fiber in cement mortar increased as the mPP contents was increased. The bond properties increased with the mPP contents. The microstructure of macro synthetic fiber surface was examined after the pullout test to analyze the frictional resistant force according to mPP contents during the pullout process of macro synthetic fiber in cement mortar. The scratched of macro synthetic fiber increased with the mPP contents.

The Prevalence and Characteristics of Positional Obstructive Sleep Apnea

  • Kim, Cheon-Sik;Lee, Yong-Seok;Cho, Cheon-Ung;Pae, Sang-Ho;Lee, Sang-Ahm
    • Korean Journal of Clinical Laboratory Science
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    • v.44 no.2
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    • pp.52-58
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    • 2012
  • Patients with obstructive sleep apnea (OSA) often have more aggravated symptoms in the supine position. We tried to investigate the clinical characteristics and the predictive factors for positional OSA. Polysomnographic data were reviewed for OSA patients (apnea hypopnea index, $AHI{\geq}5$) from April, 2008 to April, 2011 at the Asan Medical Center. Clinical data, comorbid medical condition data and questionnaires (SF-36, MFI-20, ESS, BDI, STAI) were assessed. All patients were classified into two groups: positional patients (PP) group and non-positional patients (NPP) group. PP was defined as a patient who had the AHI in the supine position was at least twice as high as that in the lateral position. The body position of patients was confirmed by sleep position sensor and video monitor. All patients had at least 30 minutes of positional and 30 minutes of non-positional sleep. We compared clinical, medical, polysomnographic data, and questionnaire results between two (PP and NPP) groups and investigated predictive factors for the PP group using binary logistic regression analysis. In total, 371 patients were investigated. 265 (71.4%) was categorized as PP group and 106 (28.5%) as NPP group. The mean age ($mean{\pm}SD$) was higher in the PP group ($52.4{\pm}9.8$) than in the NPP group ($49.5{\pm}11.9$) (p<0.05). Comparison of sleep parameters between the PP and the NPP group showed that the PP group had significantly lower BMI (PP: $26.1{\pm}3.2kg/m^2$; NPP: $27.8{\pm}4.3kg/m^2$, p<0.001), neck circumference (PP: $39.7{\pm}2.8cm$; NPP: $41.5{\pm}3.7cm$, p<0.001) and hypertension rate (PP: n=89/265 (33.5%); NPP: n=48/106 (45.2%), p=0.0240). In the PP group, the percentage of deep sleep (PP: $8.7{\pm}8.1%$; NPP: $5.6{\pm}7.0%$, P=0.001) and rapid eye movement (REM) (PP: $17.5{\pm}6.1%$; NPP: $14.0{\pm}6.9%$, p<0.001) were significantly higher whereas the percentage of light sleep (stage N1) was significantly lower than the NPP group (PP: $30.4{\pm}12.3$; NPP: $44.5{\pm}20.8%$, p<0.001). During the sleep, the AHI in the supine position (PP: $48.6{\pm}19.5$; NPP: $60.5{\pm}22.6$, p<0.001) and in the non-supine position (PP: $9.4{\pm}8.9$; NPP: $48.4{\pm}24.8$, p=<0.001) were significantly lower and the minimal arterial oxygen saturation in non-REM sleep was significantly higher in the PP group (PP: $80.3{\pm}7.6$; NPP: $75.1{\pm}9.9$, p=<0.001). There were no significant differences in all questionnaires including quality of life. The results of the binary logistic regression analysis showed that age, the amount of REM sleep(%) and AHI were significant predictive factors for positional OSA. The significant predictive factors for positional OSA were older age, higher percentage of REM and lower AHI. The questionnaire results were not significantly different between the two groups.

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Quality Characteristics of Dumpling Shell Containing Pleurotus eryngii Powder (새송이버섯 분말을 첨가한 만두피의 품질 특성)

  • Kang, Bok-Hee;Shin, Eun-Jeong;Lee, Sang-Han;Lee, Dong-Sun;Hur, Sang-Sun;Kim, Seong-Ho;Son, Seok-Min;Lee, Jin-Man
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.40 no.4
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    • pp.570-574
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    • 2011
  • This study was conducted to investigate the quality characteristics of dumpling shells with added Pleurotus eryngii powder (PP) (2%, 4%, 6%). The weight after cooking and volume of the dumpling shells increased with the addition of PP. The water absorption of the dumpling shells was not significantly different by the addition of PP. Turbidity after cooking increased and hardness decreased by adding PP. The L value after cooking decreased with the addition of PP, and the b value was highest when the content of PP was 6%. Adhesiveness increased by adding PP and springiness decreased when PP content was above 4%. Chewiness and gumminess decreased by adding the powder. There were no differences among the control, 2%, and 4% samples in cohesiveness values, but cohesiveness significantly decreased with the addition of 6% of powder. Color characteristics showed low values when PP was added at more than 6% according to sensory characteristics tests. No significant differences were found in flavor, taste, smoothness, moisture, or adhesiveness of the dumpling shells after cooking according to additions of PP. Chewiness was higher by adding PP compared to the control, but no significant differences were found by additions of PP.

Effect on postoperative pulmonary arterial pressure with preoperative hemodynamic data in VSD (심실중격결손증에서 수술전 혈류역학치가 수술후 폐동맥압력에 미치는 영향)

  • 성숙환
    • Journal of Chest Surgery
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    • v.19 no.2
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    • pp.238-242
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    • 1986
  • The prognosis of patients with VSD and pulmonary hypertension is at least partially related to the reversibility of pulmonary hypertension after surgery. To predict postoperative pulmonary arterial pressure, immediate postbypass values were compared with preoperative hemodynamic data in 18 surgically closed VSD patients aged 6 to 80 months. The following results were obtained. 2] There was a good correlation between preoperative PP/PS and postoperative PP/PS in patients aged over 24 months [r=0.685, p<0.05], and in patients whose QP/QS were over 2.0 [r=0.686, p<0.01]. 3] There was also a good correlation between pump time and postoperative PP in total patients [r=0.697, p<0.005]. 4] Direct correlations were found between preoperative PP/PS and immediate postbypass PP/PS in patients aged over 24 months and in patients whose QP/QS>2.0, but the effect of CPB would participate in some degree. So it may be necessary to reevaluate their relationship after the effect of CPB have been disappeared.

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Morphological Properties of Binary Blends of Polyolefins Synthesized by Metallocene and Ziegler-Natta Catalysts (Ziegler-Natta와 메탈로센 촉매로 합성된 폴리올레핀 2원 블렌드의 상 형태학)

  • Kwag, Hanjin;Kim, Hak Lim;Choe, Soonja
    • Applied Chemistry for Engineering
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    • v.10 no.6
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    • pp.944-948
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    • 1999
  • The morphological properties of four binary blends of polyethylene synthesized by metallocene catalyst(MCPE) and four polyolefins prepared by Ziegler-Natta catalyst have been investigated to interpret the effect of micro-molecular structure on the phase morphology and interfacial behavior; four binary blend systems studied are high density polyethylene(HDPE)-metallocene polyethylene (MCPE), polypropylene(PP)-MCPE, poly(propylene-co-ethylene) (CoPP)-MCPE, and poly(propylene-co-ethylene-co-1-butylene) (TerPP)-MCPE, and they are all phase separated. The HDPE-MCPE blend shows evenly growing homogeneous HDPE domain on the continuous MCPE phase, on the other hand, the rest of three blends show complex heterogeneous phase behavior. The PP-MCPE blend shows that PP and MCPE and completely phase separated and phase inversion takes place at 50% MCPE. The CoPP-MCPE and TerPP-MCPE show enhanced interface due to the same micro-molecular structure of ethylene, and phase inversion takes place at 40% MCPE. In particular, TerPP-MCPE blend shows improved phase morphology between interfaces, and this may be arisen from the comonomer contents in TerPP, which are 1-butene and ethylene having the same chemical structure as that of MCPE. The enhancement of the phase morphology in the TerPP-MCPE blend is correlated with the mechanical and morphological properties. Thus, although the four blend systems are phase separated, the phase morphology suggests that the order of interfacial adhesion strength be HDPE-MCPE > TerPP-MCPE > CoPP-MCPE > PP-MCPE and that micro-molecular structure between constituents be one of major factors giving enhanced interfacial adhesion.

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Ammonium Adsorption Property of Acrylic Acid and Styren Grafting Polypropylene Non-Woven Fabric Synthesized by Photo-induced Polymerization (광조사 중합법에 의해 합성된 PP-g-AA와 PP-g-St 부직포의 암모니아성 질소 흡착특성 비교)

  • Park, Hyun-Ju;Na, Choon-Ki
    • Journal of Environmental Science International
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    • v.17 no.11
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    • pp.1255-1263
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    • 2008
  • The efficiency of PP-g-AA and PP-g-St nonwoven fabric synthesized by photoinduced polymerization as an adsorbent for removal $NH_3-N$ from waste water was evaluated. The results evidently indicate that the adsorption capacities of $NH_3-N$ onto PP-g-AA nonwoven fabric were extremely superior to those onto sulfonated PP-g-St nonwoven fabric, PK and zeolite. PP-g-AA nonwoven fabric showed the maximum adsorption capacity of $NH_3-N$ at the degree of grafting of 80 wt.%. The adsorption behaviour of $NH_3-N$ onto PP-g-AA and sulfonated PP-g-St nonwoven fabric was controlled by an ion exchange reaction, and tended to be similar to both trends of Langmiur and Freundlish isotherm. Futhermore, PP-g-AA non-woven fabric could be regenerated more than 5 times by a simple washing with 0.1N HCl with no decrease of adsorption capacity and no degradation of physical properties. Also sulfonated PP-g-St nonwoven fabric could be regenerated by washing with 0.1N ${H_2}{O_4}$. However, their regeneration efficiency was significantly low because grafting layer acted as functional radical for adsorption was continuously desquamated in the adsorption or regeneration processes, which resulted in decrease of adsorption capacity and weight of adsorbent. All results obtained from this study indicate that the $NH_3-N$ removal capacity of PP-g-AA non-woven fabric was extremely superior to those of PP-g-St non-woven fabric, PK and zeolite.

Effects of Filler Characteristics and Processing Conditions on the Electrical, Morphological and Rheological Properties of PE and PP with Conductive Filler Composites

  • Kim, Youn-Hee;Kim, Dong-Hyun;Kim, Ji-Mun;Kim, Sung-Hyun;Kim, Woo-Nyon;Lee, Heon-Sang
    • Macromolecular Research
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    • v.17 no.2
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    • pp.110-115
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    • 2009
  • The electrical, morphological and rheological properties of melt and dry mixed composites of poly ethylene (PE)/graphite (Gr), polypropylene (PP)/Gr and PP/nickel-coated carbon fiber (NCCF) were investigated as a function of filler type, filler content and processing temperature. The electrical conductivities of dry mixed PP/NCCF composites were increased with decreasing processing temperature. For the melt mixed PP/NCCF composites, the electrical conductivities were higher than those of the melt mixed PE/Gr and PP/Gr composites, which was attributed to the effect of the higher NCCF aspect ratio in allowing the composites to form a more conductive network in the polymer matrix than the graphite does. From the results of morphological studies, the fillers in the dry mixed PP/NCCF composites were more randomly dispersed compared to those in the melt mixed PP/NCCF composites. The increased electrical conductivities of the dry mixed composites were attributed to the more random dispersion of NCCF compared to that of the melt mixed PP/NCCF composites. The complex viscosities of the PP/Gr composites were higher than those of the PP/NCCF composites, which was attributed to the larger diameter of the graphite particles than that of the NCCF. Furthermore, the fiber orientation in the 'along the flow' direction during melt mixing was attributed to the decreased complex viscosities of the melt mixed PP/NCCF composites compared those of the melt mixed PP/Gr composites.

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Cranioplasty Using Autologous Bone versus Porous Polyethylene versus Custom-Made Titanium Mesh : A Retrospective Review of 108 Patients

  • Kim, Jun-Ki;Lee, Sang-Bok;Yang, Seo-Yeon
    • Journal of Korean Neurosurgical Society
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    • v.61 no.6
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    • pp.737-746
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    • 2018
  • Objective : The purpose of this study was to compare the cosmetic outcome and complications after cranioplasty (CP) due to three different implant materials, and analyze the mean implant survival and cumulative survival rate based on these results. Methods : We reviewed 108 patients retrospectively who underwent CP between January 2014 and November 2016. Autologous bone (AB; 45 patients) and synthetic materials with porous polyethylene (PP; 32 patients) and custom-made 3-dimensional printed titanium mesh (CT; 31 patients) were used as implants. Results : Regardless of implanted materials, more than 89.8% of the CP patients were satisfied with the cosmetic outcome. No statistically significant difference was observed among the three groups. The overall postoperative complication rates of each group were 31.1% in the AB group, 15.6% in the PP group and 3.2% in the CT group. The CT group showed lower complication rates compared with AB and PP groups (${\chi}^2$-test : AB vs. PP, p=0.34; AB vs. CT, p=0.00; PP vs. CT, p=0.03). The AB and PP groups demonstrated a higher post-CP infection rate (11.1% and 6.3%) than the CT group (3.2%). However, no significant difference in the incidence of post-CP infection was observed among the three groups. The PP and CT groups demonstrated a higher mean implant survival time and cumulative survival rate than the AB group at the last follow-up (p<0.05). Conclusion : In comparison with AB and PP, cranioplasty with CT shows benefits in terms of lower post-CP complication, less intraoperative bleeding loss, shorter operation time and in-hospital stay. The PP and CT groups showed higher implant survival time and cumulative survival rate compared with the AB group.

Miscibility and Bleaching of Modified Polypropylene (개질 Polypropylene의 혼화성과 표백)

  • Cho, Kyu-Min;Cho, In-Sul;Chang, Du-Sang;Lee, Eun-Woo;Kim, Oh-Nyen
    • Textile Coloration and Finishing
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    • v.10 no.6
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    • pp.33-41
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    • 1998
  • 이 연구는 염색성이 열악한 polypropylene(PP) 섬유의 염색성을 개선하기 위해 추진한 것이다. 연구목적에 따라서 PP 섬유를 개질하기 위해 1차 cellulosic유도체를 추출하고 이 유도체와 PP를 9:1의 혼합비율로 섞어 master batch를 만든 다음 master batch 17%와 PP를 blending하여 개질 PP를 만들었다. 이렇게 제조된 개질 PP는 혼합된 변성 cellulosic polymer의 영향으로 착색이 심하게 되어 있으므로 이를 표백하는 것을 이 연구의 목적으로 하였다. 연구결과 blend한 개질 PP(Grand P)의 혼화성이 우수하였고, 아염소산나트륨에 표백적성을 가지며, 표백의 최적조건은 표백제의 농도가 0.1% $NaClO_2$, 표백온도 $70^\circ{C}$, 표백시간 30분이었다.

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