• Title/Summary/Keyword: PP-Wood

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Mechanical Properties of Alkali Treated Kenaf Fiber Filled PP Bio-Composites (알칼리 처리된 Kenaf 섬유가 충전된 Polypropylene/Kenaf 바이오복합재의 기계적 특성)

  • Kim, Samsung;Lee, Byoung-Ho;Kim, Hyun-Joong;Oh, Sei Chang;Ahn, Sye-Hee
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.3
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    • pp.222-230
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    • 2009
  • This study was to investigate the effect of alkali treatment for long kenaf fiber to improve fiber surface characterics by removal of wax, lignin and hemicellulose which affect adversely for matrix union. SEM observation was also studied to check out the interface adhesion improvement by the alkali pre-treatment. From the result, interface coherence increased by 3% alkali pre-treatment and reached a maximum by 5% alkali pre-treatment. However, the 3% the bio-composites treated with 3% alkali was highest tensile and flexural strength than other.

Simultaneous Determination of Isocyanates by High Performance Liquid Chromatography (고속액체크로마토그래피를 이용한 이소시아네이트의 동시 정량)

  • Lee, Seon Joo;Lee, Kwang Mook;Roh, Young Man
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.4 no.2
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    • pp.137-147
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    • 1994
  • This study was designed to identify and quantitate airborne isocyanate simultaneously by HPLC. These samples were collected using 1-(2-pyridyl)piperazine(1-2PP) coated glass fiber filter from polyurethane painting works at 8 wood furniture factories in Kimpo and Inchun. The results obtained were as follows : 1. The most suitable mobile phase condition of simultaneously analyzing isocyanates was 0.01 M ammonium acetate buffer ACN(70/30) adjusted to pH 6.2 from the beginning of the analysis to 20 min and 0.01 M ammonium acetate buffer/ACN(50/50) adjusted to pH 6.2 from 21 min to 40 min using the gradient mode. The peaks of isocyanates were able to obtain within 30 min. 2. The recovery efficiencies for 2,6-TDI, 2,4-TDI, HDI and MDI urea derivates spiked at the target concentration on coated glass fiber tillers were 91.00, 93.42, 91.31 and 94.21 %, respectively. 3. The qualitative analysis of the isocyanates samples from polyurethane spray painting works in wood furnture factories identified Ihree isocyanates, 2,6-TDI, 2,4-TDI and MOI. And their concentration ranges were 0-312.6, 0-56.3 and $0-62.1{\mu}g/m^3$, respectively. A disadvantage of using the colorimetric method for isocyanate analysis is its inability of separating isocyanates. This study identified such three isocyanates as 2,6-TDI, 2,4-TDI and MDI from polyurethane spray painting works in wood furniture factories. These isocyanates were successfully quantitated by HPLC by modifying the mobile phase condition and switching to gradient mode.

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Nano-Kenaf Cellulose Effects on Improved Mechanical Properties of Polypropylene Composite (나노 케냐프 셀룰로오스가 폴리프로필렌 복합소재의 물성 증가에 미치는 영향)

  • Oh, Jeong Seok;Lee, Seong-Hoon;Bumm, Sughun;Kim, Kwang-Jea
    • Polymer(Korea)
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    • v.37 no.5
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    • pp.613-617
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    • 2013
  • The effects of nano size kenaf cellulose fiber on mechanical property of polypropylene (PP) composite were investigated. The addition of nano-kenaf in place of natural kenaf showed higher tensile strength, flexural strength, impact strength, and heat deflection temperature compared to the natural kenaf filled PP composite, while it shows lower melt flow index, elongation%, and flexural modulus. These seemed to be due to the increased surface area of nano-kenaf fiber contacting PP matrix and reduced impurities such as volatile extractives on the fiber surface.

Automatic Skin Basal Cell Carcinoma Detection Using Protophorphyrin IX((PpIX) Fluorescence Image (PpIX 형광영상을 이용한 피부 기저세포암 자동검출)

  • Yu, Hong-Yeon;Jun, Do-Young;Kim, Min-Sung;Hong, Sung-Hoon
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.45 no.1
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    • pp.47-54
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    • 2008
  • In this paper, we propose an auto-detection algorithm of basal cell carcinoma(BCC) from the protophorphyrin IX(PpIX) fluorescence image induced by appling the methyl 5-aminolaevulinate(MAL) ointment-induced protophorphyrin IX(PpIX) to the skin tumour area and then shining the wood lamp on the area. The proposed algorithm first generates 3 mask areas-tumor area, suspected tumor area and tumor free area and then applies local watershed algorithm to the turner and the suspected tumor areas to make small watershed regions that include similar luminance value pixels. Next, small watershed regions are merged by hierarchical queue based fast region merging that uses the difference between the average luminance values of adjacent watershed regions as a region merging criterion and finally BCC regions are detected. 50 tissue samples are acquired from the tumour regions of 10 patients with BCC that are extracted by using the proposed algorithm and are performed pathological examination by expert dermatologist. Experiment result shows the rate of tumor detection from BCC lesion using presurgical in vivo of MAL-indeuced PpIX fluorescence has high sensitivity 94.1% and relatively high specificity 82.6%.

Color Change and Tensile Properties of Wood Flour Reinforced Polypropylene Composites; Influence of Photostabilizers

  • Lee, Sun-Young
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.2
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    • pp.171-178
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    • 2009
  • A comparative analysis of the hindered amine light stabilizers (HALS) and UV abosrber (UVA) and their respective photostabilizing effect on wood plastic composites (WPCs) are reported in this study. The influence of accelerated weathering on the mechanical properties of the composites and the microscopic morphology of a degraded layer on the cross section and the surface were studied. UV absorbers were more efficient at preventing composite lightening than was UV stabilizer. The amount of whitening decreased with the increase of photostabilizers. With the addition of a UV absorber (Tinuvin360), the tensile modulus and strength of the composites increased slightly. However, the addition of a light stabilizer (Tinuvin770) and a UV absorber decreased the tensile modulus and strength of the composites. After 250 and 500 hr exposure, tensile modulus and strength of the un stabilized and stabilized composites decreased. The tensile strength of UV absorber (Chimassorb81)-stabilized composites was significantly greater than that of control and light stabilizer (Tinuvin770)- and UV absorber (Tinuvin360)-stabilized composites. UV absorber-stabilized samples showed less whitening and photodegradation than control and light stabilizer-stabilized samples.

Water Absorption of Wood Flour-Polypropylene Composites: Effects of Wood Species, Filler Particle Size and Coupling Agent (목분-폴리프로필렌 복합재의 수분흡수율 : 목재수종, 충진제 입자크기 및 상용화제의 영향)

  • Kang, In-Aeh;Lee, Sun-Youn;Doh, Geum-Hyun;Chun, Sang-Jin;Yoon, Seung-Lak
    • Journal of the Korean Wood Science and Technology
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    • v.38 no.4
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    • pp.298-305
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    • 2010
  • The effects of wood species, chemical components, filler loading level, filler particle size, and coupling agent on the water absorption property of the wood flour filled polypropylene (PP) composites were investigated in this study. After 500, 1,000, 1,500, 2,000, 2,500 and 3,000 hr water immersion, Quercus (Quercus accutisima Carr.) and Maackia (Maackia amuresis Rupr. et Maxim) showed significantly lower water absorption properties compared to Larix (Larix kaempferi Lamb.). As wood flour loading increases from 10 to 50 wt%, most wood species showed increased water absorption after a given immersion period. Particle size of wood flour proved to have very significant effects on water absorption of the composites. The effect of coupling agent was positive in terms of lowering water absorption of the composites. As the treatment level of coupling agent increases, the water absorption of the composites decreases. The lowest water absorption was obtained at the lower wood flour loading (Maackia), smaller particle size and by the addition of coupling agent. Thickness swelling of the composites shows close dependency on water absorption.

Evaluation of the Impact on Manufacturing Temperature and Time in the Production Process of Bio-composites (바이오복합재료 제조 공정시 제조온도 및 시간에 의한 영향 평가)

  • Park, Sang-Yong;Han, Gyu-Seong;Kim, Hee-Soo;Yang, Han-Seung;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.1 s.129
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    • pp.29-37
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    • 2005
  • The main objective of this research was conducted to evaluate the impacts on the thermoplastic polymer which is a matrix polymer and the rice husk flour (RHF) which is a reinforcing filler relative to the manufacturing temperature and time when bio-composites were manufactured. In order to evaluate the impacts on the rice husk flour relative to the manufacturing temperature, the rice husk flour was persevered for 10 minutes to 2 hours period at $220^{\circ}C$ temperature which was then added with the polypropylene (PP) and low-density polyethylene (LDPE) to complete the manufacturing process of the bio-composites and measure the corresponding mechanical properties. As preserving time increased at $220^{\circ}C$, the tensile and impact strength were decreased due to the thermal degradation of the main components within the rice husk flour. The thermogravimetric analysis (TGA) was used to measure weight loss caused by the actual manufacturing temperature and the result was that the thermoplastic polymer had not scarcely occurred weight change, but there had been increasing rate of weight loss relative to time for the rice husk flour and the bio-composites under the consistent temperature of $220^{\circ}C$ for 2 hour time period. Therefore, the proper manufacturing temperature and time settings are significantly important features in order to prevent the reduction of mechanical properties which were induced throughout the manufacturing process under the high manufacturing temperature.

Mechanical Properties of Wood Flour Polypropylene Composites: Effect of Cycled Temperature Change (Wood Flour 폴리프로필렌 복합재료의 기계적 특성: 반복적 온도 변화의 영향)

  • Lee, S.Y.;Chun, S.J.;Doh, G.H.;Park, S.B.;Choi, S.I.
    • Elastomers and Composites
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    • v.46 no.3
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    • pp.218-222
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    • 2011
  • The effect of cycled temperature change on the mechanical properties of wood flour(50 wt.% and 70 wt.%) polypropylene WPC(Wood Plastic Composites) was investigated in this study. Flexural modulus and flexural strength of the WPC showed a decrease due to the degradation of interfacial adhesion between polymer matrix and wood flour by the freeze-thaw test regardless of the cycled number. At the higher loading level of wood flour, the reduction of the flexural modulus was remarkable. After the cycled heat-freeze test, it was found that the flexural modulus and flexural strength of the WPC were lower at the high temperature ($60^{\circ}C$) and higher at the low temperature ($-20^{\circ}C$). At the low temperature ($-20^{\circ}C$) which is below glass transition temperature of polypropylene ($-10^{\circ}C$), WPC is in a glassy state which brings about the high stiffness and strength. At the high temperature ($60^{\circ}C$), the flexural modulus and flexural strength of the WPC with 50 wt.% wood flour were lower because of the increase of polymer ductility.

Postural Risk Assessment of Young Tree Tending Operations in for Managing Pinus Densiflora and Larix Kaempferi Plantations (소나무와 일본잎갈나무 조림지 관리를 위한 어린나무가꾸기의 작업 자세 위험도 분석)

  • Lee, Eun-Jai;Lee, Sang-Tae;Han, Sang-Kyun;Cho, Koo-Hyun
    • Journal of the Korean Society of Industry Convergence
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    • v.24 no.3
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    • pp.271-281
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    • 2021
  • Pinus densiflora and Larix kaempferi forests not only extended the plantation management area but also cultivated to the sustainable wood supply chain during the last 5-years. These prescriptions are primarily done by manual operation activities, particularly in young tree tending. Two types of tending activities, brashing by brush cutter(BB) and pruning by pruning shear and saw(PP), were selected for the investigate of musculoskeletal disorders' level and postural risks using Ovako Working Posture Analysis System (OWAS). The postural risk indexes (BB and PP) ranged from 115 to 125 and 102 to 105, respectively. There is no significant difference between the species. The young tree tending operations had low postural risks. The results may be used as basic data to develop technical guideline for safe young trees.

Improvement of Interfacial Adhesion for Surface treated Rice Husk Flour-Filled Polypropylene Bio-Composites (표면처리에 의한 왕겨분말-폴리프로필렌 바이오복합재의 계면 접착력 향상)

  • Lee, Byoung-Ho;Kim, Hee-Soo;Choi, Seung-Woo;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.3
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    • pp.38-45
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    • 2006
  • The main objective of this study is the improvement of the interfacial adhesion of RHF-polypropylene (PP) bio-composites through NaOH and acetic acid treated RHF. After manufacturing of untreated and NaOH and acetic acid treated RHF filled PP bio-composites, the effect on interfacial adhesion of bio-composites was investigated. Tensile strength of the bio-composites made from treated RHF with NaOH and acetic acid was higher than that of the untreated bio-composites. The RHF surface before and after NaOH and acetic acid treatment was clearly confirmed by scanning electron microscopy (SEM) micrograph. It was found that both treatments result in a removal of impurity materials of RHF surface by SEM micrographs. The chemical structures of untreated and NaOH and acetic acid treated RHF were confirmed by fourier transform infrared (FTIR). The crystallization structure and crystallinity of non-treated, NaOH and acetic acid treated RHF were investigated by wide-angle X-ray scattering (WAXS).