• 한국산학기술학회논문지
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• 제4권3호
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• pp.172-176
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• 2003

본 논문은 금형의 온도 변화가 사출성형품의 미시구조에 미치는 영향에 관해 연구했다. 웰드라인의 폭과 길이는 금형온도가 증가함에 따라 모두 감소되었다 그리고 금형의 온도에 따른 결정성수지인 PP(Polypropylene)와 비결정성수지인 PS(Polystyrene)의 치수안정성에 관해 연구했다. PS성형품은 금형온도가 높을수록 수축률이 줄어들고, 두께 편차가 적어졌고, PP성형품의 경우에는 결정의 생성으로 인해 상반된 경향이 나타났다. 캐비티의 충전성과 전사성은 금형온도가 높을수록 향상되었다.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.291-291
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• 2006

Two different sources of clay, Na-Bentonite (Thai local clay) and Na-Montmorillonite were modified with Hexadodeccyltrimethyl ammonium bromide. The nanocomposites of polypropylene were successfully prepared via melt blending in a co-rotating twin screw extruder by using PP-g-MA as a compatibilizer at various contents of organoclays. The morphology of nanocomposites was investigated by using XRD and SEM. The results showed that the intercalated and exfoliated structures were obtained. The thermal behavior was also studied by using DSC and TGA. The degradation temperature of filled PP was greater than that of unfilled PP by 20%. And, the tensile strength and modulus were improved when a small amount of organoclays were added.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 봄 학술발표회 논문집(I)
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• pp.76-79
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• 1999

The purpose of this study is to investigate the spalling properties of high-performance concrete with the kinds of aggregates and polypropylene(below PP) fiber contents. According to the experimental results, concrete contained no PP fiber take place in the form of the surface spalling and the failure of specimens after fire test regardless of the kinds of aggregates. Concrete contained more than 0.05% of PP fiber with the kinds of aggregates does not take place the spalling. Concrete using basalt has better performance in spalling resistance that concrete using granite and limestone. It is found that residual compressive strength has 50~60% of their original strength. Although specimens after exposed at high temperature are cured at water for 28days, they do not recover their original strength.

• 유변학
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• 제5권1호
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• pp.65-75
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• 1993

PP에 PE를 용융혼합하여 방사불안정성을 줄일수 있는 방사조건에 대한 연구를 수 행하였다. 연신공명에 대한 주파수 분석결과 harmonic overtone이 나타나고 연식공명의 주 기가 체류시간에 비례함을 밝혔다. PP에 PE를 혼합시킴으로써 연신공명을 줄일수 있었으나 PE가 연속상이 되는 PE함유량에서는 임계연신비보다 낮은 연신비에서 사절이 발생하였다. 또한 낮은 방사온도에서는 melt fracture 현상이 연신공명을 쉽게 일어나게 하는 용인으로 작용하여 PP/PE 혼합물의 방사 안정성을 저해하였다, 토출량이 같을 때 방사구 지름은 연 신공명의 Dmax/Dmax 값에 영향을 미치지 않았고 방사길이가 짧으면 임계연신비가 증가하였 다. 방사구 L/D가 클때에는 방사구 L/D가 연신공명에 영향을 미치지 않았으나 방사구 L/D 가 짧을 때에는 임계연신비가 크게 저하되었다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 추계학술대회논문집A
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• pp.238-243
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• 2000

The effect of the temperature, the fatigue and the test speed on DEN(double edged notch) specimen which was made by the pp-rubber composites during fracture was stuied. DEN specimen was made on PP-rubber composites through the injection molding. With increasing temperature the fracture strength is linearly decrease and the fracture energy is first increase by $0^{\circ}C$ and after that decrease. In the same temperature the fracture strength during increasing the notch radius is hardly increase. The fracture behaviour at low and high test speed is different entirely. At high test speed plastic region is small and fracture behaviour was seen to brittle fracture tendency. The deformation mechanism of polypropylene-rubber composites during fracture was studied by SEM fractography. A strong plastic deformation of the matrix material ahead of the notch/crack occured. The deformation seem to be enhanced by a thermal blunting of the notch/crack.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2009년도 춘계학술대회 논문집
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• pp.151-152
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• 2009

We coated $TiO_2$ thin films on particles by a rotating cylindrical plasma chemical vapor deposition (PCVD) process and investigated the effects of various process variables on the morphology and growth of thin films. The polypropylene (PP) particles were rotated with the cylindrical PCVD reactor and they were coated with $TiO_2$ thin films uniformly by the deposition of thin mm precursors in the gas phase. The $TiO_2$ thin films were coated on the PP particles uniformly and the thickness of thin films almost proportional to the deposition time. The $TiO_2$ thin films grew more quickly on the PP particles with increasing rotation speed of the reactor. This study shows that a rotating cylindrical PCVD reactor can be a good method to coat high-quality $TiO_2$ thin films uniformly on particles.

• 유변학
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• 제6권2호
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• pp.147-156
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• 1994

폴리프로필렌 이산화티타늄 첨가 폴리프로필렌을 심초형 복합 방사하여 첨가제를 섬유의 중심부분, 또 표면부분에 차별분포시켰다. TiO2의 함량이 증가함에 따라 점도(η)와 저장탄성계수(G＇)는 증가하였다. 전자현미경으로 파단면의 모폴로지를 관찰한 결과 TiO2와 함량이 증가함에 따라 감소하는 경향을 보였다. TiO2의 함량 증가에 따라 강력, 절단신도, 그리고 탄성계수는 감소하였다. 복합방사한 섬유의 TiO2 함량이 2% 미만일 때는 homo PP 보다 강력이 좋아졌다. 복합 섬유의 탄성계수는 중심부에 homo PP가 분포한 경우가 더 컸 고 강력과절단 신도는 중심부에 filled PP가 분포한 경우가 더 컸다.

• 폴리머
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• 제39권2호
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• pp.268-274
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• 2015

In this paper, the isothermal crystallization kinetics of a functional PP (FPP) with different grafting yields (GY)-methacryloxyethyltrimethyl ammonium chloride (DMC) grafted PP were investigated by differential scanning calorimetry (DSC). The results showed that the crystallization rate of FPP (GY=4.83%) was the highest for all of the studied samples. Furthermore, for the FPP with different GY, the value of $t_{1/2}$ became longer with increasing the grafting yield (GY). The possible explanation was that the quaternary ammonium groups introduced affected the crystallization process of the FPP in two opposite directions, i.e. promoting the nucleation and hindering the transport of the chain molecules towards the growing nuclei. Polarized optical micrographs showed that the DMC chains acted as nucleating agents, which accelerated the nucleation. In addition, the results showed the FPP had lower nucleation free energy than the PP. This study would be useful for designing the processing parameters of the grafted samples.

• Bulletin of the Korean Chemical Society
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• 제24권12호
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• pp.1809-1813
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• 2003

Monomeric antioxidant 1 was prepared by the reaction of 3,5-di-tert-butyl-4-hydroxybenzyl alcohol with N-[4-(chlorocarbonyl)phenyl]maleimide in the presence of imidazole. Monomeric antioxidant 2, bearing carbamate group, was synthesized from the reaction of 3,5-di-tert-butyl-4-hydroxybenzyl alcohol and azidomaleimide. Antioxidant 3 was prepared by the reaction of N-(4-hydroxyphenyl)maleimide and 3-(3,5-ditert-butyl-4-hydroxyphenyl) propionic chloride in the presence of triethylamine. These reactive antioxidants were grafted onto polypropylene (PP) by melt-processing with free radical initiators in a mini-max moulder. From the infrared spectra of the grafted PP, it was found that the monomeric antioxidants were grafted onto PP. IR spectroscopic methods were used for the quantitative determination of the extent of grafting of monomeric antioxidant. To optimize the reaction conditions, the influences of the concentration of DCP, monomeric antioxidant, reaction time and temperature on the extent of grafting were studied.

• Macromolecular Research
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• 제11권5호
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• pp.347-351
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• 2003

The hydrophobic ligand-containing hollow polypropylene (PP) membranes were synthesized by the mutual radiation induced graft copolymerization with glycidylmethacrylate (GMA) onto hollow PP membrane followed by the subsequent functionalization with L-phenylalanine. FT-IR, elemental analysis and UV spectroscopy were utilized to characterize copolymer composition, and degree of grafting, functionalization conversion and ${\gamma}$-globulins adsorption. The degree of grafting on the PP surface increased with the reaction time and total dose of E-beam. In the subsquent functionalization, the amount of L-phenylalanine increased with the increase in the degree of grafting and the degree of conversion was about 30%. The ${\gamma}$-globulins adsorption experiments showed that adsorption capacity had a maximum value at pH 8. The ${\gamma}$-globulins adsorption capacity in the basic pH region was higher than in the acidic pH region.